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20 pages, 622 KB  
Article
A Multilevel Fuzzy AHP Model for Green Furniture Evaluation: Enhancing Resource Efficiency and Circular Design Through Lifecycle Integration
by Wenxin Deng and Mu Jiang
Systems 2025, 13(9), 734; https://doi.org/10.3390/systems13090734 (registering DOI) - 25 Aug 2025
Abstract
This study addresses this gap by proposing a multilevel fuzzy evaluation model combined with an analytic hierarchy process (AHP) to quantify the greenness of furniture products across their entire lifecycle. Focusing on an office desk as a case study, we developed an indicator [...] Read more.
This study addresses this gap by proposing a multilevel fuzzy evaluation model combined with an analytic hierarchy process (AHP) to quantify the greenness of furniture products across their entire lifecycle. Focusing on an office desk as a case study, we developed an indicator system encompassing environmental attributes, resource efficiency, energy consumption, economic costs, and quality performance. Weighting results revealed that environmental attributes (27.2%) and resource efficiency (27.2%) dominated the greenness evaluation, with material recycling rate (33.5%) and solid waste pollution (24.3%) as critical sub-indicators. The prototype achieved a moderate greenness score of 70.38/100, highlighting optimization potential in renewable material adoption (10% current rate) and modular design for disassembly. Mechanically recycled materials could reduce lifecycle emissions by 18–25% in key categories. The model demonstrates scalability for diverse furniture types and informs policy-making by prioritizing high-impact areas such as toxic material reduction and energy-efficient manufacturing, thus amplifying its global and interdisciplinary multiplier effects. Full article
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19 pages, 365 KB  
Article
The Self-Transcendence in Chapter “De Chong Fu 德充符” of the Zhuangzi—Starting from Kant’s Symbolic Relationship Between Beauty and Morality
by Miao Deng and Cuiqin Li
Religions 2025, 16(9), 1096; https://doi.org/10.3390/rel16091096 - 25 Aug 2025
Abstract
Judging a person’s appearance as beautiful or ugly is not a factual description but an aesthetic act. Kant believed that the human figure is the ideal of beauty, and at the same time, beauty can positively symbolize morality. However, regarding the correlation between [...] Read more.
Judging a person’s appearance as beautiful or ugly is not a factual description but an aesthetic act. Kant believed that the human figure is the ideal of beauty, and at the same time, beauty can positively symbolize morality. However, regarding the correlation between aesthetics and morality, the Chapter “De Chong Fu 德充符” in the Zhuangzi offers us a strikingly insightful perspective that is transcendent and religious. The characters depicted in “De Chong Fu 德充符” have incomplete physical forms and ugly appearances, which seemingly do not qualify as symbols of morality in Kant’s sense. Yet, their behavior and demeanor precisely reflect their detachment from external physical forms and their inner virtue being full. This inner virtue embodies a religious ethic that transcends individual and subjective perspectives. This paper posits that there is a deeper and more thought-provoking connection between virtue and physical form in Zhuangzi’s philosophy. The aim of this paper is to explore the issue of self-transcendence in Zhuangzi’s philosophy from the perspective of religious ethics, using the relationship between the body, beauty, and virtue in Lao–Zhuang philosophy as a guiding thread. This paper will be divided into three main parts: the first part introduces the topic through the symbolic relationship between beauty and morality in Kant; the second part discusses the transcendence of aesthetics and physical form in Daoist philosophy and provides a section-by-section analysis of Chapter “De Chong Fu 德充符” of the Zhuangzi; and the third part summarizes the relationship between virtue and form in “De Chong Fu 德充符”. The paper argues that the transcendence of the physical form by virtue, as reflected in Chapter “De Chong Fu 德充符”, is an embodiment of religious ethics. In Lao–Zhuang philosophy, due to their deep understanding of the nature of beauty and the nature of the body, there is no necessary positive connection between beauty and form. Virtue does not necessarily need to rely on beauty as a symbol to be realized, and there can still be a positive connection between a defective physical form and virtue. In conclusions, the paper proposes the modern inspiration of self-transcendence reflected in Zhuangzi’s “De Chong Fu 德充符”. Full article
14 pages, 2680 KB  
Article
Molecular Epidemiology of tet(A)-v1-Positive Carbapenem-Resistant Klebsiella pneumoniae in Pediatric Patients in a Chinese Hospital
by Chen Xu, Chunli Li, Yuanyuan Li, Xiangkun Zeng, Yi Yang, Mi Zhou, Jiani Jiang, Yunbing Li, Guangfen Zhang, Xiaofan Li, Jiayi You, Yi Liu, Lili Huang, Sheng Chen and Ning Dong
Antibiotics 2025, 14(9), 852; https://doi.org/10.3390/antibiotics14090852 - 22 Aug 2025
Viewed by 185
Abstract
Background: The emergence and spread of the tigecycline resistance gene tet(A)-v1 in carbapenem-resistant Klebsiella pneumoniae (CRKP) poses significant public health challenges. However, the prevalence of tet(A)-v1-positive CRKP, especially in pediatric patients, remains poorly understood. This study aims to address the gap [...] Read more.
