Skip to Content

50 Results Found

  • Article
  • Open Access
18 Citations
5,764 Views
18 Pages

Performance of Poly Alpha Olefin Nanolubricant

  • Nader Dolatabadi,
  • Ramin Rahmani,
  • Homer Rahnejat,
  • Colin P. Garner and
  • Charles Brunton

The viscosity and tribological behavior of nanofluids formed by dispersed nano-diamond particles within Poly-Alpha-Olefin (PAO6) lubricant is studied at different concentrations. The variation of coefficient of friction with nanoparticle concentratio...

  • Article
  • Open Access
5 Citations
4,739 Views
15 Pages

25 August 2021

The catalytic dehydration of a bio-based fatty alcohol was performed using Al2O3 prepared by solvothermal synthesis for selective production of long-chain linear-alpha-olefins (LAO). The effect of the synthesis temperature of alumina precursors on th...

  • Article
  • Open Access
18 Citations
2,892 Views
20 Pages

Performance Evaluation of WMA Containing Re-Refined Acidic Sludge and Amorphous Poly Alpha Olefin (APAO)

  • Mansour Fakhri,
  • Danial Arzjani,
  • Pooyan Ayar,
  • Maede Mottaghi and
  • Nima Arzjani

17 March 2021

The use of waste materials has been increasingly conceived as a sustainable alternative to conventional materials in the road construction industry, as concerns have arisen from the uncontrolled exploitation of natural resources in recent years. Re-r...

  • Article
  • Open Access
11 Citations
4,843 Views
14 Pages

26 June 2020

We developed polypropylene-based single-polymer composites (PP-SPC) with blends of amorphous poly-alpha-olefin (APAO) and random polypropylene copolymer (rPP) as matrix material and polypropylene (PP) woven fabric as reinforcement. Our goal was to ut...

  • Article
  • Open Access
16 Citations
4,105 Views
26 Pages

10 May 2021

High production costs and poor storage stability have become important constraints in the manufacture of modified asphalt binder. To simplify the production process and reduce the production cost, amorphous poly alpha olefin (APAO) and polyphosphoric...

  • Article
  • Open Access
3 Citations
4,070 Views
16 Pages

Electrochemical Synthesis of Zirconium Pre-Catalysts for Homogeneous Ethylene Oligomerization

  • Giyjaz E. Bekmukhamedov,
  • Aleksandr V. Sukhov,
  • Aidar M. Kuchkaev,
  • Khasan R. Khayarov,
  • Alexander V. Gerasimov,
  • Irina V. Vasilenko,
  • Sergei V. Kostjuk and
  • Dmitry G. Yakhvarov

12 December 2019

The catalytic activity of electrochemically synthesized zirconium carboxylates was studied in the process of ethylene oligomerization. Zirconium carboxylates were electrochemically synthesized directly from metallic zirconium and corresponding carbox...

  • Article
  • Open Access
9 Citations
4,853 Views
15 Pages

The effect of wax molecular weight distribution on the efficacy of two alpha olefin-maleic anhydride paraffin inhibitors (PIs) having different densities of alkyl side-chains were examined in light West Texas crude in the absence and presence of asph...

  • Feature Paper
  • Article
  • Open Access
7 Citations
4,115 Views
13 Pages

19 May 2022

The selective transformation of secondary alcohols to alpha-olefins is a challenging task in heterogeneous catalysis, as is the case of 4-methyl-2-pentanol (4M2Pol) conversion to 4-methyl-1-pentene (4M1P). Herein, the co-precipitated yttria-stabilize...

  • Article
  • Open Access
13 Citations
4,098 Views
19 Pages

8 July 2024

Carbon dioxide (CO2) injection for enhanced oil recovery (EOR) has attracted great attention due to its potential to increase ultimate recovery from mature oil reservoirs. Despite the reported efficiency of CO2 in enhancing oil recovery, the high mob...

