Heterogeneous Materials Based on Polymers
A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Polymeric Materials".
Deadline for manuscript submissions: closed (20 December 2024) | Viewed by 3014
Special Issue Editors
Interests: polymers and environment; heterogeneous materials based on polymers; polyolefins; interfacial agents; interphase; interface; functionalization; plastic wastes; blends; composites
Special Issues, Collections and Topics in MDPI journals
Interests: polymers and environment; heterogeneous materials based on polymers; polyolefins; interfacial agents; interphase; interface; functionalization; plastic wastes; blends; composites
Special Issues, Collections and Topics in MDPI journals
Special Issue Information
Dear Colleagues,
This Special Issue is dedicated to Heterogeneous Materials Based on Polymers. At this point, it is important to remark that it is the long-range elasticity, high strength, and high viscosity which define the macromolecular nature of organic polymers, depending on the inter-molecular forces’ intensity. These properties emerge as a direct consequence of the size and constitution of the covalent structures of the macromolecules, determined by the interchain interactions at the distance of a primary bond (thermosetting polymers), or by secondary interactions between sufficiently large polymer chains able to induce strong interchain forces that endow the matter with enough structural integrity to be useful and handled (thermoplastic polymers), which—conversely to thermosetting polymers—can soften and flow under temperature and shear fields. The combination of these polymers with other substances (fillers, reinforcements, fibers, other polymers, et cetera) with the aim of obtaining lower costs in a shorter time frame, rather than simply correcting an undesired property is still a growing and promising research direction, and is being applied to obtain novel outstanding materials. In any case, it is the role played by the contact regions between the components (the interphase) which governs and defines the ultimate properties of the material. The inter-phase is defined as that dynamic and finite spatial region between the borders of each couple of different phases which are microscopically in contact. Transport phenomena occur at the nanoscale level through the atoms (or small groups of atoms) placed there, and are responsible for the momentum, mass, and energy balances between both phases. On this basis, the study of the interphases with the aim of controlling the properties of any given multi-component system has been established, giving rise to the concept of tailor-made materials. In any case, from a heterogeneous polymer-based materials perspective following either top-down or bottom-up approaches, the strategy of designing materials rather than designing with materials emerges.
Dr. Jesús-María García-Martínez
Dr. Emilia P. Collar
Guest Editors
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Keywords
- polymer composites
- polymer blends
- interfaces
- interphases
- coupling agents
- interfacial agents
- compatibilization
- reinforcement
- fillers
- thermoplastic composites
- thermoset composites
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