Polymerization Technologies in the Presence of Nanoparticles

A special issue of Processes (ISSN 2227-9717). This special issue belongs to the section "Materials Processes".

Deadline for manuscript submissions: closed (20 February 2022) | Viewed by 9243

Special Issue Editor


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Guest Editor
Department of Water Industry Engineering, Kinneret Academic College, Galilee, Israel
Interests: polymer synthesis and processing; advanced polymers and nanocomposites; electrically conductive polymers and composites; hydrophilic and hydrophobic surface modifications; anti-microbial and anti-biofouling surfaces; polymer and composites characterization techniques

Special Issue Information

Dear Colleagues,

Polymeric nanocomposites are attracting significant attention as advanced materials and their applications in many fields, such as electrical and electronic, automotive and transportation, architecture and construction, and sports. For a long time, there has been a need for the development of polymeric materials with specific properties that require high functionality. To meet their needs, many nanocomposites with high functionality are newly researched and developed. High-functional nanocomposites must exhibit mechanical, electronic, or chemical performance in harsher and tougher conditions than normal.

This Special Issue Introduces the different approaches for polymerization techniques in the presence of nanoparticles. This Special Issue Introduces a wide range of high-functional nanocomposites such as high-performance polymers, high-temperature polymers, engineering materials for flexible displays, super-engineering polymers, high gas barrier films, and liquid crystalline polymers, etc.

This Special Issue will demonstrate the multidisciplinary aspect of the selected subject and bring together original papers and reviews covering (but not restricted to) the following topics:

  1. Advanced design of nanocomposites with functional polymers and nanoparticles;
  2. Development of controlled delivery systems based on nanocomposites;
  3. Grafting of polymer chains to nanoparticle surfaces;
  4. Drugs delivery incorporating nanoparticles in nanomedicine;
  5. Design of smart nano-objects for target applications in EOR (enhanced oil recovery), pharmacy, agriculture, and water purification. 

Dr. Ran Suckeveriene
Guest Editor

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Keywords

  • polymerization
  • nanoparticles
  • nanocomposites
  • in situ
  • post-polymerization modification
  • grafting
  • step polymerization
  • polycondensation
  • controlled polymerization
  • free-radical polymerization

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Published Papers (3 papers)

