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Keywords = magma–carbonate interaction

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19 pages, 15681 KB  
Article
Genesis of W Mineralization in the Caledonian Granite Porphyry of the Chuankou W Deposit, South China: Insights from Fluid Inclusions and C–H–O–S Isotopes
by Wei Liu, Yi Wang, Yong-Jun Shao, Wen-Jing Mao and Zhongfa Liu
Appl. Sci. 2025, 15(19), 10553; https://doi.org/10.3390/app151910553 - 29 Sep 2025
Viewed by 898
Abstract
The Chuankou deposit is a super-large W deposit formed during the Indosinian collision event in South China, and its mineralization is suggested to be related to the Indosinian muscovite granite. However, two types of W mineralizations were discovered in the Caledonian granite porphyry [...] Read more.
The Chuankou deposit is a super-large W deposit formed during the Indosinian collision event in South China, and its mineralization is suggested to be related to the Indosinian muscovite granite. However, two types of W mineralizations were discovered in the Caledonian granite porphyry in the Chuankou W deposit: disseminated scheelite and quartz-wolframite-scheelite vein mineralizations. The genesis of W mineralization in the Caledonian granite porphyry is not yet clear. This paper focuses on fluid microthermometry and stable isotopes (C, H, O, S) analysis of the quartz and scheelite in the ores in the Caledonian granite porphyry in the Chuankou W deposit. The aims are to determine the nature and evolution of the ore-forming fluids, the origin of the ore-forming materials involved in the two types of W mineralization in the Caledonian granite porphyry, and to provide a detailed discussion of the deposit’s genesis. Microthermometry results of fluid inclusions with scheelite and quartz from two stages show that the average homogenization temperature in the quartz-veins within the Caledonian granite porphyry is 248 °C, and the average salinity is 6.31 wt.% NaCl eq (n = 85), the average homogenization temperature in the quartz-veins within the slate is 219 °C, and the average salinity is 5.57 wt.% NaCl eq (n = 49). The ore-forming fluids experienced an evolution from high temperature and high salinity to low temperature and low salinity. Sulfur isotope compositions show that the δ34S values of pyrite and arsenopyrite in the quartz-veins within the Caledonian granite porphyry are 2.06 to 3.28‰ and −0.38 to 0.21‰, respectively, and the δ34S value of pyrite in the quartz-veins within the slate is −1.72 to 0.47‰. The δ34S values of each stage are close to 0‰, indicating that the origin of sulfur mainly from magma. The H-O isotope compositions of the quartz indicate that the ore-forming fluid was primarily magmatic water. The low δ18OH2O values (1.74 to 1.58‰) are influenced by fluid–rock interactions or the incorporation of atmospheric precipitation. The carbon isotopes (δ13C = −9.5 to 8.3‰) indicate a magmatic origin, but the C isotopes of quartz in the quartz-veins within the slate shift toward sedimentary rocks, reflecting the incorporation of rock components in the late mineralization period. These isotopic differences indicate that the fluid–rock interaction gradually strengthened during fluid evolution. Full article
(This article belongs to the Section Earth Sciences)
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19 pages, 6850 KB  
Article
Geochronology and Geochemistry of the Galale Cu–Au Deposit in the Western Segment of the Bangong–Nujiang Suture Zone: Implications for Molybdenum Potential
by Chang Liu, Zhusen Yang, Xiaoyan Zhao and Jingtao Mao
Minerals 2025, 15(9), 975; https://doi.org/10.3390/min15090975 - 15 Sep 2025
Viewed by 1077
Abstract
The Galale Cu–Au deposit lies on the northern margin of the western Gangdese metallogenic belt, near the western edge of the Gangdese arc within the Bangong–Nujiang suture zone. Unlike the well-studied Miocene Cu belt in southern Gangdese, this region remains insufficiently investigated, particularly [...] Read more.