Background: The emergence and spread of the tigecycline resistance gene tet(A)-v1 in carbapenem-resistant Klebsiella pneumoniae (CRKP) poses significant public health challenges. However, the prevalence of tet(A)-v1-positive CRKP, especially in pediatric patients, remains poorly understood. This study aims to address the gap by performing an in-depth analysis of isolates collected from a children’s hospital in China. Methods: A 4-year retrospective study was conducted in the children’s hospital in Suzhou, China. Non-duplicated specimens were obtained from pediatric patients, and antimicrobial susceptibility profiles were assessed. Whole-genome sequencing and bioinformatics analyses were conducted to characterize the genetic background, antimicrobial resistance determinants, hypervirulence-associated genes, diversity of tet(A)-v1-carrying plasmids, the genetic environment of tet(A)-v1, and the potential for clonal transmission. Conjugative transferability of tet(A)-v1-carrying plasmids was also evaluated via conjugation assays. Results: Of the 73 tet(A)-v1-positive CRKP isolates from pediatric patients, 10.96% were non-susceptible to tigecycline. These isolates exhibited high genetic diversity, spanning across 13 STs (sequence types), with ST17 being predominant. Three carbapenemases were identified, with IMP being the most common. Isolates from diverse backgrounds, such as ST17, ST20, ST323, ST792, and ST3157, demonstrated evidence of clonal transmission. The tet(A)-v1 gene was located on 14 distinct plasmids across seven replicon types, with IncFIA/IncHI1 and IncFII being most commonly detected. All tet(A)-v1-carrying plasmids were multidrug-resistant, and 68.49% were conjugatively transferable, indicating a high potential for horizontal transfer. Four genetic contexts bordering tet(A)-v1 were identified, which points to active clonal dissemination. Conclusions: Although limited to a single hospital, this study represents one of the first in-depth investigations of tet(A)-v1-positive CRKP in pediatric patients, providing valuable insights into the prevalence and spread of tet(A)-v1 in this vulnerable group. These findings emphasize the urgent need for enhanced surveillance and infection control measures to curb the spread of tet(A)-v1-positive CRKP in pediatric healthcare environments, offering critical insights to mitigate its public health impact. Full article
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20 pages, 3701 KB  
Article
Residual Skewness Monitoring-Based Estimation Method for Laser-Induced Breakdown Spectroscopy
by Bin Zhu, Xiangcheng Shen, Tao Liu, Sirui Wang, Yuhua Hang, Jianhua Mo, Lei Shao and Ruizhi Wang
Electronics 2025, 14(17), 3343; https://doi.org/10.3390/electronics14173343 - 22 Aug 2025
Viewed by 130
Abstract
To address the challenges of narrow peak characteristics and low signal-to-noise ratio (SNR) detection in Laser-Induced Breakdown Spectroscopy (LIBS), in this paper, we combine the Sparse Bayesian Learning–Baseline Correction (SBL-BC) algorithm with residual skewness monitoring to propose a spectral estimation method tailored for [...] Read more.
