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In-Depth Investigations in Bioenergy

A special issue of Energies (ISSN 1996-1073). This special issue belongs to the section "A: Sustainable Energy".

Deadline for manuscript submissions: 31 December 2024 | Viewed by 6888

Special Issue Editors


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Guest Editor
Department of Environmental Biotechnology, Faculty of Geoengineering, University of Warmia and Mazury in Olsztyn, Sloneczna St. 45G, 10-709 Olsztyn, Poland
Interests: methane fermentation; biohydrogen production; ADM1; modeling of anaerobic digestion
Special Issues, Collections and Topics in MDPI journals

E-Mail Website
Guest Editor
Department of Environmental Biotechnology, Faculty of Geoengineering, University of Warmia and Mazury in Olsztyn, Sloneczna St. 45G, 10-709 Olsztyn, Poland
Interests: valorization of agri-food waste; wastewater treatment; membrane filtration
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

The Special Issue "In-Depth Investigations in Bioenergy" aims to provide a comprehensive exploration of various aspects related to bioenergy production, utilization and sustainability. In addition, it is dedicated to the examination of bioenergy sources, technologies, environmental impacts and policy considerations and aims to provide a thorough understanding of the current state and future opportunities in this field.

The scope of this topic includes, but is not limited to, the following:

(1) Bioenergy sources and conversion technologies:
Examination of the various bioenergy sources such as biomass, biofuels and biogas.
In-depth analysis of conversion technologies, including thermochemical, biochemical and biological processes.

(2) Sustainability and environmental impact:
Assessment of the environmental footprint of bioenergy production and use.
Exploration of sustainable practices, land use considerations and impacts on biodiversity.

(3) Technological advances and innovations:
Investigating the latest technological developments in bioenergy production.
Exploring innovative approaches to increase efficiency, reduce costs and minimize environmental impact.

(4) Economic viability and market dynamics:
Analyzing the economic feasibility and competitiveness of bioenergy projects in the energy market.
Assessment of market trends, challenges and opportunities for the introduction of bioenergy.

(5) Policy framework and regulatory landscape:
Examination of national and international policies influencing bioenergy development.
Discussing the regulatory framework in relation to sustainability, carbon emissions and incentives for bioenergy projects.

(6) Integration with renewable energy systems:
Exploring the integration of bioenergy with other renewable energy sources for a diversified and sustainable energy portfolio.
Evaluation of hybrid energy systems and their potential contribution to the overall energy matrix.

(7) Challenges and research gaps:
Identifying and analyzing the challenges facing the bioenergy sector.
Exploring research gaps and areas requiring further investigation to overcome barriers to widespread adoption.

(8) Future prospects and emerging trends:
Anticipating future developments in bioenergy technologies and their potential impact.
Investigating emerging trends that could shape the path of bioenergy research and implementation.

Dr. Katarzyna Bułkowska
Prof. Dr. Magdalena Zielińska
Guest Editors

Manuscript Submission Information

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Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Energies is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • bioenergy sustainability
  • thermochemical conversion
  • biofuel production
  • environmental impact assessment
  • renewable energy integration
  • challenges in bioenergy
  • market dynamics in bioenergy
  • bioenergy infrastructure development
  • decentralized energy systems
  • lignocellulosic biomass utilization
  • emerging trends in bioenergy
  • cellulosic ethanol pathways
  • algal biofuel production
  • microbial fuel cell applications

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Published Papers (3 papers)

