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Crystal Chemical Design of Inorganic Materials: From Structural Features to Advanced Physical Properties

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Materials Chemistry".

Deadline for manuscript submissions: closed (30 September 2021) | Viewed by 2813

Special Issue Editors


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Guest Editor
Kola Science Centre, Russian Academy of Sciences, 184209 Apatity, Russia
Interests: crystal chemistry of inorganic compounds; X-ray crystallography; modular and topological analysis of crystal structures; structure–properties relationship
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Guest Editor
Faculty of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia
Interests: inorganic materials; LED; tricalcium phosphate; luminescence; vanadates
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

It is our pleasure to announce a Special Issue on “Crystal Chemical Design of Inorganic Materials: From Structural Features to Advanced Physical Properties” of the Materials Journal.

Modern chemistry of inorganic materials is based on a detailed analysis of the features of crystal structures of compounds, since even the slightest changes in chemical composition or atomic coordinational environment can lead to a significant change in the quality of observed physical properties. This basic principle is realized in a wide range of types of inorganic materials used in modern technologies.

The crystal chemical design of new compounds involves a direct synthesis of compounds with optimal compositions taking into account structural data, which makes it possible to use one type of inorganic matrix for different technological applications. Thus, the basic principle of solid state chemistry is realized: from chemical composition and crystal structure features to advanced physical properties.

The purpose of this Special Issue is to summarize the data on different types of inorganic matrices exhibiting crystal chemical variability and isomorphic capacity, which is expressed in different types of physical properties.

Dr. Sergey M. Aksenov
Dr. Dina V. Deyneko
Guest Editors

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Keywords

  • solid state chemistry
  • inorganic crystal chemistry
  • advanced materials
  • crystal engineering and design
  • physical properties
  • structure–properties relationship

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Published Papers (1 paper)

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Research

19 pages, 6059 KiB  
Article
Upper Critical Solution Temperature Polymer Phase Transition as a Tool for the Control of Inorganic Salt Crystallization Process
by Marcin Lemanowicz, Esteban Wong Munoz, Anna Mielańczyk, Krzysztof Kiraga and Andrzej Gierczycki
Materials 2021, 14(18), 5373; https://doi.org/10.3390/ma14185373 - 17 Sep 2021
Cited by 1 | Viewed by 1935
Abstract
In this paper, the experimental research concerning the impact of the hydrophilic-hydrophobic transition of a polymer exhibiting the Upper Critical Solution Temperature (UCST) onto the crystallization process of inorganic salt is presented. A hypothesis was postulated that under favorable process conditions the sudden [...] Read more.
In this paper, the experimental research concerning the impact of the hydrophilic-hydrophobic transition of a polymer exhibiting the Upper Critical Solution Temperature (UCST) onto the crystallization process of inorganic salt is presented. A hypothesis was postulated that under favorable process conditions the sudden change of macromolecules properties and the resulting appearance of insoluble particles will induce the nucleation process of the salt. Since the transition point parameters may be precisely designed, the described mechanism would eliminate the stochastic nature of the crystallization process. Although performed experiments proved that the postulated process mechanism was incorrect, the presence of macromolecules had a significant impact on the crystallization course. The stochastic nature of the process was not eliminated; nevertheless, it seems that a specific point of nucleation was created which was independent of the cloud point temperature (TCP) of the polymer. Moreover, the surface morphology of crystals was changed. Full article
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