Topic Editors

Faculty of Geology, State University of Rio de Janeiro, Rio de Janeiro 20559-900, RJ, Brazil
Faculty of Geology, State University of Rio de Janeiro, Rio de Janeiro 20559-900, RJ, Brazil

Marine Isotope Geochemistry: Recoding Ocean History and Climate Change

Abstract submission deadline
30 November 2025
Manuscript submission deadline
31 January 2026
Viewed by
2731

Topic Information

Dear Colleagues,

The study of ocean geochemistry was among the earliest scientific efforts to estimate the Earth's age, initially based on the hypothesis that seawater salinity has increased consistently over geological time. However, this hypothesis was later dismissed, as maintaining a constant rate of salinity increase proved unlikely. Evidence suggests that the hydrosphere is as old as Earth’s earliest rocks. Research utilizing oxygen isotopes in Earth's oldest zircon crystals, dating to approximately 4.2 billion years, indicates the presence of an ocean from that time. Nonetheless, the most significant insights into the ocean's geochemical evolution derive from recent rocks recorded in sediments. These sediment compositions are interpreted as reflective of ocean water compositions, based on the premise that they were deposited in isotopic equilibrium with the surrounding seawater.

The hypothesis of isotopic equilibrium between ancient carbonates and the marine waters in which they formed is supported by the observation that modern carbonate sediments exhibit isotopic signatures akin to those of contemporary marine waters. Consequently, isotopic records in carbonate rocks are considered representative of ancient ocean compositions, spanning from the Archean to the present. Researchers have broadened their studies by correlating isotopic variation curves, particularly from carbonate rocks with defined stratigraphic positions, with climatic shifts, focusing especially on the Phanerozoic. Advances in isotopic analysis now allow for diverse applications, with ongoing improvements to these techniques. Presently, commonly analyzed isotopes include light mass isotopes (Hydrogen, Carbon, Oxygen, Nitrogen, and Sulfur) and heavy mass isotopes (Strontium, Neodymium, Iron, Zinc, Copper, Lead, Mercury, Molybdenum, Calcium, Chromium, Cadmium, Lithium, and Magnesium, among others under development).

This Topic aims to deepen the understanding of isotopic methods, both stable and radiogenic, in reconstructing oceanic evolution. We invite researchers and professionals across disciplines to contribute their studies on isotopic signatures in aquatic environments. Through this work, the isotopic history of the oceans can illuminate broader planetary evolution and inform our understanding of climate changes essential to sustaining life.

Prof. Dr. Mauro César Geraldes
Dr. Guilherme Loriato Potratz
Topic Editors

Keywords

  • oceans
  • geochemistry
  • isotopic evolution
  • climate change
  • marine

Participating Journals

Journal Name Impact Factor CiteScore Launched Year First Decision (median) APC
Geosciences
geosciences
2.1 5.1 2011 23.4 Days CHF 1800 Submit
Journal of Marine Science and Engineering
jmse
2.8 5.0 2013 15.6 Days CHF 2600 Submit
Sustainability
sustainability
3.3 7.7 2009 19.3 Days CHF 2400 Submit

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Published Papers (2 papers)

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21 pages, 19080 KB  
Article
Provenance Evolution Since the Middle Pleistocene in the Western Bohai Sea, North China: Integrated Rare Earth Element Geochemistry and Sedimentological Records
by Shuyu Wu, Jun Liu and Yongcai Feng
J. Mar. Sci. Eng. 2025, 13(9), 1632; https://doi.org/10.3390/jmse13091632 - 26 Aug 2025
Viewed by 744
Abstract
Despite extensive research on sediment provenance in the Bohai Sea (BS), a significant knowledge gap persists concerning long-term provenance evolution, particularly in the western BS since the Middle Pleistocene. This shortcoming limits reconstructions of paleoenvironmental evolution and its interplay with climatic variability and [...] Read more.
Despite extensive research on sediment provenance in the Bohai Sea (BS), a significant knowledge gap persists concerning long-term provenance evolution, particularly in the western BS since the Middle Pleistocene. This shortcoming limits reconstructions of paleoenvironmental evolution and its interplay with climatic variability and sea-level fluctuations. This study presents integrated Rare Earth Element (REE) geochemical and sedimentological analyses of sediments from core DZQ01 in the western BS. The mean ΣREE concentration of 178.78 μg/g is characterized by pronounced light REE (LREE) enrichment relative to heavy REE (HREE). Chondrite- and upper continental crust (UCC)-normalized patterns exhibit distinct negative Eu anomalies, variable Ce anomalies, marked LREE enrichment, and pronounced LREE/HREE fractionation. Grain size exerts the dominant control on REE distribution, whereas the weak correlation between HREE fractionation parameter indices (e.g., Gd/Yb) and redox-sensitive proxies (e.g., δEuUCC and δCeUCC) confirms their fidelity as provenance indicators. When integrated with the δEuUCC-δCeUCC diagram, discriminant functions, and paleoenvironmental proxies (Rb/Sr and Mg/Ca ratios), the data indicate that, during interglacial highstands, the Yellow River (YR) was the principal source, delivering fine-grained terrigenous material from the Loess Plateau and thereby elevating REE concentrations. Conversely, glacial lowstands shifted the depositional environment to subaerial conditions, with the YR, Hai River, and Luan River supplying a coarse-fine admixture. Multi-river provenance and dilution by coarse detritus collectively lowered REE concentrations during these intervals. Full article
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22 pages, 12234 KB  
Article
Enhanced Continental Weathering and Intense Upwelling Drove the Deposition of Organic-Rich Shales in the Late Permian Dalong Formation, South China
by Yin Gong, Yiming Li, Peng Yang, Meng Xiang, Zhou Zhou, Zhongquan Zhang, Xing Niu and Xiangrong Yang
J. Mar. Sci. Eng. 2025, 13(2), 357; https://doi.org/10.3390/jmse13020357 - 15 Feb 2025
Cited by 2 | Viewed by 993
Abstract
Marine black shales are important to geologists, because they are not only potential sources and reservoir rocks for shale gas/oil, but also, their deposition could influence the climatic and oceanic environments. Here, a detailed study of the shales in the Dalong Formation in [...] Read more.
Marine black shales are important to geologists, because they are not only potential sources and reservoir rocks for shale gas/oil, but also, their deposition could influence the climatic and oceanic environments. Here, a detailed study of the shales in the Dalong Formation in South China was conducted to understand the changes in continental weathering and upwelling and their influences on organic matter accumulation in the late Permian. The results revealed that the deposition of the Dalong and Daye Formations could be divided into five stages, with the highest TOC values (>2%) being observed in stages 2 and 4, intermediate TOCs (~1% to 2%) being observed in stages 1 and 3, and the lowest TOC values (<1%) being observed in stage 5. This study attributed the enhanced organic matter accumulation in stages 2 and 4 to enhanced continental weathering (high CIA values and δ26Mg values) and intense upwelling (high Mo/TOC ratios and low δ13Corg and CoEF × MnEF values), both of which contributed to high primary productivity and increased anoxia of the bottom waters, further leading to the accumulation of organic matter. Overall, both enhanced continental weathering and upwelling contributed to the development of anoxia, even euxinia, of the seawater and further triggered an end-Permian mass extinction (EPME). Full article
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