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Research

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18 pages, 3447 KiB  
Article
Co-Pyrolysis of Woody Biomass and Oil Shale—A Kinetics and Modelling Study
by Alejandro Lyons Ceron, Richard Ochieng, Shiplu Sarker, Oliver Järvik and Alar Konist
Energies 2024, 17(5), 1055; https://doi.org/10.3390/en17051055 - 23 Feb 2024
Cited by 1 | Viewed by 1059
Abstract
The co-pyrolysis of biomass and fossil fuels has been the subject of studies on sustainable energy. Co-feeding oil shale with woody biomass can contribute to a transition into carbon neutrality. The present study analysed the thermal decomposition behaviour of oil shale and biomass [...] Read more.
The co-pyrolysis of biomass and fossil fuels has been the subject of studies on sustainable energy. Co-feeding oil shale with woody biomass can contribute to a transition into carbon neutrality. The present study analysed the thermal decomposition behaviour of oil shale and biomass blends (0:1, 3:7, 1:1, 7:3, 9:1, and 1:0) through thermogravimetric analysis (TGA) at 80–630 °C with a heating rate of 10 °C/min in CO2 and N2 atmospheres. A comparison of theoretical and experimental residual mass yields of oil shale–biomass mixtures indicated no significant interactions between the fuels. The blends contributed to a decrease of up to 34.4 wt% in solid residues compared to individual pyrolysis of oil shale, and the TGA curves were shifted from up to 10 °C to a lower temperature when the biomass ratio increased. The use of a CO2 atmosphere resulted in the production of solid residues, comparable to the one obtained with the N2 atmosphere. CO2 atmosphere can be used in oil shale–biomass co-pyrolysis, without affecting the decomposition process or increasing the yield of residues. A kinetic model method is proposed based on TGA data at 10, 20, and 30 °C/min. The apparent activation energies for a temperature range of 200–520 °C were in the order of 139, 155, 164, 197, 154, and 167 kJ/mol for oil shale–biomass 0:1, 3:7, 1:1, 7:3, 9:1, and 1:0 blends, respectively. From the isoconversional kinetic analysis, a two-stage pyrolysis was observed, which separated biomass and oil shale pyrolysis. A simulation of biomass and oil shale co-pyrolysis was conducted in Aspen Plus® using TGA-derived kinetic data. The model prediction resulted in a close match with the experimental thermogravimetric data with absolute errors from 1.75 to 3.78%, which highlights the relevance of TGA analysis in simulating co-pyrolysis processes. Full article
(This article belongs to the Special Issue In-Depth Investigations in Bioenergy)
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Review

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25 pages, 4914 KiB  
Review
Blockchain-Based Management of Recyclable Plastic Waste
by Katarzyna Bułkowska, Magdalena Zielińska and Maciej Bułkowski
Energies 2024, 17(12), 2937; https://doi.org/10.3390/en17122937 - 14 Jun 2024
Viewed by 1755
Abstract
Effective management of recyclable plastic waste is critical for environmental sustainability and economic viability. Blockchain technology has transformative potential in addressing the challenges of plastic waste management. Currently, the inefficiency of plastic recycling systems results in low recycling rates and significant environmental impacts [...] Read more.
Effective management of recyclable plastic waste is critical for environmental sustainability and economic viability. Blockchain technology has transformative potential in addressing the challenges of plastic waste management. Currently, the inefficiency of plastic recycling systems results in low recycling rates and significant environmental impacts due to poor sorting, contamination, and limited technology application. However, innovations such as chemical recycling, solvent-based techniques, and biotechnology offer promising advances in the management of plastic waste. Blockchain technology provides a transparent, decentralized ledger that enhances traceability and incentives through smart contracts, decentralized applications (DApps), and digital watermarks. These blockchain solutions can improve waste tracking, automate payments, and reward participants who recycle responsibly. Although significant investment in technology and education is required, integrating blockchain with the Internet of Things (IoT) and artificial intelligence (AI)-driven analytics could revolutionize plastic waste management by creating transparent, efficient, and collaborative recycling ecosystems. Blockchain technology has immense potential to redefine the management of plastic waste and promote a sustainable, circular economy. Full article
(This article belongs to the Special Issue In-Depth Investigations in Bioenergy)
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32 pages, 785 KiB  
Review
An Overview of Pyrolysis as Waste Treatment to Produce Eco-Energy
by Ana B. Cuevas, David E. Leiva-Candia and M. P. Dorado
Energies 2024, 17(12), 2852; https://doi.org/10.3390/en17122852 - 10 Jun 2024
Viewed by 3153
Abstract
The aim of this review is to understand the progress in waste material management through pyrolysis to produce eco-energy. The growing demand for energy, combined with the depletion of traditional fossil fuels and their contribution to environmental problems, has led to the search [...] Read more.
The aim of this review is to understand the progress in waste material management through pyrolysis to produce eco-energy. The growing demand for energy, combined with the depletion of traditional fossil fuels and their contribution to environmental problems, has led to the search for waste-to-energy technologies in pursuit of carbon neutrality. While municipal residues are only part of the waste management problem, the impact of discarded plastics on the environment and landfills is significant. Plastics not only take centuries to decompose, but also seriously pollute the oceans. Pyrolysis is a thermochemical process that allows for the thermal decomposition of waste in the absence of oxygen. There are several types of pyrolytic reactors, including batch and continuous ones. Batch reactors are preferred to process polymeric waste, with studies highlighting the importance of optimizing parameters, i.e., type of feedstock, heating rate, and pyrolysis temperature. Moreover, the choice of reactor type can influence the yield and structure of the final compounds. Furthermore, various studies have highlighted the gas heating value obtained through waste pyrolysis and how the composition of the liquid fraction is influenced by the type of polyethylene used. Though scientific interest in pyrolysis is remarkable, as publications have increased in recent years, kinetics studies are scarce. Overall, pyrolysis is a promising technique for managing waste materials to produce energy. Ongoing research and development in this area offer significant potential for improving the sustainability of waste management systems. Full article
(This article belongs to the Special Issue In-Depth Investigations in Bioenergy)
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Planned Papers

