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31 pages, 3516 KB  
Review
Design, Control, and Applications of Granular Jamming Grippers in Soft Robotics
by J. Cortes and C. Miranda
Robotics 2025, 14(10), 132; https://doi.org/10.3390/robotics14100132 - 24 Sep 2025
Viewed by 687
Abstract
Granular jamming grippers have emerged as a versatile solution in soft robotics due to their ability to manipulate objects of various shapes and sizes, earning them the label of “universal grippers”. They are composed of granular material confined within an elastic membrane that [...] Read more.
Granular jamming grippers have emerged as a versatile solution in soft robotics due to their ability to manipulate objects of various shapes and sizes, earning them the label of “universal grippers”. They are composed of granular material confined within an elastic membrane that conforms to the object like a fluid and solidifies upon vacuum application, enabling a firm grip through friction and grain interlocking. This work provides a systematic review of the state of the art, addressing their physical principles, the influence of grain and membrane properties, performance characterization methods, and applications across diverse fields. Additionally, the main control variables of these grippers closely related to state variables used in control systems are discussed, along with the current knowledge gaps. Finally, five potential directions for future research are proposed. Full article
(This article belongs to the Special Issue Dynamic Modeling and Model-Based Control of Soft Robots)
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18 pages, 6058 KB  
Article
Fe2+-Coupled Organic-Substrate-Enhanced Nitrogen Removal in Two-Stage Anammox Biofilm Reactors
by Yingchun Bao, Qilong Ge, Siyuan Li, Xiaowei Wang, Xuwen Zheng and Zhenguo Chen
Processes 2025, 13(5), 1603; https://doi.org/10.3390/pr13051603 - 21 May 2025
Viewed by 536
Abstract
Anammox is a novel and energy-efficient biological nitrogen removal technology. Enhancing its performance in treating low-strength nitrogen wastewater is essential for expanding its practical applications. In response to challenges such as low nitrogen removal efficiency (NRE), poor operational stability, limited environmental resistance, and [...] Read more.
Anammox is a novel and energy-efficient biological nitrogen removal technology. Enhancing its performance in treating low-strength nitrogen wastewater is essential for expanding its practical applications. In response to challenges such as low nitrogen removal efficiency (NRE), poor operational stability, limited environmental resistance, and the interference of organic compounds commonly found in real wastewater, this study developed a two-stage upflow anammox biofilm reactor system (R1 and R2) enhanced by an Fe2+-coupled organic substrate strategy for deep nitrogen removal under low-nitrogen conditions. Results showed that sodium acetate at a chemical oxygen demand (COD) concentration of 40 mg/L provided the greatest enhancement to anammox activity, achieving an average total nitrogen removal efficiency (NRE) of 90.02%. However, the reactor performance was significantly inhibited under higher COD conditions (e.g., COD = 60 mg/L). Under an influent Fe2+ concentration of 10 mg/L, the reactors’ NRE increased and then decreased as the COD concentration rose from 0 to 100 mg/L, resulting in the highest efficiency being achieved at an average NRE of 94.11%, observed under 10 mg/L Fe2+ coupled with 60 mg/L of COD in the two-stage anammox system. Scanning electron microscopy revealed that the co-addition of Fe2+ and organic substrates led to the formation of granular protrusions and pores on the sludge surface, which favored the structural stability of the biomass. At a COD level of 40 mg/L, the contents of extracellular polymeric substances and heme c in anammox biofilm were significantly higher compared to the addition of 10 mg/L Fe2+ alone, whereas excessive COD inhibited both indicators. These findings suggest that moderate levels of Fe2+ coupled with organic matter can promote anammox activity for deep nitrogen removal, while excessive organics have inhibitory effects. This study provides theoretical support for enhancing nitrogen removal from low-strength wastewater using Fe2+ and organic-substrate-assisted anammox processes. Full article
(This article belongs to the Special Issue Research on Water Pollution Control and Remediation Technology)
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28 pages, 6761 KB  
Article
Hadron Identification Prospects with Granular Calorimeters
by Andrea De Vita, Abhishek, Max Aehle, Muhammad Awais, Alessandro Breccia, Riccardo Carroccio, Long Chen, Tommaso Dorigo, Nicolas R. Gauger, Ralf Keidel, Jan Kieseler, Enrico Lupi, Federico Nardi, Xuan Tung Nguyen, Fredrik Sandin, Kylian Schmidt, Pietro Vischia and Joseph Willmore
Particles 2025, 8(2), 58; https://doi.org/10.3390/particles8020058 - 16 May 2025
Cited by 2 | Viewed by 1212
Abstract
In this work we consider the problem of determining the identity of hadrons at high energies based on the topology of their energy depositions in dense matter, along with the time of the interactions. Using GEANT4 simulations of a homogeneous lead tungstate calorimeter [...] Read more.
