Metal-Organic Frameworks: The Architecture of Chemistry

A special issue of Inorganics (ISSN 2304-6740). This special issue belongs to the section "Organometallic Chemistry".

Deadline for manuscript submissions: 30 September 2025 | Viewed by 746

Special Issue Editors


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Guest Editor
Henan Academy of Sciences, Zhengzhou, China
Interests: organometallic electrochemistry; catalysts; MOF-based; defective engineering; structure-effect relationship; 3D printing
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Co-Guest Editor
Laboratory for Zero-Carbon Energy, Institute of Innovative Research, Tokyo Institute of Technology, Tokyo 152-8550, Japan
Interests: coordination chemistry; nuclear chemistry; solution chemistry; separation chemistry; coordination polymer; metal-organic framework; ionic liquid; nuclear fuel cycle; reprocessing; radioactive wastes; urban mining; actinides; f-block elements; fission products; platinum group metals; thermodynamics; kinetics; reaction mechanism
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

We are pleased to invite you to contribute to this Special Issue of Inorganics titled “Metal–Organic Frameworks: The Architecture of Chemistry”. This Special Issue focuses on metal–organic frameworks (MOFs), a rapidly advancing field of research. MOFs, characterized by their tunable structures and properties, have emerged as promising materials for diverse applications. The key contents and highlights of this Special Issue include the state-of-the-art research on MOF synthesis, properties, and applications. The prospects of MOFs in energy storage, catalysis, sensing, and drug delivery are discussed. While promising, the field faces challenges in scalability, stability, and environmental impact.

MOFs are characterized by their ultra-high surface area, tunable pore size and shape, and diverse chemical functionality. The combination of metal centers and organic linkers allows for a near-infinite variety of structures and compositions, leading to a wide range of properties and applications. While promising, the field faces challenges in scalability, stability, and environmental impact.

This Special Issue welcomes original research articles and reviews exploring the cutting-edge research on metal–organic frameworks (MOFs). Topics span from synthesis methodologies to property optimization, as well as applications in catalysis, gas separation, energy storage, and beyond. Contributions highlighting novel MOF architectures, functionalization strategies, and cross-disciplinary collaborations are especially encouraged.

Dr. Shuailong Guo
Dr. Koichiro Takao
Guest Editors

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Keywords

  • metal–organic frameworks (MOFs)
  • chemical stability
  • porosity
  • self-assembly
  • metal ions/clusters
  • catalysis
  • gas adsorption/separation
  • energy storage/conversion
  • 3D printing

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Published Papers (1 paper)

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Review

21 pages, 10371 KiB  
Review
Applications of MOFs and Their Derivatives in Lithium–Oxygen Battery Cathodes: Development and Challenges
by Haitao Ma, Shaohua Luo, Jun Cong and Shengxue Yan
Inorganics 2025, 13(2), 56; https://doi.org/10.3390/inorganics13020056 - 13 Feb 2025
Viewed by 470
Abstract
Lithium–oxygen batteries have attracted considerable attention in recent years due to their high energy density and potential applications. However, the slow kinetics of the cathode reaction and the unstable products in lithium–oxygen batteries have limited their practical applications. Metal–organic frameworks (MOFs) and their [...] Read more.
Lithium–oxygen batteries have attracted considerable attention in recent years due to their high energy density and potential applications. However, the slow kinetics of the cathode reaction and the unstable products in lithium–oxygen batteries have limited their practical applications. Metal–organic frameworks (MOFs) and their derivatives have emerged as a novel class of functional materials, thus becoming ideal candidates for the cathode of lithium–oxygen batteries. This is due to their high specific surface area, structural tunability, and abundant active sites. This paper presents a review of the research progress made in the field of MOFs and their derivatives in the cathode of lithium–oxygen batteries. It provides a summary of the design and synthesis strategies employed in the development of MOF-based catalysts, with a particular focus on the application of primary MOFs materials, MOF-derived materials and MOF composite materials in Li-O2 batteries. Additionally, it analyses the catalytic mechanism of MOFs and their derivatives in the ORR/OER. The comprehensive analysis demonstrates that MOFs and their derivatives are ideal candidates for the cathodes of lithium–oxygen batteries due to their high specific surface area, structural tunability, and abundant active sites. However, the electrical conductivity of MOFs is usually low and needs to be enhanced by composites or derivative materials. This paper reviews the research progress on MOFs and their derivatives in lithium–oxygen battery cathodes, focuses on the design and synthesis strategies of MOF-based catalysts, and discusses their catalytic mechanisms in the ORR/OER. Full article
(This article belongs to the Special Issue Metal-Organic Frameworks: The Architecture of Chemistry)
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