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Application of Rapid Design and Preparation Methods for Advanced Structural and Functional Inorganic Materials

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Advanced Composites".

Deadline for manuscript submissions: closed (20 August 2022) | Viewed by 11285

Special Issue Editors

Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
Interests: scintillators; LED/LD phosphors; crystal; transparent ceramics; containerless technology

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Guest Editor
Institute of High Technologies and Advanced Materials, Far Eastern Federal University, 8, Sukhanova St., 690091 Vladivostok, Russia
Interests: SPS technology; ceramic welding; ultra high temperature ceramics; biological porous materials; nuclear waste storage ceramics
Special Issues, Collections and Topics in MDPI journals

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Guest Editor
Institute of Science-Intensive Technologies and Advanced Material, Far Eastern Federal University, 690091 Vladivostok, Russia
Interests: SPS technology; ceramic welding; ultra high temperature ceramics; biological porous materials; nuclear waste storage ceramics
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

With the development of new devices, apparatuses and application fields, the demand for the R&D of advanced structural and functional materials is increasing. Rapid material design and preparation methods have recently gained much research interest in both the research and application communities due to the time-saving and high-efficiency advantages they offer as compared to conventional techniques. These include the theoretical calculation, high-throughput component screening technology using powders or films. The application of Spark Plasma Sintering (SPS), Selective Laser Sintering (SLS), flash sintering in ceramics preparation, rapid growth of high quality crystals by Optical Floating Zone method or micro-pulling down method (μ-PD), functional glass preparation by containerless aerodynamic levitation method, etc. Therefore, a series of new materials have been developed, and consequently, novel structures and/or high performances have been presented. This Special Issue covers these topics and focuses on the recent progress of rapid design and preparation methods for advanced structural and functional inorganic materials.

Dr. Yun Shi
Dr. Oleg Shichalin
Prof. Dr. Evgeniy Papynov
Guest Editors

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Keywords

  • high throughput technology
  • Optical Floating Zone (OFZ) method 
  • micro Pulling Down (μ-PD) method 
  • Spark Plasma Sintering (SPS) technology
  • aerodynamic levitation technology
  • Selective Laser Sintering (SLS) technology 
  • Liquid Phase Epitaxy (LPE) method

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Published Papers (5 papers)