  • Article
  • Open Access
618 Views
13 Pages

Polymerization Reaction Kinetics of Poly α-Olefin and Numerical Simulation of a Continuous Polymerization Reactor

  • Jianxin Shi,
  • Jinxue He,
  • Qiang Yao,
  • Ruilong Li,
  • Dan Liu,
  • Xuemei Liang and
  • Lin Wang

22 October 2025

The hydrodynamic and reaction characteristics of poly-alpha-olefin (PAO) polymerization in a continuous stirred tank reactor (CSTR) under Eulerian–Eulerian multiphase flow and a finite-rate chemical kinetics model were studied in this paper. A...

  • Article
  • Open Access
3 Citations
3,282 Views
19 Pages

A detailed understanding of the interactions between wax and asphaltenes with other components of crude oils and the effect of treatments with paraffin inhibitors (PIs) and asphaltene dispersants (ADs), with a focus on identifying specific structure-...

  • Article
  • Open Access
6 Citations
2,274 Views
13 Pages

10 November 2023

The purpose of this study is to investigate the use of SiO2 nanoparticles in assisting with surfactants and polymers for tertiary oil recovery, with the aim of enhancing oil recovery. The article characterizes the performance of SiO2 nanoparticles, i...

  • Article
  • Open Access
238 Views
13 Pages

Toxicokinetic and Partial Mass Balance Assessment of 14C-Alpha Olefins in Rats

  • Quan Shi,
  • Jamie Dunn,
  • Juan-Carlos Carrillo,
  • Michael G. Penman,
  • Robert H. Powrie,
  • Corinne Haines,
  • Hua Shen,
  • Yuan Tian,
  • Sophie Jia and
  • Peter J. Boogaard
  • + 1 author

2 February 2026

Higher olefins are a class of alkenes widely used as intermediates in the production of essential consumer and industrial products. This radiolabel disposition and partial mass balance study investigated the distribution and excretion of four 14C-rad...

  • Article
  • Open Access
11 Citations
6,914 Views
14 Pages

The Mechanism of Rh-Catalyzed Transformation of Fatty Acids to Linear Alpha olefins

  • Sondre H. Hopen Eliasson,
  • Anamitra Chatterjee,
  • Giovanni Occhipinti and
  • Vidar R. Jensen

Linear alpha olefins (LAOs) are key commodity chemicals and petrochemical intermediates that are currently produced from fossil resources. Fatty acids are the obvious renewable starting material for LAOs, which can be obtained via transition-metal-ca...

  • Article
  • Open Access
3,445 Views
10 Pages

21 July 2021

Decarbonylation of carboxylic acids provides an effective protocol for producing alpha olefins; however, previous literature has focused on the palladium-bisphosphine catalysts and has only sporadically studied the palladium-monophosphine catalyst. T...

  • Article
  • Open Access
3 Citations
2,528 Views
11 Pages

α-Olefin Oligomerization Mediated by Group 4 Metallocene Catalysts: An Extreme Manifestation of the Multisite Nature of Methylaluminoxane

  • Francesco Zaccaria,
  • Antonio Vittoria,
  • Giuseppe Antinucci,
  • Roberta Cipullo and
  • Vincenzo Busico

28 December 2024

Group 4 metallocenes are competent catalysts for the oligomerization of higher α-olefins. Among the many chemical and physical variables of importance in the process, one is the choice of cocatalyst (activator). The impact of various activators...

  • Article
  • Open Access
2 Citations
2,579 Views
16 Pages

17 January 2024

This investigation explores the synthesis of advanced catalysts for epoxidizing long-chain linear α-olefins, a pivotal process in the chemical industry for generating critical intermediates. Employing a hydrothermal technique, we developed four...

  • Review
  • Open Access
47 Citations
12,052 Views
50 Pages

Ni-Based Complexes in Selective Ethylene Oligomerization Processes

  • Giyjaz E. Bekmukhamedov,
  • Aleksandr V. Sukhov,
  • Aidar M. Kuchkaev and
  • Dmitry G. Yakhvarov

Linear alpha-olefins are widely used in the petrochemical industry and the world demand for these compounds increases annually. At present, the main method for producing linear alpha-olefins is the homogeneous catalytic ethylene oligomerization. This...