In this work we consider the problem of determining the identity of hadrons at high energies based on the topology of their energy depositions in dense matter, along with the time of the interactions. Using GEANT4 simulations of a homogeneous lead tungstate calorimeter with high transverse and longitudinal segmentation, we investigated the discrimination of protons, positive pions, and positive kaons at 100 GeV. The analysis focuses on the impact of calorimeter granularity by progressively merging detector cells and extracting features like energy deposition patterns and timing information. Two machine learning approaches, XGBoost and fully connected deep neural networks, were employed to assess the classification performance across particle pairs. The results indicate that fine segmentation improves particle discrimination, with higher granularity yielding more detailed characterization of energy showers. Additionally, the results highlight the importance of shower radius, energy fractions, and timing variables in distinguishing particle types. The XGBoost model demonstrated computational efficiency and interpretability advantages over deep learning for tabular data structures, while achieving similar classification performance. This motivates further work required to combine high- and low-level feature analysis, e.g., using convolutional and graph-based neural networks, and extending the study to a broader range of particle energies and types. Full article
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21 pages, 2616 KB  
Article
Association Analysis of Benzo[a]pyrene Concentration Using an Association Rule Algorithm
by Minyi Wang and Takayuki Kameda
Air 2025, 3(2), 15; https://doi.org/10.3390/air3020015 - 12 May 2025
Viewed by 713
Abstract
Benzo[a]pyrene is an important indicator of polycyclic aromatic hydrocarbons pollution that exhibits complex atmospheric dynamics influenced by meteorological factors and suspended particulate matter (SPM). Herein, the factors influencing B(a)P concentration were elucidated by analyzing the monthly environmental data for Kyoto, Japan, [...] Read more.
Benzo[a]pyrene is an important indicator of polycyclic aromatic hydrocarbons pollution that exhibits complex atmospheric dynamics influenced by meteorological factors and suspended particulate matter (SPM). Herein, the factors influencing B(a)P concentration were elucidated by analyzing the monthly environmental data for Kyoto, Japan, from 2001 to 2021 using an improved association rule algorithm. Results revealed that B(a)P concentrations were 1.3–3 times higher in cold seasons than in warm seasons and SPM concentrations were lower in cold seasons. The clustering performance was enhanced by optimizing the K-means method using the sum of squared error. The efficiency and reliability of the traditional Apriori algorithm were enhanced by restructuring its candidate itemset generation process, specifically by (1) generating C2 exclusively from frequent itemset L₁ to avoid redundant database scans and (2) implementing the iterative pruning of nonfrequent subsets during Lk → Ck+1 transitions, adding the lift parameter, and eliminating invalid rules. Strong association rules revealed that B(a)P concentrations ≤ 0.185 ng/m3 were associated with specific meteorological conditions, including humidity ≤ 58%, wind speed ≥ 2 m/s, temperature ≥ 12.3 °C, and pressure ≤ 1009.2 hPa. Among these, changes in pressure had the most substantial impact on the confidence of the association rules, followed by humidity, wind speed, and temperature. Under the influence of high SPM concentrations, favorable meteorological conditions further accelerated pollutant dispersion. B(a)P concentration increased with increasing pressure, decreasing temperature, and decreasing wind speed. Principal component analysis confirmed the robustness and accuracy of our optimized association rule approach in quantifying complex, nonlinear relationships, while providing granular, interpretable insights beyond the traditional methods. Full article
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14 pages, 991 KB  
Review
Emergent Magnetic Monopoles in Quantum Matter
by Maria Cristina Diamantini
Condens. Matter 2025, 10(2), 20; https://doi.org/10.3390/condmat10020020 - 1 Apr 2025
Viewed by 1687
Abstract
Magnetic monopoles, though elusive as elementary particles, emerge as quantum excitations in granular quantum materials. Under certain conditions, they can undergo Bose condensation, leading to the formation of a novel state of matter known as the superinsulator. In this state, charge carriers, Cooper [...] Read more.
