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High-Entropy Alloys in New Technological Applications

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Manufacturing Processes and Systems".

Deadline for manuscript submissions: closed (10 July 2022) | Viewed by 7592

Special Issue Editor


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Guest Editor
Applied Materials Physics, Department of Materials Science and Engineering, Royal Institute of Technology (KTH), SE-10044 Stockholm, Sweden
Interests: high-entropy alloys; amorphous materials; non-collinear magnetism; plasticity

Special Issue Information

Dear Colleagues,

Over the past decade, a radically new alloying strategy has emerged with the enormous potential to make a great impact on the way materials are developed today. Traditionally, metallurgists have added small amounts of certain elements to tailor the properties of an alloy with one principal element. Even though properties can effectively be modified this way, the approach in itself is very limiting. The new alloying strategy involves the combination of multiple principal components in relatively high concentrations, which gives rise to the so-called high-entropy alloys. Because, in recent years, the progress with traditional materials has slowed down, researchers are now looking for alternative solutions. High-entropy alloys can potentially provide unique tailored solutions due to the large number of possible combinations of elements to create new materials with improved properties. Particularly, the possibility of overcoming dilemmas and barriers associated with traditional alloys, such as strength ductility trade-offs, makes high-entropy alloys a very exciting type of materials. The challenges to overcome come from the great number of possible element combinations to form high-entropy alloys. Hence, the combined efforts of experimental work and computational modeling is needed for these materials to reach their full potential. The growing relevance of these materials has been broadly recognized, and recently, they have been identified as the number one topic of the upcoming decades. This Special Issue reviews the latest technological applications and advances of high-entropy alloys.

Dr. Raquel Lizárraga
Guest Editor

Manuscript Submission Information

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Keywords

  • high-entropy alloys
  • first principles theory
  • mechanical properties
  • thermodynamical properties

Published Papers (2 papers)

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Research

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18 pages, 2572 KiB  
Article
Microstructure, Phase Formation and Heat-Treating of Novel Cast Al-Mg-Zn-Cu-Si Lightweight Complex Concentrated Aluminum Based Alloy
by Spyridon Chaskis, Eva Stachouli, Evangelos Gavalas, Marianthi Bouzouni and Spyros Papaefthymiou
Materials 2022, 15(9), 3169; https://doi.org/10.3390/ma15093169 - 27 Apr 2022
Cited by 9 | Viewed by 2756
Abstract
In the current work, a novel complex concentrated aluminum alloy is designed and studied. In order to investigate the unknown region of the multicomponent phase diagrams, thermo-physical parameters and the CALPHAD method were used to understand the phase formation of the Al58 [...] Read more.
In the current work, a novel complex concentrated aluminum alloy is designed and studied. In order to investigate the unknown region of the multicomponent phase diagrams, thermo-physical parameters and the CALPHAD method were used to understand the phase formation of the Al58Mg18Zn12Cu5Si7 at.% (Al47.4Mg13.3Zn23.8Cu9.6Si6wt.%) alloy with a low-density of 2.63 g/cm3. The CALPHAD methodology showed good agreement with both the investigated microstructure and the thermodynamic parameters. The designed alloy was manufactured using an induction furnace and pour mold casting process. This study avoids the use of expensive, dangerous or scarce alloying elements and focuses instead on the utilization of widely available relatively cheaper elements. The microstructural evolution as a function of the heat-treatment was studied by means of different microstructural characterization techniques. The hardness, compressive strength and electrical conductivity of the as-cast and heat-treated alloy at room temperature were studied and correlated with the previously characterized microstructure. The alloy is characterized by a multiphase microstructure with major α-Al matrix reinforced with various secondary phases. In terms of mechanical properties, the developed alloy exhibited a high hardness value of 249 Vickers and compressive strength of 588 MPa. The present work provides a valuable insight for researchers, who aim to design and produce industry-like Aluminum based complex concentrated alloys (CCAs). Full article
(This article belongs to the Special Issue High-Entropy Alloys in New Technological Applications)
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Review

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46 pages, 12986 KiB  
Review
Tribological Performance of High-Entropy Coatings (HECs): A Review
by Payank Patel, Amit Roy, Navid Sharifi, Pantcho Stoyanov, Richard R. Chromik and Christian Moreau
Materials 2022, 15(10), 3699; https://doi.org/10.3390/ma15103699 - 21 May 2022
Cited by 19 | Viewed by 3928
Abstract
Surface coatings that operate effectively at elevated temperatures provide compatibility with critical service conditions as well as improved tribological performance of the components. High-entropy coatings (HECs), including metallic, ceramics, and composites, have gained attention all over the world and developed rapidly over the [...] Read more.
Surface coatings that operate effectively at elevated temperatures provide compatibility with critical service conditions as well as improved tribological performance of the components. High-entropy coatings (HECs), including metallic, ceramics, and composites, have gained attention all over the world and developed rapidly over the past 18 years, due to their excellent mechanical and tribological properties. High-entropy alloys (HEAs) are defined as alloys containing five or more principal elements in equal or close to equal atomic percentage. Owing to the high configurational entropy compared to conventional alloys, HEAs are usually composed of a simple solid solution phase, such as the BCC and FCC phases, instead of complex, brittle intermetallic phases. Several researchers have investigated the mechanical, oxidation, corrosion and wear properties of high-entropy oxides, carbides, borides, and silicates using various coating and testing techniques. More recently, the friction and wear characteristics of high-entropy coatings (HECs) have gained interest within various industrial sectors, mainly due to their favourable mechanical and tribological properties at high temperatures. In this review article, the authors identified the research studies and developments in high-entropy coatings (HECs) fabricated on various substrate materials using different synthesis methods. In addition, the current understanding of the HECs characteristics is critically reviewed, including the fabrication routes of targets/feedstock, synthesis methods utilized in various research studies, microstructural and tribological behaviour from room temperature to high temperatures. Full article
(This article belongs to the Special Issue High-Entropy Alloys in New Technological Applications)
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