The Galale Cu–Au deposit lies on the northern margin of the western Gangdese metallogenic belt, near the western edge of the Gangdese arc within the Bangong–Nujiang suture zone. Unlike the well-studied Miocene Cu belt in southern Gangdese, this region remains insufficiently investigated, particularly in terms of geochemical characterization, leading to an ambiguous metallogenic model and a debated tectonic setting—specifically, the unresolved issue of subduction polarity across the Bangong–Nujiang suture. This tectonic ambiguity has important implications for understanding magma sources, metal transport pathways, and, consequently, for guiding mineral exploration strategies in the area. To address this, we conducted zircon U–Pb dating on the ore-related quartz diorite and granodiorite, yielding crystallization ages of 84.05 ± 0.34 Ma and 77.20 ± 0.69 Ma, respectively. Integrated with previous data, these results constrain mineralization to 83–89 Ma, which includes both skarn-type Cu–polymetallic and porphyry-type Cu mineralization. Regional comparisons support a tectonic model involving slab rollback and southward subduction of the Bangong–Nujiang oceanic lithosphere. Geochemical analyses of quartz diorite, granodiorite, and monzonitic granite show high-K calc-alkaline, peraluminous I-type affinities, with enrichment in LREEs and LILEs, and depletion in HREEs and HFSEs. Notably, the monzonitic granite is marked by high SiO2, Sr/Y, and Rb/Sr ratios, low Zr/Hf, strong LREE enrichment, weak Eu anomalies, and pronounced Nb–Ta depletion, indicating high oxygen fugacity and favorable conditions for Mo mineralization. The deposit formed through tectono-magmatic processes related to the closure of the Bangong–Nujiang Neo-Tethys Ocean. Subduction and subsequent lithospheric delamination induced partial melting of mantle and crustal sources, generating quartz diorite and granodiorite intrusions. Magmatic fluids interacted with carbonate wall rocks to form skarn assemblages, concentrating ore metals along structures. The mineralization formed within the contact zones between intrusions and surrounding country rocks. Late-stage granite porphyry intrusions (~77 Ma), inferred from major, trace, and rare earth element compositions to have the highest Mo potential, may represent an extension of earlier skarn mineralization in the area (83–89 Ma). This study presents the first comprehensive geochemical dataset for the Galale deposit, refines its metallogenic model, and identifies key geochemical indicators (e.g., Sr, Y, Nb, Rb, Zr, Hf) for Mo exploration. Full article
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39 pages, 8119 KB  
Article
Magmatic Redox Evolution and Porphyry–Skarn Transition in Multiphase Cu-Mo-W-Au Systems of the Eocene Tavşanlı Belt, NW Türkiye
by Hüseyin Kocatürk, Mustafa Kumral, Hüseyin Sendir, Mustafa Kaya, Robert A. Creaser and Amr Abdelnasser
Minerals 2025, 15(8), 792; https://doi.org/10.3390/min15080792 - 28 Jul 2025
Cited by 1 | Viewed by 2154
Abstract
This study explores the magmatic and hydrothermal evolution of porphyry–skarn–transitional Cu-Mo-W-Au systems within the Nilüfer Mineralization Complex (NMC), located in the westernmost segment of the Eocene Tavşanlı Metallogenic Belt, NW Türkiye. Through integration of field data, whole-rock geochemistry, Re–Os molybdenite dating, and amphibole–biotite [...] Read more.
This study explores the magmatic and hydrothermal evolution of porphyry–skarn–transitional Cu-Mo-W-Au systems within the Nilüfer Mineralization Complex (NMC), located in the westernmost segment of the Eocene Tavşanlı Metallogenic Belt, NW Türkiye. Through integration of field data, whole-rock geochemistry, Re–Os molybdenite dating, and amphibole–biotite mineral chemistry, the petrogenetic controls on mineralization across four spatially associated mineralized regions (Kirazgedik, Güneybudaklar, Kozbudaklar, and Delice) were examined. The earliest and thermally most distinct phase is represented by the Kirazgedik porphyry system, characterized by high temperature (~930 °C), oxidized quartz monzodioritic intrusions emplaced at ~2.7 kbar. Rising fO2 and volatile enrichment during magma ascent facilitated structurally focused Cu-Mo mineralization. At Güneybudaklar, Re–Os geochronology yields an age of ~49.9 Ma, linking Mo- and W-rich mineralization to a transitional porphyry–skarn environment developed under moderately oxidized (ΔFMQ + 1.8 to +0.5) and hydrous (up to 7 wt.