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Keywords = REE enrichment

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29 pages, 47976 KB  
Article
An Occurrence of Pyroxmangite in the NYF Granitic Pegmatite of the Gabal El-Bakriya Intrusion, Arabian–Nubian Shield
by Danial M. Fathy, Faris A. Abanumay, Shehata Ali, Esam S. Farahat, Andrey Bekker and Mokhles K. Azer
Minerals 2025, 15(10), 1027; https://doi.org/10.3390/min15101027 - 28 Sep 2025
Viewed by 213
Abstract
We report here, for the first time on the Nubian Shield, the western half of the Arabian–Nubian Shield (ANS), pegmatite-hosted pockets with a unique mineralogy, including pyroxmangite. It represents the second discovery on the ANS, where the first one was at Jabal Aja [...] Read more.
We report here, for the first time on the Nubian Shield, the western half of the Arabian–Nubian Shield (ANS), pegmatite-hosted pockets with a unique mineralogy, including pyroxmangite. It represents the second discovery on the ANS, where the first one was at Jabal Aja on the Arabian Shield, the eastern half of the ANS. One of the most remarkable aspects of pyroxmangite is its rarity and the potential economic value of its use in jewelry and decorative applications. Pegmatites are associated with A-type granites of the Gabal El-Bakriya intrusion (GEBI), Eastern Desert, Egypt. Mineralized pegmatites occur at the margin of the alkali-feldspar granite and exhibit gradational contacts with the host rocks. The pegmatites were emplaced as plugs and dikes within the intrusion and along its periphery. Pyroxmangite appears as coarse-grained, massive black aggregates or as disseminated crystals. The pegmatites are composed of K-feldspars and quartz, with subordinate amounts of albite, micas, and mafic minerals. Accessory phases include monazite-(Ce), zircon, fergusonite, xenotime, fluorite, pyrochlore, allanite, thorite, bastnäsite, samarskite, cassiterite, beryl, and pyrochlore. Pyroxmangite-bearing assemblages consist essentially of pyroxmangite and garnet, with accessory pyrochroite, quartz, zircon, magnetite, and fluorite. Geochemically, the pegmatites are highly evolved, with elevated SiO2 content (76.51–80.69 wt.%) and variable concentrations of trace elements. They show significant enrichment in Nb (Nb > Ta), Y, REE, Zr, Th, U, and F, consistent with NYF-type pegmatites. REE contents range from 173.94 to 518.21 ppm, reflecting diverse accessory mineral assemblages. Tectonically, the pegmatites crystallized in a post-collisional setting, representing a late-stage differentiate of the A-type GEBI magma. Mineralization is concentrated in the apical and marginal zones of the granitic cupola and is dominated by barite, fluorite, Nb-Ta oxides, REE minerals, and uranium-bearing phases. The highly evolved granites, greisens, pegmatites, and quartz-fluorite veins of the GEBI have a high economic potential, deserving further exploration. Full article
(This article belongs to the Special Issue Igneous Rocks and Related Mineral Deposits)
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18 pages, 5103 KB  
Article
Geochemical Characterisation of Strategic Elements (Li, Co, Ni, Cu, Ga, Ge, and REEs) in Bottom Ash from the Thermal Power Plant (Afşin–Elbistan, Türkiye)
by Leyla Kalender, Hatice Kara, Mehmet Ali Ertürk, Cihan Yalçın, Mehmet Deniz Turan and Emine Cicioğlu Sütçü
Minerals 2025, 15(10), 1026; https://doi.org/10.3390/min15101026 - 28 Sep 2025
Viewed by 288
Abstract
This study investigates the concentrations and geochemical behaviour of strategic elements—including Li, Co, Ni, Cu, Ga, Ge, rare earth elements (REEs), and yttrium (Y)—in bottom ash samples from the Afşin–Elbistan thermal power plant, Türkiye. Thirty bottom ash samples were analysed, revealing average ∑LREE [...] Read more.
