Search Results (212)

Decarbonizing air travel poses a major technological challenge, driven by the substantial power requirements of the drivetrain and the demanding weight and volume constraints of airborne systems. One promising avenue involves leveraging the high specific energy of hydrogen by designing compact, high-power fuel cell stacks to supply power for electric drivetrains. However, a key drawback of such propulsion architectures is the substantial heat generated within the fuel cells, which necessitates bulky and heavy thermal management systems to ensure safe and continuous operation. This study investigates a proposed air-based thermal management system, which operates by introducing pulsating heat pipes into the bipolar plates of a High-Temperature Polymer Electrolyte Membrane Fuel Cell (HT-PEM FC) stack. If proven to be feasible, heat pipe assisted air cooling may provide the benefit of reducing overall system complexity by decreasing the number of components in the thermal management system. To evaluate the thermal performance of the proposed system, a one-dimensional thermal model was initially developed in a previous study to describe the temperature distribution along the length of a heat pipe. Building upon this foundation, the present work extends the model by incorporating a two-dimensional Computational Fluid Dynamic (CFD) analysis to account for geometry-specific effects within the hexagonal design. Results indicate that the heat transfer from the hexagonal heat pipe geometry to the coolant air flow was marginally overestimated in previous analytical calculations. Revised heat transfer rates led to a shift in the predicted temperature distributions, resulting in the need for either increased external airflow, extended condenser sections, or reduced inlet temperatures to maintain target operating conditions. Although these adjustments may result in a slight increase in system mass and parasitic power consumption, the overall impact is limited, and the heat pipe-assisted air cooling approach remains theoretically feasible. Based on the results, design modifications are proposed and their impact on thermal performance is evaluated to address the challenges of heat rejection and temperature uniformity. A modification based on variation and optimization of PHP meander lengths was evaluated using the updated model and it significantly improved temperature homogeneity across the evaporator. Full article

Research on hydrogen production by chemical methods has focused on combining metals to carry out the hydrolysis reaction under ambient conditions. In particular, aluminum and lithium metals were considered, with lithium used at low concentrations in order to activate aluminum. Under these conditions, the metals can react with water to obtain the maximum hydrogen yield. The main objective of this work was to prepare the lithium−aluminum alloy by mechanical milling and its chemical reaction with water to produce hydrogen under laboratory conditions. A high–energy Spex mill was used for material preparation and the time scheduled for alloys preparation was relatively short. Several techniques were used for its characterization, such as X–ray diffraction, scanning electron microscopy, gas chromatography, and low-temperature physical adsorption. According to the results, two phases were produced during the milling process when using 5% lithium. The volume of hydrogen generated was measured using a graduated burette. Depending on the volume obtained, the aluminum reacted to generate hydrogen with an efficiency of 95.24%. No additives or catalysts were used in material synthesis or hydrogen production. According to these results, the hydrogen does not require any purification because it is clean hydrogen and can therefore be used directly in fuel cells. Full article

We engineered a compact methanol steam reforming (MSR) system tailored to power a 1 kW High-Temperature Proton Exchange Membrane (HT-PEM) fuel cell. The unit integrates an evaporator, reformer, and burner within a cylindrical titanium-alloy vacuum flask to minimize parasitic heat loss. Guided by an Artificial Intelligence Complex System Response (AICSR) framework, we developed a segmented catalyst architecture that positions an optimized Pd/ZnO/Al₂O₃ catalyst downstream of a commercial Cu–Zn catalyst bed. This spatial configuration reduces palladium consumption by >50% while maintaining a hydrogen generation rate of 8000 sccm at 250 °C. During a 40 h stability test, the system exhibited a low deactivation rate of 0.235% h⁻¹, with methanol conversion decaying gradually from 98.1% to 88.7%. The downstream PdZn intermetallic phase actively promoted the water–gas shift (WGS) reaction, restricting CO concentration to an average of 3.9% (minimum 2.5%). Achieving a system thermal efficiency of 88.589% and a 20 min startup time, this design validates AI-assisted spatial catalyst distribution as a highly viable strategy for compact hydrogen generation. Full article

