Search Results (78)

Biomass reforming under mild conditions for synergistic hydrogen production, driven by renewable solar energy, has rapidly emerged as a promising strategy that not only enables the efficient reutilization of biomass but also facilitates the generation of high-purity hydrogen. In this work, ZnCdS (ZCS) nanoparticles and CoWO₄ (CW) nanocrystals were assembled via a solvothermal method to construct a ZCS/CW S-type heterojunction composite. The resultant materials’ physicochemical characteristics were methodically described. With lignin model compounds (PP-ol) and sodium lignosulfonate as substrates, the ZnCdS/CoWO₄-10% catalyst demonstrated a significant generation of hydrogen activity, producing hydrogen at rates of 223.30 μmol·g⁻¹·h⁻¹ and 140.28 μmol·g⁻¹·h⁻¹, respectively, according to experimental results. The formation of heterojunctions endows composite photocatalysts with higher hydrogen evolution rates compared to single-component catalysts. This is attributed to energy band bending at the interface of the heterojunction, which facilitates efficient charge separation while maintaining strong redox capabilities. High-value compounds like phenol and acetophenone were formed when the oxidation products in the post-reaction lignin model compound solution were subsequently analyzed using high-performance liquid chromatography. Additionally, a convincing mechanism for the catalytic reaction was suggested. It is expected that this study will offer a viable route for the creation of effective photocatalytic materials, high-value organic waste transformation, and sustainable hydrogen production. Full article

Imagine picking up an e-scooter or e-bike from a charging dock on campus that combines solar panels with a filtered rainwater refill fountain, a mobile phone charging point, climbing plants, and insect habitats. What if the space also offered composting for food waste, shelter from the rain, and a space to meet friends—open to all to support the university’s civic role in the wider city? This paper explores the ideas affecting biodiversity, health, and wellbeing of co-created design explorations of 15-minute city principles on university campuses. Originating from urban planning, the 15-minute city proposes that essential needs like education, healthcare, work, and leisure are accessible by active travel. Applied to a university campus, it means students and staff can access classrooms, housing, food, and recreation in just 15 minutes. Beyond convenience, this approach is argued to foster inclusive, mixed-use, and potentially ecologically regenerative spaces. Drawing on regenerative design thinking—which aims to restore and co-evolve human and natural systems—this participatory design research critically responds to top-down models by involving students and university stakeholders in co-creating visions for a 15-minute campus. The results show that through this participatory design process, cocreators contributed to shaping ideas that foster belonging, emotional attachment, and co-responsibility for place. The research concludes by proposing an innovative reorientation of the 15-minute-city—from a model concerned primarily with needs and efficiency, to one grounded in ecological consciousness, autonomy, and human–nature co-evolution. Full article

The rapid proliferation of Chat Generative Pre-trained Transformer (ChatGPT) marks a pivotal moment in artificial intelligence, eliciting responses from academic shock to industrial awe. As these technologies advance from passive tools toward proactive, agentic systems, their transformative potential and inherent risks are magnified globally. This paper presents a comprehensive, critical review of ChatGPT’s impact across five key domains: natural language understanding (NLU), content generation, knowledge discovery, education, and engineering. While ChatGPT demonstrates profound capabilities, significant challenges remain in factual accuracy, bias, and the inherent opacity of its reasoning—a core issue termed the “Black Box Conundrum”. To analyze these evolving dynamics and the implications of this shift toward autonomous agency, this review introduces a series of conceptual frameworks, each specifically designed to illuminate the complex interactions and trade-offs within these domains: the “Specialization vs. Generalization” tension in NLU; the “Quality–Scalability–Ethics Trilemma” in content creation; the “Pedagogical Adaptation Imperative” in education; and the emergence of “Human–LLM Cognitive Symbiosis” in engineering. The analysis reveals an urgent need for proactive adaptation across sectors. Educational paradigms must shift to cultivate higher-order cognitive skills, while professional practices (including practices within education sector) must evolve to treat AI as a cognitive partner, leveraging techniques like Retrieval-Augmented Generation (RAG) and sophisticated prompt engineering. Ultimately, this paper argues for an overarching “Ethical–Technical Co-evolution Imperative”, charting a forward-looking research agenda that intertwines technological innovation with vigorous ethical and methodological standards to ensure responsible AI development and integration. Ultimately, the analysis reveals that the challenges of factual accuracy, bias, and opacity are interconnected and acutely magnified by the emergence of agentic systems, demanding a unified, proactive approach to adaptation across all sectors. Full article