This study investigates the concentrations and geochemical behaviour of strategic elements—including Li, Co, Ni, Cu, Ga, Ge, rare earth elements (REEs), and yttrium (Y)—in bottom ash samples from the Afşin–Elbistan thermal power plant, Türkiye. Thirty bottom ash samples were analysed, revealing average ∑LREE and ∑HREE concentrations of 86.3 µg/g and 3.3 µg/g, respectively, resulting in an L/H ratio of 24.9, indicating pronounced enrichment in light REEs. The total ∑REE + Y concentration (111 µg/g) is comparable to the background value for coal but approximately 1.5 times lower than those reported for average Chinese coals and the upper continental crust (UCC). REE contents significantly exceed those of sedimentary (5.36 µg/g), mafic (16.77 µg/g), and felsic (3.60 µg/g) rocks. Elevated Li (30.5 µg/g) and Ni (114.4 µg/g) concentrations point to a mafic magmatic source, whereas Cu (28.7 µg/g) likely originates from basic volcanic rocks such as those of the Dağlıca Complex and the Kemaliye Formation. Chondrite-normalised REE patterns show Dy depletion relative to mafic rocks and Ho depletion compared to sedimentary rocks. Positive δEu anomalies (>1) support a mafic or UCC provenance, while slightly positive δCe values indicate hydrothermal leaching influences. The co-precipitation of Ce with Ca–Mg hydroxides and clay minerals in coal-bearing lacustrine sediments is suggested. Ga enrichment is attributed to aluminium-rich clay minerals and organic matter. Overall, these geochemical signatures reflect combined inputs from hydrothermal leaching and volcanic weathering within a coal-bearing lacustrine environment. Full article
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14 pages, 1352 KB  
Article
Ecological Imprint of Rare Earth Mining on Microbial Communities and Water Quality Across Depth and Distance Gradients in Ganzhou, China
by Yian Wang, Fei Shi, Fengxiang Lang, Guohua Wang, Yan Mao, Yingjie Xiao, Li Yin, Genhe He and Yonghui Liao
Microorganisms 2025, 13(10), 2236; https://doi.org/10.3390/microorganisms13102236 - 24 Sep 2025
Viewed by 354
Abstract
Rare earth element (REE) mining exerts profound impacts on aquatic ecosystems, yet the microbial community responses and water quality under such stress remain underexplored. In this study, the surface (0.2 m) and subsurface (1.0 m) water along a spatial transect from proximal to [...] Read more.
Rare earth element (REE) mining exerts profound impacts on aquatic ecosystems, yet the microbial community responses and water quality under such stress remain underexplored. In this study, the surface (0.2 m) and subsurface (1.0 m) water along a spatial transect from proximal to distal points was investigated in a REE-mining area of Ganzhou, China. Physicochemical analyses revealed pronounced gradients of nitrogen (e.g., NH4+−N, NO3−N), heavy metals (e.g., Mn, Zn, Pb), and REEs (e.g., La, Nd, Ce), with higher accumulation near mining sources and partial attenuation downstream. Dissolved oxygen and redox potential indicated mildly reducing conditions at contaminated points, potentially promoting denitrification and altering nitrogen cycling. Metagenomic sequencing showed significant shifts in microbial community composition, with enrichment of metal- and nitrogen-tolerant taxa, and key denitrifiers (e.g., Acidovorax, Bradyrhizobium, Rhodanobacter), particularly at upstream polluted points. KEGG-based gene annotation highlighted dynamic nitrogen transformations mediated by multiple pathways, including nitrification, denitrification, dissimilatory nitrate reduction to ammonium, and nitrogen fixation. Notably, genes associated with nitrite and nitrate reduction (e.g., nir, nar, nrf) were enriched near mining sources, indicating enhanced nitrogen conversion potential, while downstream activation of nitrogen-fixing genes suggested partial ecosystem recovery. Meanwhile, some microbial such as Variovorax carried metal tolerant genes (e.g., ars, chr, cnr). These findings demonstrate that REE and heavy metal contamination restructure microbial networks, modulate nitrogen cycling, and create localized ecological stress gradients. This study provides a comprehensive assessment of mining-related water pollution, microbial responses, and ecological risks, offering valuable insights for monitoring, restoration, and sustainable management of REE-impacted aquatic environments. Full article
(This article belongs to the Section Environmental Microbiology)
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19 pages, 8169 KB  
Article
Preparation of a Porous Tri-n-decylamine Modified Adsorbent for the Efficient Removal of Uranium and Iron from Rare Earth
by Zihang Yi, Lifeng Chen, Shichang Zhang, Juan Liu, Zhifu Ye, Mohammed F. Hamza, Yuezhou Wei and Shunyan Ning
Metals 2025, 15(10), 1064; https://doi.org/10.3390/met15101064 - 23 Sep 2025
Viewed by 244
Abstract
The presence of impurities Fe and trace radioactive U in rare earth elements (REEs) may lead to a significant decline in the performance of high-purity rare earth products. For deep removal from REEs in a green and efficient way, an amine-functionalized silica-based adsorbent, [...] Read more.
