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Photocatalysis: Recent Developments and Technological Advancements

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Catalytic Materials".

Deadline for manuscript submissions: closed (30 November 2021) | Viewed by 5194

Special Issue Editor


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Guest Editor
Material Science Department, Faculty of Engineering, Tokai University, 259-1292 Hiratsuka, Japan
Interests: photocatalytic materials

Special Issue Information

Dear Colleagues,

Water purification is one of the main issues for sustainable development for the future. After the discovery of the photocatalytic behavior of graphitic carbon nitride g-C₃N₄, research on catalysts has increased in order to improve their performance by combining with other composites such as nanometer-sized TiO₂, semiconductors like ZnO, ZnS, and CdS and noble metal nanoparticles. The fascinating properties of g-C₃N₄ include visible light response, good oxidation power, environmental friendliness, good chemical and thermal stability, metal-free nature, easy fabrication from precursors, and easy modifications of its polymer structure. The processing of inorganic nanoparticles has been improved by sol-gel techniques, deposition, like lase ablation, and hydrothermal methods. Typically, the active catalyst is deposited on a skeleton with high porosity consisting of stable oxides or carbonaceous materials. The photocatalytic performance strongly depends on the bandgap, but also other parameters, such as the recombination rate, carrier concentration, electron mobility, and modification of orbitals of attached particles such as dyes or nanosized noble metal particles. The photocatalytic performance increases, when the surface area becomes large, and the amount of absorbed solution and diffusion to the active surface is enhanced. Photocatalysts can not only improve the efficiency of various chemical reactions, but have also successfully demonstrated water purification through the degradation of organic pollutants, even including bacteria or viruses. This emerging interdisciplinary research is expected to increase its importance in the near future.

Prof. Dr. Wilfried Wunderlich
Guest Editor

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Keywords

  • Photocatalysts
  • Nanomaterials
  • Water purification
  • Oxidation behavior
  • Bandgap

Published Papers (2 papers)

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Research

18 pages, 6039 KiB  
Article
Photocatalytic Degradation of Cefixime Trihydrate by Bismuth Ferrite Nanoparticles
by Ammara Nazir, Shoomaila Latif, Syed Farooq Adil, Mufsir Kuniyil, Muhammad Imran, Mohammad Rafe Hatshan, Farah Kanwal and Baji Shaik
Materials 2022, 15(1), 213; https://doi.org/10.3390/ma15010213 - 28 Dec 2021
Cited by 23 | Viewed by 2560
Abstract
The present work was carried out to synthesize bismuth ferrite (BFO) nanoparticles by combustion synthesis, and to evaluate the photocatalytic activity of synthesized bismuth ferrite nanoparticles against cefixime trihydrate. BFO nanoparticles were successfully synthesized using bismuth (III) nitrate and iron (III) nitrate by [...] Read more.
The present work was carried out to synthesize bismuth ferrite (BFO) nanoparticles by combustion synthesis, and to evaluate the photocatalytic activity of synthesized bismuth ferrite nanoparticles against cefixime trihydrate. BFO nanoparticles were successfully synthesized using bismuth (III) nitrate and iron (III) nitrate by a combustion synthesis method employing different types of fuels such as maltose, succinic acid, cinnamic acid, and lactose. The effects of the different types of fuels on the morphology and size of the bismuth ferrite nanoparticles were investigated. Characterization of the as-obtained bismuth ferrite nanoparticles was carried out by different techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM), Energy-Dispersive Spectroscopy (EDS), N2-sorption analysis, Fourier-transform infrared spectroscopy (FT-IR), and ultraviolet-visible (UV–vis) spectroscopy. Photoluminescence studies were also carried out for the various bismuth ferrite nanoparticles obtained. Degradation of cefixime trihydrate was investigated under sunlight to evaluate the photocatalytic properties of the bismuth ferrite nanoparticles, and it was found that the bismuth ferrite nanoparticles followed first-order degradation kinetics in solar irradiation in the degradation of antibiotic, cefixime trihydrate. Full article
(This article belongs to the Special Issue Photocatalysis: Recent Developments and Technological Advancements)
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13 pages, 5776 KiB  
Article
Application of Photocatalytic Concrete Paving Blocks in Poland—Verification of Effectiveness of Nitric Oxides Reduction and Novel Test Method
by Hubert Witkowski, Janusz Jarosławski and Anna Tryfon-Bojarska
Materials 2020, 13(22), 5183; https://doi.org/10.3390/ma13225183 - 17 Nov 2020
Cited by 6 | Viewed by 2147
Abstract
Photocatalytic concrete is one of the most promising concrete technologies of the past decades. Application of nanometric TiO2 to cement matrices enables the reduction of harmful airborne pollutants. Although a number of implementations of this technology are described in this paper, problems [...] Read more.
Photocatalytic concrete is one of the most promising concrete technologies of the past decades. Application of nanometric TiO2 to cement matrices enables the reduction of harmful airborne pollutants. Although a number of implementations of this technology are described in this paper, problems related to test conditions are also reported. One major issue is the sufficient light irradiation that for higher latitudes can be significantly reduced. In this paper, a field campaign on the implementation of photocatalytic concrete pavement in Warsaw (52.23° N) is briefly described. Based on experience from the field campaign, a novel test method is developed. In the research, the effectiveness of nitric oxide reduction is verified at natural light irradiation for various dates of solar position at noon in central Poland (51.83° N). The results confirm the benefits of using photocatalytic materials at higher latitudinal locations. The experimental setup presented in the study combines the advantages of controlled measurement conditions typical in laboratory tests with the possibility of including natural sunlight conditions in the investigation process. Full article
(This article belongs to the Special Issue Photocatalysis: Recent Developments and Technological Advancements)
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