The thermal decomposition (pyrolysis) of polypropylene has been investigated as a viable method for polymer waste recycling and the production of hydrogen-rich fuel. This study examined the effects of atmosphere, temperature, and catalytic systems based on iron oxide and strontium titanate, with a focus on gas-phase composition and reaction dynamics. A reactor geometry conducive to in-bed reforming was utilized, leading to a purer gas output compared to commonly reported results, making it suitable for solid oxide fuel cell (SOFC) applications. The hydrogen concentration was enhanced with increasing temperature, primarily due to the intensified reforming of methane and higher hydrocarbons. However, only marginal improvements were observed between 700 °C and 800 °C, which limits the benefits of higher energy input. The introduction of small amounts of water vapor (approximately 3% relative humidity) resulted in a reduction in solid residue formation by approximately 50% and a slight increase in hydrogen yield. Conversely, CO₂ atmospheres suppressed hydrogen production and increased residual solids but allowed for better control over reaction dynamics. The combined strontium titanate iron oxide catalyst (S-STO@Fe_xO_γ) demonstrated high efficacy, reducing solid residues to nearly zero and producing gas mixtures containing up to 45% hydrogen. This indicates significant potential for application and further development. These findings underscore the feasibility of in-bed reforming in polypropylene pyrolysis as a waste-to-energy strategy for hydrogen-rich fuel production, warranting further optimization and investigation for SOFC integration. Full article

Hydrogen fuel cell buses (HFCBs) offer a promising zero-emission solution for sustainable public transportation. However, the high energy consumption of auxiliary systems, particularly heating, ventilation and air conditioning (HVAC), significantly impacts overall vehicle efficiency by increasing hydrogen consumption. This study investigates the influence of the HVAC load on the energy efficiency of hydrogen fuel cell buses under different driving conditions and seasonal ambient temperatures. Using a MATAB/Simulink-based simulation framework, the interaction between the fuel cell system, battery dynamics, and HVAC operation is modeled to quantify energy consumption under urban, highway and mixed driving conditions. Simulation was conducted at 7 °C and 35 °C with varying HVAC load levels of 50% and 100% to represent harsh winter and summer conditions. Results demonstrated that HVAC operation can account for a substantial portion of total energy consumption, reducing the vehicle range and fuel cell efficiency. Full article

Multi-stack Polymer electrolyte Membrane Fuel Cell (PEMFC) systems are increasingly adopted in heavy-duty mobility to overcome the power limitations and thermal instability of single-stack configurations. However, the overall energy efficiency, hydrogen utilization, and thermal behavior of multi-stack fuel cell trucks are highly dependent on the applied Power Management System (PMS). In this study, high-fidelity, system-level dynamic model of multi-stack fuel cell truck was developed using Matlab/Simscape^TM, and three PMS approaches (rule-based control, state-machine control, and fuzzy logic control) were comparatively evaluated. The analysis includes coolant temperature regulation, hydrogen consumption, battery State of Charge (SoC) dynamics, and the parasitic power demand of Balance of Plant (BoP) components. Results show that the fuzzy logic PMS provides the most balanced operating profile by smoothing transient fuel cell loading and actively leveraging the battery during high-demand periods. In the thermal domain, the fuzzy logic PMS reduced temperature overshoot by up to 61.20%, demonstrating the most stable thermal control among the three strategies. Hydrogen consumption decreased by 3.08% and 0.89% compared with the rule-based and state-machine PMS, respectively, while parasitic power consumption decreased by 7.12% and 3.32%, confirming improvements in overall energy efficiency. TOPSIS-based multi-criteria decision analysis further showed that the fuzzy logic PMS achieved the highest closeness coefficient (0.9112), indicating superior system-level performance. These findings highlight the importance of PMS design for achieving energy-optimal and thermally stable operation of multi-stack PEMFC trucks and provide practical guidance for future control strategies, heavy-duty mobility applications, and next-generation hydrogen powertrain optimization. Full article