The presence of impurities Fe and trace radioactive U in rare earth elements (REEs) may lead to a significant decline in the performance of high-purity rare earth products. For deep removal from REEs in a green and efficient way, an amine-functionalized silica-based adsorbent, TNDA/SiO2-P, was prepared by a simple vacuum impregnation method, which had a high organic loading rate of 31.2 wt.%. The experimental results showed that it exhibited good adsorption selectivity for uranium and iron, with separation factors SFU/REE = 20147 and SFFe/REE = 88128 in 5 M HCl. The adsorption kinetics was fast, with equilibrium obtained in 120 min. The 0.1 M HCl can desorb U and Fe efficiently. The deep removal of U and Fe from REEs including Sc can be achieved through chromatographic column separation with high enrichment. FT-IR, XPS and DFT calculations mutually confirmed that protonated TNDA/SiO2-P exhibited a selective mechanism for uranium and iron in complex anion species in the hydrochloric acid system. This demonstrates its potential for efficiently removing trace impurities U and Fe from REEs. Full article
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27 pages, 3998 KB  
Article
Geochemical Features and Mobility of Trace Elements in Technosols from Historical Mining and Metallurgical Sites, Tatra Mountains, Poland
by Magdalena Tarnawczyk, Łukasz Uzarowicz, Wojciech Kwasowski, Artur Pędziwiatr and Francisco José Martín-Peinado
Minerals 2025, 15(9), 988; https://doi.org/10.3390/min15090988 - 17 Sep 2025
Cited by 1 | Viewed by 293
Abstract
Ore mining and smelting are often related to environmental pollution. This study provides information about the geochemical features of Technosols at historical mining and metallurgical sites in the Tatra Mountains, southern Poland, evaluating the contents of potentially toxic trace elements (PTTE) and their [...] Read more.
Ore mining and smelting are often related to environmental pollution. This study provides information about the geochemical features of Technosols at historical mining and metallurgical sites in the Tatra Mountains, southern Poland, evaluating the contents of potentially toxic trace elements (PTTE) and their behaviours in soils, as well as the influence of soil properties on PTTE mobility. Thirteen soil profiles were studied in eight abandoned mining and smelting sites. PTTE concentrations, including rare earth elements (REE), were measured using ICP-MS and ICP-OES. Selected elements (Cu, Zn, Pb, Cd, As, Sb, Ba, Sr, Co, Ni, Mn and Cr) were fractionated using the modified European Community Bureau of Reference (BCR) four-step sequential extraction. Contamination of soils with PTTE was compared against Polish regulatory limits, which were exceeded for Cu, Zn, Pb, Mo, Hg, As, Co, Ni and Ba, with concentrations exceeding limits by 16, 18, 34 and 160 times for Cu, Hg, As and Ba, respectively, in some profiles. Based on geochemical features depending on parent material properties, the soils examined were divided into three groups. Group I Technosols (near-neutral soils developed from Fe/Mn-ore and carbonate-bearing mining waste) were particularly enriched in Co, Ni, Mn and REE. Group II Technosols (acidic soils developed from polymetallic ore-bearing aluminosilicate mining waste) contained elevated concentrations of Cu, Zn, Hg, As, Sb, Bi, Co, Ag, Ba, Sr, U and Th; they contained lower contents of REE than Group I Technosols. Group III Technosols (soils developed in smelting-affected areas and containing metallurgical waste) were rich in Cu, As, Sb, Ba, Hg, Co and Ag and contained the lowest REE contents among the studied soils. Sequential BCR extraction revealed that PTTE mobility varied strongly according to soil group, with higher mobility of Mn, Cu and Zn in acidic polymetallic ore-derived soils (Group II), while carbonate-rich soils (Group I) showed mainly immobile forms. Metallurgical slag-derived soils (Group III) exhibited complex PTTE behaviour controlled by organic matter and Fe/Mn oxides. Soil properties (pH, carbonates and TOC) seem to control PTTE mobility. Full article
(This article belongs to the Section Environmental Mineralogy and Biogeochemistry)
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13 pages, 2034 KB  
Article
Rare Earth Elements in Bottom Sediments of the Northern Part of Lake Umbozero, Murmansk Region, Russia
by Eugenia Krasavtseva, Sergey Sandimirov, Irina Elizarova, Maria Malysheva, Dmitriy Makarov and Nikolay Kaganovich
Minerals 2025, 15(9), 973; https://doi.org/10.3390/min15090973 - 14 Sep 2025
Viewed by 383
Abstract
The chemical composition of bottom sediments in the northern part of Lake Umbozero, located in close proximity to a closed rare metal mine in the Murmansk Region, was studied. This study is a continuation of our research into the impact of closed rare [...] Read more.
