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Keywords = elastic recovery coefficient

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20 pages, 1551 KB  
Article
Viscoelastic Compression Behavior and Model Characterization of Alfalfa Blocks Under Different Conditions
by Jiawen Hu, Qiankun Fu, Hongxu Xing, Xiucheng Yang, Yang Li and Jun Fu
Agriculture 2026, 16(1), 119; https://doi.org/10.3390/agriculture16010119 - 2 Jan 2026
Viewed by 699
Abstract
Alfalfa is a high-quality forage crop whose viscoelastic properties strongly influence the performance of baling, pickup, and stacking operations. In this study, small alfalfa block specimens were tested using a universal testing machine to investigate stress relaxation and creep behaviors under different moisture [...] Read more.
Alfalfa is a high-quality forage crop whose viscoelastic properties strongly influence the performance of baling, pickup, and stacking operations. In this study, small alfalfa block specimens were tested using a universal testing machine to investigate stress relaxation and creep behaviors under different moisture contents (12%, 15%, 18%), densities (100, 150, 200 kg/m3), and maximum compressive stresses (8, 12, 16 kPa). Experimental data were fitted using viscoelastic models for parameter analysis. Results indicated that the relaxation response consisted of a rapid attenuation followed by a slow stabilization phase. The five-element Maxwell model achieved a higher fitting accuracy (coefficient of determination, R2 > 0.997) than the three-element model. The creep process exhibited three stages, including instantaneous elastic deformation, decelerated creep, and steady-state deformation, and it was accurately represented by the five-element Kelvin model (R2 > 0.998). Increasing moisture content reduced stiffness, while moderate moisture improved viscosity and shape retention. Higher density enhanced blocks compactness, stiffness, and damping characteristics, resulting in smaller deformation. The viscoelastic response to compressive stress showed moderate enhancement followed by attenuation under overload, with the best recovery and deformation resistance observed at 12 kPa. These findings elucidate the viscoelastic behavior of alfalfa blocks and provide theoretical support and engineering guidance for evaluating bale stability and optimizing pickup–clamping parameters. Full article
(This article belongs to the Section Agricultural Technology)
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20 pages, 4047 KB  
Article
Research on Mixing Uniformity Evaluation and Molding Method for Crumb Rubber Asphalt Mixtures
by Wenhua Wang, Yi Lu, Lingdi Kong, Wenke Yan, Yilong Li, Mulian Zheng, Chuan Lu and Guanglei Qu
Materials 2025, 18(22), 5245; https://doi.org/10.3390/ma18225245 - 20 Nov 2025
Viewed by 744
Abstract
The broader adoption of crumb rubber asphalt mixtures (CRAM) as sustainable pavement materials is currently limited by two key technical barriers. Firstly, there is a lack of standardized methods to evaluate mixing uniformity. Secondly, the material’s tendency for elastic recovery after compaction remains [...] Read more.
The broader adoption of crumb rubber asphalt mixtures (CRAM) as sustainable pavement materials is currently limited by two key technical barriers. Firstly, there is a lack of standardized methods to evaluate mixing uniformity. Secondly, the material’s tendency for elastic recovery after compaction remains problematic. These barriers ultimately hinder the realization of CRAM’s full potential in vibration reduction, noise abatement, and resource recycling. To improve the performance evaluation system of CRAM and promote its development in engineering applications. Based on the distribution characteristics of crumb rubber in asphalt mixtures, this study established a crumb rubber distribution area moment model. It proposed a coefficient of area–distance variation to evaluate the mixing uniformity of CRAM. Through compaction tests and orthogonal tests, the effects of mixing process, mixing time, mixing temperature, compaction temperature, compaction times, and compaction method on the mixing uniformity and performance of CRAM are systematically investigated. The results show that, compared with specimens prepared by