Magnetic monopoles, though elusive as elementary particles, emerge as quantum excitations in granular quantum materials. Under certain conditions, they can undergo Bose condensation, leading to the formation of a novel state of matter known as the superinsulator. In this state, charge carriers, Cooper pairs and anti-Cooper pairs, are bound together by an electric flux string, forming neutral electric pions. This confinement mechanism results in an infinite resistance that persists even at finite temperatures. Superinsulators behave, thus, as dual superconductors. Full article
(This article belongs to the Special Issue Superstripes Physics, 3rd Edition)
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25 pages, 4475 KB  
Article
Characterizing the Temporal Variation of Airborne Particulate Matter in an Urban Area Using Variograms
by Gokul Balagopal, Lakitha Wijeratne, John Waczak, Prabuddha Hathurusinghe, Mazhar Iqbal, Rittik Patra, Adam Aker, Seth Lee, Vardhan Agnihotri, Christopher Simmons and David J. Lary
Air 2025, 3(1), 7; https://doi.org/10.3390/air3010007 - 3 Mar 2025
Viewed by 1288
Abstract
This study aims to determine the optimal frequency for monitoring airborne pollutants in densely populated urban areas to effectively capture their temporal variations. While environmental organizations worldwide typically update air quality data hourly, there is no global consensus on the ideal monitoring frequency [...] Read more.
This study aims to determine the optimal frequency for monitoring airborne pollutants in densely populated urban areas to effectively capture their temporal variations. While environmental organizations worldwide typically update air quality data hourly, there is no global consensus on the ideal monitoring frequency to adequately resolve pollutant (particulate matter) time series. By applying temporal variogram analysis to particulate matter (PM) data over time, we identified specific measurement intervals that accurately reflect fluctuations in pollution levels. Using January 2023 air quality data from the Joppa neighborhood of Dallas, Texas, USA, temporal variogram analysis was conducted on three distinct days with varying PM2.5 (particulate matter of size ≤ 2.5 μm in diameter) pollution levels. For the most polluted day, the optimal sampling interval for PM2.5 was determined to be 12.25 s. This analysis shows that highly polluted days are associated with shorter sampling intervals, highlighting the need for highly granular observations to accurately capture variations in PM levels. Using the variogram analysis results from the most polluted day, we trained machine learning models that can predict the sampling time using meteorological parameters. Feature importance analysis revealed that humidity, temperature, and wind speed could significantly impact the measurement time for PM2.5. The study also extends to the other size fractions measured by the air quality monitor. Our findings highlight how local conditions influence the frequency required to reliably track changes in air quality. Full article
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15 pages, 5328 KB  
Article
One-Point Calibration of Low-Cost Sensors for Particulate Air Matter (PM) Concentration Measurement
by Luigi Russi, Paolo Guidorzi, Giovanni Semprini, Arianna Trentini and Beatrice Pulvirenti
Sensors 2025, 25(3), 692; https://doi.org/10.3390/s25030692 - 24 Jan 2025
Cited by 2 | Viewed by 1197
Abstract
The use of low-cost sensors has dramatically increased in recent years in all engineering sectors. In the buildings and automotive field, low-cost sensors open very interesting perspectives, because they allow one to monitor temperature and humidity distributions together with air quality in a [...] Read more.