The chemical composition of bottom sediments in the northern part of Lake Umbozero, located in close proximity to a closed rare metal mine in the Murmansk Region, was studied. This study is a continuation of our research into the impact of closed rare metal mines and tailings on the environment. Samples were collected using an open gravity sampler in two sections of the lake in three replicates. The content of rare earth elements was determined using inductively coupled plasma mass spectrometry. The total content of elements was determined both in the surface layers of bottom sediments and in the deep layers that were formed in the preindustrial period and, thus, characterize the geochemical background of the study area. The average ∑REE in the surface layers of bottom sediments of Lake Umbozero in the wastewater reception area (Site 1) reaches 774 mg/kg, while for the area located north of the discharge site (Site 2), ∑REE was 208 mg/kg. The enrichment factor (EF), the geoaccumulation index (Igeo), the coefficient of the index of potential ecological risk (Eir) and the index of potential ecological hazard (RI) were calculated. Assessing the total pollution of bottom sediments of Lake Umbozero with rare earth elements, the value of potential ecological risk reaches values corresponding to the level of low and moderate ecological risk of pollution (RISite 1 = 164; RISite 2 = 104). The conducted correlation analysis allowed us to establish the main phases containing rare earth elements in the bottom sediments of Lake Umbozero—oxyhydroxide complex compounds with iron and manganese. Full article
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15 pages, 2807 KB  
Article
Investigation of the Coloration Mechanisms of Yellow-Green Nephrite from Ruoqiang (Xinjiang), China
by Boling Huang, Mingxing Yang, Xihan Yang, Xuan Wang, Ting Fang, Hongwei Han and Shoucheng Wang
Minerals 2025, 15(9), 961; https://doi.org/10.3390/min15090961 - 10 Sep 2025
Viewed by 455
Abstract
This study systematically investigates the color origin and coloration mechanisms of yellow-green nephrite from Ruoqiang, Xinjiang, using multiple analytical techniques including hyperspectral colorimetry, X-ray fluorescence (XRF) spectroscopy, titrimetry, laser ablation inductively coupled plasma–mass spectrometry (LA-ICP-MS), Raman spectroscopy and ultraviolet–visible (UV-Vis) spectroscopy. A pioneering [...] Read more.
This study systematically investigates the color origin and coloration mechanisms of yellow-green nephrite from Ruoqiang, Xinjiang, using multiple analytical techniques including hyperspectral colorimetry, X-ray fluorescence (XRF) spectroscopy, titrimetry, laser ablation inductively coupled plasma–mass spectrometry (LA-ICP-MS), Raman spectroscopy and ultraviolet–visible (UV-Vis) spectroscopy. A pioneering quantitative model (R2 = 0.942) was established between hue (H) and the Fe2O3 ratio (Fe2O3/TFe), revealing that the coloration mechanism is jointly governed by Fe3+ charge transfer (300–400 nm absorption band) and Fe2+→Fe3+ transitions (600–630 nm absorption band). Furthermore, the intensity variation in the 3651 cm−1 Raman peak serves to further confirm the critical role of Fe3+ occupancy in the tremolite lattice for color modulation. In combination with the partition patterns of Rare Earth elements (REEs) (right-leaning LREE distribution with negative Eu anomaly) and trace element characteristics, this study supports the classification of Ruoqiang yellow-green nephrite as a high oxygen fugacity magnesian marble-type deposit. In this type of deposit, the ore-forming environment facilitates Fe3+ enrichment and yellow-green hue formation. The findings provide new theoretical insights into the chromatic genesis of yellow-green nephrite and hold significant implications for its identification, quality grading, and research on metallogenic mechanisms. Full article
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24 pages, 9433 KB  
Article
Enrichment and Fractionation of Rare Earth Elements in High-Altitude Thick Weathered Crust Elution-Deposited Rare Earth Ore
by Zhenyue Zhang, Dan Li, Fei Long, Ruan Chi and Zhuo Chen
Minerals 2025, 15(9), 932; https://doi.org/10.3390/min15090932 - 1 Sep 2025
Viewed by 566
Abstract
Weathered crust elution-deposited rare earth ores (WCE-REOs) are the primary global source of medium and heavy rare earth elements (M/HREEs). The recent discovery of high-altitude (1500–2500 m) WCE-REOs in southern Yunnan Province, China, presents new opportunities for the development of M/HREE resources. This [...] Read more.
Weathered crust elution-deposited rare earth ores (WCE-REOs) are the primary global source of medium and heavy rare earth elements (M/HREEs). The recent discovery of high-altitude (1500–2500 m) WCE-REOs in southern Yunnan Province, China, presents new opportunities for the development of M/HREE resources. This study investigates the enrichment and fractionation mechanisms of rare earth elements (REEs) in these deposits through a systematic analysis of three representative weathering profiles associated with the Lincang granite batholith. The analytical results indicate that the profiles consist mainly of clay minerals (kaolinite, halloysite, illite, minor montmorillonite) and iron oxides, with high SiO2 (64.10–74.40 wt.%) and Al2O3 (15.50–20.20 wt.%) and low CaO/MgO—typical of weathered REE deposits. The total REE contents (238.12–1545.53 ppm) show distinct fractionation: LREE-enriched upper layers and HREE-enriched deeper zones. Sequential extraction revealed that the REEs in the Lincang granite weathering profiles predominantly occur in ion-exchangeable, residual, and iron-manganese oxide-bound states (>95% total REEs). Ion-exchangeable REEs showed depth-dependent enrichment (peaking at 819.96 ppm), while iron-manganese oxides exhibited a strong REE affinity (up to 47% total REEs), with amorphous phases that were preferentially enriched in Ce (partitioning >80%). Fissure systems exerted critical control over the redistribution of elements, particularly REEs. Full article
(This article belongs to the Section Mineral Processing and Extractive Metallurgy)
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22 pages, 4916 KB  
Article
The Genesis and Geological Significance of the Chaluo Granite in Yidun Magmatic Arc, Western Sichuan, China: Constraints from the Zircon U-Pb Chronology, Elemental Geochemistry and S-Pb-Hf Isotope
by Wenjing Yang, Tianshe Cheng, Xuebin Zhang, Lijun Guo, Xujiang Cheng, Xingfang Duo, Hangyu Fan, Hongsheng Gao, Lipeng Tu, Meng Zhao and Weihong Dong
Minerals 2025, 15(9), 916; https://doi.org/10.3390/min15090916 - 28 Aug 2025
Viewed by 604
Abstract
The Chaluo granite is situated in the middle section of the Yidun magmatic arc in western Sichuan Province, China. It holds great significance for the study of the geological evolution of the Paleo-Neotethys tectonic belts. The Chaluo granite mainly consists of alkaline feldspar, [...] Read more.