% H2O) magmatic conditions. Kozbudaklar represents a more reduced, volatile-poor skarn system, leading to Mo-enriched scheelite mineralization typical of late-stage W-skarns. The Delice system, developed at the contact of felsic cupolas and carbonates, records the broadest range of redox and fluid compositions. Mixed oxidized–reduced fluid signatures and intense fluid–rock interaction reflect complex, multistage fluid evolution involving both magmatic and external inputs. Geochemical and mineralogical trends—from increasing silica and Rb to decreasing Sr and V—trace a systematic evolution from mantle-derived to felsic, volatile-rich magmas. Structurally, mineralization is controlled by oblique fault zones that localize magma emplacement and hydrothermal flow. These findings support a unified genetic model in which porphyry and skarn mineralization styles evolved continuously from multiphase magmatic systems during syn-to-post-subduction processes, offering implications for exploration models in the Western Tethyan domain. Full article
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21 pages, 7915 KB  
Article
Hydrochemical Characteristics and Association of Hot Springs on Small-Scale Faults in Southern Yunnan–Tibet Geothermal Zone
by Linyang Zhuo, Xun Zhou, Changpei Zou, Yanqiu Wu, Guangbin Tao, Ruirui Cheng, Yixuan Wang and Jingru Ma
Water 2025, 17(10), 1481; https://doi.org/10.3390/w17101481 - 14 May 2025
Cited by 1 | Viewed by 1742
Abstract
Hydrogeochemical characteristics and temperature variations in fault-controlled, deep-circulation thermal springs elucidate water–rock interaction dynamics and hydrothermal circulation depths, providing critical insights into fault permeability and stress accumulation. To investigate the coexistence of high-temperature and medium-low-temperature thermal springs on small-scale faults and their distinct [...] Read more.
Hydrogeochemical characteristics and temperature variations in fault-controlled, deep-circulation thermal springs elucidate water–rock interaction dynamics and hydrothermal circulation depths, providing critical insights into fault permeability and stress accumulation. To investigate the coexistence of high-temperature and medium-low-temperature thermal springs on small-scale faults and their distinct circulation mechanisms, hydrochemical and isotopic analyses were conducted on 13 water samples (9 proximal on the Xiangbaihe Fault) in western Yunnan. The hot springs along the Xiangbaihe Fault are predominantly classified as the Na-HCO3 type, derived from carbonate and aluminosilicate hydrolysis. δ2H and δ18O confirmed a meteoric origin, with recharge elevations spanning 2465–3286 m (Gaoligong Mountain). Inverse hydrochemical modeling demonstrated progressive mineral transfer and water–rock interactions along the fault’s east–west axis. Conservative elements (Cl, Li) suggested a shared geothermal fluid source or reservoir affiliation. BLZ reservoir temperatures (194–221 °C) were classified as a high-temperature system, whereas others (58–150 °C) represented medium-low-temperature systems. Although each thermal spring represents a distinct geothermal system, reservoir interconnectivity is inferred. Notably, despite uniform lithology, variations in spring temperature and elemental composition are attributed to a subsurface magma chamber beneath BLZ, heterogeneous fault geometries, differential reservoir temperatures, and variable cold-water mixing ratios. This study establishes a framework for understanding groundwater circulation in small-scale fault-associated geothermal systems, with implications for tectonic activity monitoring and geothermal resource assessment. Full article
(This article belongs to the Section Hydrogeology)
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16 pages, 6676 KB  
Article
Metasomatic to Hydrothermal Genesis of Natural Calcium Silicate Hydrates (C-S-H): Evidence from Lessini Mountains, Veneto Volcanic Province, Italy
by Michele Mattioli, Matteo Giordani and Franco Filippi
Minerals 2025, 15(1), 26; https://doi.org/10.3390/min15010026 - 28 Dec 2024
Viewed by 2431
Abstract
We report the occurrence of natural calcium silicate hydrates (C-S-H) from the Grolla quarry in the Lessini Mountains of Northern Italy. These minerals are formed by basic and ultrabasic magma interacting with carbonate rocks. The mineral assemblage includes thaumasite, xonotlite, tobermorite, and plombierite, [...] Read more.