The below list represents only planned manuscripts. Some of these manuscripts have not been received by the Editorial Office yet. Papers submitted to MDPI journals are subject to peer-review.

Title: Blockchain-based management of recyclable plastic waste
Authors: Bułkowska Katarzyna; Zielińska Magdalena; Bułkowski Maciej
Affiliation: Department of Environmental Biotechnology, Faculty of Geoengineering, University of Warmia and Mazury in Olsztyn, Sloneczna St. 45G, 10-709 Olsztyn, Poland
Abstract: Our paper deals with the innovative field of blockchain technology applied to the management of recyclable plastic waste. The aim is to provide valuable insights into how this emerging technology can revolutionize the processes related to plastic waste by providing transparency, efficiency, and sustainability.

Title: An overview of pyrolysis as waste treatment to produce eco-energy
Authors: María del Pilar Dorado Pérez
Affiliation: Department of Physical Chemistry and Applied Thermodynamics, Universidad de Córdoba, Spain, Campus de Rabanales, Campus de Excelencia Internacional Agroalimentario ceiA3, 14071 Córdoba, Spain

Title: Techno-economic analysis of biodiesel production by simulation using Aspen Plus
Authors: Abul Kalam Azad; Pedada Sai Swaroop
Affiliation: School of Engineering and Technology, Central Queensland University, Melbourne, Australia

Title: Thermal depolymerization of waste activated sludge
Authors: Katarzyna Bułkowska; Magdalena Zielińsk
Affiliation: University of Warmia and Mazury in Olsztyn, Poland

Title: Refuse Derived Fuel and its Components Thermal Decomposition Kinetics at Low-Temperature Pyrolysis Conditions
Authors: Kacper Świechowski
Affiliation: Department of Applied Bioeconomy, Wrocław University of Environmental and Life Sciences, Chełmońskiego Str 37a, 51-630 Wrocław, Poland
Abstract: In this study, the thermal decomposition by thermogravimetric analysis (TGA) of eight types of basic refuse-derived fuel (RDF) components and two RDF blends made of those components were studied. The RDF components contained two material types organic and synthetic. The thermo-gravimetric analysis conditions were temperature up to 500 °C, heating rates of 5, 10, and 15 °C×min-1 and a nitrogen atmosphere. Based on the TGA data, the kinetic parameters of thermal decomposition according to Coats-Redfern and Kissinger methods were determined. Next, the at-tempt to determine the process kinetics of any RDF based on a weighted average of the share of individual components and their kinetic parameters was taken. The results showed that it is possible to predict the thermal decomposition (mass loss) of the RDF blend and its kinetics parameters based on the weighted average content of individual components and their thermal decomposition. Nevertheless, this approach needs to be taken with caution since some errors depending on the kinetics determination approach and method chosen are present. It was also observed that low-temperature pyrolysis of RDF can be divided into 3 specific decomposition zones related to water evaporation (25-200 °C), organic component decomposition (200-400 °C), and synthetic component decomposition (400-500 °C).