The Chaluo granite is situated in the middle section of the Yidun magmatic arc in western Sichuan Province, China. It holds great significance for the study of the geological evolution of the Paleo-Neotethys tectonic belts. The Chaluo granite mainly consists of alkaline feldspar, quartz, and biotite, with a small amount of apatite. LA-ICP-MS zircon U-Pb dating yielded crystallization ages of (87 ± 3) Ma for the Chaluo granite, indicating its formation in the Late Cretaceous. Elemental geochemical testing results showed that the Chaluo granite exhibits I-type granite characteristics. It has undergone significant fractional crystallization processes, with high SiO2 contents (72.83–76.63 wt%), K (K2O/Na2O = 1.33–1.53), Al2O3 (Al2O3 = 12.24–13.56 wt%, A/CNK = 0.91–1.08), and a high differentiation index (DI = 88.91–92.49). Notably, the MgO contents were low (0.10–0.26 wt%), and there were significant depletions of Nb, Sr, Ti, and Eu, while Rb, Pb, Th, U, Zr, and Hf were significantly enriched. The total rare earth element (REE) contents were relatively low (211–383 ppm), showing significant light REE (LREE) enrichment (LREE/HREE = 4.46–5.57) and a pronounced negative Eu anomaly (δEu = 0.09–0.17). In situ zircon Hf analyses, combined with 206Pb/238U ages, gave εHf(t) values ranging from −3.8 to 1.72 and two-stage Hf ages (tDM2) of 875–1160 Ma. Together with the S and Pb isotope compositions of the Chaluo granite, its magma likely originated from the partial melting of Middle–Neoproterozoic sedimentary rocks enriched in biogenic S. The tectonic-setting analysis indicates that the Chaluo granite formed in a post-orogenic intracontinental extensional environment. This environment was triggered by the northward subduction-collision of the Lhasa block, followed by slab break-off and the upwelling of the asthenosphere in the Neo-Tethys orogenic belt. We propose that the Paleo-Tethys tectonic belt was influenced by the Neo-Tethys tectonic activity, at least in the Yidun magmatic arc region during the Late Cretaceous. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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21 pages, 19080 KB  
Article
Provenance Evolution Since the Middle Pleistocene in the Western Bohai Sea, North China: Integrated Rare Earth Element Geochemistry and Sedimentological Records
by Shuyu Wu, Jun Liu and Yongcai Feng
J. Mar. Sci. Eng. 2025, 13(9), 1632; https://doi.org/10.3390/jmse13091632 - 26 Aug 2025
Viewed by 1218
Abstract
Despite extensive research on sediment provenance in the Bohai Sea (BS), a significant knowledge gap persists concerning long-term provenance evolution, particularly in the western BS since the Middle Pleistocene. This shortcoming limits reconstructions of paleoenvironmental evolution and its interplay with climatic variability and [...] Read more.
Despite extensive research on sediment provenance in the Bohai Sea (BS), a significant knowledge gap persists concerning long-term provenance evolution, particularly in the western BS since the Middle Pleistocene. This shortcoming limits reconstructions of paleoenvironmental evolution and its interplay with climatic variability and sea-level fluctuations. This study presents integrated Rare Earth Element (REE) geochemical and sedimentological analyses of sediments from core DZQ01 in the western BS. The mean ΣREE concentration of 178.78 μg/g is characterized by pronounced light REE (LREE) enrichment relative to heavy REE (HREE). Chondrite- and upper continental crust (UCC)-normalized patterns exhibit distinct negative Eu anomalies, variable Ce anomalies, marked LREE enrichment, and pronounced LREE/HREE fractionation. Grain size exerts the dominant control on REE distribution, whereas the weak correlation between HREE fractionation parameter indices (e.g., Gd/Yb) and redox-sensitive proxies (e.g., δEuUCC and δCeUCC) confirms their fidelity as provenance indicators. When integrated with the δEuUCC-δCeUCC diagram, discriminant functions, and paleoenvironmental proxies (Rb/Sr and Mg/Ca ratios), the data indicate that, during interglacial highstands, the Yellow River (YR) was the principal source, delivering fine-grained terrigenous material from the Loess Plateau and thereby elevating REE concentrations. Conversely, glacial lowstands shifted the depositional environment to subaerial conditions, with the YR, Hai River, and Luan River supplying a coarse-fine admixture. Multi-river provenance and dilution by coarse detritus collectively lowered REE concentrations during these intervals. Full article
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22 pages, 7924 KB  
Article
Confirmation of Significant Iron Formations During “Boring Billion” in Altyn Region, China: A Case Study of the Dimunalike Iron Deposit
by Wencheng Liu, Fanqi Kong, Haibo Ding, Jing Zhang and Mingtian Zhu
Minerals 2025, 15(9), 905; https://doi.org/10.3390/min15090905 - 26 Aug 2025
Viewed by 658
Abstract
It is generally believed that the ancient oceans during the “boring billion” (1.85–0.8 Ga) lacked the capacity to form large-scale iron formations (IFs), though localized small-scale IFs deposition persisted. The Altyn region of China hosts abundant IFs, with the Dimunalike IFs being the [...] Read more.
