Thin Films by Atomic Layer Deposition: Properties and Applications

A special issue of Coatings (ISSN 2079-6412). This special issue belongs to the section "Surface Characterization, Deposition and Modification".

Deadline for manuscript submissions: closed (31 August 2021) | Viewed by 6720

Special Issue Editors


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Guest Editor
Department of Visual Optics, Seoul National University of Science and Technology, Seoul, Korea
Interests: semiconductor device physics; electronic/optoelectronic devices; energy harvesting devices; thin film growth mechanism

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Guest Editor
Department of Materials Science and Engineering, Seoul National University of Science and Technology, Seoul, Korea
Interests: atomic layer deposition; thin film processing; resistance-based memory devices; synaptic and neuromorphic devices

Special Issue Information

Dear Colleagues,

The strong demand for faster computing speed and lower power consumption have led to the continuous scaling down of complementary metal oxide semiconductor (CMOS) devices, including smaller transistor feature sizes and thinner gate oxides with complicated three-dimensional structure, such as Fin-FET or gate-all-around (GAA) structures. Vertically stacked devices are of great importance in Flash and new nonvolatile memory applications. Despite the progress in such devices, rapid advances in device performance has been limited by the presence of high interface density and other nonstoichiometric defects, which inevitably increase the leakage current and significantly threaten the long-term reliability of the device. As a method to improve the film quality, atomic layer deposition (ALD), favored for its low-temperature self-limiting growth mechanism, has been employed especially in nanoscale devices. It can offer high uniformity, superior conformality (step coverage), and accurate thickness control. While characterizing device performance, the parasitic resistance, leakage current, and band alignment between gate dielectric and semiconductor layers are important factors. In addition, a thorough understanding of the properties of ALD-grown thin films is fundamental to designing devices using both mature and emergent ALD-grown materials.

The topics of this Special Issue include, but are not limited to:

  • Thin films by atomic layer deposition;
  • Material characterization techniques (SEM, TEM, XPS, AFM, XRD etc.);
  • Optical/electrical characterization techniques (PL, Raman, IV, CV, Hall, DLTS, etc.);
  • Surface passivation and coatings using ALD thin films;
  • Fundamental and functional properties of surface and interfaces;
  • Device fabrication, characterization and reliability using ALD thin films.

Prof. Hogyoung Kim
Prof. Byung Joon Choi
Guest Editors

Manuscript Submission Information

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Keywords

  • Atomic layer deposition
  • High-k dielectric gate oxide
  • Surface passivation
  • Emerging electronic thin film materials
  • Device fabrication and characterization

Published Papers (2 papers)

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Research

10 pages, 2894 KiB  
Article
Effect of Oxygen Source on the Various Properties of SnO2 Thin Films Deposited by Plasma-Enhanced Atomic Layer Deposition
by Jong Hyeon Won, Seong Ho Han, Bo Keun Park, Taek-Mo Chung and Jeong Hwan Han
Coatings 2020, 10(7), 692; https://doi.org/10.3390/coatings10070692 - 18 Jul 2020
Cited by 15 | Viewed by 3528
Abstract
Herein, we performed a comparative study of plasma-enhanced atomic layer deposition (PEALD) of SnO2 films using Sn(dmamp)2 as the Sn source and either H2O plasma or O2 plasma as the oxygen source in a wide temperature range of [...] Read more.
Herein, we performed a comparative study of plasma-enhanced atomic layer deposition (PEALD) of SnO2 films using Sn(dmamp)2 as the Sn source and either H2O plasma or O2 plasma as the oxygen source in a wide temperature range of 100–300 °C. Since the type of oxygen source employed in PEALD determines the growth behavior and resultant film properties, we investigated the growth feature of both SnO2 PEALD processes and the various chemical, structural, morphological, optical, and electrical properties of SnO2 films, depending on the oxygen source. SnO2 films from Sn(dmamp)2/H2O plasma (SH-SnO2) and Sn(dmamp)2/O2 plasma (SO-SnO2) showed self-limiting atomic layer deposition (ALD) growth behavior with growth rates of ~0.21 and 0.07–0.13 nm/cycle, respectively. SO-SnO2 films showed relatively larger grain structures than SH-SnO2 films at all temperatures. Interestingly, SH-SnO2 films grown at high temperatures of 250 and 300 °C presented porous rod-shaped surface morphology. SO-SnO2 films showed good electrical properties, such as high mobility up to 27 cm2 V−1·s−1 and high carrier concentration of ~1019 cm−3, whereas SH-SnO2 films exhibited poor Hall mobility of 0.3–1.4 cm2 V−1·s−1 and moderate carrier concentration of 1 × 1017–30 × 1017 cm−3. This may be attributed to the significant grain boundary and hydrogen impurity scattering. Full article
(This article belongs to the Special Issue Thin Films by Atomic Layer Deposition: Properties and Applications)
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8 pages, 2016 KiB  
Article
Carrier Modulation in Bi2Te3-Based Alloys via Interfacial Doping with Atomic Layer Deposition
by Sang-Soon Lim, Kwang-Chon Kim, Seunghyeok Lee, Hyung-Ho Park, Seung-Hyub Baek, Jin-Sang Kim and Seong Keun Kim
Coatings 2020, 10(6), 572; https://doi.org/10.3390/coatings10060572 - 18 Jun 2020
Cited by 12 | Viewed by 2771
Abstract
The carrier concentration in Bi2Te3-based alloys is a decisive factor in determining their thermoelectric performance. Herein, we propose a novel approach to modulate the carrier concentration via the encapsulation of the alloy precursor powders. Atomic layer deposition (ALD) of [...] Read more.
The carrier concentration in Bi2Te3-based alloys is a decisive factor in determining their thermoelectric performance. Herein, we propose a novel approach to modulate the carrier concentration via the encapsulation of the alloy precursor powders. Atomic layer deposition (ALD) of ZnO and SnO2 was performed over the Bi2Te2.7Se0.3 powders. After spark plasma sintering at 500 °C for 20 min, the carrier concentration in the ZnO-coated samples decreased, while the carrier concentration in the SnO2-coated samples increased. This trend was more pronounced as the number of ALD cycles increased. This was attributed to the intermixing of the metal ions at the interface. Zn2+ substituted for Bi3+ at the interface acted as an acceptor, while Sn4+ substituted for Bi3+ acted as a donor. This indicates that the carrier concentration can be adjusted depending on the materials deposited with ALD. The use of fine powders changes the carrier concentration more strongly, because the quantity of material deposited increases with the effective surface area. Therefore, the proposed approach would provide opportunities to precisely optimize the carrier concentration for high thermoelectric performance. Full article
(This article belongs to the Special Issue Thin Films by Atomic Layer Deposition: Properties and Applications)
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