The use of low-cost sensors has dramatically increased in recent years in all engineering sectors. In the buildings and automotive field, low-cost sensors open very interesting perspectives, because they allow one to monitor temperature and humidity distributions together with air quality in a widespread and punctual way and allow for the control of all energy parameters. The main issue remains the validation of the measurements. In this work, we propose an innovative approach to verify the measurements given by some low-cost systems built ad hoc for automotive applications. Two independent low-cost measurement systems were set to measure Particulate Air Matter (PM) concentration, TVOC concentration, CO2 concentration, formaldehyde concentration, air temperature, relative humidity, pressure, air flow velocity, and GPS position. These systems were calibrated for PM concentration measurement by comparison with standard and certified sensors used by the regional authority of the Emilia-Romagna region (ARPAE, Italy) for characterizing air quality. The duration of the analysis, three days, is not representative of the diverse environmental conditions that occur across different seasons. However, the innovation of this approach lies in both the in-field comparison of low-cost and high-quality sensors and the use of proper conversion approaches for mass concentration measurements. A quantitative analysis of the sensors’ performance is given, with a focus on the effects of time granularity, relative humidity, mass conversion from particle counts, and size detection response. The results show that the low-cost sensors’ measurements of air temperature, relative humidity, and particle number concentration are in good agreement with high-quality sensors’ measurements, with a strong impact of relative humidity on performance indicators. Overall, good quality and consistency of the data among the sensors were achieved. Full article
(This article belongs to the Special Issue Integrated Sensor Systems for Environmental Applications)
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14 pages, 3232 KB  
Article
Experimental Investigation on Unloading-Induced Sliding Behavior of Dry Sands Subjected to Constant Shear Force
by Wengang Dang, Kang Tao, Jinyang Fu and Bangbiao Wu
Appl. Sci. 2025, 15(1), 401; https://doi.org/10.3390/app15010401 - 3 Jan 2025
Cited by 2 | Viewed by 1009
Abstract
Infilled joints or faults are often subjected to long-term stable shear forces, and nature surface processes of normal unloading can change the frictional balance. Therefore, it is essential to study the sliding behavior of such granular materials under such unloading conditions, since they [...] Read more.
Infilled joints or faults are often subjected to long-term stable shear forces, and nature surface processes of normal unloading can change the frictional balance. Therefore, it is essential to study the sliding behavior of such granular materials under such unloading conditions, since they are usually the filling matter. We conducted two groups of normal unloading direct shear tests considering two variables: unloading rate and the magnitude of constant shear force. Dry sands may slide discontinuously during normal unloading, and the slip velocity does not increase uniformly with unloading time. Due to horizontal particle interlacing and normal relaxation, there will be sliding velocity fluctuations and even temporary intermissions. At the stage of sliding acceleration, the normal force decreases with a higher unloading rate and increases with a larger shear force at the same sliding velocity. The normal forces obtained from the tests are less than those calculated by Coulomb’s theory in the conventional constant-rate shear test. Under the same unloading rate, the range of apparent friction coefficient variation is narrower under larger shear forces. This study has revealed the movement patterns of natural granular layers and is of enlightening significance in the prevention of corresponding geohazards. Full article
(This article belongs to the Topic Geotechnics for Hazard Mitigation)
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25 pages, 3504 KB  
Article
The Distributions and Dependences of 3D Particle Morphology Characteristics for Crushed and Natural Sands by X-Ray uCT Investigations
by Hao Yang, Xu Li, Junhui Zhang, Zhengbo Hu and Shengnan Li
Materials 2024, 17(23), 5805; https://doi.org/10.3390/ma17235805 - 27 Nov 2024
Cited by 1 | Viewed by 936
Abstract
The morphology of an individual particulate refers to its shape characteristics and size properties, which both play important roles for granular matter in physics, mechanics, chemistry, and biology. In this study, ellipsoidality is defined as a 3D shape index for evaluating particle roundness, [...] Read more.
The morphology of an individual particulate refers to its shape characteristics and size properties, which both play important roles for granular matter in physics, mechanics, chemistry, and biology. In this study, ellipsoidality is defined as a 3D shape index for evaluating particle roundness, and an explicit calculation method is applied. The dependences of 3D shape characteristics (aspect ratios, sphericity, and ellipsoidal degree) on particle size (ranges from 0.063 mm to 5.0 mm) are adequately investigated with the X-ray micro-computed microtomography (uCT) imaging for hundreds of thousands of particles of crushed and natural sands. This study focuses on comparing and evaluating the specific surface area and equivalent diameter, suggesting that particle segregation and changes in surface area may explain the strong dependence of particle shape on size. The correlation between different shape metrics was analyzed by comparing crushed sand with natural sand to provide theoretical support for material filling and mechanical behaviour. The significant differences in the microscale particle size indexes of different sands by single grading are used to provide data references for further analyses of the effect of material microscale on material properties in future discrete element particle simulations. Full article
(This article belongs to the Section Construction and Building Materials)
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14 pages, 3818 KB  
Article
Compaction Evolution and Mechanisms of Granular Materials Due to Gyratory Shearing
by Teng Man
Materials 2024, 17(22), 5525; https://doi.org/10.3390/ma17225525 - 12 Nov 2024
Viewed by 1172
Abstract
Granular systems, no matter whether they are dry or saturated, are commonly encountered in both natural scenarios and engineering applications. In this work, we tackle the compaction problem of both dry and saturated granular systems under gyratory shearing compaction, where particles are subjected [...] Read more.