Hydrogen, renowned for its clean energy profile and high energy density, is a pivotal energy carrier for addressing global energy and environmental challenges. Solid oxide fuel cells (SOFCs) and proton ceramic fuel cells (PCFCs) have garnered significant interest due to their direct chemical-to-electrical-energy conversion, fuel flexibility, high efficiency, and environmental compatibility. However, conventional perovskite-based air electrodes suffer from sluggish oxygen reduction reaction (ORR) kinetics and insufficient structural stability at intermediate temperatures. Spinel oxides, distinguished by excellent chemical stability and thermal expansion compatibility, have emerged as promising alternatives; however, their broader application is constrained by their limited ionic conductivity and catalytic activity. This review systematically elucidates the crystal structure, intrinsic advantages, and advanced design strategies of spinel oxides. It particularly focuses on A- and B-site doping techniques for precise modulation of thermal expansion and enhancement of electrocatalytic performance, alongside high-entropy engineering approaches that bolster high-temperature stability. Finally, the review comprehensively discusses remaining challenges and future prospects for the implementation of spinel oxides in nanostructured ceramic fuel cells. Full article

Perfluorosulfonic acid (PFSA) membranes suffer from severe conductivity decay caused by dehydration at elevated temperatures, hindering their application in medium- to high-temperature proton exchange membrane fuel cells (MHT-PEMFCs). To address this, Nafion/SiO₂ composite membranes with systematically varied filler contents were fabricated via a sol–gel-assisted casting strategy to enhance hydration stability and proton transport. Spectroscopic and microscopic analyses reveal a homogeneous nanoscale dispersion of SiO₂ within the Nafion matrix, along with strong interfacial hydrogen bonding between SiO₂ and sulfonic acid groups. These interactions effectively suppress polymer crystallinity and stabilize hydrated ionic domains. Thermogravimetric analysis confirms markedly improved water retention in the composite membranes at intermediate temperatures. Proton conductivity measurements at 50% relative humidity (RH) identify the Nafion/SiO₂-3 membrane as exhibiting optimal transport behavior, delivering the highest conductivity of 61.9 mS·cm⁻¹ at 120 °C and significantly improved conductivity retention compared to Nafion 117. Furthermore, single-cell tests under MHT-PEMFC conditions (120 °C, 50% RH) demonstrate the practical efficacy of these membrane-level enhancements, with the Nafion/SiO₂-3 membrane exhibiting an open-circuit voltage and peak power density 11.2% and 8.9% higher, respectively, than those of pristine Nafion under identical MEA fabrication and operating conditions. This study elucidates a clear structure–property–transport relationship in SiO₂-reinforced PFSA membranes, demonstrating that controlled inorganic incorporation is a robust strategy for extending the operational temperature window of PFSA-based proton exchange membranes toward device-level applications. Full article

High-temperature proton exchange membranes (HT-PEMs) are critical components of high-temperature fuel cells, facilitating proton transport and acting as a barrier to fuel and electrons; however, their performance is hampered by persistent issues of phosphoric acid leaching and oxidative degradation. Herein, a novel HT-PEM with abundant hydrogen bond network is constructed by incorporating nanoscale polyhedral oligomeric silsequioxane functionalized with eight pendent sulfhydryl groups (POSS-SH) into poly(4,4′-diphenylether-5,5′-bibenzimidazole) (OPBI) matrix. POSS, a cage-like nanostructured hybrid molecule, features a well-defined silica core and highly designable surface organic groups, offering unique potential for enhancing membrane performance at the molecular level. Through controlled reactions between sulfhydryl groups and allyl glycidyl ether (AGE), two functional POSS crosslinkers—octa-epoxide POSS (OE-POSS) and mixed sulfhydryl-epoxy POSS (POSS-S-E)—were synthesized. These were subsequently used to fabricate crosslinked OPBI membranes (OPBI-OE-POSS and OPBI-POSS-S-E) via epoxy–amine coupling. The OPBI-POSS-S-E membranes demonstrated exceptional oxidative stability, which is attributed to the free radical scavenging ability of the retained sulfhydryl groups on the nano-sized POSS framework. After soaking in Fenton’s reagent at 80 °C for 108 h, the OPBI-POSS-S-E-20% membrane retained 79.4% of its initial weight, significantly surpassing both the OPBI-OE-POSS-20% and pristine OPBI membranes. The PA-doped OPBI-POSS-S-E-20% membrane achieved a proton conductivity of 50.8 mS cm⁻¹ at 160 °C, and the corresponding membrane electrode assembly delivered a peak power density of 724 mW cm⁻², highlighting the key role of POSS as a nano-modifier in advancing HT-PEM performance. Full article