single compaction and compaction after high-temperature curing, CRAM specimens prepared by secondary compaction exhibit superior mechanical performance. The 24 h elastic recovery rate of these specimens is reduced to 24% of that in single-compacted specimens. The mixing process and mixing time have a significant impact on the mixing uniformity of CRAM. Pre-mixing crumb rubber with aggregates or extending the mixing time can improve the CRAM mixing uniformity by 45% and 18%, respectively. The mixing and compaction temperatures primarily affect the bulk density and Marshall stability of the specimens. When the mixing and compaction temperatures are 180 °C and 170 °C, respectively, the bulk density and Marshall stability of the molded specimens reach their maximum values. Through orthogonal analysis, the optimal mixing method for CRAM is determined as follows: mix aggregates and crumb rubber at 180 °C for 40 s, then add asphalt and continue mixing for another 80 s. The optimal process for secondary compaction is as follows: the first compaction at 170 °C, compacting each side 47 times, and the second compaction at 80 °C, compacting each side 23 times. Full article
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22 pages, 6608 KB  
Article
Dynamic Response of Fracture Networks and the Evolution of Waterflood Fronts During Fracture-Flooding
by Bintao Zheng, Liaoyuan Zhang, Yunfan Liu, Yuan Li, Yuzhe Zhang, Xiaodan Li and Lei Li
Processes 2025, 13(11), 3592; https://doi.org/10.3390/pr13113592 - 6 Nov 2025
Cited by 2 | Viewed by 540
Abstract
This study investigates the dynamic response of fracture networks and the evolution of waterflood fronts during fracture-flooding in low-permeability and tight reservoirs. By establishing a discrete fracture model that incorporates geomechanical heterogeneity and natural fractures, and utilizing the Barton-Bandis criterion to describe fracture [...] Read more.
This study investigates the dynamic response of fracture networks and the evolution of waterflood fronts during fracture-flooding in low-permeability and tight reservoirs. By establishing a discrete fracture model that incorporates geomechanical heterogeneity and natural fractures, and utilizing the Barton-Bandis criterion to describe fracture stress-sensitive behavior, the fracture-flooding process was simulated and analyzed under two scenarios: considering versus ignoring the time-varying stress effect. The results demonstrate that when the time-varying stress effect is considered, fracture conductivity gradually recovers with increasing injection pressure, as the elevated fluid pressure within the fractures reduces the effective normal stress, promoting elastic dilation of the fracture aperture. This is evidenced by the average conductivity coefficient increasing from 0.4 (near-closure) to 0.99 (fully open) during the injection period. This recovery mechanism promotes a “wall-imbibition-dominated” flow pattern. In contrast, neglecting this effect leads to a “fracture-tip-breakthrough-dominated” mode, causing poor front uniformity. Quantitative analysis of the front morphology confirms this improvement: the perimeter-to-area ratio decreased from 2.507 to 1.647, and the coefficient of variation dropped from 0.490 to 0.324. This research provides an important theoretical basis for optimizing fracture-flooding operations and enhancing oil recovery. Full article
(This article belongs to the Special Issue Flow Mechanisms and Enhanced Oil Recovery)
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21 pages, 4394 KB  
Article
Experimental Investigation of Nanodiamond Reinforcement in PU for Enhancing Mechanical, Scratch, Rheological, Thermal, and Shape-Memory Properties
by Markapudi Bhanu Prasad, Nashmi H. Alrasheedi, P. S. Rama Sreekanth, Borhen Louhichi, Santosh Kumar Sahu and Nitesh Dhar Badgayan
Polymers 2025, 17(21), 2947; https://doi.org/10.3390/polym17212947 - 4 Nov 2025
Cited by 3 | Viewed by 1282
Abstract
Shape-memory polymers (SMPs) are a unique class of smart materials capable of recovering their original shape upon external stimuli, with thermoresponsive polyurethane (PU) being one of the most widely studied systems. However, the relatively low mechanical strength, thermal stability, and durability of PU [...] Read more.