To address the challenges of narrow peak characteristics and low signal-to-noise ratio (SNR) detection in Laser-Induced Breakdown Spectroscopy (LIBS), in this paper, we combine the Sparse Bayesian Learning–Baseline Correction (SBL-BC) algorithm with residual skewness monitoring to propose a spectral estimation method tailored for LIBS. In LIBS spectra, discrete peaks are susceptible to baseline fluctuations and noise, while the Gaussian dictionary modeling and fixed convergence criterion of the existing SBL-BC lead to the inaccurate characterization of narrow peaks and high computational complexity. To overcome these limitations, we introduce a residual skewness dynamic tracking mechanism to mitigate residual negative skewness accumulation caused by positivity constraints under high noise levels, preventing traditional convergence criterion failure. Simultaneously, by eliminating the dictionary matrix and directly modeling the spectral peak vector, we transform matrix operations into vector computations, better aligning with LIBS’s narrow peak features and high-channel-count processing requirements. Through simulated and real spectral experiments, the results demonstrate that this method outperforms the SBL-BC algorithm in terms of spectral peak fitting accuracy, computational speed, and convergence performance across various SNRs. It effectively separates spectral peaks, baseline, and noise, providing a reliable approach for both quantitative and qualitative analysis of LIBS spectra. Full article
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22 pages, 4366 KB  
Article
Controlled Fabrication of pH-Visualised Silk Fibroin–Sericin Dual-Network Hydrogels for Urine Detection in Diapers
by Yuxi Liu, Kejing Zhan, Jiacheng Chen, Yu Dong, Tao Yan, Xin Zhang and Zhijuan Pan
Gels 2025, 11(8), 671; https://doi.org/10.3390/gels11080671 - 21 Aug 2025
Viewed by 202
Abstract
Urine pH serves as an indicator of systemic acid–base balance and helps detect early-stage urinary and renal disorders. However, conventional monitoring methods rely on instruments or manual procedures, limiting their use among vulnerable groups such as infants and bedridden elderly individuals. In this [...] Read more.
Urine pH serves as an indicator of systemic acid–base balance and helps detect early-stage urinary and renal disorders. However, conventional monitoring methods rely on instruments or manual procedures, limiting their use among vulnerable groups such as infants and bedridden elderly individuals. In this study, a pH-responsive smart hydrogel was developed and integrated into diapers to enable real-time, equipment-free, and visually interpretable urine pH monitoring. An optimised degumming process enabled one-step preparation of a silk fibroin–sericin aqueous solution. We employed a visible light-induced photo-crosslinking strategy to fabricate a dual-network hydrogel with enhanced strength and stability. Increasing sericin content accelerated gelation (≤15 min) and improved performance, achieving a maximum stress of 54 kPa, strain of 168%, and water absorption of 566%. We incorporated natural anthocyanins and fine-tuned them to produce four distinct colour changes in response to urine pH, with significantly improved colour differentiation (ΔE). Upon contact with urine, the hydrogel displays green within the normal pH range, indicating a healthy state. At the same time, a reddish-purple or blue colour serves as a visual warning of abnormal acidity or alkalinity. This intelligent hydrogel system combines rapid gelation, excellent mechanical properties, and a sensitive visual response, offering a promising platform for body fluid monitoring. Full article
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16 pages, 485 KB  
Article
Exploring the Relationship Between Students’ Language Learning Curiosity and Academic Achievement: The Mediating Role of Foreign Language Anxiety
by Honggang Liu, Tong Li, Hongying Zheng, Yang Li and Jiqun Fan
Behav. Sci. 2025, 15(8), 1133; https://doi.org/10.3390/bs15081133 - 20 Aug 2025
Viewed by 261
Abstract
Curiosity and anxiety are critical emotional factors influencing language learning; yet, existing studies often overlook their combined effects and the mechanisms through which they shape academic achievements. This study aimed to explore the relationships among language learning curiosity, foreign language anxiety, and academic [...] Read more.