  • Article
  • Open Access
13 Citations
4,552 Views
22 Pages

A New Insight into the Comonomer Effect through NMR Analysis in Metallocene Catalysed Propene–co–1-Nonene Copolymers

  • Qiong Wu,
  • Alberto García-Peñas,
  • Rosa Barranco-García,
  • María Luisa Cerrada,
  • Rosario Benavente,
  • Ernesto Pérez and
  • José Manuel Gómez-Elvira

31 July 2019

The “comonomer effect” is an intriguing kinetic phenomenon in olefin copolymerization that still remains without a detailed explanation. It typically relates to the rate of enhancement undergone in ethylene and propene catalytic polymeriz...

  • Article
  • Open Access
9 Citations
3,404 Views
18 Pages

Kinetic Study on Microwave-Assisted Oligomerization of 1-Decene over a HY Catalyst

  • Snunkhaem Echaroj,
  • Channarong Asavatesanupap,
  • Sumaeth Chavadej and
  • Malee Santikunaporn

14 September 2021

A promising production route for a high-quality base stock for lubricants is the oligomerization of high molecular-weight olefins in a high energy efficiency system. Oligomerization of 1-decene (C10) was conducted in a microwave-assisted system over...

  • Article
  • Open Access
19 Citations
5,510 Views
17 Pages

21 January 2022

A detailed molecular fingerprint of raw pyrolysis oil from plastic wastes is a new research area. The present study focuses for the first time on the chemical recycling of plastic marine litter; we aim to chemically characterize the obtained raw pyro...

  • Article
  • Open Access
20 Citations
5,412 Views
10 Pages

27 February 2018

Three oil–miscible phosphonium ionic liquids with different structures were synthesized and used as additives for a Poly Alpha Olefin 10 (PAO 10) lithium lubricating grease. Different from other additives, the ionic liquids participated in saponifica...

  • Article
  • Open Access
16 Citations
2,894 Views
13 Pages

The Indirect Tribological Role of Carbon Nanotubes Stimulating Zinc Dithiophosphate Anti-Wear Film Formation

  • Jarosław Kałużny,
  • Andrzej Kulczycki,
  • Wojciech Dzięgielewski,
  • Adam Piasecki,
  • Bartosz Gapiński,
  • Michał Mendak,
  • Tomasz Runka,
  • Damian Łukawski,
  • Oleksandr Stepanenko and
  • Krzysztof Kempa
  • + 1 author

Experimental studies reveal that the simultaneous addition of zinc dialkyl dithiophosphates (ZDDPs) and multi-wall carbon nanotubes (MWCNTs) to a poly-alpha-olefin base oil strongly reduces wear. In this paper, it is shown that MWCNTs promote the for...

  • Article
  • Open Access
3 Citations
2,398 Views
11 Pages

17 April 2023

Data were obtained on the copolymerization of ethylene with α-olefins over supported titanium–magnesium catalysts (TMC) prepared on the same magnesium dichloride support but differing in the composition and oxidation state of titanium. Th...

  • Article
  • Open Access
5 Citations
2,714 Views
11 Pages

27 July 2022

The use of CO2 as a CO surrogate for the carbonylation of olefin has attracted considerable attention due to its abundance, readily availability, nontoxicity, and recyclability. In this work, we describe the synthesis of methyl propionate (MPA), a ke...

  • Article
  • Open Access
1 Citations
3,320 Views
12 Pages

Perfluorinated tetradecanoic acid was added as an additive to a base oil and tested under full film elastohydrodynamic (EHD) contact conditions between a steel ball and a steel disc. By varying key performance parameters, we aimed to assess the feasi...