Granular systems, no matter whether they are dry or saturated, are commonly encountered in both natural scenarios and engineering applications. In this work, we tackle the compaction problem of both dry and saturated granular systems under gyratory shearing compaction, where particles are subjected to constant pressure and continuous shear rate, which is quite different from the traditional cyclic shearing compaction. Such phenomena are crucial to the compaction of asphalt mixtures or soils in civil engineering and can be extended to other areas, such as powder processing and pharmaceutical engineering. In this study, we investigated the behavior of both dry and fully saturated mono-dispersed granular materials under gyratory shearing compaction using the discrete element method (DEM) and found that the gyratory speed or interstitial fluid viscosity has almost no impact on the compaction behavior, while the pressure and the particle size play more important roles. Additionally, it is the inertial time scale which dictates the compaction behavior under gyratory shearing in most cases; meanwhile, the viscous time scale can also have influence in some conditions. This work determines the similarity and unity between the granular gyratory compaction and the rheology of granular systems, which has direct relevance to various natural and engineering systems. Full article
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38 pages, 2806 KB  
Article
Removal of Organic Micropollutants and Microplastics via Ozonation Followed by Granular Activated Carbon Filtration
by Zoé Béalu, Johanna Walther, Attaallah Abusafia, Korinna Altmann, Maren Meurer, Oliver Gretzschel, Michael Schäfer and Heidrun Steinmetz
Environments 2024, 11(11), 241; https://doi.org/10.3390/environments11110241 - 31 Oct 2024
Cited by 5 | Viewed by 4913
Abstract
Discharge from Wastewater Treatment Plants (WWTPs) can result in the emission of organic micropollutants (OMPs) and microplastics (MPs) into the aquatic environment. To prevent this harmful release, a pilot plant consisting of an ozonation followed by a granular activated carbon (GAC) filter was [...] Read more.
Discharge from Wastewater Treatment Plants (WWTPs) can result in the emission of organic micropollutants (OMPs) and microplastics (MPs) into the aquatic environment. To prevent this harmful release, a pilot plant consisting of an ozonation followed by a granular activated carbon (GAC) filter was operated at a WWTP in Germany, and its side-effects on the concentrations of nitrogen (N) and phosphorous (P) compounds were measured. Over 80% of OMPs and transformation products were removed during the operating time (around 6000 bed volumes) no matter the ozone dose (from around 0.1 to 0.5 mgO3/mgDOC), except for Diatrizoic acid, whose breakthrough appeared at 3500 BV. Formation of the oxidation by-product, NDMA, increased with higher ozone doses, but the concentration remained below 100 ng/L. Bromate was formed at a higher ozone dose (>0.4 mgO3/mgDOC) but at a low concentration—below 10 µg/L. The MP particles detected in the inflow (PE, SBR, PP, and PS) were effectively eliminated to a high degree, with a removal rate of at least 92%. Carbon parameters (COD, DOC, and SAC254) were removed further by the pilot plant, but to different extents. As expected, nitrate was formed during ozonation, while nitrite’s concentration decreased. Further, nitrite decreased and nitrate increased within the GAC filter, while ammonium was eliminated by at least 90%. Total P concentration decreased after the pilot, but the concentration of PO4-P increased. Full article
(This article belongs to the Special Issue Advanced Technologies of Water and Wastewater Treatment (2nd Edition))
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15 pages, 9374 KB  
Article
Pathological Study of Demyelination with Cellular Reactions in the Cerebellum of Dogs Infected with Canine Distemper Virus
by José Manuel Verdes, Camila Larrañaga, Guillermo Godiño, Belén Varela, Victoria Yozzi, Victoria Iribarnegaray, Luis Delucchi and Kanji Yamasaki
Viruses 2024, 16(11), 1719; https://doi.org/10.3390/v16111719 - 31 Oct 2024
Cited by 1 | Viewed by 1793
Abstract
The purpose of this study was to examine the relationship between demyelination and cellular reactions in the cerebellum of Canine Distemper Virus (CDV)-infected dogs. We subdivided the disease staging by adding the degree of demyelination determined by Luxol Fast Blue staining to the [...] Read more.