We report the occurrence of natural calcium silicate hydrates (C-S-H) from the Grolla quarry in the Lessini Mountains of Northern Italy. These minerals are formed by basic and ultrabasic magma interacting with carbonate rocks. The mineral assemblage includes thaumasite, xonotlite, tobermorite, and plombierite, often intergrown with other silicates, as well as minor amounts of carbonates and sulfates. Common zeolites in this area include chabazite, phillipsite/harmotome, natrolite, and thomsonite. Although less abundant, these zeolites are typically associated with calcite, fluoroapophyllite, and barite. The Grolla quarry outcrop allows for the study of the in situ complex crystalline overgrowths and specific crystal chemistry of rare natural mineral phases, such as C-S-H minerals, formed under metasomatic to hydrothermal conditions. Full article
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32 pages, 7755 KB  
Article
Ore Genesis of the Lower Urgen Porphyry Molybdenum Deposit in the Northern Great Xing’an Range, Northeast China: Constraints from Molybdenite Re-Os Dating, Fluid Inclusions, and H-O-S-Pb Isotopes
by Guangliang Zhang, Wei Xie, Shouqin Wen, Qingdong Zeng, Lingli Zhou, Hui Wang, Kailun Zhang, Tieqiao Tang and Pengcheng Ma
Minerals 2023, 13(9), 1189; https://doi.org/10.3390/min13091189 - 10 Sep 2023
Cited by 2 | Viewed by 2783
Abstract
The Lower Urgen molybdenum deposit (44,856 t Mo @ 0.141%), situated in the northern Great Xing’an Range, is a newly discovered porphyry molybdenum deposit. Mineralization is characterized by veinlet-disseminated- and vein-type quartz–sulfide orebodies primarily occurring in the cupola of the Early Cretaceous granite [...] Read more.
The Lower Urgen molybdenum deposit (44,856 t Mo @ 0.141%), situated in the northern Great Xing’an Range, is a newly discovered porphyry molybdenum deposit. Mineralization is characterized by veinlet-disseminated- and vein-type quartz–sulfide orebodies primarily occurring in the cupola of the Early Cretaceous granite porphyry stock. In this study, we present a detailed description of the ore geology, molybdenite Re-Os dating, H-O-S-Pb isotopic compositions, and fluid inclusion (FI) analyses including petrography, laser Raman, and microthermometry to precisely constrain the timing of ore formation, the origin of ore-forming fluids and materials, as well as the metal precipitation mechanism. Molybdenite Re-Os dating yielded two model ages of 141.2 ± 1.5 and 147.7 ± 1.7 Ma, coeval with the regional Late Jurassic–Early Cretaceous molybdenum metallogenesis. The hydrothermal process can be divided into three stages: the quartz–molybdenite(–pyrite) stage, quartz–polymetallic sulfide stage, and quartz–carbonate stage. Four types of FIs were distinguished for quartz, including two-phase liquid-rich (L-type), saline (S-type), CO2-rich (C1-type), and CO2-bearing (C2-type) FIs. Microthermometric data showed that the homogenization temperatures and salinities from the early to late stages were 240–430 °C, 5.0–11.9, and 30.1–50.8 wt% NaCl equiv.; 180–280 °C and 3.0–9.1 wt% NaCl equiv.; and 120–220 °C and 0.2–7.9 wt% NaCl equiv., respectively, suggesting a decreasing trend. H-O isotopic compositions indicate that the ore-forming fluids were initially of magmatic origin with the increasing incorporation of meteoric water. S-Pb isotopic compositions indicate that the ore-forming materials originated from granitic magmas, and the mineralization is genetically related to the ore-bearing granite porphyry stock in the deposit. Fluid immiscibility and fluid–rock interaction are collectively responsible for the massive deposition of molybdenite in stage 1, whereas fluid mixing and immiscibility played a critical role in the deposition of polymetallic sulfide in stage 2. Full article
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22 pages, 3615 KB  
Review
Mineralization and Skarn Formation Associated with Alkaline Magma Chambers Emplaced in a Limestone Basement: A Review
by Marco Knuever, Daniela Mele and Roberto Sulpizio
Minerals 2023, 13(9), 1184; https://doi.org/10.3390/min13091184 - 9 Sep 2023
Cited by 6 | Viewed by 4425
Abstract
The emplacement of shallow magma chambers within a carbonate basement is a typical feature of many volcanic systems around the world. The accompanying formation of exoskarns, endoskarns, cumulates, exsolved fluids and differentiated melts at the interface between the magma chamber and carbonate host-rock [...] Read more.