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Research

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8 pages, 3333 KiB  
Article
Preparation of a Novel CO2-Responsive Polymer/Multiwall Carbon Nanotube Composite
by Yonggang Ma, Xin Chen, Dehui Han, Zhe Zhao and Wenting Lu
Processes 2021, 9(9), 1638; https://doi.org/10.3390/pr9091638 - 11 Sep 2021
Viewed by 2017
Abstract
A CO2-responsive composite of multiwall carbon nanotube (MWCNT) coated with polydopamine (PDA) and polydimethylamino-ethyl methacrylate (PDMAEMA) was prepared. The PDA was first self-polymerized on the surface of carbon nanotube. 2-bromoisobutyryl bromide (BiBB) was then immobilized by PDA and then initiated the [...] Read more.
A CO2-responsive composite of multiwall carbon nanotube (MWCNT) coated with polydopamine (PDA) and polydimethylamino-ethyl methacrylate (PDMAEMA) was prepared. The PDA was first self-polymerized on the surface of carbon nanotube. 2-bromoisobutyryl bromide (BiBB) was then immobilized by PDA and then initiated the ATRP of DMAEMA on the carbon nanotube surface. The resulting composite was characterized by Fourier-transform infrared spectroscopy (FTIR) and transmission electron microscopy (TEM). The CO2-responsive test was performed by bubbling CO2 into the mixture of MWCNT-PDA-PDMAEMA composite in water. A well-dispersed solution was obtained and the UV-Vis transmittance decreased dramatically. This is attributed to the reaction between PDMAEMA and CO2. The formation of ammonium bicarbonates on the surface of carbon nanotubes leads to the separation of nanotube bundles. This process can be reversed as the removal of CO2 by bubbling N2. Full article
(This article belongs to the Special Issue Polymerization Technologies in the Presence of Nanoparticles)
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13 pages, 4171 KiB  
Article
Preparation of Hybrid Polyaniline/Nanoparticle Membranes for Water Treatment Using an Inverse Emulsion Polymerization Technique under Sonication
by Itamar Chajanovsky and Ran Y. Suckeveriene
Processes 2020, 8(11), 1503; https://doi.org/10.3390/pr8111503 - 20 Nov 2020
Cited by 7 | Viewed by 2648
Abstract
This manuscript describes a novel in situ interfacial dynamic inverse emulsion polymerization process under sonication of aniline in the presence of carbon nanotubes (CNT) and graphene nanoparticles in ethanol. This polymerization method is simple and very rapid (up to 10 min) compared to [...] Read more.
This manuscript describes a novel in situ interfacial dynamic inverse emulsion polymerization process under sonication of aniline in the presence of carbon nanotubes (CNT) and graphene nanoparticles in ethanol. This polymerization method is simple and very rapid (up to 10 min) compared to other techniques reported in the literature. During polymerization, the nanoparticles are coated with polyaniline (PANI), forming a core-shell structure, as confirmed by high-resolution scanning electron microscopy (HRSEM) and Fourier-Transform Infrared (FTIR) measurements. The membrane pore sizes range between 100–200 nm, with an average value of ~119 ± 28.3 nm. The film resistivity decreased when treated with alcohol, and this behavior was used for selection of the most efficient alcohol as a solvent for this polymerization technique. The membrane permeability of the PANI grafted CNT was lower than the CNT reference, thus demonstrating better membranal properties. As measured by water permeability, these are ultrafiltration membranes. An antimicrobial activity test showed that whereas the reference nanoparticle Bucky paper developed a large bacterial colony, the PANI grafted CNT sample had no bacterial activity. The thicker, 2.56 mm membranes exhibited high salt removal properties at a low pressure drop. Such active membranes comprise a novel approach for future water treatment applications. Full article
(This article belongs to the Special Issue Polymerization Technologies in the Presence of Nanoparticles)
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Review

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21 pages, 8022 KiB  
Review
Ultrasonically Induced Polymerization and Polymer Grafting in the Presence of Carbonaceous Nanoparticles
by Sarah Cohen, Evgeni Zelikman and Ran Yosef Suckeveriene
Processes 2020, 8(12), 1680; https://doi.org/10.3390/pr8121680 - 19 Dec 2020
Cited by 11 | Viewed by 3709
Abstract
Nanotechnology refers to technologies using at least one nanometric dimension. Most advances have been in the field of nanomaterials used in research and industry. The vast potential of polymeric nanocomposites for advanced materials and applications such as hybrid nanocomposites with customized electrical conductivity, [...] Read more.
Nanotechnology refers to technologies using at least one nanometric dimension. Most advances have been in the field of nanomaterials used in research and industry. The vast potential of polymeric nanocomposites for advanced materials and applications such as hybrid nanocomposites with customized electrical conductivity, anti-bacterial, anti-viral, and anti-fog properties have attracted considerable attention. The number of studies on the preparation of nanocomposites in the presence of carbon materials, i.e., carbon nanotubes (CNTs) and graphene, has intensified over the last decade with the growing interest in their outstanding synergic properties. However, the functionality of such nanocomposites depends on overcoming three key challenges: (a) the breakdown of nanoparticle agglomerates; (b) the attachment of functional materials to the nanoparticle surfaces; and (c) the fine dispersion of functional nanoparticles within the polymeric matrices. Ultrasonic polymerization and grafting in the presence of nanoparticles is an innovative solution that can meet these three challenges simultaneously. These chemical reactions are less well known and only a few research groups have dealt with them to date. This review focuses on two main pathways to the design of ultrasonically induced carbon-based nanocomposites: the covalent approach which is based on the chemical interactions between the carbon fillers and the matrix, and the non-covalent approach which is based on the physical interactions. Full article
(This article belongs to the Special Issue Polymerization Technologies in the Presence of Nanoparticles)
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