This study examines the performance of a proton exchange membrane fuel cell operated in electrochemical hydrogen compression (EHC) mode, focusing on the effects of temperature, relative humidity (RH), and pressure on water management and efficiency. Two humidification strategies were investigated: (i) a dry cathode with humidified anode hydrogen and (ii) a flooded cathode with controlled anode humidification. Experiments were conducted at different temperatures (from 35 to 70 °C), RH levels (from 0 to 100%), and compression ratios of 1 and 2, using polarization curves, electrochemical impedance spectroscopy, and linear sweep voltammetry (LSV). In the dry cathode configuration, optimal performance occurred at 70 °C with fully humidified anode gas, achieving current densities above 2 A cm⁻² at voltages below 0.3 V. Partial humidification caused instability due to membrane dehydration. In the flooded cathode, high cathode pressure increased mass transport resistance, while excessive inlet humidification promoted flooding and consequently reduced the efficiency. LSV results highlighted the trade-off between proton conductivity and hydrogen back diffusion, particularly for thin membranes used in this study. The findings demonstrate that precise water balance is essential for stable and efficient EHC operation and provide guidelines for optimizing compression performance, supporting the development of high-efficiency and low-maintenance hydrogen compression systems for stationary and mobile applications. Full article

In terms of their high efficiency and low environmental impact, proton exchange membrane fuel cells (PEMFC) are becoming increasingly essential in the development of hydrogen electric vehicles. Despite these advantages, optimizing hydrogen consumption remains difficult because of the highly nonlinear behavior of PEMFC systems and their sensitivity to variations in operating conditions. This article outlines an intelligent control approach based on extremum seeking control (ESC), based on an artificial neural network (ANN) model, to improve hydrogen utilization in hydrogen electric vehicles. Experimental data on current, voltage, and temperature are collected, preprocessed, and used to train the ANN model of the PEMFC. The ESC algorithm uses this predictive ANN model to adjust the fuel cell current in real time, ensuring voltage stability while reducing hydrogen consumption. The simulation results demonstrate that the ANN-based ESC system provides voltage stability under dynamic load variations and achieves approximately 2.7% hydrogen savings without affecting the experimental current profile, validating the efficacy of the suggested strategy for effective hydrogen management in fuel cell electric vehicles. Full article

Integrating electrochemical fuel cells and internal combustion engines can enhance the total efficiency and sustainability of power systems. This study presents a promising solution by integrating a Proton Exchange Membrane Fuel Cell (PEMFC) with a mini gas turbine, forming a hybrid system called the “Oya System.” This approach aims to mitigate the efficiency losses of gas turbines during high ambient temperatures. The hybrid model was designed using Aspen Plus for modelling and the EES simulation program for solving mathematical equations. The primary objective of this research is to enhance the efficiency of gas turbine systems, particularly under elevated ambient temperatures. The results demonstrate a notable increase in efficiency, rising from 37.97% to 43.06% at 10 °C (winter) and from 31.98% to 40.33% at 40 °C (summer). This improvement, ranging from 5.09% in winter to 8.35% in summer, represents a significant achievement aligned with the goals of the Oya System. Furthermore, integrating PEMFC contributes to environmental sustainability by utilising hydrogen, a clean energy source, and reducing greenhouse gas emissions. The system also enhances efficiency through waste heat recovery, further optimising performance and reducing energy losses. This research highlights the critical role of interface engineering in the hybrid system, particularly the interaction between the PEMFC and the gas turbine. Integrating these two systems involves complex interfaces that facilitate the transfer of electrochemistry, energy, and materials, optimising the overall performance. This aligns with the conference session’s focus on green technologies and resource efficiency. The Oya System exemplifies how innovative hybrid systems can enhance performance while promoting environmentally friendly processes. Full article