The emplacement of shallow magma chambers within a carbonate basement is a typical feature of many volcanic systems around the world. The accompanying formation of exoskarns, endoskarns, cumulates, exsolved fluids and differentiated melts at the interface between the magma chamber and carbonate host-rock is well documented through mineralogical and geochemical studies of ejected skarns and cumulates and through fluid and melt inclusion studies. This review presents the current knowledge on the interaction of alkaline magma chambers with carbonate-bearing host-rocks, with a focus on the geochemical evolution and mineralization at the outer margins of the magma chamber and the accessory mineral phases at Somma-Vesuvius, Colli Albani and Merapi volcanic systems. Furthermore, we discuss how this interaction and its products, especially the CO2 released during the thermometamorphic decarbonation of the carbonate host-rock, impacts the eruptive behavior in all three systems. Full article
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20 pages, 6872 KB  
Article
Genesis and Evolution of Hydrothermal Fluids in the Formation of the High-Grade Hishikari Gold Deposit: Carbon, Oxygen, and Sulfur Isotopic Evidence
by Yuichi Morishita and Yoriko Yabe
Minerals 2022, 12(12), 1595; https://doi.org/10.3390/min12121595 - 12 Dec 2022
Cited by 6 | Viewed by 3976
Abstract
The Hishikari low-sulfidation epithermal gold (Au) deposit in Kyushu, Japan, is world-famous for its premium ore. It has been hypothesized that magmatic contributions to the hydrothermal fluid during early stages of mineralization is possible, even if the hydrothermal fluids for many Au occurrences [...] Read more.
The Hishikari low-sulfidation epithermal gold (Au) deposit in Kyushu, Japan, is world-famous for its premium ore. It has been hypothesized that magmatic contributions to the hydrothermal fluid during early stages of mineralization is possible, even if the hydrothermal fluids for many Au occurrences near the Hishikari deposit are of meteoric origin and are influenced by basement sedimentary rocks. The purpose of this study is to obtain constraints on the genesis and evolution of hydrothermal fluids in the formation of the high-grade Hishikari Au deposit by carbon and oxygen isotope ratios of calcite-bearing samples. Since the microanalysis of carbon and oxygen isotope ratios in every 12 μm of the calcite-bearing sample along the growth direction (corresponding to 10 years of the Hishikari mineralization) scatter in a particular range, the fluid evolution might not be a gradual change from a magmatic to a meteoric origin. Alternatively, a rapid turnover of two fluids might be happening locally. The average sulfur isotope ratio of hydrothermal pyrite is similar to that of the adjacent magma. However, according to the secondary ion mass spectrometry (SIMS) microanalysis, local pyrite with extremely low sulfur isotope ratios may interact with basement sedimentary rocks. Unlike other epithermal Au deposits in the vicinity, rapid local mixing of the magmatic-origin deep fluid and meteoric-origin fluid reacted with organic matter containing basement sedimentary rocks might cause gold precipitation at the Hishikari deposit. Full article
(This article belongs to the Special Issue Geochemistry and Genesis of Hydrothermal Ore Deposits)
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14 pages, 5926 KB  
Article
The Hornsby Quarry Geosite, NSW, Australia—A Geoheritage Treasure
by Trudi A. Semeniuk
Land 2022, 11(12), 2124; https://doi.org/10.3390/land11122124 - 25 Nov 2022
Cited by 6 | Viewed by 4209
Abstract
Quarrying for aggregate material at Hornsby in New South Wales (Australia) exposed a >100 m-deep cross-section of the volcanic neck of a Jurassic diatreme, which extruded through the Sydney Basin deposits. The cross-section reveals volcanic features at many scales. Globally, there are very [...] Read more.
Quarrying for aggregate material at Hornsby in New South Wales (Australia) exposed a >100 m-deep cross-section of the volcanic neck of a Jurassic diatreme, which extruded through the Sydney Basin deposits. The cross-section reveals volcanic features at many scales. Globally, there are very few instances of such excellent 3D exposure. It is arguable that this exposure alone makes it a geosite of international value. However, evaluation of the Hornsby Diatreme using a geoheritage toolkit shows that it meets various geoheritage conservation criteria, being a reference site, and an historically and culturally important site, as well as hosting important archival material. It has significant features at various scales: at the macroscale, where dish beds are visible on all quarry walls, preserving the structure formed during volcanic accretion and later caldera collapse; at the mesoscale, where breccia and surge layers are visible, providing insight into how magma interacted with various host rock types; and at the microscale, where lapilli, chilled margins on host rock blocks, and carbon-rich xenoliths are visible in hand specimens. As such, the Hornsby Quarry hosts a world-class array of volcanic features and preserves an important period of volcanic and post-volcanic history within the Sydney Basin, fostering geoeducation and geotourism. Full article
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47 pages, 28501 KB  
Article
Clues of Lithosphere, Atmosphere and Ionosphere Variations Possibly Related to the Preparation of La Palma 19 September 2021 Volcano Eruption
by Dedalo Marchetti, Kaiguang Zhu, Hanshuo Zhang, Zeren Zhima, Rui Yan, Xuhui Shen, Wenqi Chen, Yuqi Cheng, Xiaodan He, Ting Wang, Jiami Wen, Donghua Zhang and Yiqun Zhang
Remote Sens. 2022, 14(19), 5001; https://doi.org/10.3390/rs14195001 - 8 Oct 2022
Cited by 16 | Viewed by 4307
Abstract
On 19 September 2021, La Palma Cumbre Vieja Volcano started an eruption classified as Volcanic Explosive Index (VEI) 3. In this study, at least the six months prior to such an event have been investigated to search for possible lithosphere–atmosphere–ionosphere bottom-up interactions. The [...] Read more.