Shape-memory polymers (SMPs) are a unique class of smart materials capable of recovering their original shape upon external stimuli, with thermoresponsive polyurethane (PU) being one of the most widely studied systems. However, the relatively low mechanical strength, thermal stability, and durability of PU limit its broader functional applications. PU/ND composites containing 0.1–0.5 wt.% ND were fabricated via melt blending and injection molding method. The objective was to evaluate the effect of ND reinforcement on the mechanical, scratch, thermal, rheological, and shape-memory properties. Results show that tensile strength increased up to 114% and Young’s modulus by 11% at 0.5 wt.% ND, while elongation at break decreased due to restricted chain mobility. Hardness improved by 21%, and scratch resistance was significantly enhanced, with the coefficient of friction reduced by 56% at low loads. Thermal stability was improved, with the maximum degradation temperature shifting from 350 °C (pure PU) to 362 °C (0.5 wt.% PU/ND) and char yield increasing by 34%. DSC revealed an increase in glass transition temperature from 65 °C to 68.6 °C. Rheological analysis showed an 89% reduction in damping factor (tan δ), indicating enhanced elasticity. Shape-memory tests confirmed notable improvements in both shape fixity and recovery ratios across successive cycles compared to neat PU, with the highest enhancements observed for the 0.5 wt.% PU/ND nanocomposite—showing up to 7.6% higher fixity and 32% higher recovery than pure PU. These results demonstrate that ND reinforcement effectively strengthens PU while preserving and improving its shape-memory behavior, making the composites promising candidates for high-performance smart materials in sensors, actuators, and aerospace applications. Full article
(This article belongs to the Special Issue Polyurethane Composites: Properties and Applications)
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27 pages, 36375 KB  
Article
Calibration Framework for Modeling Nonlinear Viscoelastic–Plastic Behavior of Bioresorbable Polymers in Finite Element Analysis for Stent Applications
by Nicklas Fiedler, Thomas Kleine, Stefan Oschatz, Selina Schultz, Niels Grabow and Kerstin Lebahn
Polymers 2025, 17(21), 2863; https://doi.org/10.3390/polym17212863 - 27 Oct 2025
Viewed by 922
Abstract
Finite element analysis (FEA) is common in biomedical engineering for combining design and material development, with model validation crucial for accurate prediction of material behavior. Simplified geometries are commonly needed in stent development due to high effort in prototype manufacturing. This study outlines [...] Read more.
Finite element analysis (FEA) is common in biomedical engineering for combining design and material development, with model validation crucial for accurate prediction of material behavior. Simplified geometries are commonly needed in stent development due to high effort in prototype manufacturing. This study outlines a methodology for FEA validation related to stent development-related FEA validation using injection-molded planar 2D substructures from a stent design with two types of polymers: poly(l-lactide) (PLLA) and poly(glycolide-co-trimethylene carbonate) (PGA-co-TMC). Specimens underwent quasi-static and cyclic testing, including loading, stress relaxation, unloading, and strain recovery. The material model coefficients for FEA were calibrated for three different constitutive models: linear elastic–plastic (LEP), Parallel Rheological Framework (PRF), and Three-Network (TN) model. The validation of planar stent segment expansion (PSSE) showed strong agreement with the experiments in deformation patterns, with varying force–displacement responses. The PRF and TN models provided better fits for behavioral predictions, with the PRF model being especially favorable for PLLA, while all models exhibited limitations for PGA-co-TMC. This study proposes a robust approach for the material modeling in stent development, enabling efficient material screening and stent design optimization through a simplified 2D validation setup. Material model accuracy depends strongly on calibration–load case congruence, while phenomenological approaches (PRF) show enhanced model robustness against load case variations compared to physically coupled models (TN). Full article
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22 pages, 5445 KB  
Article
Effect of Adding Molybdenum on Microstructure, Hardness, and Corrosion Resistance of an AlCoCrFeNiMo0.25 High-Entropy Alloy
by Mariusz Walczak, Wojciech J. Nowak, Wojciech Okuniewski and Dariusz Chocyk
Materials 2025, 18(19), 4566; https://doi.org/10.3390/ma18194566 - 30 Sep 2025
Cited by 5 | Viewed by 1125
Abstract
Recent literature reports have shown that individual HEAs, especially those of the AlCoCrFeNi composition system alloyed with appropriately selected elements, exhibit excellent mechanical properties and corrosion resistance, making them promising candidates for replacing conventional materials such as austenitic steels in corrosive environments. Therefore, [...] Read more.