Citation networks are fundamental for analyzing the mechanisms and patterns of knowledge creation and dissemination. While most studies focus on pairwise attachment between papers, they often overlook compound relational structures, such as co-citation. Combining two key empirical features, superlinear node inflow and the temporal decay of node influence, we propose the Triangular Evolutionary Model of Superlinear Growth and Aging (TEM-SGA). The fitting results demonstrate that the TEM-SGA reproduces key structural properties of real citation networks, including degree distributions, generalized degree distributions, and average clustering coefficients. Further structural analyses reveal that the impact of aging varies with structural scale and depends on the interplay between aging and growth, one manifestation of which is that, as growth accelerates, it increasingly offsets aging-related disruptions. This motivates a degenerate model, the Triangular Evolutionary Model of Superlinear Growth (TEM-SG), which excludes aging. A theoretical analysis shows that its degree and generalized degree distributions follow a power law. By modeling interactions among triadic closure, dynamic expansion, and aging, this study offers insights into citation network evolution and strengthens its theoretical foundation. Full article

A growing body of scholarship recognizes the importance of understanding the inner dimensions of transformations to sustainability at individual, collective, and system levels and their influence on the behavior of individuals and groups and the types of institutions that prevail. This review summarizes and synthesizes scholarship on the inner dimensions of regeneration, a subject of growing interest in the sustainability science literature. Regeneration refers to a process of rebuilding or renewing an asset, resource, ecosystem, individual, family, organization, community, or place. It enables the expression of nature’s capacity for self-organization and empowers social-ecological systems to revive themselves through positive reinforcing cycles. The review seeks to improve understanding of the characteristics and meanings of regenerative mental models, mindsets, and cultures. It begins with definitions, then describes methods, summarizes results, and discusses what regenerative mental models and mindsets look like when they become part of culture and are scaled to larger social-ecological systems. Full article

Electro-oxidation of urea (UOR) in alkaline medium is one of the most effective alternative ways of producing green hydrogen, as the oxidation potential in UOR is less and thermodynamically more favorable than conventional water oxidation. The development of cost-effective materials in catalyzing UOR is recently seeking more attention in the research hotspot. Suitably modifying the Ni-based catalysts towards active site creation and preventing surface passivation is much important in this context, following which we reported the synthesis of Ni₃S₂ (NS) supported with CuCo (CC) bimetallic (NSCC). A simple hydrothermal route for NS synthesis and the electrodeposition method for CuCo (CC) deposition is adapted in a self-supported manner. The NS and CC catalysts exhibited sheet-like morphology, as confirmed by SEM and TEM analysis. The bimetallic CC deposition prevented the surface passivation of nickel sulfide (NS) over oxygen evolution reaction (OER) and improved the charge-transfer kinetics. The NSCC catalyst catalyzed UOR in an alkaline medium, which required a lower potential of 1.335 V vs. RHE to attain the current density of 10 mAcm⁻², with a lower Tafel slope value of 131 mVdec⁻¹. In addition, a two-electrode cell setup is constructed with an operating cell voltage of 1.512 V for delivering 10 mAcm⁻² current density. This study illustrates the new strategy of designing heterostructure catalysts for electrocatalytic UOR. Full article

