Natural Polymeric Materials: Polysaccharides and Carbohydrate Polymers

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Circular and Green Polymer Science".

Deadline for manuscript submissions: 31 October 2024 | Viewed by 3851

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Faculty of Chemistry, Adam Mickiewicz University in Poznań, Uniwersytetu Poznańskiego 8, 61-614 Poznań, Poland
Interests: mesoporous materials; biomaterials; functionalization and surface modification; characterization and analysis of materials; heterogeneous catalysis; catalysts' preparation; catalysis on metals; acid-base catalysis; active substance-delivery systems
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Special Issue Information

Dear Colleagues,

Natural polymeric materials (NPMs) perfectly fit the increasingly common trend of green and sustainable chemistry. Within this group, biopolymers based on carbohydrates, particularly polysaccharides, should be distinguished, since they are readily available at low costs, making them one of the main building blocks of plants. Therefore, growing interest in research on the preparation, modification, and potential application of NMPs as structural components, carriers of active substances (e.g., in pharmaceutic and cosmetic products or functional foods), as well as in separation processes, biotechnology, and energy storage, may be observed. This indicates that NPMs may constitute an alternative to the currently used synthetic polymers, and this field of research carries enormous potential, both in the area of basic research and application.

Accordingly, this Special Issue is devoted to the most recent high-quality original research papers or comprehensive reviews covering all aspects of the synthesis, structural modification, characterization, and application of carbohydrate/polysaccharide-based natural polymeric materials.

Dr. Agata Wawrzyńczak
Dr. Agnieszka Feliczak-Guzik
Guest Editors

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Keywords

  • synthesis and characterization of carbohydrate/polysaccharide-based NPLs
  • structural modifications and functionalization of carbohydrate/polysaccharide-based NPsL
  • encapsulation processes
  • drug-delivery systems
  • polysaccharide-based bionanocomposites
  • polysaccharide-based hydrogels
  • polysaccharide-based membranes
  • electroactive NPLs

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Published Papers (3 papers)

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Research

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21 pages, 4388 KiB  
Article
Microspheres Based on Blends of Chitosan Derivatives with Carrageenan as Vitamin Carriers in Cosmeceuticals
by Kamila Lewicka, Anna Smola-Dmochowska, Piotr Dobrzyński, Natalia Śmigiel-Gac, Katarzyna Jelonek, Monika Musiał-Kulik and Piotr Rychter
Polymers 2024, 16(13), 1815; https://doi.org/10.3390/polym16131815 - 26 Jun 2024
Viewed by 1117
Abstract
Chitosan (CS) has a natural origin and is a biodegradable and biocompatible polymer with many skin-beneficial properties successfully used in the cosmetics and pharmaceutical industry. CS derivatives, especially those synthesized via a Schiff base reaction, are very important due to their unique antimicrobial [...] Read more.
Chitosan (CS) has a natural origin and is a biodegradable and biocompatible polymer with many skin-beneficial properties successfully used in the cosmetics and pharmaceutical industry. CS derivatives, especially those synthesized via a Schiff base reaction, are very important due to their unique antimicrobial activity. This study demonstrates research results on the use of hydrogel microspheres made of [chitosan-graft-poly(ε-caprolactone)]-blend-(ĸ-carrageenan)], [chitosan-2-pyridinecarboxaldehyde-graft-poly(ε-caprolactone)]-blend-(ĸ-carrageenan), and chitosan-sodium-4-formylbenzene-1,3-disulfonate-graft-poly(ε-caprolactone)]-blend-(ĸ-carrageenan) as innovative vitamin carriers for cosmetic formulation. A permeation study of retinol (vitamin A), L-ascorbic acid (vitamin C), and α-tocopherol (vitamin E) from the cream through a human skin model by the Franz Cell measurement system was presented. The quantitative analysis of the release of the vitamins added to the cream base, through the membrane, imitating human skin, showed a promising profile of its release/penetration, which is promising for the development of a cream with anti-aging properties. Additionally, the antibacterial activity of the polymers from which the microspheres are made allows for the elimination of preservatives and parabens as cosmetic formulation ingredients. Full article
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Review

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18 pages, 779 KiB  
Review
Biodegradable Conducting Polymer-Based Composites for Biomedical Applications—A Review
by Tabrej Khan, Gayathri Vadivel, Balan Ramasamy, Gowtham Murugesan and Tamer A. Sebaey
Polymers 2024, 16(11), 1533; https://doi.org/10.3390/polym16111533 - 29 May 2024
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Abstract
In recent years, researchers have increasingly directed their focus toward the biomedical field, driven by the goal of engineering polymer systems that possess a unique combination of both electrical conductivity and biodegradability. This convergence of properties holds significant promise, as it addresses a [...] Read more.
In recent years, researchers have increasingly directed their focus toward the biomedical field, driven by the goal of engineering polymer systems that possess a unique combination of both electrical conductivity and biodegradability. This convergence of properties holds significant promise, as it addresses a fundamental requirement for biomedical applications: compatibility with biological environments. These polymer systems are viewed as auspicious biomaterials, precisely because they meet this critical criterion. Beyond their biodegradability, these materials offer a range of advantageous characteristics. Their exceptional processability enables facile fabrication into various forms, and their chemical stability ensures reliability in diverse physiological conditions. Moreover, their low production costs make them economically viable options for large-scale applications. Notably, their intrinsic electrical conductivity further distinguishes them, opening up possibilities for applications that demand such functionality. As the focus of this review, a survey into the use of biodegradable conducting polymers in tissue engineering, biomedical implants, and antibacterial applications is conducted. Full article
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19 pages, 2598 KiB  
Review
Microneedles Based on a Biodegradable Polymer—Hyaluronic Acid
by Jagoda Chudzińska, Agata Wawrzyńczak and Agnieszka Feliczak-Guzik
Polymers 2024, 16(10), 1396; https://doi.org/10.3390/polym16101396 - 14 May 2024
Viewed by 1436
Abstract
Transdermal transport can be challenging due to the difficulty in diffusing active substances through the outermost layer of the epidermis, as the primary function of the skin is to protect against the entry of exogenous compounds into the body. In addition, penetration of [...] Read more.
Transdermal transport can be challenging due to the difficulty in diffusing active substances through the outermost layer of the epidermis, as the primary function of the skin is to protect against the entry of exogenous compounds into the body. In addition, penetration of the epidermis for substances hydrophilic in nature and particles larger than 500 Da is highly limited due to the physiological properties and non-polar nature of its outermost layer, namely the stratum corneum. A solution to this problem can be the use of microneedles, which “bypass” the problematic epidermal layer by dispensing the active substance directly into the deeper layers of the skin. Microneedles can be obtained with various materials and come in different types. Of special interest are carriers based on biodegradable and biocompatible polymers, such as polysaccharides. Therefore, this paper reviews the latest literature on methods to obtain hyaluronic acid-based microneedles. It focuses on the current advancements in this field and consequently provides an opportunity to guide future research in this area. Full article
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