It is generally believed that the ancient oceans during the “boring billion” (1.85–0.8 Ga) lacked the capacity to form large-scale iron formations (IFs), though localized small-scale IFs deposition persisted. The Altyn region of China hosts abundant IFs, with the Dimunalike IFs being the largest and most representative, characterized by typical banded iron–silica layers. Detailed fieldwork identified a tuff layer conformably contacting the IFs at the roof rocks of IFs and a ferruginous mudstone layer at the floor rocks of IFs in drill core ZK4312. Geochemical and zircon U-Pb-Hf isotopic analyses were performed. The tuff has a typical tuff structure, mostly made of quartz, and contains a significant amount of natural sulfur. It also has high SiO2 content (77.90%–80.49%) and sulfur content (0.78%–3.06%). The ferruginous mudstone has a volcanic clastic structure and is mainly composed of quartz and chlorite, with abundant coeval pyrite. It shows lower SiO2 content (53.83%–60.32%) and higher TFe2O3 content (10.29%–16.24%). Both layers share similar rare earth element (REE) distribution patterns and trace element compositions, with light REE enrichment and negative Eu, Nb, and Ti anomalies, consistent with arc volcanic geochemistry. Zircon U-Pb ages indicate crystallization of the tuff at 1102 ± 13 Ma and maximum deposition of the mudstone at 1110 ± 41 Ma. These data suggest formation during different stages of the same volcanic–sedimentary process. The εHf(t) values (3.60–12.35 for tuff, 2.92–8.19 for mudstone) resemble those of Algoma-type IF host rocks, implying derivation from re-melted new crust. The Dimunalike IFs likely formed in a submarine volcanic–sedimentary environment. In conclusion, although the Mesoproterozoic ocean was generally in a low-oxygen state, which was not conducive to large-scale IF deposition, localized submarine volcanic–hydrothermal activity could still lead to IF formation. Full article
(This article belongs to the Special Issue Geochemical, Isotopic, and Biotic Records of Banded Iron Formations)
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34 pages, 17975 KB  
Article
Moderate Rare Metal Enrichment by Auto-Assimilation in the Neoproterozoic Gabal Um Samra Granites, Eastern Desert, Egypt
by Heba S. Mubarak, Mokhles K. Azer, Adel A. Surour, Hilmy E. Moussa, Paul D. Asimow and Mona Kabesh
Minerals 2025, 15(9), 898; https://doi.org/10.3390/min15090898 - 24 Aug 2025
Viewed by 658
Abstract
The Gabal Um Samra (GUS) compound intrusion in the Eastern Desert of Egypt consists of a co-magmatic series of syenogranite and alkali feldspar granite. Accessory minerals (e.g., zircon, monazite, allanite) are abundant. Geochemically, the GUS intrusion is a classic A-type granite. It is [...] Read more.