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Research

11 pages, 3078 KiB  
Article
Ce3+, Pr3+ Co-Doped Lu3Al5O12 Single Crystals and Ceramics: A Comparative Study
by Yifei Xiong, Yun Shi, Haibo Wang, Qian Zhang, Tong Wu, Qiang Yuan, Kaicheng Ma, Tongtong Li, Zhenzhen Zhou, Jinghong Fang, Huan He, Jinqi Ni, Qian Liu, Jiangding Yu, Sheng Cui, Oleg Shichalin and Eugeniy Papynov
Materials 2022, 15(24), 9025; https://doi.org/10.3390/ma15249025 - 17 Dec 2022
Cited by 2 | Viewed by 1492
Abstract
Ce3+, Pr3+ co-doped Lu3Al5O12 (Ce, Pr:LuAG) single crystals and ceramics were prepared using the optical floating zone (OFZ) and reactive vacuum sintering methods, respectively. The microstructure, photo- (λex = 450 nm), and radio-luminescence (under [...] Read more.
Ce3+, Pr3+ co-doped Lu3Al5O12 (Ce, Pr:LuAG) single crystals and ceramics were prepared using the optical floating zone (OFZ) and reactive vacuum sintering methods, respectively. The microstructure, photo- (λex = 450 nm), and radio-luminescence (under X-ray excitation) performance, as well as scintillation light yield (LY, under γ-ray, 137Cs source) of both materials, were investigated and compared. Ce, Pr:LuAG ceramics had an in-line transmittance of approximately 20% in the visible light range, while the analogous crystals were more transparent (~65%). The X-ray excited luminescent (XEL) spectra showed the characteristic Ce 3+ and Pr3+ emissions located at 310 nm, 380 nm, and 510 nm. The highest LY of the Ce, Pr:LuAG ceramics reached 34,112 pho/MeV at 2 μs time gate, which is higher than that of a single crystal. The ratio of LY values (LY2/LY0.75) between shaping times of 0.75 μs and 2 μs indicated a faster scintillation decay of ceramics regarding single crystals. It was ascribed to the lower effective concentration of luminescent activators in single crystals because of the coefficient segregation effect. Full article
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8 pages, 5098 KiB  
Article
Fabrication of Ni–Cu–W Graded Coatings by Plasma Spray Deposition and Laser Remelting
by Jie Liao, Liangbo Zhang, Cong Peng, Yandong Jia, Gang Wang, Hui Wang and Xuguang An
Materials 2022, 15(8), 2911; https://doi.org/10.3390/ma15082911 - 15 Apr 2022
Cited by 2 | Viewed by 1522
Abstract
In this study, Ni–Cu–W graded coatings are produced by atmospheric plasma spraying and subsequently remelted by laser. The surface morphology, hardness, compositional fluctuations and corrosion resistance of the Ni–Cu–W coating are investigated. The coatings after laser remelting are densified and become more homogenous [...] Read more.
In this study, Ni–Cu–W graded coatings are produced by atmospheric plasma spraying and subsequently remelted by laser. The surface morphology, hardness, compositional fluctuations and corrosion resistance of the Ni–Cu–W coating are investigated. The coatings after laser remelting are densified and become more homogenous with an excellent corrosion resistance and high hardness, which can be used to explore the new materials. Full article
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19 pages, 10946 KiB  
Article
Investigation of the Densification Behavior of Alumina during Spark Plasma Sintering
by Maksim S. Boldin, Alexander A. Popov, Evgeni A. Lantsev, Aleksey V. Nokhrin and Vladimir N. Chuvil’deev
Materials 2022, 15(6), 2167; https://doi.org/10.3390/ma15062167 - 15 Mar 2022
Cited by 15 | Viewed by 2158
Abstract
The article presents the results of the investigation of the mechanism of the densification behavior of alumina-based ceramics during spark plasma sintering. The role of the heating rates and additives were investigated. The first (initial) stage of sintering was investigated by the Young–Cutler [...] Read more.
The article presents the results of the investigation of the mechanism of the densification behavior of alumina-based ceramics during spark plasma sintering. The role of the heating rates and additives were investigated. The first (initial) stage of sintering was investigated by the Young–Cutler model. The second (intermediate) stage of sintering was investigated as a process of plastic deformation of a porous body under external pressure. It was shown that, at the initial stage, the formation of necks between the particles is controlled by grain boundary diffusion (the activation energy is Qb ≈ 20 kTm). At this stage, accommodation of the shape of the alumina particles is also occurring (an increase in the packing density). The accommodation process facilitates the shrinkage of the powder, which is reflected in a decrease in the effective activation energy of shrinkage at low heating rates (10 °C/min) to Qb ≈ 17 kTm. At