On 19 September 2021, La Palma Cumbre Vieja Volcano started an eruption classified as Volcanic Explosive Index (VEI) 3. In this study, at least the six months prior to such an event have been investigated to search for possible lithosphere–atmosphere–ionosphere bottom-up interactions. The lithosphere has been analysed in terms of seismicity getting advantages from the high-density local seismic network. Possible atmospheric alterations related to the volcano emissions or release of gases due to the uplift of the magmatic chamber have been searched in SO2, aerosol, dimethyl sulphide, and CO. The magnetic field on Earth’s surface has been studied by ground geomagnetic observatories. The status of the ionosphere has been investigated with two satellite missions: China Seismo Electromagnetic Satellite (CSES) and European Space Agency Swarm constellation, with Total Electron Content (TEC) retrieved from global maps. We identified a temporal migration of the seismicity from November 2020 at a depth of 40 km that seems associable to magma migration, firstly to a deep chamber at about 15 km depth and in the last 10 days in a shallow magma chamber at less than 5 km depth. The atmospheric composition, ground geomagnetic field, and ionosphere showed anomalies from more than three months before the eruption, suggesting a possible influence from the bottom geo-layers to the upper ones. CSES-01 detected an increase of electron density, confirmed by TEC data, and alterations of vertical magnetic field on ground Guimar observatory that are temporal compatible with some volcanic low seismic activity (very likely due to the magma uplift), suggesting an eventual electromagnetic disturbance from the lithosphere to the ionosphere. A final increase of carbon monoxide 1.5 months before the eruption with unusually high values of TEC suggests the last uplifting of the magma before the eruption, confirmed by a very high shallow seismicity that preceded the eruption by ten days. This work underlines the importance of integrating several observation platforms from ground and overall space to understand geophysics better, and, in particular, the natural hazard affecting our planet. Full article
(This article belongs to the Special Issue Multi-Sensor Remote Sensing Data for Volcanic Hazards Monitoring)
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20 pages, 5461 KB  
Article
Metallogenesis of the Bawang Sn-Zn Polymetallic Deposit, Wuxu Ore Field, Guangxi, South China: U-Pb Dating and C-O-S-Pb Isotopic Constraints
by Enyun Liang, Dezhi Huang, Guangqian Zeng, Gengyin Liu, Guangjun Zou, Peng Luo and Di Chen
Minerals 2022, 12(2), 137; https://doi.org/10.3390/min12020137 - 25 Jan 2022
Cited by 7 | Viewed by 4101
Abstract
The Bawang deposit, located in the west of Wuxu ore field, southern section of the Nandan-Hechi metallogenic belt, is a medium-sized tin–zinc polymetallic deposit. Its genesis has been a matter of debate because of lacking constraints from isotope geology. In this study, LA-MC-ICP-MS [...] Read more.
