Search Results (17)

Conventional continuum thermodynamics is characterized by a classical form of the energy law and the second law of thermodynamics in the form of the Clausius–Duhem inequality. This thermodynamic framework fails to capture certain features in material response as, e.g., length scale effects, temperature waves in rigid heat conductors and diffusion phenomena. Typically, such material characteristics are associated with pronounced non-localities in time and space. To tackle these issues, non-conventional thermodynamic approaches might be appropriate. The employment of non-conventional thermodynamics is very attractive, as it enables the extension of the applicability of conventional thermodynamics in a simple way. A specific non-conventional thermodynamic framework has previously been proposed as a generalization of irreversible thermodynamics. Energy supply effects were neglected in this work. However, energy supply terms may become important when discussing thermodynamical consistency of many physical models. The present paper extends the applicability of the proposed non-conventional thermodynamic framework by accounting for energy supply densities and demonstrates its capabilities by addressing Cattaneo’s heat conduction law—known for predicting temperature waves—and thermo-diffusion coupling theories. It is shown that, within the adopted thermodynamics, the considered physical models are thermodynamically consistent and that the resulting field theories admit formulations within a variational framework for rate problems; in this sense, the models are properly formulated. Full article

The paper addresses the second law of thermodynamics through the Clausius–Duhem inequality in its general form, with entropy flux and entropy production given by suitable constitutive functions. For definiteness the paper investigates possible models of elastic solids where, to account for non-local properties, the stress depends on strain gradients up to second order. While previous approaches are developed through variational formulations or by applying the virtual power method, here it is shown that no change in the energy balance or the form of kinetic energy is necessary; it is sufficient that the entropy flux be given by a suitable constitutive function. The paper also emphasizes that non-local constitutive properties arise from the Clausius–Duhem thermodynamic inequality, while variational formulations and the virtual power method are in fact limited to the purely mechanical context, as they involve only the equation of motion. Full article

Thermodynamic constraints must be satisfied for the parameters of a constitutive relation, particularly for a model describing an electromagnetic (or any other) material with the intention of giving that model a physical meaning. We present sufficient conditions for the parameters of the constitutive relation of an electromagnetic Zener-type fractional 2D and 3D anisotropic model so that a weak form of the thermodynamic (entropy) inequality is satisfied. Moreover, for such models, we analyze the corresponding thermodynamic constraints for field reconstruction and regularity in the 2D anisotropic case. This is carried out by the use of the matrix version of the Bochner theorem in the most general form, including generalized functions as elements of a matrix, which appear in that theorem. The given numerical results confirm the calculus presented in the paper. Full article

This paper revisits some aspects connected with the methods for the determination of thermodynamically consistent models. While the concepts apply to the general context of continuum physics, the details are developed for the modelling of deformable dielectrics. The symmetry condition arising from the balance of angular momentum is viewed as a constraint for the constitutive equations and is shown to be satisfied by sets of objective fields that account jointly for deformation and electric field. The second law of thermodynamics is considered in a generalized form where the entropy production is given by a constitutive function possibly independent of the other constitutive functions. Furthermore, a representation formula is applied for solving the Clausius–Duhem inequality with respect to the chosen unknown fields. Full article

This paper addresses the modelling of material behaviour in terms of differential (or rate) equations. To comply with the objectivity principle, recourse is made to invariant fields in the Lagrangian description or to objective time derivatives in the Eulerian description. The thermodynamic consistency is investigated in terms of the Clausius–Duhem inequality with two unusual features. Firstly, the (non-negative) entropy production is viewed as a constitutive function per se. Secondly, the inequality is viewed as a constraint on the pertinent fields and it is solved by using a representation formula, which allows for the the admissibility of a class of models. For definiteness, models of heat conduction are established, within Lagrangian descriptions, while models of the Navier–Stokes–Voigt fluid are investigated within Eulerian descriptions. In connection with thermo-viscous fluids, evolution equations are investigated within the Eulerian description. It is shown that the thermodynamic consistency is compatible with both objective and non-objective evolution equations. Full article

The paper is devoted to the modeling of nonlinear viscoelastic materials. The constitutive equations are considered in differential form via relations between strain, stress, and their derivatives in the Lagrangian description. The thermodynamic consistency is established by using the Clausius–Duhem inequality through a procedure that involves two uncommon features. Firstly, the entropy production is regarded as a positive-valued constitutive function per se. This view implies that the inequality is in fact an equation. Secondly, this statement of the second law is investigated by using an algebraic representation formula, thus arriving at quite general results for rate terms that are usually overlooked in thermodynamic analyses. Starting from strain-rate or stress-rate equations, the corresponding finite equations are derived. It then emerges that a greater generality of the constitutive equations of the classical models, such as those of Boltzmann and Maxwell, are obtained as special cases. Full article