Curiosity and anxiety are critical emotional factors influencing language learning; yet, existing studies often overlook their combined effects and the mechanisms through which they shape academic achievements. This study aimed to explore the relationships among language learning curiosity, foreign language anxiety, and academic achievement among junior high school students. A total of 870 students from southeastern China, including 7 selected for semi-structured interviews, participated in the study. Quantitative data were analyzed through SPSS and AMOS with structural equation modeling, while qualitative data were examined using thematic analysis in NVivo to identify profile-based patterns. The findings revealed that students showed relatively high curiosity and moderate anxiety in English language learning. Consistent with our hypotheses, curiosity positively predicted academic achievement, while anxiety had a negative effect. Foreign language anxiety partially mediated the relationship between curiosity and academic performance. Qualitative data supported these findings, showing that curiosity fostered engagement and reduced anxiety in real learning contexts. These findings support the control-value theory of academic emotions and offer theoretical and practical implications for emotional regulation in language education. Full article
(This article belongs to the Section Educational Psychology)
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24 pages, 6274 KB  
Article
Accurate Prediction of Voltage and Temperature for a Sodium-Ion Pouch Cell Using an Electro-Thermal Coupling Model
by Hekun Zhang, Zhendong Zhang, Yelin Deng and Jianxu Yu
Batteries 2025, 11(8), 312; https://doi.org/10.3390/batteries11080312 - 16 Aug 2025
Viewed by 349
Abstract
Due to their advantages, such as abundant raw material reserves, excellent thermal stability, and superior low-temperature performance, sodium-ion batteries (SIBs) exhibit significant potential for future applications in energy storage and electric vehicles. Therefore, in this study, a commercial pouch-type SIB with sodium iron [...] Read more.
Due to their advantages, such as abundant raw material reserves, excellent thermal stability, and superior low-temperature performance, sodium-ion batteries (SIBs) exhibit significant potential for future applications in energy storage and electric vehicles. Therefore, in this study, a commercial pouch-type SIB with sodium iron sulfate cathode material was investigated. Firstly, a second-order RC equivalent circuit model was established through parameter identification using multi-rate hybrid pulse power characterization (M-HPPC) tests at various temperatures. Then, both the specific heat capacity and entropy coefficient of the sodium-ion battery were measured through experiments. Building upon this, an electro-thermal coupling model was developed by incorporating a lumped-parameter thermal model that accounts for the heat generation of the tabs. Finally, the prediction performance of this model was validated through discharge tests under different temperature conditions. The results demonstrate that the proposed electro-thermal coupling model can achieve the simultaneous prediction of both temperature and voltage, providing valuable references for the future development of thermal management systems for SIBs. Full article
(This article belongs to the Special Issue Batteries: 10th Anniversary)
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25 pages, 1380 KB  
Article
Retail Service, Pricing, and Channel Selection Strategies for Fashion Products in a Two-Stage Decision Model
by Liwen Liu, Xuejuan Li, Siyu Zhu and Mengyao Wang
Mathematics 2025, 13(16), 2575; https://doi.org/10.3390/math13162575 - 12 Aug 2025
Viewed by 360
Abstract
Fashion products are typically sold through both online and offline channels during two distinct phases: the launch and markdown period. Pricing strategies present significant challenges for manufacturers, particularly as consumers increasingly adopt strategic purchasing behaviors. Key factors, including product fashion utility, purchase timing, [...] Read more.
Fashion products are typically sold through both online and offline channels during two distinct phases: the launch and markdown period. Pricing strategies present significant challenges for manufacturers, particularly as consumers increasingly adopt strategic purchasing behaviors. Key factors, including product fashion utility, purchase timing, and consumer characteristics, complicate manufacturers’ channel selection, pricing decisions, and service strategy formulation—necessitating deeper investigation. This paper establishes a two-echelon supply chain model featuring a fashion manufacturer and a retailer to determine optimal channel, pricing, and service strategies across both selling periods amid strategic consumer behavior. We examine four channel strategies: (1) the MM strategy: the manufacturer operates both channels (online and offline channels) during both periods (launch and markdown period); (2) the MR strategy: the manufacturer operates both channels during the launch stage, and the retailer sells online during the markdown period; (3) the RR strategy: the manufacturer sells offline, and the retailer operates the online channel during both stages; (4) the RM strategy: the manufacturer sells online during both stages, and the retailer sells through the offline channel. Our analysis yields critical insights: When off-season discounts are limited, the manufacturer should maintain direct control of both channels. However, when the off-season discount is significant, the manufacturer needs to set the channel strategy according to the fashion utility. If the fashion utility is small, direct sales through offline channels during the launch period, while entrusting the retailer to distribute in online channels during both periods, should be adopted. If the fashion utility is large, a dual-channel, two-stage, entirely direct sales strategy should be adopted. This study elucidates the optimal manufacturer channel and pricing strategy options and provides some theoretical contributions and practical implications. Full article
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31 pages, 5529 KB  
Review
Advancement in Functionalized Electrospun Nanofiber-Based Gas Sensors: A Review
by Yanjie Wang, Zhiqiang Lan, Jie Wang, Kun Zhu, Jian He, Xiujian Chou and Yong Zhou
Sensors 2025, 25(16), 4896; https://doi.org/10.3390/s25164896 - 8 Aug 2025
Viewed by 355
Abstract
In recent years, electrospinning technology has sparked a revolution in the nanoengineering of gas-sensing materials. Nanofibers based on metal oxide semiconductors, carbon materials, or conductive polymers prepared by the electrospinning process have exhibited inspiring properties, including a large specific surface area, porous structure, [...] Read more.
