Recent Developments in Nanochemistry for Heterogeneous Catalysis Advancements (2nd Edition)

A special issue of Nanomaterials (ISSN 2079-4991). This special issue belongs to the section "Energy and Catalysis".

Deadline for manuscript submissions: 30 April 2025 | Viewed by 2543

Special Issue Editors


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Guest Editor
REQUIMTE, Chemistry Department, Universidade do Porto, Porto, Portugal
Interests: heterogeneous catalysis; sulfur compound oxidation; desulfurization processes; polyoxometalate (POM); functionalized silica materials; glycerol oxidation
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Guest Editor
Chemical and Environmental Engineering Group, ESCET, Universidad Rey Juan Carlos, Madrid, Spain
Interests: metal–organic catalysts (MOFs); chemical engineering; heterogeneous catalysis; fine chemistry

Special Issue Information

Dear Colleagues,

This Special Issue is a continuation of a previous Special Issue, “Advances in Heterogeneous Catalysis in Nanochemistry”.

Heterogeneous catalysis has played an important role in the development of more sustainable chemistry for many research areas, as well as for the chemical industry, where many processes involve catalysts. Hence, any single advance in the field of catalysis, including the development of novel catalytic materials, catalyst synthesis strategies, and sustainable catalytic processes, may have a considerable impact on societal progress and will ensure a greener environment for forthcoming generations, addressing global energy and environmental challenges.

The unique synergy between surface chemistry and nanostructure has led to many exciting developments in the field of heterogeneous catalysis, gradually becoming the hotspot of materials science and promising to revolutionize chemical manufacturing. The aim of this Special Issue is to cover promising recent research and novel trends in heterogeneous catalysis employing various nanostructured materials for extensive applications in the fields of thermal catalysis, photocatalysis, electrocatalysis, photoelectrocatalysis, biocatalysis, etc., in research areas ranging from environmental remediation to organic transformations and renewable energy. Submissions are welcome in the form of original research manuscripts or critical review papers that represent the scientific field.

Dr. Fátima Mirante
Dr. Pedro Leo
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

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Keywords

  • nanostructured materials
  • heterocatalysts
  • biocatalysts
  • conventional catalysts
  • renewable energy
  • environmental remediation

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Related Special Issue

Published Papers (2 papers)

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Research

14 pages, 2233 KiB  
Article
URJC-1: Stable and Efficient Catalyst for O-Arylation Cross-Coupling
by Elena García-Rojas, Pedro Leo, Jesús Tapiador, Carmen Martos and Gisela Orcajo
Nanomaterials 2024, 14(13), 1103; https://doi.org/10.3390/nano14131103 - 27 Jun 2024
Viewed by 850
Abstract
The design of metal–organic frameworks (MOFs) allows the definition of properties for their final application in small-scale heterogeneous catalysis. Incorporating various catalytic centers within a single structure can produce a synergistic effect, which is particularly intriguing for cross-coupling reactions. The URJC-1 material exhibits [...] Read more.
The design of metal–organic frameworks (MOFs) allows the definition of properties for their final application in small-scale heterogeneous catalysis. Incorporating various catalytic centers within a single structure can produce a synergistic effect, which is particularly intriguing for cross-coupling reactions. The URJC-1 material exhibits catalytic duality: the metal centers act as Lewis acid centers, while the nitrogen atoms of the organic ligand must behave as basic centers. The impact of reaction temperature, catalyst concentration, and basic agent concentration was evaluated. Several copper-based catalysts, including homogeneous and heterogeneous MOF catalysts with and without the presence of nitrogen atoms in the organic ligand, were assessed for their catalytic effect under optimal conditions. Among the catalysts tested, URJC-1 exhibited the highest catalytic activity, achieving complete conversion of 4-nitrobenzaldehyde with only 3% mol copper concentration in one hour. Furthermore, URJC-1 maintained its crystalline structure even after five reaction cycles, demonstrating remarkable stability in the reaction medium. The study also examined the impact of various substituents of the substrate alcohol on the reaction using URJC-1. The results showed that the reaction had high activity when activating substituents were present and for most cyclic alcohols rather than linear ones. Full article
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12 pages, 1508 KiB  
Article
Heteropolyacids@Silica Heterogeneous Catalysts to Produce Solketal from Glycerol Acetalization
by Catarina N. Dias, Isabel C. M. S. Santos-Vieira, Carlos R. Gomes, Fátima Mirante and Salete S. Balula
Nanomaterials 2024, 14(9), 733; https://doi.org/10.3390/nano14090733 - 23 Apr 2024
Viewed by 1315
Abstract
The composites of heteropolyacids (H3PW12, H3PMo12) incorporated into amine-functionalized silica materials were used for the first time as heterogeneous catalysts in the valorization of glycerol (a major waste from the biodiesel industry) through acetalization reaction [...] Read more.
The composites of heteropolyacids (H3PW12, H3PMo12) incorporated into amine-functionalized silica materials were used for the first time as heterogeneous catalysts in the valorization of glycerol (a major waste from the biodiesel industry) through acetalization reaction with acetone. The polyoxotungstate catalyst H3PW12@AptesSBA-15 exhibited higher catalytic efficiency than the phosphomolybdate, achieving 97% conversion and 97% of solketal selectivity, after 60 min at 25 °C, or 91% glycerol conversion and the same selectivity, after 5 min, performing the reaction at 60 °C. A correlation between catalytic performance and catalyst acidity is presented here. Furthermore, the stability of the solid catalyst was investigated and discussed. Full article
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Planned Papers

The below list represents only planned manuscripts. Some of these manuscripts have not been received by the Editorial Office yet. Papers submitted to MDPI journals are subject to peer-review.

Title: Nanomaterial ZnO synthesis and its photocatalytic applications-A review
Authors: Xihui wang, Chunxiang Zhu
Affiliation: Institute of Materials Science and Engineering, University of Connecticut
Abstract: Zinc oxide (ZnO), a cheap, abundant, biocompatible, and wide band gap semiconductor material with easy tunable morphologies and properties, makes it one of the mostly studied metal oxides in the area of materials science, physics, chemistry, biochemistry, and solid-state electronics. Its versatility, easy bandgap engineering with transitional and rare earth metals, as well as the diverse nanomorphology empower ZnO as a promising photocatalyst. The use of ZnO as a functional material is attracting increased attention both for academia and industry, especially under the current energy paradigm shift towards clean and renewable sources. Extensive work has been performed in recent years using ZnO as an active component for different photocatalytic applications. Therefore, a thorough and timely review of the process is nessacery. The aim of this review is to provide a general summary of the current state of ZnO nanostructures, synthesis strategies, and modification approaches, with the main application focus on the photocatalysis, serving as an introduction, a reference, and an inspiration for future research.

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