  • Article
  • Open Access
7 Citations
2,578 Views
17 Pages

Implanting MnO2 into Hexagonal Boron Nitride as Nanoadditives for Enhancing Tribological Performance

  • Xiaorong Chen,
  • Wenting Chen,
  • Linyi Zhang,
  • Minli Zeng,
  • Shiming Yang,
  • Zanhe Yang,
  • Oluwafunmilola Ola,
  • Kunyapat Thummavichai,
  • Nannan Wang and
  • Yanqiu Zhu

23 March 2022

Hexagonal boron nitride nanosheets (h-BNNs) show great potential in the field of tribology due to their typical two-dimensional layered structure and are essential for replacing conventional sulfur/phosphate-containing additives. However, the large p...

  • Article
  • Open Access
16 Citations
5,349 Views
17 Pages

Correlation between Lubricating Oil Characteristic Parameters and Friction Characteristics

  • Yanshuang Wang,
  • Qingguo Qiu,
  • Pu Zhang,
  • Xudong Gao,
  • Zhen Zhang and
  • Pengcheng Huang

In order to help one to judge the friction properties of lubricating oils without tests, this paper intends to establish the correlation between the characteristic parameters of lubricating oils and the friction properties. The elastohydrodynamic and...

  • Article
  • Open Access
11 Citations
4,919 Views
16 Pages

The requirements for the fuel economy of modern industry continue to drive the progress of low-viscosity lubricants. The present work reports the application of polyether amine derivatives as friction modifiers to improve the tribological properties...

  • Article
  • Open Access
5 Citations
3,160 Views
15 Pages

Tribological Properties of Polydopamine-Modified Ag as Lubricant Oil Additives

  • Yanxin Zhang,
  • Jun Cheng,
  • Changfeng Lu,
  • Hao Chen,
  • Guoxin Xie,
  • Lin Zhang and
  • Jianbin Luo

1 December 2022

Nanoparticles agglomerate easily because of their high surface energy, which seriously reduces their tribological properties as lubricant additives. In this work, the core-shell nanoparticles Ag@polydopamine (PDA) were successfully prepared by the se...

  • Article
  • Open Access
1,031 Views
18 Pages

Performance Analysis of New Deuterium Tracer for Online Oil Consumption Measurements

  • Francesco Marzemin,
  • Martin Vareka,
  • Kevin Gschiel,
  • Bernhard Rossegger,
  • Peter Grabner,
  • Michael Engelmayer and
  • Nicole Wermuth

The accurate and precise measurement of lubricating oil consumption is critical for developing environmentally friendly internal combustion engines, particularly hydrogen-fueled internal combustion engines. The deuterium tracer method is based on the...

  • Article
  • Open Access
8 Citations
3,727 Views
16 Pages

Friction Behavior of Silver Perrhenate in Oil as Lubricating Additive for Use at Elevated Temperatures

  • Junhai Wang,
  • Ting Li,
  • Tingting Yan,
  • Xiaoyi Wei,
  • Xin Qu and
  • Shuai Yuan

8 July 2019

In this study, we use an aqueous solution synthesis method to prepare silver perrhenate powders and suspend them into a poly alpha olefin (PAO) base oil with polyoxyethylene octylphenyl ether. Four ball tests and ball-on-disk reciprocating mode are p...

  • Article
  • Open Access
5 Citations
3,986 Views
15 Pages

Alkylated Polyphenyl Ethers as High-Performance Synthetic Lubricants

  • Renguo Lu,
  • Hiroshi Tani,
  • Shinji Koganezawa and
  • Masayuki Hata

21 October 2022

Lubricants exhibiting both thermal and chemical stability that consequently generate less hydrogen during friction are required to avoid the hydrogen embrittlement of moving mechanical components. The present work studied the effects of the length an...

  • Article
  • Open Access
1 Citations
1,829 Views
16 Pages

21 February 2025

Anodizing can generate porous wear-resistant layers, which can act as reservoirs for gradually releasing lubricants. Studies on the formation of zinc dialkyl dithiophosphate (ZDDP) tribofilms in non-ferrous metals are relatively rare. Furthermore, ad...

