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Polymers
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Polymer-Inorganic Materials Composite and Its Potential Application
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Polymer-Inorganic Materials Composite and Its Potential Application

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Applications".

Deadline for manuscript submissions: closed (15 June 2023) | Viewed by 7814

Special Issue Editors

Dr. Muhammad M. Hossain

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Guest Editor
Mechanical Engineering Department, Sungkyunkwan University, Seoul, Korea
Interests: polymer; graphene; CNT; thin-film; thermoelectricity; membrane; photocatalysis; sensor; metal oxide semiconductor; metal nanoparticles; electrical conductivity
Special Issues, Collections and Topics in MDPI journals
Dr. Mudassir Hasan

E-Mail Website
Guest Editor
Department of Chemical Engineering, King Khalid University, Abha, Saudi Arabia
Interests: polymer; polymer composite; membrane; adsorption, separation; water purification; thermal properties; electrical properties
Dr. Md. Arifur Rahim

E-Mail Website
Guest Editor
Centre for Advanced Solid and Liquid-based Electronics and Optics, School of Chemical Engineering, The University of New South Wales, Kensington, Australia
Interests: supramolecular chemistry; coordination-driven self-assembly; biomimetic synthesis; layer-by-layer assembly; soft matter; coordination polymers; metal-organic frameworks; metal-phenolic networks; metallogels; nanocomposites; plasmonic nanoparticles; hybrid soft materials; drug delivery; materials for energy and environmental applications; liquid metal composites
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Insertion of inorganic materials into polymers is usually applied for fabricating polymer composites or hybrid materials with enhanced mechanical, optical, electrical, electronic, sensing, energy production, thermal, adsorption, and catalytical properties. Major inorganic materials, such as graphene, CNT, carbon nanomaterials, various metal nanoparticles, and their oxides, are utilized for enhancing the intrinsic properties of the polymer as a polymer–inorganic hybrid composite. So, this Special Issue will focus on the fabrication of polymer–inorganic hybrid materials and their application in sensors (moisture sensors, chemical sensors, gas sensors, temperature sensors, and so on), mechanical property enhancement of polymers as polymer composites, membrane application using adsorption and separation application for the purification of water, thermoelectric device for the generation of electricity, enhancement of electrical conductivity of polymers, photocatalytic applications, electronic applications, thermal stability, and thermal conductivity modification.

Dr. Muhammad M. Hossain
Dr. Mudassir Hasan
Dr. Md. Arifur Rahim
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Polymers is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • polymer–inorganic composite
  • membrane
  • sensor
  • energy generation
  • electrical conductivity
  • mechanical properties
  • optical properties
  • solar cell
  • catalysis
  • thermoelectric device
  • thermal stability
  • thermal conductivity

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Published Papers (3 papers)

