Perspectives on CO2 Separation and Capture Technologies

A special issue of Separations (ISSN 2297-8739). This special issue belongs to the section "Analysis of Energies".

Deadline for manuscript submissions: closed (31 October 2023) | Viewed by 2573

Special Issue Editor


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Guest Editor
Physical Chemistry Laboratory, School of Chemical Engineering, Aristotle University of Thessaloniki (AUTh), 54124 Thessaloniki, Greece
Interests: supercritical fluids; CO2 capture; phase equilibrium; equations of state

Special Issue Information

Dear Colleagues,

Carbon dioxide was identified as one of the main contributors to climate change several years ago. Svante Arrhenius quantified the contribution of carbon dioxide to the greenhouse effect already in 1896 (S. Arrhenius, On the Influence of Carbonic Acid in the Air upon the Temperature of the Ground, Philosophical Magazine and Journal of Science, Series 5, Volume 41, 1896, pp. 237-276).

However, only recently, climate change was broadly considered as one of the most important threats for the environment and humanity. Therefore, significant research effort is currently made for capturing CO2 from the flue gases produced from fossil fuel combustion or other industrial processes. Despite such intensive research efforts, carbon capture and storage (CCS) is considered as a significant engineering challenge, with the main goal being the development of an efficient technology that does not substantially increase the overall cost of processes and especially the electricity cost.

Therefore, this Special Issue calls for the submission (including research articles, communications, and reviews) of experimental, computational, and theoretical studies, focusing on carbon capture and storage, including (but not limited to): (a) CO2 absorption, chemical or physical, including the development and evaluation of novel solvents and the rigorous thermodynamic modeling of such CO2-containing non-ideal multicomponent mixtures, (b) adsorption on surfaces, (c) membrane separation, (d) cryogenic separation, (e) chemical looping combustion methods.

Dr. Ioannis Tsivintzelis
Guest Editor

Manuscript Submission Information

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Keywords

  • CO2 capture
  • post-combustion separation
  • pre-combustion separation
  • alkanolamines
  • amines
  • chemical absorption
  • physical absorption
  • adsorption on surfaces
  • membrane separation
  • chemical looping
  • phase equilibrium
  • equations of state
  • thermophysical properties
  • process design
  • novel solvents
  • phase separation solvents

Published Papers (1 paper)

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Research

12 pages, 4532 KiB  
Article
Carbon Dioxide Chemical Absorption Using Diamines with Different Types of Active Centers
by Diego Gómez-Díaz, José Manuel Navaza and Antonio Rumbo
Separations 2022, 9(11), 343; https://doi.org/10.3390/separations9110343 - 3 Nov 2022
Cited by 2 | Viewed by 1861
Abstract
The present research analyzes chemical solvents based on the use of diamines (Ethylenediamine-EDA, 1,2-Dimethylethylenediamine-DMEDA and Tetramethylethylenediamine-TMEDA) for carbon dioxide absorption, taking into account the type of amino centers in the molecules. The presence and type of radicals can affect amine solubility in water, [...] Read more.
The present research analyzes chemical solvents based on the use of diamines (Ethylenediamine-EDA, 1,2-Dimethylethylenediamine-DMEDA and Tetramethylethylenediamine-TMEDA) for carbon dioxide absorption, taking into account the type of amino centers in the molecules. The presence and type of radicals can affect amine solubility in water, reaction mechanism, reaction kinetics, etc. Diamines have been considered interesting candidates for carbon dioxide chemical absorption, observing a high influence of the molecule structure. The present work analyzes a series of solvents based on diamines with the same chain length between amino centers, but different types of radicals. This study shows an important variability in the behavior of these solvents. EDA-based solvents have shown high absorption rates and stability, but carbamate hydrolysis is relatively low, avoiding an increase in carbon dioxide loading. Full article
(This article belongs to the Special Issue Perspectives on CO2 Separation and Capture Technologies)
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