Against the backdrop of China’s urban transformation from incremental expansion to stock regeneration, community regeneration has emerged as a critical mechanism for enhancing urban governance efficacy. As fundamental units of urban systems, the regeneration of communities requires comprehensive approaches to address complex socio-spatial challenges, with public participation serving as the core driver for achieving sustainable renewal goals. However, significant regional disparities persist in the effectiveness of public participation across China, necessitating the systematic institutionalization of participatory practices. Guangzhou, as a pioneering city in institutional innovation and the practical exploration of urban regeneration, provides a representative case for examining the evolutionary trajectory of participatory planning. This research employs Arnstein’s Ladder of Participation theory, utilizing literature analysis and comparative case studies to investigate the evolution of participatory mechanisms in Guangzhou’s community regeneration over four decades. The study systematically examined the transformation of public engagement models across multiple dimensions, including organizational frameworks of participation, participatory effectiveness, diversified financing models, and the innovation of policy instruments. Three paradigm shifts were identified: the (1) transition of participants from “passive responders” to “active constructors”, (2) advancement of engagement phases from “fragmented intervention” to “whole-cycle empowerment”, and (3) evolution of participation methods from “unidirectional communication” to “collaborative co-governance”. It identifies four drivers of participatory effectiveness: policy frameworks, financing mechanisms, mediator cultivation, and engagement platforms. To enhance public engagement efficacy, the research proposes the following: (1) a resilient policy adaptation mechanism enabling dynamic responses to multi-stakeholder demands, (2) a diversified financing framework establishing a “government guidance + market operation + resident contribution” cost-sharing model, (3) a professional support system integrating “localization + specialization” capacities, and (4) enhanced digital empowerment and institutional innovation in participatory platform development. These mechanisms collectively form an evolutionary pathway from “symbolic participation” to “substantive co-creation” in urban regeneration governance. Full article

Powders with phase composition including quasi-amorphous phases and calcium carbonate CaCO₃ in the form of calcite or aragonite and sodium halite NaCl as a reaction by-product were synthesized from 0.5M aqua solutions of sodium silicate and 0.5M aqua solutions of calcium and/or magnesium chlorides. Starting solutions were taken in quantities which could provide precipitation of hydrated calcium and/or magnesium silicates with molar ratios Ca/Si = 1 (CaSi), Mg/Si = 1 (MgSi) or (Ca+Mg)/Si = 1 (CaMgSi). Hydrated calcium and/or magnesium silicates, hydrated silica, magnesium carbonate, hydrated magnesium carbonate or hydrated magnesium silicate containing carbonate ions are suspected as components of quasi-amorphous phases presented in synthesized powders. Heat treatment of synthesized powders at 400, 600, 800 °C and pressed preceramic samples at 900, 1000, 1100 and 1200 °C were used for investigation of thermal evolution of the phase composition and microstructure of powders and ceramic samples. Mass loss of powder samples under investigation during heat treatment was provided due to evacuation of H₂O (m/z = 18), CO₂ (m/z = 44) and NaCl at temperatures above its melting point. After sintering at 1100 °C, the phase composition of ceramic samples included wollastonite CaSiO₃ (CaSi_1100); enstatite MgSiO₃, clinoenstatite MgSiO₃ and forsterite Mg₂SiO₄ (MgSi_1100); and diopside CaMgSi₂O₆ (CaMgSi_1100). After sintering at 1200 °C, the phase composition of ceramics CaSi_1200 included pseudo-wollastonite CaSiO₃. After heat treatment at 1300 °C, the phase composition of MgSi_1300 powder included preferably protoenstatite MgSiO₃. The phase composition of all samples after heat treatment belongs to the oxide system CaO–MgO–SiO₂. Ceramic materials in this system are of interest for use in different areas, including refractories, construction materials and biomaterials. Powders prepared in the present investigation, both via precipitation and via heat treatment, can be used for the creation of materials with specific properties and in model experiments as lunar regolith simulants. Full article

The growing importance of customer experience management (CEM) in the tourism sector has led to a proliferation of research interests in satisfaction enhancement, loyalty, and value co-creation. This study proposes a systematic and exhaustive thematic and bibliometric analysis of 3874 articles on CEM in the tourism industry published in the Scopus database between 1979 and 2024. Following the guidelines of the PRISMA protocol, the study uses Bibliometrix (version 4.4.1) in R and VOSviewer (version 1.6.20) to map publication trends, author networks, thematic and chronological evolution, and influential contributions. A qualitative content analysis of the most cited works, guided by grounded theory, revealed the main antecedents, consequences, mediators, and moderators of customer experience management. This analysis is embodied in the proposal of a conceptual model that illustrates the dynamic relationship between these elements and provides the basis for future research for theoretical enrichment and empirical validation. The results offer actionable insights for academics and industry practitioners alike, with the aim of promoting authentic and memorable tourism experiences. Full article

