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Liquid Crystals and Other Partially Disordered Molecular Systems

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Optical and Photonic Materials".

Deadline for manuscript submissions: 10 September 2024 | Viewed by 1269

Special Issue Editor


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Guest Editor
Institute of Molecular Physics, Polish Academy of Sciences, 60-179 Poznań, Poland
Interests: liquid crystals; ferroelectricity; electro-optic; elasticity; viscosity; composites; nanomaterials; soft matter

Special Issue Information

Dear Colleagues,

Liquid crystals are materials that possess both the characteristics of liquids and solids due to their partially ordered molecular structure. The molecules in liquid crystals exhibit some degree of alignment while maintaining a certain level of disorder. This unique arrangement gives rise to intriguing physical properties that differ from ordinary liquids or solids.

Liquid crystals have diverse physical properties that make them suitable for various applications. One of their most well-known applications is liquid crystal displays (LCDs), which utilize the optical properties of liquid crystals to produce visual representations. The alignment of liquid crystal molecules can be controlled by applying electric fields, allowing for the manipulation of light transmission through the display.

Apart from LCDs, liquid crystals also find applications in other fields, such as electro-optical devices, photonics, and sensors. Liquid crystals can self-assemble into organized structures, and their properties can be modified by adding different compounds or varying the temperature. By incorporating liquid crystals into polymer matrices, interesting hybrid materials called polymer-dispersed liquid crystals can be obtained, which have unique optical and mechanical properties.

Non-trivial properties are exhibited by liquid crystals doped with micro- and nanoparticles, composite materials, hybrid materials, and complex molecular systems.

In addition to liquid crystals, there are other molecular systems that exhibit partial disorder, such as liquid crystal polymers, block copolymers, and colloidal suspensions. These partially disordered materials have attracted attention due to their potential for achieving desired properties through manipulation of molecular arrangement.

In conclusion, liquid crystals and other partially disordered molecular systems possess intriguing properties that make them valuable in various applications. Understanding the nature and behavior of these materials is essential for their further development and utilization in fields ranging from electronics to materials science.

Dr. Dorota Dardas
Guest Editor

Manuscript Submission Information

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Keywords

  • liquid crystals
  • LCDs
  • electro-optical devices
  • photonics
  • molecular systems
  • block copolymers

Published Papers (2 papers)

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Research

13 pages, 1980 KiB  
Article
Plasmid DNA Complexes in Powder Form Studied by Spectroscopic and Diffraction Methods
by Aleksandra Radko, Sebastian Lalik, Natalia Górska, Aleksandra Deptuch, Jolanta Świergiel and Monika Marzec
Materials 2024, 17(14), 3530; https://doi.org/10.3390/ma17143530 - 17 Jul 2024
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Abstract
Currently, new functional materials are being created with a strong emphasis on their ecological aspect. Materials and devices based on DNA biopolymers, being environmentally friendly, are therefore very interesting from the point of view of applications. In this paper, we present the results [...] Read more.
Currently, new functional materials are being created with a strong emphasis on their ecological aspect. Materials and devices based on DNA biopolymers, being environmentally friendly, are therefore very interesting from the point of view of applications. In this paper, we present the results of research on complexes in the powder form based on plasmid DNA (pDNA) and three surfactants with aliphatic chains containing 16 carbon atoms (cetyltrimethylammonium chloride, benzyldimethylhexadecylammonium chloride and hexadecylpyridinium chloride). The X-ray diffraction results indicate a local hexagonal packing of DNA helices in plasmid DNA complexes, resembling the packing for corresponding complexes based on linear DNA. Based on the Fourier-transform infrared spectroscopy results, the DNA conformation in all three complexes was determined as predominantly of A-type. The two relaxation processes revealed by dielectric spectroscopy for all the studied complexes are connected with two different contributions to total conductivity (crystallite part and grain boundaries). The crystallite part (grain interior) was interpreted as an oscillation of the polar surfactant head groups and is dependent on the conformation of the surfactant chain. The influence of the DNA type on the properties of the complexes is discussed, taking into account our previous results for complexes based on linear DNA. We showed that the type of DNA has an impact on the properties of the complexes, which has not been demonstrated so far. It was also found that the layer of pDNA–surfactant complexes can be used as a layer with variable specific electric conductivity by selecting the frequency, which is interesting from an application point of view. Full article
(This article belongs to the Special Issue Liquid Crystals and Other Partially Disordered Molecular Systems)
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21 pages, 12831 KiB  
Article
Dielectric Modes in Antiferroelectric and Ferroelectric Liquid Crystals in a Pure Enantiomeric Version and a Racemic Mixture
by Paweł Perkowski and Magdalena Urbańska
Materials 2024, 17(13), 3335; https://doi.org/10.3390/ma17133335 - 5 Jul 2024
Viewed by 533
Abstract
The dielectric properties of synclinic (ferroelectric SmC*) and anticlinic (antiferroelectric SmCA*) smectic liquid crystals composed of molecules of one chiral version (S) are presented and compared with properties of racemic mixture (R, S), showing SmC and SmCA phases. The racemic [...] Read more.
The dielectric properties of synclinic (ferroelectric SmC*) and anticlinic (antiferroelectric SmCA*) smectic liquid crystals composed of molecules of one chiral version (S) are presented and compared with properties of racemic mixture (R, S), showing SmC and SmCA phases. The racemic mixture completely loses its ferroelectric and antiferroelectric properties. Surprisingly, only one dielectric mode observed in the antiferroelectric SmCA* phase disappeared in the dielectric response of the racemic SmCA phase. Additionally, we observed that in the SmC phase, seen in the racemic mixture, the weak dielectric mode (named the X mode) is detected, which seems to be the continuation of the PL mode existing in the racemic SmCA. Moreover, this mode in the racemic SmC has nothing to do with the Goldstone mode, typical for the SmC* phase. This paper describes in detail the real and imaginary parts of dielectric permittivity in smectic phases for the enantiomer and racemate with and without a DC field, compares the properties of the X and PL modes, and discusses the full scheme of dielectric modes in enantiomer and racemate. Full article
(This article belongs to the Special Issue Liquid Crystals and Other Partially Disordered Molecular Systems)
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