In recent years, electrospinning technology has sparked a revolution in the nanoengineering of gas-sensing materials. Nanofibers based on metal oxide semiconductors, carbon materials, or conductive polymers prepared by the electrospinning process have exhibited inspiring properties, including a large specific surface area, porous structure, and nice stability, with bright application prospects in advanced gas sensors. Meanwhile, the increasingly expanding applications of gas sensors, such as the Internet of Things (IoT), the food industry, disease diagnosis, etc., have raised higher sensor performance requirements. To further enhance the gas-sensing performance of nanofibers, the scheme of functionalized nanofiber strategies, either in electrospinning or post-treatment, has been proposed and verified. This review systematically summarized the nanostructures, gas-sensing properties, and functional mechanisms of modified nanofibers. Additionally, the perspectives and challenges regarding electrospun nanofibers for gas sensing were discussed. Full article
(This article belongs to the Special Issue Electrospun Composite Nanofibers: Sensing and Biosensing Applications)
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45 pages, 3787 KB  
Review
Electromigration Failures in Integrated Circuits: A Review of Physics-Based Models and Analytical Methods
by Ping Cheng, Ling-Feng Mao, Wen-Hao Shen and Yu-Ling Yan
Electronics 2025, 14(15), 3151; https://doi.org/10.3390/electronics14153151 - 7 Aug 2025
Viewed by 749
Abstract
Electromigration (EM), current-driven atomic diffusion in interconnect metals, critically threatens integrated circuit (IC) reliability via void-induced open circuits and hillock-induced short circuits. This review examines EM’s physical mechanisms, influencing factors, and advanced models, synthesizing seven primary determinants: current density, temperature, material properties, microstructure, [...] Read more.
Electromigration (EM), current-driven atomic diffusion in interconnect metals, critically threatens integrated circuit (IC) reliability via void-induced open circuits and hillock-induced short circuits. This review examines EM’s physical mechanisms, influencing factors, and advanced models, synthesizing seven primary determinants: current density, temperature, material properties, microstructure, geometry, pulsed current, and mechanical stress. It dissects the coupled contributions of electron wind force (dominant EM driver), thermomigration (TM), and stress migration (SM). The review assesses four foundational modeling frameworks: Black’s model, Blech’s criterion, atomic flux divergence (AFD), and Korhonen’s theory. Despite advances in multi-physics simulation and statistical EM analysis, achieving predictive full-chip assessment remains computationally challenging. Emerging research prioritizes the following: (i) model order reduction methods and machine-learning solvers for verification of EM in billion-scale interconnect networks; and (ii) physics-informed routing optimization to inherently eliminate EM violations during physical design. Both are crucial for addressing reliability barriers in IC technologies and 3D heterogeneous integration. Full article
(This article belongs to the Section Electronic Materials, Devices and Applications)
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20 pages, 2238 KB  
Review
The Pathogenesis and Medical Treatment of Depression: Opportunity and Challenge
by Mengjiao Xu, Zhiyu Zhang, Zhoudong Zhang, Dong Liu, Yanguo Shang, Chenglun Tang, Weipeng Wang, Huanqiu Li, Bengang You, Hanjie Ying and Tao Shen
Neurol. Int. 2025, 17(8), 120; https://doi.org/10.3390/neurolint17080120 - 4 Aug 2025
Viewed by 695
Abstract
Depression is a common mental disorder with high economic burden, characterized by high disability and mortality rates. The etiology of depression remains unclear to date, and there are various hypotheses regarding the pathogenesis of depression in clinical practice, including the monoamine neurotransmitter hypothesis, [...] Read more.