A “thermal-annealing vacancy-filling” synthesis strategy was developed to engineer cobalt single-atom catalysts (Co-MoS₂/RGO) for exceptional hydrogen evolution reaction (HER) performance. By anchoring atomic Co onto Frenkel defect-engineered MoS₂ nanosheets supported by reduced graphene oxide (RGO), we achieved simultaneous optimization of catalytic stability, electrical conductivity, and active site accessibility. The optimized Co₃-MoS₂/RGO hybrid demonstrates remarkable alkaline HER activity, requiring only 94.0 mV overpotential to achieve 10 mA cm⁻² current density while maintaining excellent durability over extended operation. The atomically dispersed Co promoted HER kinetics through electronic structure modulation of MoS₂ basal planes, creation of catalytic active centers, and defect-mediated synergies. The RGO further contributed to performance enhancement by preventing nanosheet aggregation, facilitating charge transfer, and exposing active sites. This defect engineering strategy provides a facile method for developing cost-effective, stable, and high-performance electrocatalysts for sustainable hydrogen production. Full article

In today’s rapidly evolving digital landscape and accelerating technological development, industrial clusters play a crucial role in fostering innovation and ensuring sustainable economic growth. However, their effectiveness largely depends on the organization of optimal interactions between the participants, which implies a balanced allocation of resources and the co-evolution of capitals within the cluster. In this paper, we introduce strategic tools designed to form cluster capital by integrating financial, technological, and intellectual resources to create a sustainable environment for technological innovation implementation. To solve the set tasks, we developed a mathematical model based on the entropy approach and network analysis methods. This was developed to model and optimize the resource distribution among the cluster participants. The application of the proposed model using the example of the PenzaStankoMash industrial machine-building cluster has shown that the optimal configuration of the actors’ capitals in clusters contributes to the creation of synergetic effects. This increases the innovation potential and overall efficiency of the system. Our modeling considered various capital allocation scenarios, leading us to conclude that a balanced approach is important. The results of this study contribute to an in-depth understanding of the mechanisms for optimizing interactions in clusters. They contain specific strategic tools for managing capitals in clusters and contribute to the development of industrial policy based on the principles of a systematic approach. Full article

Sign language machine translation (SLMT)—the task of automatically translating between sign and spoken languages or between sign languages—is a complex task within the field of NLP. Its multi-modal and non-linear nature require the joint efforts of sign language (SL) linguists, technical experts, and SL users. Effective user involvement is a challenge that can be addressed through co-creation. Co-creation has been formally defined in many fields, e.g., business, marketing, educational, and others; however, in NLP and in particular in SLMT, there is no formal, widely accepted definition. Starting from the inception and evolution of co-creation across various fields over time, we develop a relationship typology to address the collaboration between deaf, hard of hearing, and hearing researchers and the co-creation with SL users. We compare this new typology to the guiding principles of participatory design for NLP. We then assess 111 articles from the perspective of involvement of SL users and highlight the lack of involvement of the sign language community or users in decision-making processes required for effective co-creation. Finally, we derive formal guidelines for co-creation for SLMT which take the dynamic nature of co-creation throughout the life cycle of a research project into account. Full article