Title: Use of membrane techniques for the removal and recovery of nitrogen and phosphorus from the liquid fraction of anaerobic digestate
Authors: Zielińska M.; Bułkowska K.
Affiliation: Department of Environmental Biotechnology, University of Warmia and Mazury in Olsztyn, Słoneczna St. 45G, 10-709 Olsztyn, Poland
Abstract: Characteristics of digestate from the anaerobic digestion of organic waste; the impact of digestate separation methods on the properties of its liquid fraction. Use of membrane techniques (ultrafiltration, reverse osmosis, membrane distillation) for the treatment of the liquid fraction of digestate; methods to minimize the effects of fouling and scaling of membranes. Different scenarios of handling permeate and retentate with the aim of nitrogen removal; use of nitrification/denitrification, partial nitrification/denitrification, partial nitrification/Anammox. Different scenarios of handling permeate and retentate with the aim of i) recovery of nitrogen; ii) recovery of phosphorus; iii) combined recovery of nitrogen and phosphorus. Evaluation of the use of anaerobic membrane bioreactors to improve the performance of anaerobic digestion in terms of the composition of the liquid fraction of the digestate, the recovery possibilities and the degree of waste valorization. Future prospects for the use of membrane techniques to valorize organic waste by recovering nutrients from digestate.

Title: Combustion of pelletized coffee residues for bioenergy valorization within a circular economy vision
Authors: Antonio Scarfone; Giuseppe Toscano; Angelo Del Giudice; Andrea Acampora; Elisa Fischetti; Thomas Gasperini; Vincenzo Civitarese
Affiliation: 1 Consiglio per la Ricerca in Agricoltura e l’Analisi Dell’Economia Agraria (CREA), Rome, Italy 2 Università Politecnica delle Marche, Ancona, Italy
Abstract: Coffee is one of the most widely consumed beverages in the world; the European Union alone consumes about 2.5 million tons of coffee per year. As millions of tons of coffee are used, millions of tons of waste are generated, becoming an attractive material for circular economy flows. However, exploiting such a resource is challenging from different points of view, including real energy potential, supply chain management, and safety for humans and the environment. This study explores the potential of utilizing pelletized coffee grounds, coffee waste, and wood-coffee mixtures as sustainable bioenergy sources within the framework of a circular economy. By investigating the combustion characteristics and energy output of these materials, the research aims to demonstrate their viability as alternatives to conventional fossil fuels. The findings indicate that coffee residues exhibit favorable combustion properties with respect to heating value, but also high concentrations of elements such as nitrogen (N) and sulfur (S) compared to conventional pellets obtained from other agricultural residues. In conclusion, coffee residues present good energy potential but also some parameters to monitor during combustion due to the risk of generating greenhouse gases and acid rain. The study underscores the importance of innovative waste management strategies in achieving sustainable energy goals and highlights further research challenges in finding optimal solutions for the energetic valorization of food waste.

Title: Bio-Energy production
Authors: João Carlos Moura Bordado
Affiliation: CERENA, Instituto Superior Técnico, University of Lisbon, 1049-001 Lisbon, Portugal
Abstract: Forests have the natural and major process of CO2 capture, and therefor the wood and the forest residues are the key for the future of Bio-Energy production. Unfortunately, the gasification and pyrolysis processes to convert wood into a bio-oil have a rather low overall yield and the produced bio-oil has a doubtful quality, very often with over 20 % water content, and very unstable. The purification and subsequent stabilization by Hydrogenation have unbearable costs… This is why all the industrial units using the Fischer-Tropsch process become broke and the remaining rather small demonstration units survive on the base of subsidies. Our research team followed a different approach, and we made the option to develop a process of simultaneous catalytic depolymerization of lignin and celluloses, in liquid phase, at moderate temperatures to avoid the destruction of the sugar molecular segments. With this process that we call “Direct liquefaction” we recover more than 70 % of the sugar structures present in cellulose and hemicellulose, and with one overall yield of liquefaction of 94 % on a dry basis. ( 1 ton of dry wood converts to 940 Kg of liquid) In the first step of scale-up of the process, we constructed a Pilot Plant (full AISI 316 L) that produces continuously 3 Ton per day of liquified wood. The process is now protected by two patents, and we believe that it will become of relevance in future Bio-refineries.

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