  • Article
  • Open Access
63 Citations
6,035 Views
22 Pages

Insights into the Effects of Pore Size Distribution on the Flowing Behavior of Carbonate Rocks: Linking a Nano-Based Enhanced Oil Recovery Method to Rock Typing

  • Amin Rezaei,
  • Hadi Abdollahi,
  • Zeinab Derikvand,
  • Abdolhossein Hemmati-Sarapardeh,
  • Amir Mosavi and
  • Narjes Nabipour

As a fixed reservoir rock property, pore throat size distribution (PSD) is known to affect the distribution of reservoir fluid saturation strongly. This study aims to investigate the relations between the PSD and the oil–water relative permeabi...

  • Communication
  • Open Access
12 Citations
3,733 Views
11 Pages

Preparation of Poly-1-butene Nanofiber Mat and Its Application as Shutdown Layer of Next Generation Lithium Ion Battery

  • Hanjin Jeong,
  • Sohee Kim,
  • Manjae Gil,
  • Sanghoon Song,
  • Tae-Ho Kim and
  • Kyung Jin Lee

1 October 2020

Nonwoven nanofiber webs from polyolefin show great potential in various fields such as nanofilters, high performance membranes and separators in lithium ion batteries (LiB). Although nonwoven microfiber webs can be obtained by the well-established me...

  • Article
  • Open Access
38 Citations
7,638 Views
12 Pages

Viscosity Models for Polymer Free CO2 Foam Fracturing Fluid with the Effect of Surfactant Concentration, Salinity and Shear Rate

  • Shehzad Ahmed,
  • Khaled Abdalla Elraies,
  • Muhammad Rehan Hashmet and
  • Alvinda Sri Hanamertani

26 November 2017

High quality polymer free CO2 foam possesses unique properties that make it an ideal fluid for fracturing unconventional shales. In this paper, the viscosity of polymer free fracturing foam and its empirical correlations at high pressure high tempera...

  • Article
  • Open Access
1 Citations
1,988 Views
10 Pages

6 October 2023

The harmful effects of wear can be reduced through proper lubrication of the frictional parts. When exposed to excessive loads, the lubricant film is displaced from the surfaces, and even the adhesive lubricant layer may rupture. Additives known as E...

  • Article
  • Open Access
22 Citations
4,162 Views
19 Pages

Characterization and Tribological Performances of Graphene and Fluorinated Graphene Particles in PAO

  • Yanjie Chen,
  • Enzhu Hu,
  • Hua Zhong,
  • Jianping Wang,
  • Ayush Subedi,
  • Kunhong Hu and
  • Xianguo Hu

20 August 2021

Graphene has been widely used as a lubricating additive to reduce the energy consumption of engines and improve fuel economy because of its unique crystal structure. Herein, graphene (GR) and fluorinated graphene (F-GR) nanoparticles were prepared by...

  • Article
  • Open Access
68 Citations
9,411 Views
26 Pages

17 June 2021

Low-cost optical particle counters effectively measure particulate matter (PM) mass concentrations once calibrated. Sensor calibration can be established by deriving a linear regression model by performing side-by-side measurements with a reference i...

  • Article
  • Open Access
3 Citations
1,748 Views
16 Pages

Research and Evaluation of Foam-Drainage Corrosion-Inhibition Hydrate Anti-Aggregation Integrated Agent

  • Weijun Ni,
  • Guohao Yang,
  • Jie Dong,
  • Yansong Pan,
  • Gang Chen and
  • Xuefan Gu

14 September 2023

In natural gas exploitation, foam drainage, corrosion inhibition and hydrate inhibition of wellbore fluid are conventional operations. However, there is often a problem where multiple chemical agents cannot be effectively used together and can only b...