The maritime pine (Pinus pinaster) is the main conifer species in Portugal, occurring mainly in the central and northern regions of the country. In addition to its environmental significance, it plays an important socio-economic role, supported by a robust forest sector. In the face of climate change driven by the release of CO₂ into the atmosphere, forests play an essential role in mitigating these changes by storing large amounts of carbon in their biomass. This study assesses the impact of forest management, focusing on thinning, on carbon accumulation in naturally regenerating maritime pine forests in the municipality of Boticas, Portugal and compares scenarios with and without forest intervention. To simulate forest growth scenarios, the Modispinaster software is used, and through mathematical models adjusted for the species and input of initial field data, it generates scenarios of forest evolution regarding biomass and carbon accumulation. Additionally, it allows for the visualization of the forest’s dendrometric characteristics throughout the cycle, enabling the creation of the carbon balance and its analysis across multiple scenarios. The results demonstrate that management based on thinning increases carbon retention, reducing early mortality and promoting the growth of larger diameter trees. Although natural forests initially accumulate more carbon, the reduction in competition in managed forests allows for greater carbon accumulation from the 24th year onwards, reaching 178 tons at the end of the cycle, in contrast to 143 tons in unmanaged areas. The carbon balance result in the unmanaged (natural) forest was negative (−18 tons), while in the managed forest, the result was positive (54 tons). This supports the thesis that thinning, although more intense and less frequent than mortality events, is more effective than the absence of interventions. Thinned forests optimize the carbon balance in Pinus pinaster, improving long-term retention by reducing competition and mortality. Managed forests show a positive carbon balance, highlighting the importance of sustainable management in mitigating climate change and strengthening ecological resilience. Full article

With the continuous development of information and communication technology, “software-defined vehicle” has become the trend of the times. The intelligent connected vehicle (ICV) is becoming a new direction for the development of the automotive industry. Nevertheless, the absence of cooperative innovation in the ICV sector, the dispersal of industrial chain resources, and the absence of enduring and consistent cooperation pose significant obstacles to value co-creation. Therefore, this paper constructs a value co-creation evolutionary game model of the innovation ecosystem of the ICV industry with the automotive enterprise, an intelligent automotive solution provider and the government as players, and applies prospect theory to optimize the tripartite evolutionary game. The payment matrix is established, the expected revenue is analyzed for each player’s strategies, and the replication dynamic equation and evolutionary stability strategy are analyzed. Finally, the theoretical research is validated through numerical simulation. The aim is to promote value co-creation by analyzing the co-evolution mechanism of various stakeholder strategies in the ICV innovation ecosystem. The results show the following: (1) The best evolutionary stability strategy is the positive cross-border cooperation between the automotive enterprise and the intelligent automotive solution provider, while the government gradually does not provide subsidies. (2) The government’s subsidy support should be controlled within an appropriate range. If the subsidy is too great, the marginal effect of incentives will gradually weaken. (3) The players’ willingness to integrate across borders can be enhanced by a higher level of trust and resource complementarity between the automotive enterprise and intelligent automotive solution provider. Also, liquidated damages and opportunity loss can effectively prevent the occurrence of negative integration behaviors. (4) The greater the risk attitude coefficient and risk aversion coefficient of the automotive enterprise and intelligent automotive solution provider, the more conducive they are to the occurrence of positive integration behavior. Full article

This study explores the potential of laser surface modification (LSM) to enhance the biological properties of melt-derived bioactive glasses, specifically 45S5 and ICIE16, which are key in medical implants due to their bone-regenerating capabilities. Despite their bioactivity, these materials have limitations in cellular adhesion due to their smooth surfaces. LSM enables the creation of precise surface patterns that could improve interactions with biological environments. This study involved surface texturing bioactive glass (BG) samples using CO₂ and femtosecond (fs) laser systems, modifying the laser average power, scanning speed, line spacing, and number of passes. Characterization methods included optical and stereoscopic microscopy, profilometry, and solubility tests in Tris-HCl buffer to evaluate surface roughness evolution, morphology, and bioactive behavior. The findings demonstrated significant modifications in surface properties post-texturing. The CO₂ laser-treated surfaces preserve the increased roughness values after 75 days of immersion in Tris-HCl buffer for both 45S5 and ICIE16 melt-quenched bioactive glasses, showing a potential long-term osteoconductivity enhancement. On the contrary, the femtosecond laser-treated surfaces revealed a preferential apatite precipitation ability at the pattern grooves. Femtosecond laser modification stands as a suitable technique to provide preferential osteoconductivity characteristics when conducted on the surface of bioactive glass with moderate reactivity, such as ICIE16 bioactive glass. Full article