The purpose of this study was to examine the relationship between demyelination and cellular reactions in the cerebellum of Canine Distemper Virus (CDV)-infected dogs. We subdivided the disease staging by adding the degree of demyelination determined by Luxol Fast Blue staining to the previously reported disease staging from the acute stage to the chronic stage, and investigated the relationship between demyelination in the cerebellum and the number and histological changes in astroglia, microglia, and Purkinje cells in each stage. Reactions of astrocytes and microglia were observed at an early stage when demyelination was not evident. Changes progressed with demyelination. Demyelination initially began in the medulla adjoining the fourth ventricle and gradually spread to the entire cerebellum, including the lobes. CDV immune-positive granules were seen from the early stage, and inclusion bodies also appeared at the same time. CDV immune-positive reaction and inclusion bodies were observed in astrocytes, microglia, neurons, ependymal cells, and even leptomeningeal mononuclear cells. On the other hand, infiltration of CDV-immunoreactive particles from the pia mater to the gray matter and further into the white matter through the granular layer was observed from an early stage. Purkinje cells decreased from the intermediate stage, and a decrease in cells in the granular layer was also observed. There was no clear association between age and each stage, and the stages did not progress with age. Full article
(This article belongs to the Special Issue Canine Distemper Virus)
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16 pages, 1554 KB  
Article
Trihalomethane Formation Potential at the Barekese Water Treatment Plant and the Related Cancer Risk to Consumers in the Kumasi Metropolis of Ghana
by Nathaniel Kabral Wezenamo Fellalaga, Lawson Mensah, Bright Kwaku Agbekey, Ethel Bentil, Lilian Waaley and Geophery Kwame Anornu
Water 2024, 16(21), 3089; https://doi.org/10.3390/w16213089 - 29 Oct 2024
Cited by 1 | Viewed by 1706
Abstract
The prevalence of disinfection by-products in drinking water supplies is a global concern due to their carcinogenicity. However, the monitoring of DBPs such as trihalomethanes (THMs) and haloacetic acids (HAAs) in drinking water supplies is non-existent in many developing Asian, South American, and [...] Read more.
The prevalence of disinfection by-products in drinking water supplies is a global concern due to their carcinogenicity. However, the monitoring of DBPs such as trihalomethanes (THMs) and haloacetic acids (HAAs) in drinking water supplies is non-existent in many developing Asian, South American, and African countries. The formation of THMs during disinfection arises from a reaction between the disinfectant and natural organic matter in the water, particularly, dissolved organic carbon (DOC). This reaction is hastened by increases in temperature, high levels of disinfectant doses or residual, elevated water pH, long disinfection contact times, and high DOC concentrations. However, the inclusion of a granular activated carbon adsorption process in the water treatment process is the most effective method for the removal of the main precursor (DOC) for the formation of THMs in treated water. The Barekese WTP, which disinfects with chlorine, has no adsorption process for DOC removal, and supplies over 80% of pipe-borne water to the city of Kumasi in Ghana, was assessed for the THM formation potential (THMFP). A THM predictive model was used to determine the potential THM concentration in the final water. The THMFP at the Barekese WTP ranged between 22.42 and 38.94 µg/L, which was below the 100 µg/L threshold set by the WHO. The lifetime average daily doses were 3.9494 × 10−4 µg/Kg/d and 3.9294 × 10−4 µg/Kg/d for male and female consumers, respectively. The lifetime integrative cancer risks associated with consumption of the water were 1.817 × 10−5 and 1.808 × 10−5 for males and females, respectively. The cancer risk posed was acceptably low. However, direct measurement of DBPs is required to corroborate these findings and verify the cancer risk posed to the consumers of treated water from the Barekese WTP to inform policies, regulations, public health interventions, and investment. Full article
(This article belongs to the Section Water and One Health)
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13 pages, 2934 KB  
Article
Recovery and Restructuring of Fine and Coarse Soil Fractions as Earthen Construction Materials
by Mazhar Hussain, Ines Lamrous, Antony Provost, Nathalie Leblanc, Hafida Zmamou, Daniel Levacher and Abdoulaye Kane
Sustainability 2024, 16(20), 8952; https://doi.org/10.3390/su16208952 - 16 Oct 2024
Viewed by 1407
Abstract
Excessive consumption of natural resources to meet the growing demands of building and infrastructure projects has put enormous stress on these resources. On the other hand, a significant quantity of soil is excavated for development activities across the globe and is usually treated [...] Read more.