Recent literature reports have shown that individual HEAs, especially those of the AlCoCrFeNi composition system alloyed with appropriately selected elements, exhibit excellent mechanical properties and corrosion resistance, making them promising candidates for replacing conventional materials such as austenitic steels in corrosive environments. Therefore, in the present study, the high-entropy alloy AlCoCrFeNiMo0.25 was examined and compared with AISI 304L steel and the reference alloy AlCoCrFeNi. The HEA was produced by arc melting in vacuum. The effect of molybdenum addition (5% at.) on the structure, mechanical properties, and corrosion resistance was evaluated. Potentiodynamic polarization and electrochemical impedance spectroscopy tests were carried out in a 3.5% NaCl solution in a three-electrode electrochemical system. The addition of molybdenum to AlCoCrFeNiMox alloy additionally caused, along with the BCC phase, the formation of σ phase and FCC phase (less than 1%), as well as changes in the microstructure, leading to the fragmentation of grains and the formation of a mosaic structure. On the basis of nanoindentation tests, it was established that the addition of Mo increases hardness and elastic modulus and improves nanoindentation coefficients H/E and H3/E2, as well as an increase in the elastic recovery index while decreasing plasticity index (vs. the reference equiatomic HEA). This indicates the improvement of anti-wear properties with impact loading resistance. In turn, electrochemical tests have shown that the addition of Mo improves corrosion resistance. Corrosion pitting develops in Al- and Ni-rich areas of HEA alloys, as a result of galvanic microcorrosion related to Cr chemical segregation. In general, the addition of 5% Mo results in a fine-grained mosaic structure, which primarily translates into favorable nanoindentation and corrosion properties of the AlCoCrFeNiMo0.25 alloy. Full article
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23 pages, 6377 KB  
Article
Experimental and Numerical Study on the Restitution Coefficient and the Corresponding Elastic Collision Recovery Mechanism of Rapeseed
by Chuandong Liu, Haoping Zhang, Zebao Li, Zhiheng Zeng, Xuefeng Zhang, Lian Gong and Bin Li
Agronomy 2025, 15(8), 1872; https://doi.org/10.3390/agronomy15081872 - 1 Aug 2025
Cited by 2 | Viewed by 1754
Abstract
In this study, we aimed to address the lack of systematic research on key collision dynamics parameters (elastic restitution coefficient) in the full mechanization of rapeseed operations, which hinders the development of precision agriculture. In this present work, the restitution coefficient of rapeseed [...] Read more.
In this study, we aimed to address the lack of systematic research on key collision dynamics parameters (elastic restitution coefficient) in the full mechanization of rapeseed operations, which hinders the development of precision agriculture. In this present work, the restitution coefficient of rapeseed was systematically investigated, and a predictive model (R2 = 0.959) was also established by using Box–Behnken design response surface methodology (BBD-RSM). The results show that the collision restitution coefficient varies in the range of 0.539–0.649, with the key influencing factors ranked as follows: moisture content (Mc) > material layer thickness (L) > drop height (H). The EDEM simulation methodology was adopted to validate the experimental results, and the results show that there is a minimal relative error (−1% < δ < 1%) between the measured and simulated rebound heights, indicating that the established model shows a reliable prediction performance. Moreover, by comprehensively analyzing stress, strain, and energy during the collision process between rapeseed and Q235 steel, it can be concluded that the process can be divided into five stages—free fall, collision compression, collision recovery, rebound oscillation, and rebound stabilization. The maximum stress (1.19 × 10−2 MPa) and strain (6.43 × 10−6 mm) were observed at the beginning of the collision recovery stage, which can provide some theoretical and practical basis for optimizing and designing rapeseed machines, thus achieving the goals of precise control, harvest loss reduction, and increased yields. Full article
(This article belongs to the Section Precision and Digital Agriculture)
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22 pages, 9839 KB  
Article
Dynamic Simulation of Nano-Gel Microspheres for Plugging Preferential Flow Channels and Enhancing Oil Recovery in Waterflooded Reservoirs
by Long Ren, Cong Zhao, Jian Sun, Cheng Jing, Haitao Bai, Qingqing Li and Xin Ma
Gels 2025, 11(7), 536; https://doi.org/10.3390/gels11070536 - 10 Jul 2025
Viewed by 985
Abstract
This study addresses the unclear mechanisms by which preferential flow channels (PFCs), formed during long-term waterflooding, affect nano-gel microsphere (NGM) flooding efficiency, utilizing CMG reservoir numerical simulation software. A dynamic evolution model of PFCs was established by coupling CROCKTAB (stress–porosity hysteresis) and CROCKTABW [...] Read more.