We present a macroscale constitutive model that couples magnetism with thermal, elastic, plastic, and damage effects in an Internal State Variable (ISV) theory. Previous constitutive models did not include an interdependence between the internal magnetic (magnetostriction and magnetic flux) and mechanical fields. Although constitutive models explaining the mechanisms behind mechanical deformations caused by magnetization changes have been presented in the literature, they mainly focus on nanoscale structure–property relations. A fully coupled multiphysics macroscale ISV model presented herein admits lower length scale information from the nanoscale and microscale descriptions of the multiphysics behavior, thus capturing the effects of magnetic field forces with isotropic and anisotropic magnetization terms and moments under thermomechanical deformations. For the first time, this ISV modeling framework internally coheres to the kinematic, thermodynamic, and kinetic relationships of deformation using the evolving ISV histories. For the kinematics, a multiplicative decomposition of deformation gradient is employed including a magnetization term; hence, the Jacobian represents the conservation of mass and conservation of momentum including magnetism. The first and second laws of thermodynamics are used to constrain the appropriate constitutive relations through the Clausius–Duhem inequality. The kinetic framework employs a stress–strain relationship with a flow rule that couples the thermal, mechanical, and magnetic terms. Experimental data from the literature for three different materials (iron, nickel, and cobalt) are used to compare with the model’s results showing good correlations. Full article

The paper investigates the techniques associated with the exploitation of the second law of thermodynamics as a restriction on the physically admissible processes. Though the exploitation consists of the use of the arbitrariness occurring in the Clausius–Duhem inequality, the approach emphasizes two uncommon features within the thermodynamic analysis: the representation formula, of vectors and tensors, and the entropy production. The representation is shown to be fruitful whenever more terms of the Clausius–Duhem inequality are not independent. Among the examples developed to show this feature, the paper yields the constitutive equation for hypo-elastic solids and for Maxwell–Cattaneo-like equations of heat conduction. The entropy production is assumed to be given by a constitutive function per se and not merely the expression inherited by the other constitutive functions. This feature results in more general expressions of the representation formulae and is crucial for the compact description of hysteretic phenomena. Full article

Phenomenological constitutive models with internal variables have been applied for a wide range of material behavior. The developed models can be classified as related to the single internal variable formalism based on the thermodynamic approach by Coleman and Gurtin. The extension of this theory to so-called dual internal variables opens up new avenues for the constitutive modeling of macroscopic material behavior. This paper reveals the distinction between constitutive modeling with single and dual internal variables using examples of heat conduction in rigid solids, linear thermoelasticity, and viscous fluids. A thermodynamically consistent framework for treating internal variables with as little a priori knowledge as possible is presented. This framework is based on the exploitation of the Clausius–Duhem inequality. Since the considered internal variables are “observable but not controllable”, only the Onsagerian procedure with the use of the extra entropy flux is appropriate for the derivation of evolution equations for internal variables. The key distinctions between single and dual internal variables are that the evolution equations are parabolic in the case of a single internal variable and hyperbolic if dual internal variables are employed. Full article

Models of ferromagnetic hysteresis are established by following a thermodynamic approach. The class of constitutive properties is required to obey the second law, expressed by the Clausius–Duhem inequality, and the Euclidean invariance. While the second law states that the entropy production is non-negative for every admissible thermodynamic process, here the entropy production is viewed as a non-negative constitutive function. In a three-dimensional setting, the magnetic field and the magnetization are represented by invariant vectors. Next, hysteretic properties are shown to require that the entropy production is needed in an appropriate form merely to account for different behavior in the loading and the unloading portions of the loops. In the special case of a one-dimensional setting, a detailed model is determined for the magnetization function, in terms of a given susceptibility function. Starting from different initial magnetized states, hysteresis cycles are obtained by solving a nonlinear ordinary differential system. Cyclic processes with large and small amplitudes are established for materials such as soft iron. Full article

