Search Results (6)

As a graphene-like material, h-BN has stimulated great research interest recently due to its potential application for next-generation electronic devices. Herein, a systematic theoretical investigation of electronic structures and optical properties of C-doped and Cu-Al co-doped h-BN is carried out by the first-principles calculations. Firstly, two different C-doped h-BN structures for the para-position and ortho-position are constructed. The results show that the C ortho-doped h-BN (BCN) structure with a band gap of 3.05 eV is relatively stable, which is selected as a substate to achieve the Cu-Al co-doped h-BN. Based on this, the effect of the concentration of C atom doping on the electronic and optical properties of Cu-Al co-doped BC_xN (x = 0, 11.1% and 22.2%) is investigated. The results demonstrate that the band gap of Cu-Al co-doped BC_xN decreases and the optical properties improve with the increase in C atom concentration. The band gap and static dielectric constant of Cu-Al co-doped BC₀N, BC₁N and BC₂N are 0.98 eV, 0.87 eV and 0.23 eV and 2.34, 3.03 and 3.77, respectively. As for all Cu-Al co-doped BC_xN systems, the adsorption peak is red-shifted, and the peak intensity obviously decreases compared to the undoped h-BN. Additionally, the Cu-Al co-doped BC₂N exhibits the best response to visible light. This work will provide valuable guidance for designing and developing h-BN-based doping systems with good performance in the field of optical and photocatalysis. Full article

Abradable seal coatings represent a critical technology within the realm of advanced power systems, designed to minimize airflow channel leakage, thereby reducing energy consumption and enhancing overall efficiency. In the present study, CuAl/BN, CuAlLaF₃/BN, and CuAlY/BN abradable seal coatings were prepared using plasma spraying technology. Both the as-deposited coatings and high-temperature oxidation-treated coatings were comprehensively investigated by means of scanning electron microscopy (SEM), open-circuit potentials (OCP), potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), salt-spray corrosion testing, and bond strength evaluations. The results show that the addition of rare earth elements to the CuAl/BN coatings does not enhance the corrosion resistance of the coatings and even leads to a decrease in the corrosion resistance of the coatings. In contrast, the CuAlY/BN coatings exhibited a significant improvement in corrosion resistance following an oxidation treatment at 550 °C. This enhancement is attributed to the yttrium (Y) element, which facilitates the formation of passivation films and confers a resistance effect, thereby bolstering the coatings’ resistance to corrosion. The bond strength of the high-temperature oxidation-treated CuAlY/BN coating was improved by about 30% after 960 h of salt-spray corrosion. Full article

The size and distribution of the silicon phase and intermetallic phase are important factors affecting the properties of Al₁₁Si₃Cu₂NiMg alloy (M142). In this study, BNNS and micro-TiB₂ were used to synergistically refine and reinforce M142 composites (M142-BNNS-TiB₂). After T6 heat treatment, the comprehensive mechanical properties of M142-BN-TiB₂ composites were excellent, with an ultimate tensile strength of 463 MPa and an elongation of 2.6%. In addition, the introduction of BNNS and micro-TiB₂ changed the fracture mode of M142 from brittle fracture to quasi-cleavage fracture, and the introduction of BNNS and micro-TiB₂ refined the Si phase and intermetallic phase, which could change the origin of the crack in the composite, thus improving the ductility of the composite. Full article

Al(III) complexes have been recently investigated for their potential use in imaging with positron emission tomography (PET) by formation of ternary complexes with the radioisotope fluorine-18 (¹⁸F). Although the derivatives of 1,4,7-triazacyclononane-1,4,7-triacetic acid (NOTA) are the most applied chelators for [Al¹⁸F]²⁺ labelling and (pre)clinical PET imaging, non-macrocyclic, semi-rigid pentadentate chelators having two N- and three O-donor atoms such as RESCA1 and AMPDA-HB have been proposed with the aim to allow room temperature labelling of temperature-sensitive biomolecules. The paucity of stability data on Al(III) complexes used for PET imaging instigated a complete thermodynamic and kinetic solution study on Al(III) complexes with aminomethylpiperidine (AMP) derivatives AMPTA and AMPDA-HB and the comparison with a RESCA1-like chelator CD3A-Bn (trans-1,2-diaminocyclohexane-N-benzyl-N,N′,N′-triacetic acid). The stability constant of [Al(AMPDA-HB)] is about four orders of magnitude higher than that of [Al(AMPTA)] and [Al(CD3A-Bn)], highlighting the greater affinity of phenolates with respect to acetate O-donors. On the other hand, the kinetic inertness of the complexes, determined by following the Cu²⁺-mediated transmetallation reactions in the 7.5–10.5 pH range, resulted in a spontaneous and hydroxide-assisted dissociation slightly faster for [Al(AMPTA)] than for the other two complexes (t_1/2 = 4.5 h for [Al(AMPTA)], 12.4 h for [Al(AMPDA-HB)], and 24.1 h for [Al(CD3A-Bn)] at pH 7.4 and 25 °C). Finally, the [AlF]²⁺ ternary complexes were prepared and their stability in reconstituted human serum was determined by ¹⁹F NMR experiments. Full article

The purpose of this paper is to study the effects of the use of boron nitride (BN) and other conventional nanoparticles (Al₂O₃, CuO and TiO₂) on pressure drop and heat transfer in a microchannel. The governing equations for forced fluid flow and heat transfer were worked out by using fluent computational fluid dynamics (CFD) code. Computational results collected from fluent CFD code for Al₂O₃ as the nano-particle were compared with numerical values used in the literature for validation. The basis of a water-cooled (pure water, Al₂O₃/Water, CuO/Water, TiO₂/Water and BN/Water) smooth microchannel was outlined, and then the corresponding laminar flow and heat transfer were evaluated numerically. The results from the numerical tests (NT) express good agreement with the values found in the literature. These results also indicate, through the comparison which was performed by taking the heat transfer and pressure loss parameters between BN and other widely used conventional nanoparticles (Al₂O₃, CuO and TiO₂) into consideration, that BN is the more favorable nanoparticle. In comparison to other common nanoparticles (Al₂O₃, CuO and TiO₂), BN enhances heat transfer and slightly raised pressure losses owing to its high thermal conductivity and high velocity profile because of low density. It is also chemically stable at the highest temperature relative to most solid materials. Thus, it has a structure that can be used in cooling systems for a long time without causing a problem of agglomeration. Full article

In this study, we investigated the galvanic corrosion performance of an Aluminum–Boron Nitride (Al–BN) abradable seal coating system (with a Ni5Al bond layer and a 0Cr17Ni4Cu4Nb substrate) in chloride solution by electrochemical methods. The results indicated a three-stage process occurred during the anodic dissolution of the coupled coating system, consisting of a spontaneous pitting stage I under charge transfer control with a decreasing rate, a corrosion developing stage II under mass transfer control with an increasing rate, and a final steady stage III. Precipitation of Al(OH)₃ restricts the oxygen transport process to the cathode and induces localized acidification of the occluded pores of the Al–BN layer, which was the mechanism that could explain the changes of corrosion performance during the three immersion stages of Al–BN coating system. The study suggests that galvanic corrosion of the porous multi-layer Al–BN abradable coating system is mostly influenced by its corrosion product deposition. Full article