This study addresses the unclear mechanisms by which preferential flow channels (PFCs), formed during long-term waterflooding, affect nano-gel microsphere (NGM) flooding efficiency, utilizing CMG reservoir numerical simulation software. A dynamic evolution model of PFCs was established by coupling CROCKTAB (stress–porosity hysteresis) and CROCKTABW (water saturation-driven permeability evolution), and the deep flooding mechanism of NGMs (based on their gel properties such as swelling, elastic deformation, and adsorption, and characterized by a “plugging-migration-replugging” process) was integrated. The results demonstrate that neglecting PFCs overestimates recovery by 8.7%, while NGMs reduce permeability by 33% (from 12 to 8 mD) in high-conductivity zones via “bridge-plug-filter cake” structures, diverting flow to low-permeability layers (+33% permeability, from 4.5 to 6 mD). Field application in a Chang 6 tight reservoir (permeability variation coefficient 0.82) confirms a >10-year effective period with 0.84% incremental recovery (from 7.31% to 8.15%) and favorable economics (ROI ≈ 10:1), providing a theoretical and engineering framework for gel-based conformance control in analogous reservoirs. Full article
(This article belongs to the Special Issue Applications of Gels for Enhanced Oil Recovery)
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17 pages, 2091 KB  
Article
Weight-Based Numerical Study of Shale Brittleness Evaluation
by Yu Suo, Fenfen Li, Qiang Liang, Liuke Huang, Liangping Yi and Xu Dong
Symmetry 2025, 17(6), 927; https://doi.org/10.3390/sym17060927 - 11 Jun 2025
Viewed by 770
Abstract
The implementation of lean drilling and completion design techniques is a pivotal strategy for the petroleum and natural gas industry to achieve green, low-carbon, and intelligent transformation and innovation. These techniques significantly enhance oil and gas recovery rates. In shale gas development, the [...] Read more.
The implementation of lean drilling and completion design techniques is a pivotal strategy for the petroleum and natural gas industry to achieve green, low-carbon, and intelligent transformation and innovation. These techniques significantly enhance oil and gas recovery rates. In shale gas development, the shale brittleness index plays a crucial role in evaluating fracturing ability during hydraulic fracturing. Indoor experiments on Gulong shale oil were conducted under a confining pressure of 30 MPa. Based on Rickman’s brittleness evaluation method, this study performed numerical simulations of triaxial compression tests on shale using the finite discrete element method. The fractal dimensions of the fractures formed during shale fragmentation were calculated using the box-counting method. Utilizing the obtained data, a multiple linear regression equation was established with elastic modulus and Poisson’s ratio as the primary variables, and the coefficients were normalized to propose a new brittleness evaluation method. The research findings indicate that the finite discrete element method can effectively simulate the rock fragmentation process, and the established multiple linear regression equation demonstrates high reliability. The weights reassigned for brittleness evaluation based on Rickman’s method are as follows: the coefficient for elastic modulus is 0.43, and the coefficient for Poisson’s ratio is 0.57. Furthermore, the new brittleness evaluation method exhibits a stronger correlation with the brittleness mineral index. The fractal characteristics of crack networks and the relationship between symmetry response and mechanical parameters offer a new theoretical foundation for brittle weight distribution. Additionally, the scale symmetry characteristics inherent in fractal dimensions can serve as a significant indicator for assessing complex crack morphology. Full article
(This article belongs to the Section Engineering and Materials)
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23 pages, 5161 KB  
Article
Correlating the Effects of UV Aging on the Macro-Micro Behaviors of Asphalt with Its Molecular Mechanisms
by Han Xi, Lingyun Kong, Shixiong Hu and Songxiang Zhu
Materials 2025, 18(10), 2165; https://doi.org/10.3390/ma18102165 - 8 May 2025
Cited by 2 | Viewed by 1005
Abstract
UV radiation can change the internal molecular composition, macroscopic rheological properties, and microscopic chemical composition of asphalt. To study the effect of ultraviolet aging on asphalt and its structure–activity relationship, its rheological properties were measured by dynamic shear rheology and multiple stress recovery [...] Read more.