  • Article
  • Open Access
1 Citations
1,524 Views
18 Pages

13 December 2024

In order to characterize the volatile chemical components of Schisandra chinensis processed by different Traditional Chinese Medicine Processing methods and establish fingerprint profiles, headspace–gas chromatography–ion mobility spectro...

  • Article
  • Open Access
28 Citations
4,041 Views
21 Pages

Improvement of Steam Injection Processes Through Nanotechnology: An Approach through in Situ Upgrading and Foam Injection

  • Oscar E. Medina,
  • Yira Hurtado,
  • Cristina Caro-Velez,
  • Farid B. Cortés,
  • Masoud Riazi,
  • Sergio H. Lopera and
  • Camilo A. Franco

6 December 2019

This study aims to evaluate a high-performance nanocatalyst for upgrading of extra-heavy crude oil recovery and at the same time evaluate the capacity of foams generated with a nanofluid to improve the sweeping efficiency through a continuous steam i...

  • Article
  • Open Access
4 Citations
2,798 Views
20 Pages

Structure–Performance Relationship of Coal-Based Lubricating Base Oils and Sensitivities to Typical Additives

  • Junyi Liu,
  • Zhaojun Zhang,
  • Xia Zhou,
  • Wenjing Hu,
  • Renmin Pan and
  • Jiusheng Li

The relationship between the structure characteristics and performances of coal-based hydrogenation isomeric (CTL) base oil and metallocene-catalyzed coal-based poly-alpha-olefin (mPAO) base oil is clarified in this paper. CTL and mPAO were compared...

  • Article
  • Open Access
3 Citations
3,445 Views
17 Pages

18 September 2018

Magnesium perrhenate used as a lubricating additive was prepared by an aqueous solution method in this paper, and was suspended in a base oil poly alpha olefin (PAO6) with the aid of surface active agents (SA). The thermal stability of the mixed oil...

  • Article
  • Open Access
12 Citations
4,536 Views
15 Pages

12 December 2023

Polyethylene (PE)-based elastomers are the ideal choice for enhancing the compatibility of polypropylene/polyethylene (PP/PE) blends and improving the mechanical properties of PP-based materials. However, the issue of blend systems lies in the interp...

  • Article
  • Open Access
6 Citations
4,156 Views
15 Pages

Energy-Saving UHMW Polymeric Flow Aids: Catalyst and Polymerization Process Development

  • Muhammad Atiqullah,
  • Abdelsalam H. Al-Sarkhi,
  • Faisal M. Al-Thenayan,
  • Abdullah R. Al-Malki and
  • Hassan S. Alasiri

28 November 2019

Crude oil and refinery products are transported worldwide to meet human energy needs. During transportation via pipeline, huge pumping power is required to overcome the frictional pressure drop and the associated drag along the pipeline. The reducti...

  • Article
  • Open Access
1,586 Views
14 Pages

15 August 2024

The dilute-foam dispersion system improves oil recovery by reducing interfacial tension between oil and water, altering wettability, and diverting displaced fluids by plugging larger pores. An optimized foaming system is obtained by formability evalu...

  • Article
  • Open Access
9 Citations
2,063 Views
15 Pages

Effect of Protease Combined with Heat Treatment on the Volatile Composition and Aroma Quality in Liqueur Wine

  • Wen Li,
  • Zhen Zhang,
  • Yuanyuan Zhao,
  • Wei Li,
  • Li Wang,
  • Qi Shang,
  • Jianming Du and
  • Lina Jin

30 June 2023

The aim of this paper was to compare the effects of two clarification methods, protease combined with heat treatment and bentonite, on the aroma quality of liqueur wines, and to identify and analyze the overall differences between the basic component...

  • Article
  • Open Access
1 Citations
459 Views
24 Pages

15 October 2025

Carbon dioxide (CO2) has been widely applied in gas flooding for reservoir development due to its remarkable oil recovery potential. However, because its viscosity is lower than that of water and most crude oils, severe channeling often occurs during...