heating rates exceeding 10 °C/min, the intensity of the processes of accommodation of alumina particles turns out to be much slower than the existing diffusion processes of growth of necks between the alumina particles. It was shown that the grain boundary sliding mechanism that occurs in the second stage of sintering can play a decisive role under conditions of spark plasma sintering with a high heating rate. The found value of the activation energy at the second stage of sintering is also close to the activation energy of grain–boundary diffusion of alumina (Qb ≈ 20 kTm). The influences of the second phase particles of MgO, TiO2, and ZrO2 on densification behavior of alumina-based ceramics were investigated. Since at the first stage of sintering the densification relates with the formation of necks between the particles of alumina, the additives (0.5% vol) have no noticeable effect on this process. It was also shown that the second phase particles which are located at the grain boundaries of alumina are not involved in the slip process during the second sintering stage. Analysis shows that additives act only in the final (third) stage of spark plasma sintering of alumina. Full article
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17 pages, 7965 KiB  
Article
Wide Concentration Range of Tb3+ Doping Influence on Scintillation Properties of (Ce, Tb, Gd)3Ga2Al3O12 Crystals Grown by the Optical Floating Zone Method
by Tong Wu, Ling Wang, Yun Shi, Xintang Huang, Qian Zhang, Yifei Xiong, Hui Wang, Jinghong Fang, Jinqi Ni, Huan He, Chaoyue Wang, Zhenzhen Zhou, Qian Liu, Qin Li, Jianding Yu, Oleg Shichalin and Evgeniy Papynov
Materials 2022, 15(6), 2044; https://doi.org/10.3390/ma15062044 - 10 Mar 2022
Cited by 4 | Viewed by 2206
Abstract
To obtain a deeper understand of the energy transfer mechanism between Ce3+ and Tb3+ ions in the aluminum garnet hosts, (Ce, Tb, Gd)3Ga2Al3O12 (GGAG:Ce, Tb) single crystals grown by the optical floating zone (OFZ) [...] Read more.
To obtain a deeper understand of the energy transfer mechanism between Ce3+ and Tb3+ ions in the aluminum garnet hosts, (Ce, Tb, Gd)3Ga2Al3O12 (GGAG:Ce, Tb) single crystals grown by the optical floating zone (OFZ) method were investigated systematically in a wide range of Tb3+ doping concentration (1–66 at.%). Among those, crystal with 7 at.% Tb reached a single garnet phase while the crystals with other Tb3+ concentrations are mixed phases of garnet and perovskite. Obvious Ce and Ga loss can be observed by an energy dispersive X-ray spectroscope (EDS) technology. The absorption bands belonging to both Ce3+ and Tb3+ ions can be observed in all crystals. Photoluminescence (PL) spectra show the presence of an efficient energy transfer from the Tb3+ to Ce3+ and the gradually quenching effect with increasing of Tb3+ concentration. GGAG: 1% Ce3+, 7% Tb3+ crystal was found to possess the highest PL intensity under excitation of 450 nm. The maximum light yield (LY) reaches 18,941 pho/MeV. The improved luminescent and scintillation characteristics indicate that the cation engineering of Tb3+ can optimize the photoconversion performance of GGAG:Ce. Full article
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13 pages, 4634 KiB  
Article
Spark Plasma Sintering of WC-Based 10wt%Co Hard Alloy: A Study of Sintering Kinetics and Solid-Phase Processes
by Anastasia A. Buravleva, Alexander N. Fedorets, Anastasia A. Vornovskikh, Alexey V. Ognev, Valeria A. Nepomnyushchaya, Vladimir N. Sakhnevich, Aleksey O. Lembikov, Zlata E. Kornakova, Olesya V. Kapustina, Anna E. Tarabanova, Victor P. Reva and Igor Yu. Buravlev
Materials 2022, 15(3), 1091; https://doi.org/10.3390/ma15031091 - 30 Jan 2022
Cited by 20 | Viewed by 3038
Abstract
The paper describes the method for producing WC-10wt%Co hard alloy with 99.6% of the theoretical density and a Vickers hardness of ~1400 HV 0.5. Experimental data on densification dynamics, phase composition, morphology, mechanical properties, and grain size distribution of WC-10%wtCo using spark plasma [...] Read more.
The paper describes the method for producing WC-10wt%Co hard alloy with 99.6% of the theoretical density and a Vickers hardness of ~1400 HV 0.5. Experimental data on densification dynamics, phase composition, morphology, mechanical properties, and grain size distribution of WC-10%wtCo using spark plasma sintering (SPS) within the range of 1000–1200 °C are presented. The high quality of the product is provided by the advanced method of high-speed powder mixture SPS-consolidation at achieving a high degree of densification with minimal calculated grain growth at 1200 °C. Full article
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