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Advanced Thermochemical and Biochemical Processes for Biomass Transformation to Biofuels and Biochemicals

A special issue of Energies (ISSN 1996-1073). This special issue belongs to the section "A4: Bio-Energy".

Deadline for manuscript submissions: 15 October 2025 | Viewed by 413

Special Issue Editors


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Guest Editor
Faculty of Process and Environmental Engineering, Lodz University of Technology, Wolczanska 213, 90-924 Lodz, Poland
Interests: environmental biotechnology; chemical engineering; bioenergy

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Guest Editor
Faculty of Process and Environmental Engineering, Lodz University of Technology, 90-924 Lodz, Poland
Interests: distributed energy systems using upgraded (torrefied, torrefied and pelletized) biomass for cogeneration units; additives for fertilizers and active carbon production as a core technology for novel; more sustainable energy and agriculture systems
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Special Issue Information

Dear Colleagues,

Biomass was the first fuel used by humans and it dominated the world's energy supply until the 19th century (Industrial Revolution); it is still used, mainly in rural areas of developing countries for cooking and heating. Now, as a renewable resource, biomass is once again becoming a feedstock for the production of both fuels and chemicals. Biomass is the only renewable source of carbon and, in the long term, biochemicals can replace currently produced fossil-based chemicals.

To achieve this, and to meet sustainable development goals, in particular the challenges of the European Green Deal, we should intensify the research on and development of biomass conversion processes, both thermochemical and biological.

Biorefineries appear to be a promising approach for the full valorization of biomass into bioenergy and a range of bioproducts. However, product quality and bioprocessing strategy are highly dependent on the nature, composition, and quality of the biomass feedstock and the conversion methods used. The production of electricity, heat, and biofuels from biomass has received considerable attention in the current energy scenario. However, thermochemical conversion generally produces biofuels of inferior quality and is associated with significant production costs. Biochemical conversion, on the other hand, is less efficient in breaking down resistant biomass materials and has slower production rates. The integration of both processes not only promotes the development of a circular economy, but also alleviates the limitations of a single conversion pathway. In addition, conversion to value-added products is achieved through biological or thermochemical conversion processes. The integration of multiple technologies not only alleviates the difficulties associated with each technology, but also increases the profitability of the biorefinery and improves the energy sustainability of the overall process.

Current research in a number of research centers highlights the development, progress, and future potential of combining thermochemical and biochemical conversion processes to produce value-added chemicals and green fuels. This Special Issue of Energies therefore aims to meet the expectations of the circular economy and improve resource use.

This Special Issue focuses on different sources of biomass, thermochemical and biochemical processes, and their applications in low-carbon demand industries for the production of carbonized solid biofuels and value-added bio-products. We therefore invite papers on different types of biomass and thermochemical and biochemical process technologies, in particular their integration for bioproducts production for different industrial applications, industrial demonstration examples, case study scenarios, LCA analysis of biomass conversion plants. Topics of interest for publication include, but are not limited to, the following:

  • Thermochemical conversion of different biomass sources such as torrefaction, pyrolysis, gasification;
  • Hydrothermal processes such as -hydrolysis (HTH), -carbonization (HTC), -liquefaction (HTL), and -gasification (HTG);
  • Integration of thermochemical processes with biological processes such as hybrid pyrolysis-anaerobic digestion, HTC with anaerobic digestion, HTC with dark fermentation and photofermentation, HTL and HTG with bioconversion;
  • Biohydrogen production processes;
  • Decarbonization via waste valorization processes;
  • Safety aspects of biomass conversion processes on a semi- and industrial scalel;
  • Environmental assessment of biomass conversion;
  • LCA and TEA of biorefinery plants.

Prof. Dr. Stanislaw Ledakowicz
Dr. Szymon Szufa
Guest Editors

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Keywords

  • biomass conversion
  • biorefinery
  • torrefaction
  • pyrolysis
  • gasification hydrothermal processes
  • fermentation
  • hydrolysis
  • anaerobic digestion
  • dark fermentation
  • process integration
  • dry torrefaction
  • wet torrefaction
  • steam torrefaction
  • biofuels
  • biochar
  • biocarbon
  • biosorbents
  • activated carbon
  • by-products
  • carbonized fuel
  • biofertilizers
  • hydrochar

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Published Papers (1 paper)

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14 pages, 4468 KiB  
Article
Hydrothermal Liquefaction for Biofuel Synthesis: Assessment of VFA (Volatile Fatty Acid) and FAME (Fatty Acid Methyl Ester) Profiles from Spent Coffee Grounds
by Dimitrios Liakos, Georgia Altiparmaki, Simos Malamis and Stergios Vakalis
Energies 2025, 18(8), 2094; https://doi.org/10.3390/en18082094 - 18 Apr 2025
Viewed by 227
Abstract
Spent coffee grounds (SCGs) are an underutilized biomass resource with high potential for renewable energy and bioproduct synthesis. This study applies hydrothermal liquefaction to transform SCGs into high-quality biofuels and value-added biochemicals. Five experiments were conducted over a temperature range of 300 °C [...] Read more.
Spent coffee grounds (SCGs) are an underutilized biomass resource with high potential for renewable energy and bioproduct synthesis. This study applies hydrothermal liquefaction to transform SCGs into high-quality biofuels and value-added biochemicals. Five experiments were conducted over a temperature range of 300 °C to 380 °C, highlighting significant temperature-dependent shifts in product composition. Notably, phenolic compounds peaked at 1180.1 mg/L at 300 °C before declining sharply, while chemical oxygen demand (COD) dropped to a minimum of 13,949.8 mg/L at 350 °C—a temperature that also maximized hydrochar yield (26%) and achieved a high heating value of 32.9 MJ/kg. Plasma chromatographic analyses showed the dynamic behavior of volatile fatty acids (VFAs) and fatty acid methyl esters (FAMEs); maximum levels of acetic (540.7 mg/L), formic (67.8 mg/L), and propionic acids (155.6 mg/L) were recorded at 300 °C, whereas FAMEs such as methyl butyrate, methyl hexanoate, methyl undecanoate, and methyl palmitate increased markedly at higher temperatures due to intensified carboxylation reactions. These results denote the potential of hydrothermal liquefaction to valorize SCGs for the production of biomolecules, expanding the conventional sustainable biofuel production pathways. Full article
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