UV radiation can change the internal molecular composition, macroscopic rheological properties, and microscopic chemical composition of asphalt. To study the effect of ultraviolet aging on asphalt and its structure–activity relationship, its rheological properties were measured by dynamic shear rheology and multiple stress recovery creep tests, its chemical compositions were measured by component composition, elemental composition, and infrared spectrum tests, and its molecular weight, distribution, and molecular structure were determined by gel permeation chromatography and nuclear magnetic resonance tests. Then, the molecular weight and molecular structure, rheological properties, and microchemical aging behavior of asphalt after UV aging were characterized by correlation analysis, and the structure–activity relationship was analyzed. The results show that the deformation resistance and elastic recovery ability of asphalt after UV aging are enhanced, and the flow performance is decreased. The ultraviolet radiation caused the aromatic hydrocarbons containing naphthenes and long alkyl chains in the asphalt to break and connect with asphaltenes with a ring structure. The asphaltene content in each bitumen sample exceeded 46%, and that in KL reached 55%, indicating that the bitumen changed into a gel structure. UV aging causes the aggregation of asphalt molecules, and the aggregation of molecules narrows the molecular distribution boundary and moves in the direction of macromolecules, resulting in the reduction of the dispersion coefficient by 2–10%. Hydrogen atoms will undergo condensation and substitution reactions due to long-chain breaking, cyclization, or aromatization under UV action, and the breaking of C=C bonds in carbon atoms will increase the stable aromatic ring, strengthen the stiffness of the molecular backbone, and make it difficult for the backbone to spin. Through correlation analysis, it was found that the molecular composition index could characterize the aging behavior index of asphalt, and that the aromatic structure was the most critical molecular change. Further, it was found that the sulfoxide group and carbonyl group could be used as evaluation criteria for the UV aging of asphalt because the correlation between them was above 0.7. This study provides an essential index reference for evaluating the performance change of asphalt under ultraviolet aging to save testing time. Moreover, the molecular structure characterization revealed the changes in internal molecular composition that were behind the observed aging properties, providing a theoretical basis for research on asphalt anti-aging technology. Full article
(This article belongs to the Section Construction and Building Materials)
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21 pages, 4570 KB  
Article
Transport Characteristics of Branched-Preformed Particle Gel in Porous Media: Influence of Elastic Modulus, Matching Coefficient, and Injection Rate
by Ruping Chen, Hong He, Yuhang Tian, Zixiang Xiong, Wenli Ke, Haihua Pei and Peng Zhang
Gels 2025, 11(5), 315; https://doi.org/10.3390/gels11050315 - 23 Apr 2025
Cited by 1 | Viewed by 837
Abstract
The viscoelastic branched-preformed particle gel (B-PPG) has been successfully applied to enhance oil recovery in mature reservoirs. However, due to a lack of a clear understanding of the transport characteristics of B-PPG in porous media, the injectivity and plugging efficiency are not ideal, [...] Read more.
