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Sources, Migration and Variation Characteristics of Pollutants in Aquatic Environments

A special issue of Water (ISSN 2073-4441). This special issue belongs to the section "Water Quality and Contamination".

Deadline for manuscript submissions: 20 July 2026 | Viewed by 1471

Special Issue Editors


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Guest Editor
Lushan Botanical Garden, Chinese Academy of Sciences, Jiujiang, China
Interests: physical geography; environment; environmental impact assessment

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Guest Editor
College of Resources and Environmental Engineering, Guizhou University, Guiyang, China
Interests: rainwater chemistry; atmospheric pollution and source appointment; environmental isotope geochemistry; earth surface processes; circulation of materials
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

In the context of escalating anthropogenic pressures and climate variability, karst groundwater systems face unprecedented contamination risks due to their unique hydrological and geological characteristics. The rapid migration of pollutants through fissures and conduits, coupled with slow natural remediation processes, poses significant challenges to water security, ecosystem health, and sustainable development. This Special Issue highlights cutting-edge research on karst groundwater contamination mechanisms, contamination risk assessment, and innovative strategies for mitigating contamination, aiming to bridge scientific understanding and practical governance.

The key topics include the following:

  • ​Pollution Mechanisms and Migration Pathways

Karst aquifers are highly vulnerable to pollutants from industrial discharge (e.g., heavy metals, organic compounds), agricultural runoff (e.g., nitrates, pesticides), and urban wastewater. Contaminants propagate rapidly through interconnected conduits, with transport influenced by hydrogeological heterogeneity and climate-driven hydrological shifts.

  • ​Risk Assessment and Modeling

Advanced tools like PMF (Positive Matrix Factorization) and 3D hydrogeological modeling quantify pollution sources (e.g., sulfuric acid acocunted for 48.6% of pollution in a Chinese chemical park), while risk zoning has revealed that 67% of industrial areas are classified as high-risk due to carcinogenic metals (Cd, As).

  • ​Climate Change Interactions

Altered precipitation patterns exacerbate contamination by concentrating pollutants during droughts or accelerating their transport during heavy rainfall. Studies show increased ionic concentrations (e.g., Na⁺, Cl⁻) in Southwest China linked to reduced dilution effects.

  • ​Integrated Management and Remediation

Case studies emphasize source control (e.g., relocating high-risk industries to low-permeability zones), real-time monitoring networks, and bioremediation as solutions to water contamination. Therefore, policy frameworks must integrate geological vulnerability maps with socio-economic factors.

  • ​Interdisciplinary Solutions

Remote sensing and isotopic tracing (e.g., δ¹⁸O, δ¹³C) are used to decode the origins of pollution at heritage sites like Lijiang, while participatory governance engages communities in conservation.

Dr. Zuobing Liang
Prof. Dr. Jie Zeng
Guest Editors

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Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • karst aquifer vulnerability
  • pollution transport mechanisms
  • heavy metal contamination
  • integrated water management
  • climate change interactions

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Published Papers (2 papers)

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Research

27 pages, 10761 KB  
Article
Quality–Quantity Coupled Evaluation of Groundwater in a Typical Industrial City of the Guangdong–Hong Kong–Macao Greater Bay Area
by Xing Gong, Chengliang Li, Chengjian Deng, Bingfa Zhi, Zhuobin Lin and Zhongzhong Wang
Water 2026, 18(7), 789; https://doi.org/10.3390/w18070789 - 26 Mar 2026
Viewed by 550
Abstract
Groundwater in the coastal industrial cities of the Guangdong–Hong Kong–Macao Greater Bay Area faces rising pressure from saline–tidal intrusion, multi-source contamination, and intensive abstraction. Effective management therefore requires an integrated view of water quality and resource availability. A total of 369 groundwater samples [...] Read more.
Groundwater in the coastal industrial cities of the Guangdong–Hong Kong–Macao Greater Bay Area faces rising pressure from saline–tidal intrusion, multi-source contamination, and intensive abstraction. Effective management therefore requires an integrated view of water quality and resource availability. A total of 369 groundwater samples were collected from Quaternary porous and fractured bedrock aquifers during the wet and dry seasons. Major ions and key pollutants were analyzed, and overall quality was assessed using the improved Nemerow pollution index. A 3D transient FEFLOW model calibrated for 2022–2024 was combined with Nemerow quality classes to quantify season-specific exploitable resources by grade. The results indicate that NO3, Mn, and NO3–N are the dominant pollutants (0–202.05 mg/L, 0.001–8.91 mg/L, and 0–108 mg/L, respectively). Nemerow grading shows Class IV prevailing (47.4–54.5%), with higher Class V proportions in fractured groundwater (27.3–34.5%) than in porous groundwater (14.0–15.5%); overall quality deteriorates in the dry season. Annual mean sustainable exploitable resources are 2.72 × 108 m3/a (porous aquifers) and 1.25 × 108 m3/a (fractured aquifers). These results provide a quantitative basis for season- and quality-informed groundwater development and protection in coastal industrial cities. Full article
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15 pages, 6350 KB  
Article
Unveiling the Removal Mechanism and Electrode Fate During Electrocatalytic Treatment of Mature Landfill Leachate with Ti/RuO2–IrO2 Anodes
by Yueqi Zhu and Qingbin Song
Water 2026, 18(6), 684; https://doi.org/10.3390/w18060684 - 14 Mar 2026
Viewed by 424
Abstract
The compliant discharge of landfill leachate constitutes a pivotal factor for the effective implementation of integrated water resource management. Aged landfill leachate exhibits complex composition and an imbalanced carbon-to-nitrogen ratio. Electrocatalytic oxidation technology, as an efficient advanced oxidation process, demonstrates promising application potential. [...] Read more.
The compliant discharge of landfill leachate constitutes a pivotal factor for the effective implementation of integrated water resource management. Aged landfill leachate exhibits complex composition and an imbalanced carbon-to-nitrogen ratio. Electrocatalytic oxidation technology, as an efficient advanced oxidation process, demonstrates promising application potential. This study employed Ti/RuO2–IrO2 Anodes for the electrocatalytic oxidation treatment of aged landfill leachate. The removal efficiencies and variation patterns of chemical oxygen demand (COD), ammonia nitrogen, and total nitrogen at different current densities and reaction times were systematically investigated, along with an analysis of energy consumption and current efficiency. The degradation and transformation processes of organic matter were elucidated using Three-dimensional Excitation–Emission Matrix (EEM) Spectra. Fresh anodes and those used for 1000 h were characterized by scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS) to elucidate their failure mechanisms. The results demonstrate that electrocatalytic oxidation achieves efficient pollutant removal. At a current density of 1000 A/m2 and a reaction time of 30 min, the effluent concentrations of ammonia nitrogen and total nitrogen satisfied the discharge standards, while COD complied with emission requirements after 60 min. The pollutant removal efficiencies were positively correlated with current density and reaction time. EEM analysis revealed that the electrocatalytic process effectively disrupts the structure of macromolecular organic matter, degrading it into smaller molecules and eventually achieving complete mineralization. Electrode characterization identified titanium substrate corrosion due to coating cracks and coating detachment as the primary causes of electrode failure. This study confirms the effectiveness of electrocatalytic oxidation technology for treating aged landfill leachate, and provides a theoretical foundation and technical support for its practical engineering application. The technology exhibits considerable theoretical significance and promising application potential in the treatment of landfill leachate. Full article
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