Hydrogen energy is a pivotal alternative to lithium-ion batteries for low-altitude aircraft, offering a pathway to sustainable aviation with its zero emissions and high energy density. Nevertheless, its broader application is hindered by challenges in storage, safety, and performance under extreme conditions such as low pressure and low temperature at high altitudes. This paper systematically evaluates various hydrogen power technologies—including water-cooled and air-cooled proton exchange membrane fuel cells (PEMFCs) as well as hydrogen turbines—highlighting their respective advantages, limitations, and suitability for different aircraft types. Among these, water-cooled PEMFCs are identified as the most viable option for manned low-altitude aircraft due to their balanced performance in power density and startup capability. In contrast, air-cooled PEMFCs demonstrate distinct cost-effectiveness for lightweight drones, while hydrogen turbines show promise for long-range regional transport. Furthermore, we analyze current progress in integrating PEMFCs into aircraft platforms and discuss persistent challenges in system compatibility and environmental adaptation. Finally, potential future development directions for PEMFC applications in low-altitude aviation are outlined. Full article

The development of highly active, thermally stable, and low-CO-selective catalysts is critical for practical methanol steam reforming (MSR) to produce high-purity hydrogen for fuel cell applications. In this work, a series of Mn–Cu/Al₂O_x catalysts with varying Mn/Cu/Al molar ratios were synthesized via co-precipitation and systematically investigated to establish the relationship between composition, structure, and catalytic performance. XRD analysis revealed the formation of spinel-type CuAl₂O₄ and MnAl₂O₄ phases, with Mn preferentially occupying octahedral B-sites to form MnAl₂O₄, thereby inducing lattice distortion and inhibiting grain growth. SEM and TEM–EDS mapping confirmed uniform elemental distribution and a porous nanoscale morphology, while H₂-TPR results suggested that increasing the Mn/Cu ratio strengthens Mn–Cu interactions, shifts Cu²⁺ reduction to higher temperatures, and enhances Cu dispersion (up to 26.11 m²/g). XPS analysis indicated that Mn doping enriches Mn³⁺ species and facilitates oxygen vacancy formation, which promotes water–gas shift (WGS) activity and suppresses CO formation. Catalytic testing (240–300 °C) showed that Mn₂Cu₂Al₄O_x achieved the highest methanol conversion while maintaining low CO selectivity; in contrast, reducing the Mn/Cu ratio increased CO selectivity, detrimental to hydrogen purification. Stability tests under continuous steam exposure for 24 h demonstrated minimal activity loss (~2%) and negligible increase in CO selectivity (<1%), confirming excellent hydrothermal stability. The results indicate that tailoring the Mn/Cu ratio optimizes the balance between redox properties and metallic Cu dispersion, offering a promising route to design low-CO, durable catalysts for on-site hydrogen generation via MSR. Full article

The hydrogen energy industry is rapidly developing, positioning hydrogen refueling stations (HRSs) as critical infrastructure for hydrogen fuel cell vehicles. Within these stations, hydrogen compressors serve as the core equipment, whose performance and reliability directly determine the overall system’s economy and safety. This article systematically reviews the working principles, structural features, and application status of mechanical hydrogen compressors with a focus on three prominent types based on reciprocating motion principles: the diaphragm compressor, the hydraulically driven piston compressor, and the ionic liquid compressor. The study provides a detailed analysis of performance bottlenecks, material challenges, thermal management issues, and volumetric efficiency loss mechanisms for each compressor type. Furthermore, it summarizes recent technical optimizations and innovations. Finally, the paper identifies current research gaps, particularly in reliability, hydrogen embrittlement, and intelligent control under high-temperature and high-pressure conditions. It also proposes future technology development pathways and standardization recommendations, aiming to serve as a reference for further R&D and the industrialization of hydrogen compression technology. Full article