The idea of a canonical ensemble from Gibbs has been extended by Jean-Marie Souriau for a symplectic manifold where a Lie group has a Hamiltonian action. A novel symplectic thermodynamics and information geometry known as “Lie group thermodynamics” then explains foliation structures of thermodynamics. We then infer a geometric structure for heat equation from this archetypal model, and we have discovered a pure geometric structure of entropy, which characterizes entropy in coadjoint representation as an invariant Casimir function. The coadjoint orbits form the level sets on the entropy. By using the KKS 2-form in the affine case via Souriau’s cocycle, the method also enables the Fisher metric from information geometry for Lie groups. The fact that transverse dynamics to these symplectic leaves is dissipative, whilst dynamics along these symplectic leaves characterize non-dissipative phenomenon, can be used to interpret this Lie group thermodynamics within the context of an open system out of thermodynamics equilibrium. In the following section, we will discuss the dissipative symplectic model of heat and information through the Poisson transverse structure to the symplectic leaf of coadjoint orbits, which is based on the metriplectic bracket, which guarantees conservation of energy and non-decrease of entropy. Baptiste Coquinot recently developed a new foundation theory for dissipative brackets by taking a broad perspective from non-equilibrium thermodynamics. He did this by first considering more natural variables for building the bracket used in metriplectic flow and then by presenting a methodical approach to the development of the theory. By deriving a generic dissipative bracket from fundamental thermodynamic first principles, Baptiste Coquinot demonstrates that brackets for the dissipative part are entirely natural, just as Poisson brackets for the non-dissipative part are canonical for Hamiltonian dynamics. We shall investigate how the theory of dissipative brackets introduced by Paul Dirac for limited Hamiltonian systems relates to transverse structure. We shall investigate an alternative method to the metriplectic method based on Michel Saint Germain’s PhD research on the transverse Poisson structure. We will examine an alternative method to the metriplectic method based on the transverse Poisson structure, which Michel Saint-Germain studied for his PhD and was motivated by the key works of Fokko du Cloux. In continuation of Saint-Germain’s works, Hervé Sabourin highlights the, for transverse Poisson structures, polynomial nature to nilpotent adjoint orbits and demonstrated that the Casimir functions of the transverse Poisson structure that result from restriction to the Lie–Poisson structure transverse slice are Casimir functions independent of the transverse Poisson structure. He also demonstrated that, on the transverse slice, two polynomial Poisson structures to the symplectic leaf appear that have Casimir functions. The dissipative equation introduced by Lindblad, from the Hamiltonian Liouville equation operating on the quantum density matrix, will be applied to illustrate these previous models. For the Lindblad operator, the dissipative component has been described as the relative entropy gradient and the maximum entropy principle by Öttinger. It has been observed then that the Lindblad equation is a linear approximation of the metriplectic equation. Full article

This paper develops a phase-field approach to describe the damage within continuum mechanics. The body is associated with the standard stresses and body forces of macroscopic character. As is the case in many contexts, the phase field is a scalar variable whose time rate is governed by a constitutive equation. The generality of the approach allows the modeling of non-stationary heat conduction, mechanical hysteretic effects, and the macroscopic damage. The thermodynamic consistency is investigated through the constraint of the Clausius–Duhem inequality following the standard procedure of Rational Thermodynamics. The entropy production is considered as a constitutive function; this view was proved to be essential in the elaboration of hysteretic models. Here, the scheme is improved by viewing the entropy production as a sum of two terms, one induced by the other constitutive equations and one given by a constitutive equation of the entropy production per se. Full article

Filled rubber has been extensively used in the repairing, retrofitting, and protecting of civil infrastructures due to its superior physical and mechanical properties. However, effects of large deformation and velocity impacts on the mechanical behavior of filled rubber are not well recognized, one of the major challenges in the past investigations is that the material exhibits significant nonlinearity and sensitivity to velocity. This paper presents a hyper-viscoelastic constitutive modeling and experimental study to capture both the hyperelastic and viscoelastic behaviors of filled rubber under large shear deformation and velocity impacts. Motivated by the micro-mechanism of filled rubber, the constitutive modeling consists of an equilibrium element in parallel with an improved Maxwell element to incorporate both nonlinear hyperelasticity and rate-dependent performance governed by the readjustment and rearrangement of molecular chains in the material. A new strain energy function is developed and the physical description of parameters in the strain energy function is highlighted. The Clausius-Duhem inequality is employed to consider the thermodynamic consistency of the model. Then, stress relaxation property and stress-strain response of filled rubber upon cyclic shear loading with different strain rates (ranging from 0.08 to 12.0 s⁻¹) are experimentally studied, and some key observations are summarized. Subsequently, a “Gau-Poly” function is proposed based on the experimental data to describe the viscoelastic property of filled rubber versus strain and strain rate. Finally, stress-strain relationship and hysteretic area obtained from the experimental results were compared with the numerical results of the model, good agreement was achieved and the capacity of the model to accurately reproduce the mechanical behavior of filled rubber under a wide range of deformation and velocity impacts was verified. Full article

Bulk kinematic properties of mixtures such as velocity are known to be the density weighed averages of the constituent velocities. No such paradigm exists for the heat flux of mixtures when the constituents have different temperatures. Using standard principles such as frame indifference, we address this topic by developing linear constitutive equations for the constituent heat fluxes, the interaction force between constituents, and the stresses for a mixture of two fluids. Although these equations contain 18 phenomenological coefficients, we are able to use the Clausius-Duhem inequality to obtain inequalities involving the principal and cross flux coefficients. The theory is applied to some special cases and shown to reduce to standard results when the constituents have the same temperature. Full article

Flowing media in both industrial and natural processes are often characterized as assemblages of densely packed granular materials. Typically, the constitutive relations for the stress tensor and heat flux vector are fundamentally nonlinear. Moreover, these equations are coupled through the Clausius–Duhem inequality. However, the consequences of this coupling are rarely studied. Here we address this issue by obtaining constraints imposed by the Clausius–Duhem inequality on the constitutive relations for both the stress tensor and the heat flux vector in which the volume fraction gradient plays an important role. A crucial result of the analysis is the restriction on the dependency of phenomenological coefficients appearing in the constitutive equations on the model objective functions. Full article