The viscoelastic branched-preformed particle gel (B-PPG) has been successfully applied to enhance oil recovery in mature reservoirs. However, due to a lack of a clear understanding of the transport characteristics of B-PPG in porous media, the injectivity and plugging efficiency are not ideal, and the incremental oil recovery is not as expected, which poses a great obstacle to the large-scale popularization and application of B-PPG in mature oilfields. Thus, the influences of elastic moduli, matching coefficients, and injection rates on transport characteristics of B-PPG in porous media were investigated by conducting core flow experiments. The results indicate that the elastic modulus of B-PPG can significantly affect the injectivity and plugging efficiency. The higher the elastic modulus is, the more difficult it is to transport in the porous medium. When the particle size is similar, as the elastic modulus increases, the resistance factor (Fr) and residual resistance factor (Frr) increase. When the elastic modulus is similar, as the particle size increases, the Fr and Frr increase. As the matching coefficient decreases, the Fr and Frr decrease, reflecting the improvement of injectivity and the weakening of plugging efficiency. The higher the reservoir permeability, the lower the matching coefficient. When the reservoir permeability ranges from 0.30 to 5.30 μm2, the B-PPG with an elastic modulus of 42.2 Pa and a D50 of 525 μm can migrate smoothly into the depth of porous media and form effective plugging. As the injection rate increases, the Fr and Frr decrease, reflecting the improvement of injectivity and the weakening of plugging efficiency. Therefore, to achieve good injectivity and plugging efficiency of the B-PPG suspension, the injection rate should be in the range of 0.5 mL·min−1 to 1.5 mL·min−1. Hence, these findings could give an important understanding of the factors affecting the transport characteristics of B-PPG and provide guidance for enhancing oil recovery by B-PPG flooding in mature oilfields. Full article
(This article belongs to the Special Issue Polymer Gels for the Oil and Gas Industry)
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31 pages, 10917 KB  
Article
Rheological Insight into the 3D Printability of Carboxymethyl Cellulose-Based Hydrogels
by Itziar Insua, Oliver Etzold, Itxaso Calafel, Robert Aguirresarobe, Marcelo Calderón and Mercedes Fernández
Gels 2025, 11(4), 259; https://doi.org/10.3390/gels11040259 - 1 Apr 2025
Cited by 10 | Viewed by 4552
Abstract
Direct Ink Writing (DIW) is an advanced additive manufacturing 3D-printing technique with significant potential for producing hydrogels in biomedical and engineering applications. This study presents a comprehensive rheological analysis of the yielding and recovery properties critical for ensuring the printability of carboxymethyl cellulose [...] Read more.
Direct Ink Writing (DIW) is an advanced additive manufacturing 3D-printing technique with significant potential for producing hydrogels in biomedical and engineering applications. This study presents a comprehensive rheological analysis of the yielding and recovery properties critical for ensuring the printability of carboxymethyl cellulose (CMC)-based hydrogels incorporating atenolol, an antihypertensive agent, as the active ingredient. The viscoelastic properties under shear conditions were examined using Large Amplitude Oscillatory Shear (LAOS) testing. To obtain both qualitative and quantitative insight into hydrogel dynamics, Lissajous-Bowditch plots and Fourier Transform (FT) coefficients were analyzed. The evaluation of stress signal anharmonicity and the decomposition of stress into its elastic and viscous components allowed for distinguishing structural evolution under flow among the tested hydrogels. Additionally, the analysis of the Sequence of Physical Processes (SPP) during each deformation cycle provided deeper insight into oscillatory yielding behavior, emphasizing the role of elastic strains in determining printability. Overall, the study offers valuable understanding of the nonlinear viscoelastic behavior of CMC-based hydrogels, providing a framework for optimizing hydrogel formulations in DIW applications. Full article
(This article belongs to the Special Issue Thixotropic Gels: Mechanisms, Functions and Applications)
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25 pages, 13064 KB  
Article
Study on the Underpinning Technology for Fixed Piers of Concrete Box Girder Bridges on Mountainous Expressways
by Honglin Ran, Lin Li, Yi Wei, Penglin Xiao and Hongyun Yang
Buildings 2025, 15(7), 1031; https://doi.org/10.3390/buildings15071031 - 24 Mar 2025
Viewed by 1324
Abstract
To address the challenge of repairing the damage to concrete box girder bridge piers on mountainous highways caused by falling rocks, this paper proposes an active underpinning technique that integrates a “井”-shaped cap system, graded preloading of the foundation, and synchronized beam body [...] Read more.