Excessive consumption of natural resources to meet the growing demands of building and infrastructure projects has put enormous stress on these resources. On the other hand, a significant quantity of soil is excavated for development activities across the globe and is usually treated as waste material. This study explores the potential of excavated soils in the Brittany region of France for its reuse as earthen construction materials. Characterization of soil recovered from building sites was carried out to classify the soils and observe their suitability for earthen construction materials. These characteristics include mainly Atterberg limits, granulometry, organic matter and optimum moisture content. Soil samples were separated into fine and coarse particles through wet sieving. The percentage of fines (particles smaller than 0.063 mm) in studied soil samples range from 28% to 65%. The methylene blue value (MBV) for Lorient, Bruz and Polama soils is 1, 1.2 and 1.2 g/100 g, and French classification (Guide de terrassements des remblais et des couches de forme; GTR) of soil samples is A1, B5 and A1, respectively. The washing of soils with lower fine content helps to recover excellent-quality sand and gravel, which are a useful and precious resource. However, residual fine particles are a waste material. In this study, three soil formulations were used for manufacturing earth blocks. These formulations include raw soil, fines and restructured soil. In restructured soil, a fine fraction of soil smaller than 0.063 mm was mixed with 15% recycled sand. Restructuring of soil fine particles helps to improve soil matrix composition and suitability for earth bricks. Compressed-earth blocks of 4 × 4 × 16 cm were manufactured at a laboratory scale for flexural strength testing by using optimum molding moisture content and compaction through Proctor normal energy. Compressive strength tests were performed on cubic blocks of size 4 × 4 × 4 cm. Mechanical testing of bricks showed that bricks with raw soil had higher resistance with a maximum of 3.4 MPa for Lorient soil. Removal of coarse particles from soil decreased the strength of bricks considerably. Restructuring of fines with recycled sand improves their granular skeleton and increases the compressive strength and durability of bricks. Full article
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20 pages, 10304 KB  
Article
Chemical and Physical Characterization of Three Oxidic Lithological Materials for Water Treatment
by José G. Prato, Fernando Millán, Marin Senila, Erika Andrea Levei, Claudiu Tănăselia, Luisa Carolina González, Anita Cecilia Ríos, Luis Sagñay Yasaca and Guillermo Eduardo Dávalos
Sustainability 2024, 16(18), 7902; https://doi.org/10.3390/su16187902 - 10 Sep 2024
Cited by 2 | Viewed by 1473
Abstract
Water treatment necessitates the sustainable use of natural resources. This paper focuses on the characterization of three oxidic lithological materials (OLMs) with the aim of utilizing them to prepare calcined adsorbent substrates for ionic adsorption. The three materials have pH levels of [...] Read more.
Water treatment necessitates the sustainable use of natural resources. This paper focuses on the characterization of three oxidic lithological materials (OLMs) with the aim of utilizing them to prepare calcined adsorbent substrates for ionic adsorption. The three materials have pH levels of 7.66, 4.63, and 6.57, respectively, and organic matter contents less than 0.5%. All of the materials are sandy loam or loamy sand. Their electric conductivities (0.18, 0.07, and 0.23 dS/m) show low levels of salinity and solubility. Their CEC (13.40, 13.77, and 6.76 cmol(+)kg) values are low, similar to those of amphoteric oxides and kaolin clays. Their aluminum contents range from 7% up to 12%, their iron contents range from 3% up to 7%, their titanium contents range from 0.3% to 0.63%, and their manganese contents range from 0.007% up to 0.033%. The amphoteric oxides of these metals are responsible for their ionic adsorption reactions due to their variable charge surfaces. Their zirconium concentrations range from 100 to 600 mg/g, giving these materials the refractory properties necessary for the preparation of calcined adsorbent substrates. Our XRD analysis shows they share a common mineralogical composition, with quartz as the principal component, as well as albite, which leads to their thermal properties and mechanical resistance against abrasion. The TDA and IR spectra show the presence of kaolinite, which is lost during thermal treatments. The results show that the OLMs might have potential as raw materials to prepare calcined adsorbent substrates for further applications and as granular media in the sustainable treatment of both natural water and wastewater. Full article
(This article belongs to the Section Environmental Sustainability and Applications)
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