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Research

21 pages, 11762 KiB  
Article
Convertible Thermal Meta-Structures via Hybrid Manufacturing of Stereolithography Apparatus 3D Printing and Surface Metallization for Thermal Flow Manipulation
by Bo Li, Jianrui Zhang, Tianxiang Deng and Facai Ren
Polymers 2023, 15(1), 174; https://doi.org/10.3390/polym15010174 - 29 Dec 2022
Viewed by 1845
Abstract
For manipulating heat flow according to human desire, thermal metamaterial structures (meta-structures) have attracted growing interest. Based on the transformation thermotics and the effective medium approximation theory, we designed and fabricated a convertible thermal meta-structural device to demonstrate that multiple different heat-flow manipulations [...] Read more.
For manipulating heat flow according to human desire, thermal metamaterial structures (meta-structures) have attracted growing interest. Based on the transformation thermotics and the effective medium approximation theory, we designed and fabricated a convertible thermal meta-structural device to demonstrate that multiple different heat-flow manipulations could be conducted using a single thermal meta-structural device. The convertible meta-structures were designed by discretizing a two-dimensional plane and separating multiple square unit modules with stripe-shaped dissimilar materials of the Polydimethylsiloxane (PDMS) and solid resin with surface metallized copper (Cu). The convertible thermal meta-structure device with a relatively high geometric accuracy was fabricated via a proposed hybrid manufacturing path of “Stereolithography Apparatus (SLA) 3D printing—electroless plating—electroplating—thermally insulated packaging”. The thermal manipulation features were numerically simulated and preliminarily verified by experimental testing. Using multiple dispersed square unit modules to replace an annular region of the thermal meta-structure exhibited different thermal flow functions, including thermal cloak, thermal concentration, thermal rotation, and thermal dispersion, through the unique geometric design of the heat-flow transfer direction within each module. By rotating each square unit module at a specific angle and arranging the modules, similar to a “jigsaw puzzle”, the convertibility among different thermal manipulation functions was achieved. This path is anticipated to provide a new strategy for multifunctional meta-structures in thermo-physics and its potential engineering applications. Full article
(This article belongs to the Special Issue Polymer-Inorganic Materials Composite and Its Potential Application)
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21 pages, 6761 KiB  
Article
Effect of Colorants and Process Parameters on the Properties of Dope-Dyed Polylactic Acid Multifilament Yarns
by Naveen Kumar Balakrishnan, Stefan Siebert, Christoph Richter, Robert Groten and Gunnar Seide
Polymers 2022, 14(22), 5021; https://doi.org/10.3390/polym14225021 - 19 Nov 2022
Cited by 9 | Viewed by 3472
Abstract
The color of textile fibers is typically imparted by submersion in a high-temperature dye bath. However, the treatment of the effluent is challenging and the textile industry is therefore a major source of water pollution. Current fashion trends favor biobased polymers such as [...] Read more.
The color of textile fibers is typically imparted by submersion in a high-temperature dye bath. However, the treatment of the effluent is challenging and the textile industry is therefore a major source of water pollution. Current fashion trends favor biobased polymers such as polylactic acid (PLA) but exhaust dyeing at high temperatures causes hydrolytic degradation, reducing the crystallinity and tenacity of the yarn. To preserve the mechanical properties of PLA-based textiles, an alternative to exhaust dyeing called dope dyeing can be used, wherein colorants are incorporated into the polymer matrix during melt spinning. We evaluated this process by dope dyeing PLA with several colorants, then testing the thermal, physical, and mechanical properties of the yarn and the physical properties of circular-knitted fabrics. Although the colorants affected the crystallization behavior at lower cooling rates, during the melt-spinning process, the drawing speed had a greater effect on the crystallinity and mechanical properties of the dyed yarn. Scanning electron microscopy revealed that the colorants were well dispersed in the PLA matrix. We found that the colorants did not affect the physical properties of the knitted fabric. Our results can be used to develop more environmentally beneficial dope-dyed PLA yarn with improved mechanical properties. Full article
(This article belongs to the Special Issue Polymer-Inorganic Materials Composite and Its Potential Application)
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14 pages, 4575 KiB  
Article
Tribological Behavior of 3D-Printed Nanometer SiC and SiO2 Particle-Reinforced Polyamide 12 Composites by Selective Laser Sintering under Seawater Lubrication Condition
by Jingdong Ma, Guoyan Yu, Xianmin Wang, Jun Li, Jingquan Wu and Xianzhang Wang
Polymers 2022, 14(19), 4137; https://doi.org/10.3390/polym14194137 - 3 Oct 2022
Cited by 3 | Viewed by 1937
Abstract
Polymeric matrix composites have been widely used in the marine field. In this study, the tribological behavior under seawater-lubricated conditions of pure Polyamide 12 (PA12), micron-SiC and nanometer SiC and SiO2 particle-reinforced PA12 composites, which are prepared by selective laser sintering (SLS), [...] Read more.
Polymeric matrix composites have been widely used in the marine field. In this study, the tribological behavior under seawater-lubricated conditions of pure Polyamide 12 (PA12), micron-SiC and nanometer SiC and SiO2 particle-reinforced PA12 composites, which are prepared by selective laser sintering (SLS), were studied. The seawater absorption, hardness, contact angle and tribology performance were investigated. The results show that the addition of micron- and nano-SiC particles and nano-SiO2 particles could decrease the seawater adsorption and contact angle, and increase the hardness. Under seawater conditions, the addition of micro SiC particles can reduce the friction coefficient and wear loss, whereas the addition of nano-SiC and -SiO2 particles increases the corresponding values. The specimen printed with recycled powder has a higher friction coefficient, while having a better wear resistance. However, it increases the width and depth of the wear track in some locations. The wear mechanisms of the composite specimens are also analyzed. This was the result of the combined effects of fatigue wear and abrasive wear under seawater conditions. The latter plays a dominant role under seawater conditions. This study may provide a valuable reference for the further research and application of polymeric matrix composites in marine engineering equipment. Full article
(This article belongs to the Special Issue Polymer-Inorganic Materials Composite and Its Potential Application)
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