The Gabal Um Samra (GUS) compound intrusion in the Eastern Desert of Egypt consists of a co-magmatic series of syenogranite and alkali feldspar granite. Accessory minerals (e.g., zircon, monazite, allanite) are abundant. Geochemically, the GUS intrusion is a classic A-type granite. It is extensively fractionated, enriched in large ion lithophile elements and high field strength elements, and depleted in Ba, Sr, K, and Ti. Normalized rare earth element patterns are nearly flat, without any lanthanide tetrad anomalies, but with distinct negative Eu anomalies (Eu/Eu* = 0.14–0.22) due to feldspar fractionation. Paired Zr-Hf and Y-Ho element systematics indicate igneous rather than hydrothermal processes. The petrogenesis of the comparatively unaltered GUS intrusion offers an opportunity to refine the standard model for post-collisional felsic magmatism in the Neoproterozoic Arabian–Nubian Shield. It is explained by the partial melting of juvenile crust induced by lithospheric delamination, followed by extensive fractional crystallization. A quantitative mass-balance model shows that the granite varieties of the GUS intrusion plausibly represent liquids along a single liquid line of descent; but, if so, the more evolved, later pulses display anomalous enrichment in Rb, Nb, Ta, U, and REE. The most plausible source for this enrichment is the extraction of small-degree residual melts from earlier pulses and the mixing of the melts into the later pulses, an energetically favorable process we call “auto-assimilation”. A quantitative model shows that the residual liquid after 97.5% crystallization of the syenogranite can fit the major oxide and trace element data in the alkali feldspar granite if 0.07% by mass of this melt is added to the evolving system for each 1% crystal fractionation by mass. The GUS intrusion represents an example of moderate rare metal enrichment and concentration to sub-economic grade by auto-assimilation. Similar processes may affect intrusions that feature higher grade mineralization, but the evidence is often obscured by the extensive alteration of those deposits. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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18 pages, 3300 KB  
Article
Modes of Occurrence of Critical Elements (Li-Ga-Nb-Zr-REE) in the Late Paleozoic Coals from the Jungar Coalfield, Northern China: An Approach of Sequential Chemical Extraction
by Xiangyang Liu, Yanbo Zhang, Wei Zhao, Jian Wu and Jian Bai
Minerals 2025, 15(9), 889; https://doi.org/10.3390/min15090889 - 22 Aug 2025
Viewed by 568
Abstract
In recent years, recovering critical elements from coal has attracted considerable interest due to their significant potential and resulting advantages. A prime example is the coal-hosted Al-Ga-Li-REE deposit within the Jungar Coalfield of Inner Mongolia, northern China, where lithium (Li), gallium (Ga), and [...] Read more.
In recent years, recovering critical elements from coal has attracted considerable interest due to their significant potential and resulting advantages. A prime example is the coal-hosted Al-Ga-Li-REE deposit within the Jungar Coalfield of Inner Mongolia, northern China, where lithium (Li), gallium (Ga), and aluminum (Al) are successfully extracted from coal ash. However, the specific forms in which these elements exist, crucial for developing effective extraction methods, remain unquantified. This research investigated the distribution of Li, Ga, Nb, Zr, and rare earth elements (REEs) within the coal. The study employed a combination of analytical techniques, including inductively coupled plasma mass spectrometry (ICP-MS), sequential chemical extraction (SCE), scanning electron microscopy coupled with energy-dispersive X-ray spectrometry (SEM-EDS), and X-ray powder diffraction analysis (XRD). The analyzed coals exhibited enriched levels of Li, Ga, Zr, Nb, and REEs. Kaolinite and boehmite were the primary mineral constituents, along with minor amounts of calcite, pyrite, rutile, goyazite, and chlorite. Sequential chemical extraction revealed that Li and Ga are primarily associated with aluminosilicate phases (71.84%–84.39%) and, to a lesser degree, organic matter (12.15%–25.09%). Zirconium and Nb were also predominantly found within aluminosilicates (68.53%–95.96%). REEs occur mainly in carbonate (28.28%–60.78%), aluminosilicate (11.6%–33.08%), and organic (22.04%–29.42%) fractions. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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23 pages, 12646 KB  
Article
Titanite Textures, U-Pb Dating, Chemistry, and In Situ Nd Isotopes of the Lalingzaohuo Mafic Magmatic Enclaves and Host Granodiorites in the East Kunlun Orogen Belt: Insights into Magma Mixing Processes
by Zisong Zhao, Bingzhang Wang, Shengwei Wu and Jiqing Li
Minerals 2025, 15(9), 886; https://doi.org/10.3390/min15090886 - 22 Aug 2025
Viewed by 664
Abstract
Widespread Triassic granitic magmatism is archived in the East Kunlun Orogen Belt (EKOB) of Northern Qinghai–Tibet Plateau. Mafic magmatic enclaves (MMEs), commonly hosted in these plutons, are generally interpreted as products of magma mixing; however, the specific magmatic processes remain poorly understood. In [...] Read more.