To address the challenge of repairing the damage to concrete box girder bridge piers on mountainous highways caused by falling rocks, this paper proposes an active underpinning technique that integrates a “井”-shaped cap system, graded preloading of the foundation, and synchronized beam body correction. The technique utilizes lateral beam preloading (to eliminate the inelastic deformation of the new pile foundation) and longitudinal beam connections (to form overall stiffness). The method involves building temporary and permanent support systems in stages. Through the two-stage temporary support system transition, the removal and in situ reconstruction of the old piers, a smooth transition from the pier–beam consolidation system to the basin-type bearing system is achieved while simultaneously performing precise correction of beam torsion. The structural safety during the construction process was verified through finite element simulations and dynamic monitoring. Monitoring results show that the beam torsion recovery effect is significant (maximum lift of 5.2 mm/settlement of 7.9 mm), and the pier strain (−54.5~−51.3 με) remains within a controllable range. Before the bridge was opened to traffic, vehicle load and impact load tests were conducted. The actual measured strength and vertical stiffness of the main beam structure meet the design requirements, with relative residual deformation less than 20%, indicating that the structure is in good, elastic working condition. The vehicle running and braking dynamic coefficients (μ = 0.058~0.171 and 0.103~0.163) are both lower than the theoretical value of 0.305. The study shows that this technique enables the rapid and safe repair of bridge piers and provides important references for similar engineering projects. Full article
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26 pages, 9865 KB  
Article
A Methodological Approach for Assessing the Post-Fire Resilience of Pinus halepensis Mill. Plant Communities Using UAV-LiDAR Data Across a Chronosequence
by Sergio Larraz-Juan, Fernando Pérez-Cabello, Raúl Hoffrén Mansoa, Cristian Iranzo Cubel and Raquel Montorio
Remote Sens. 2024, 16(24), 4738; https://doi.org/10.3390/rs16244738 - 19 Dec 2024
Viewed by 1980
Abstract
The assessment of fire effects in Aleppo pine forests is crucial for guiding the recovery of burnt areas. This study presents a methodology using UAV-LiDAR data to quantify malleability and elasticity in four burnt areas (1970, 1995, 2008 and 2015) through the statistical [...] Read more.
The assessment of fire effects in Aleppo pine forests is crucial for guiding the recovery of burnt areas. This study presents a methodology using UAV-LiDAR data to quantify malleability and elasticity in four burnt areas (1970, 1995, 2008 and 2015) through the statistical analysis of different metrics related to height structure and diversity (Height mean, 99th percentile and Coefficient of Variation), coverage, relative shape and distribution strata (Canopy Cover, Canopy Relief Ratio and Strata Percent Coverage), and canopy complexity (Profile Area and Profile Area Change). In general terms, malleability decreases over time in forest ecosystems that have been affected by wildfires, whereas elasticity is higher than what has been determined in previous studies. However, a particular specificity has been detected from the 1995 fire, so we can assume that there are other situational factors that may be affecting ecosystem resilience. LiDAR metrics and uni-temporal sampling between burnt sectors and control aids are used to understand community resilience and to identify the different recovery stages in P. halepensis forests. Full article
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16 pages, 23691 KB  
Article
Effect of Grain Size on Nanometric Cutting of Polycrystalline Silicon via Molecular Dynamics Simulation
by Wen Guo, Qiuyue Yu, Guoyan Wang, Shuming Fu, Changlin Liu and Xiao Chen
Micromachines 2024, 15(6), 767; https://doi.org/10.3390/mi15060767 - 8 Jun 2024
Cited by 4 | Viewed by 2101
Abstract
The grain size effect is an important factor in determining the material removal behavior of polycrystalline silicon (p-Si). In the present study, to improve the understanding of nanoscale machining of p-Si, we performed molecular dynamics simulation of nanometric cutting on a p-Si workpiece [...] Read more.
The grain size effect is an important factor in determining the material removal behavior of polycrystalline silicon (p-Si). In the present study, to improve the understanding of nanoscale machining of p-Si, we performed molecular dynamics simulation of nanometric cutting on a p-Si workpiece and discussed the grain size effect on material removal behavior and subsurface damage formation. The simulation results indicate that when cutting on the polycrystal workpiece, the material removal process becomes unstable compared with single crystals. Higher removal efficiency, less elastic recovery and higher frictional coefficient are observed as the average grain size decreases. In the subsurface workpiece, when the grain size decreases, slip along grain boundaries merges as a nonnegligible process of the plastic deformation and suppresses the elastic deformation ahead of the cutting tool. It is also revealed that when cutting on a polycrystal workpiece with smaller grains, the average stress decreases while the workpiece temperature increases due to the impediment of heat transfer by grain boundaries. These results could provide a fundamental understanding in the material deformation mechanism of p-Si during nanoscale machining. Full article
(This article belongs to the Section D:Materials and Processing)
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