Depression is a common mental disorder with high economic burden, characterized by high disability and mortality rates. The etiology of depression remains unclear to date, and there are various hypotheses regarding the pathogenesis of depression in clinical practice, including the monoamine neurotransmitter hypothesis, the hypothalamic–pituitary–adrenal (HPA) axis dysregulation hypothesis, the inflammatory cytokine hypothesis, and the neurotrophic factor hypothesis. These theories offer specific directional aid in the clinical management of individuals suffering from depression. Medicinal intervention stands as a critical approach within the spectrum of depression treatments, and this article reviews the specific mechanisms of different hypotheses on the pathogenesis of depression in recent years, as well as the research progress on related therapeutic drugs. Full article
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20 pages, 3108 KB  
Article
Dynamic Expectation–Satisfaction Relationship in Sustainable Experiences with Product: A Comparative Study of Durable Goods, FMCG, and Digital Products
by Zhenhua Wu, Kenta Ono and Yuting Wu
Sustainability 2025, 17(15), 7045; https://doi.org/10.3390/su17157045 - 3 Aug 2025
Viewed by 474
Abstract
This study adopts a dynamic Expectancy–Disconfirmation framework to investigate the evolving nature of user satisfaction across three product categories: durable goods, fast-moving consumer goods (FMCG), and digital products. A 25-day longitudinal experiment involving 128 participants was conducted, during which users engaged with their [...] Read more.
This study adopts a dynamic Expectancy–Disconfirmation framework to investigate the evolving nature of user satisfaction across three product categories: durable goods, fast-moving consumer goods (FMCG), and digital products. A 25-day longitudinal experiment involving 128 participants was conducted, during which users engaged with their most recently purchased products and provided repeated subjective evaluations over time. The findings reveal dynamic changes in the influence of expectations and perceived performance on satisfaction throughout the product usage cycle. For durable goods and FMCG, both expectations and perceived performance gradually declined, accompanied by a weakening effect of expectations on satisfaction. In contrast, digital products exhibited greater volatility, lacking a stable experiential baseline and resulting in greater fluctuations in satisfaction trajectories. Moreover, external contextual and emotional factors were found to play a more significant role in shaping satisfaction with physical products, beyond the scope of the traditional expectancy–performance model. These insights offer theoretical and managerial implications for sustainable product and experience design. In particular, they highlight the importance of implementing experience-stabilizing strategies in digital consumption contexts to support user well-being and enhance continuous product utilization, thereby maximizing product potential and reducing waste. Full article
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25 pages, 4751 KB  
Article
Dynamic Evolution and Resilience Enhancement of the Urban Tourism Ecological Health Network: A Case Study in Shanghai, China
by Man Wei and Tai Huang
Systems 2025, 13(8), 654; https://doi.org/10.3390/systems13080654 - 2 Aug 2025
Viewed by 396
Abstract
Urban tourism has evolved into a complex adaptive system, where unregulated expansion disrupts the ecological balance and intensifies resource stress. Understanding the dynamic evolution and resilience mechanisms of the tourism ecological health network (TEHN) is essential for supporting sustainable urban tourism as a [...] Read more.