Widespread Triassic granitic magmatism is archived in the East Kunlun Orogen Belt (EKOB) of Northern Qinghai–Tibet Plateau. Mafic magmatic enclaves (MMEs), commonly hosted in these plutons, are generally interpreted as products of magma mixing; however, the specific magmatic processes remain poorly understood. In this study, we present new data on the complex zoning patterns, in situ U–Pb ages, trace element compositions, and Nd isotopic characteristics of titanite grains from the MMEs and host granodiorite of Laningzaohuo Zhongyou pluton. Whole-rock geochemical data indicate that the pluton is composed of volcanic arc-related, calc-alkaline, metaluminous I-type granodiorite. Titanite in the MMEs and the granodiorite yield similar U–Pb ages of ~244 Ma but display distinct textural and compositional features. Titanite from the granodiorite is typically euhedral, characterized by magmatic core and mantle with deuteric rim, and exhibits sector and fir-tree zoning in the core. In contrast, titanite from the MMEs is generally anhedral, also showing magmatic core and mantle as well as deuteric rims, but exhibits oscillatory zoning and incomplete sector and fir-tree zoning in the core. Titanite cores in the MMEs have εNd(t) ranging from −2.5 to −3.4, comparable to those of the coeval gabbro and MMEs elsewhere in the EKOB. These cores also show higher LREE/HREE ratios compared to titanite cores in the granodiorite, suggesting crystallization from mixed magmas with greater contributions from enriched lithospheric mantle sources. Titanite mantles in the MMEs yield εNd(t) of −4.0 to −4.8, slightly lower than the cores in the MMEs but higher than those of titanite cores and mantles in the granodiorite (−4.6 to −5.5). The mantle can be interpreted as crystallized from mixed magmas with less mafic components. Titanite rims in the MMEs have εNd(t) of −5.0 to −5.7, identical to those in the granodiorite, and have REE concentrations and Th/U and Nb/Ta ratios consistent with the titanite rims in the granodiorite, clearly indicative of crystallization from evolved, hydrated, granodioritic magmas. Plagioclase in the MMEs exhibits disequilibrium textures such as sieve texture and reverse zoning, with An36–66, contrasting with the more uniform An contents (An35–37) in the granodiorite. This suggests that plagioclase in the MMEs crystallized in an environment influenced by both mafic and felsic magmas. Amphibole thermobarometry indicates that amphibole in the MMEs crystallized at ~788 °C and ~295 MPa, slightly higher than the crystallization conditions in the granodiorite (~778 °C and ~259 MPa). We thus propose that the chemical and textural differences between titanite in the MMEs and granodiorite suggest that the MMEs formed within a mushy hybrid layer generated by injection of upwelling basaltic magma into a pre-existing granitic magma chamber. Titanite cores and mantles in the MMEs likely crystallized from variably mixed magmas. They subsequently underwent resorption and disequilibrium growth within the hybrid layer, and were eventually overgrown by rims formed from evolved interstitial granitic melts within the mushy enclaves. These findings demonstrate that the complex zoning and geochemical titanite in the MMEs provide valuable insights into magma mixing processes. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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16 pages, 8282 KB  
Article
Petrographic, Geochemical, and Geochronological Characteristics of the Granite in Yunnan and Its Constraints on Ion-Adsorption Rare Earth Element Mineralization
by Bin Zhang, Haobin Niu, Linkui Zhang, Binhui Zhang, Xiangping Zhu, Rudong Gao, Yongfei Yang and Yinggui Zou
Minerals 2025, 15(8), 872; https://doi.org/10.3390/min15080872 - 19 Aug 2025
Viewed by 532
Abstract
The TuguanZhai rare earth deposit in Tengchong, along with the Longan and Yingpanshan deposits in Longchuan, is a significant ion-adsorption type rare earth (iREE) deposit in Yunnan, China. Previous studies mainly focused on the geochemistry of residual regolith or the migration and enrichment [...] Read more.
The TuguanZhai rare earth deposit in Tengchong, along with the Longan and Yingpanshan deposits in Longchuan, is a significant ion-adsorption type rare earth (iREE) deposit in Yunnan, China. Previous studies mainly focused on the geochemistry of residual regolith or the migration and enrichment mechanism of rare earth elements (REEs), but lacked systematic analysis of the protoliths. To constrain this deposit and its protolith rock, called Tuguanzhai granite, we systematically integrate petrology features, petrogeochemistry, zircon U-Pb date, and artificial heavy mineral separation (AHMS). Specifically, iREE-host granites include two main periods in this area: the Early Cretaceous (112.13 ± 0.75 Ma) and the Paleocene–Eocene (52.78 ± 0.28 Ma, 48.56 ± 0.19 Ma). The former includes three types of biotite monzogranite with different grain sizes, and the latter is mainly medium-grained biotite monzogranite with local mylonitization. Geochemical features show that these granites generally share high alkalinity compositions (w(K2O + Na2O): 7.15 to 12.75 wt%) and potassium contents (w(K2O): 3.89 to 8.36 wt%). The mineralized granites exhibit significantly higher concentrations of the total REEs than non-mineralized granites, along with a strong enrichment of light REEs. Moreover, the results of AHMS reveal that the REE contents of apatite, allanite, and titanite in mineralized granites are 4.98, 1.29, and 1.90 times more abundant than in non-mineralized granites, respectively. Due to REEs being released from these REE-rich minerals in humid environments, there exists significant potential for iREE formation and exploration in the Early Cretaceous granites in western Yunnan. We innovatively propose the “abundance of easily leachable minerals” as a key indicator for iREE mineralization and exploration, having found it to be better than the traditional total REE contents. Full article
(This article belongs to the Special Issue Recent Developments in Rare Metal Mineral Deposits)
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