Urban tourism has evolved into a complex adaptive system, where unregulated expansion disrupts the ecological balance and intensifies resource stress. Understanding the dynamic evolution and resilience mechanisms of the tourism ecological health network (TEHN) is essential for supporting sustainable urban tourism as a coupled human–natural system. Using Shanghai as a case study, we applied the “vigor–organization–resilience–services” (VORS) framework to evaluate ecosystem health, which served as a constraint for constructing the TEHN, using the minimum cumulative resistance (MCR) model for the period from 2001 to 2023. A resilience framework integrating structural and functional dimensions was further developed to assess spatiotemporal evolution and guide targeted enhancement strategies. The results indicated that as ecosystem health degraded, particularly in peripheral areas, the urban TEHN in Shanghai shifted from a dispersed to a centralized structure, with limited connectivity in the periphery. The resilience of the TEHN continued to grow, with structural resilience remaining at a high level, while functional resilience still required enhancement. Specifically, the low integration and limited choice between the tourism network and the transportation system hindered tourists from selecting routes with higher ecosystem health indices. Enhancing functional resilience, while sustaining structural resilience, is essential for transforming the TEHN into a multi-centered, multi-level system that promotes efficient connectivity, ecological sustainability, and long-term adaptability. The results contribute to a systems-level understanding of tourism–ecology interactions and support the development of adaptive strategies for balancing network efficiency and environmental integrity. Full article
(This article belongs to the Section Complex Systems and Cybernetics)
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16 pages, 2366 KB  
Article
ZnO-Assisted Synthesis of Rouaite (Cu2(OH)3NO3) Long Hexagonal Multilayered Nanoplates Towards Catalytic Wet Peroxide Oxidation Application
by Guang Yao Zhou, Jun Guo and Ji Hong Wu
Crystals 2025, 15(8), 710; https://doi.org/10.3390/cryst15080710 - 2 Aug 2025
Viewed by 337
Abstract
Rouaite (Cu2(OH)3NO3) long hexagonal multilayered nanoplates with high purity and high crystallinity were prepared from acidic reaction solution (pH = 4.4–4.8) with the assistance of ZnO. The ZnO-assisted strategy is remarkably different from the conventional synthetic protocol [...] Read more.
Rouaite (Cu2(OH)3NO3) long hexagonal multilayered nanoplates with high purity and high crystallinity were prepared from acidic reaction solution (pH = 4.4–4.8) with the assistance of ZnO. The ZnO-assisted strategy is remarkably different from the conventional synthetic protocol that was regularly carried out in alkaline solution (pH > 11). The rouaite multilayer nanoplates displayed exceptionally high catalytic activity in the catalytic wet peroxide oxidation (CWPO) of Congo red (CR). The catalytic efficiency for CR decolorization achieved an impressive 96.3% in 50 min under near-neutral (pH = 6.76) and ambient conditions (T = 20 °C, p = 1 atm), without increasing the temperature and/or decreasing the pH value to acidic region (pH = 2–3) as is commonly employed in CWPO process for improved degradation efficiency. Full article
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13 pages, 2303 KB  
Article
A Stable Metal Chalcogenide Cluster-Based Framework Decorated with Transition Metal Complexes for an Efficient Electrocatalytic O2 Reduction Reaction
by Xiang Wang, Juan Li and Tao Wu
Nanomaterials 2025, 15(15), 1186; https://doi.org/10.3390/nano15151186 - 1 Aug 2025
Viewed by 267
Abstract
Highly efficient and stable non-Pt-based electrocatalysts for oxygen reduction reactions (ORRs) are highly desirable in energy conversion and storage systems. Herein, we report a hydrothermally synthesized metal chalcogenide cluster-based framework (NCF-3-Mn), which is decorated with transition metal complexes ([Mn(TEPA)]2+, TEPA = [...] Read more.
Highly efficient and stable non-Pt-based electrocatalysts for oxygen reduction reactions (ORRs) are highly desirable in energy conversion and storage systems. Herein, we report a hydrothermally synthesized metal chalcogenide cluster-based framework (NCF-3-Mn), which is decorated with transition metal complexes ([Mn(TEPA)]2+, TEPA = tetraethylenepentamine), for an electrocatalytic O2 reduction reaction (ORR). Benefitting from the abundant Mn-S bonds and Mn-N-C structures in NCF-3-Mn, it was found that NCF-3-Mn displayed a high onset potential (0.90 V) and an efficient four-electron transfer reaction pathway, which are much better than those of its analogue framework (T2-GaSbS). Moreover, NCF-3-Mn also exhibited a considerable long-term stability and methanol resistance toward ORRs. This work will present new opportunities for exploring the utilization of chalcogenide frameworks as novel non-Pt electrocatalysts for ORRs. Full article
(This article belongs to the Collection Micro/Nanoscale Open Framework Materials (OFMs))
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