The Bawang deposit, located in the west of Wuxu ore field, southern section of the Nandan-Hechi metallogenic belt, is a medium-sized tin–zinc polymetallic deposit. Its genesis has been a matter of debate because of lacking constraints from isotope geology. In this study, LA-MC-ICP-MS U-Pb dating of cassiterite and C-O-S-Pb isotope analyses of monominerals were used to investigate the mineralization age and source of the ore-forming minerals in the Bawang deposit. LA-ICP-MS U–Pb dating of cassiterite yielded ages of 93.1 ± 4.8 Ma and 85.3 ± 6.3 Ma, indicating that the mineralization occurred in the early Late Cretaceous. The δ13CPDB and δ18OSMOW values of calcites at the ore stage range between −0.41‰ and 0.44‰ (average = −11‰) and between 13.8‰ and 15.40‰ (average = 14.59‰), respectively. This shows that ore fluid sources were a mixture of those derived from magma and stratum. Pyrite and sphalerite have uniform δ34S values (−4.45‰~−2.20‰), indicating that sulfur is also derived from the mixing of magmatic hydrothermal and stratum fluids. The Pb isotopic composition of sulfide (206Pb/204Pb = 18.4055~18.7625, 207Pb/204Pb = 15.6745~15.7209, 208Pb/204Pb = 38.6232~39.0370) is consistent with the granite of the same age, indicating that ore-forming metals are mainly derived from magmatic hydrothermal solution. The Bawang deposit is a hydrothermal vein-type deposit in the external contact zone of Late Cretaceous granite, controlled by tectonic fractures, and formed by the interaction of magmatic hydrothermal fluid and carbonate rock. There may be large skarn-type ore bodies in the deep part. The results of this study provide insights into the research and exploration of similar deposits in Nandan-Hechi metallogenic belt and in the Youjiang Basin. Full article
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18 pages, 6979 KB  
Article
Influence of Host Marble Rocks on the Formation of Intrusive Alkaline Rocks and Carbonatites of Sangilen (E. Siberia, Russia)
by Anatoly V. Nikiforov, Elena O. Dubinina, Nikolay A. Polyakov, Amina M. Sugorakova and Aylan K. Khertek
Minerals 2021, 11(7), 666; https://doi.org/10.3390/min11070666 - 22 Jun 2021
Cited by 8 | Viewed by 3700
Abstract
The study of the O and C isotope composition of calcite from nepheline syenites, ijolites and carbonatites of the Chik intrusion and the intrusions of the Erzin–Tarbagatay group of Sangilen (Eastern Siberia, Russia) showed derivation from alkaline melts enriched with a carbonate component [...] Read more.
The study of the O and C isotope composition of calcite from nepheline syenites, ijolites and carbonatites of the Chik intrusion and the intrusions of the Erzin–Tarbagatay group of Sangilen (Eastern Siberia, Russia) showed derivation from alkaline melts enriched with a carbonate component from the host marbleized sedimentary rocks. The calculations showed that about 40% of the initial mass of carbonates involved in the interaction with silicate melts have remained after decarbonation. During the assimilation of the carbonate, an oxygen isotope exchange took place between the residual carbonate material and the silicate phase. Crystallization products of such hybrid magmas are carbonatite veins, calcite-rich nepheline rocks and their pegmatites with a calcite core. Full article
(This article belongs to the Special Issue Petrogenesis and Geochemistry in Alkaline Ultramafic Rocks)
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25 pages, 11109 KB  
Article
Evolution of Syenite Magmas: Insights from the Geology, Geochemistry and O-Nd Isotopic Characteristics of the Ordovician Saibar Intrusion, Altai-Sayan Area, Russia
by Alexander A. Vorontsov, Andrey E. Izoh, Vladimir V. Yarmolyuk, Tatyana Y. Komaritsyna, Anatoly V. Nikiforov, Olga Y. Perfilova, Sergei I. Dril, Nailya G. Rizvanova and Egor P. Dushkin
Minerals 2021, 11(5), 473; https://doi.org/10.3390/min11050473 - 30 Apr 2021
Cited by 6 | Viewed by 7258
Abstract
In this paper, we provide insight into the evolution of syenite magmas based on geological data and petrographic, geochemical, and O-Nd isotope parameters of rocks of the Saibar intrusion located within the Minusinsk Trough, Altay-Sayan area. The intrusive suite includes predominant syenites, few [...] Read more.
In this paper, we provide insight into the evolution of syenite magmas based on geological data and petrographic, geochemical, and O-Nd isotope parameters of rocks of the Saibar intrusion located within the Minusinsk Trough, Altay-Sayan area. The intrusive suite includes predominant syenites, few bodies of melanocratic and leucocratic nepheline syenites (foyaites), and granites. In addition, dykes of granites and mafic rocks are present. The U-Pb zircon age from the melanocratic foyaites was determined to be 457 ± 10 Ma? Examined rocks show fractionated light rare earth element patterns, normalized to chondrite, with (La/Sm)n varying from 4 to 9, and a weakly fractionated distribution of medium and heavy rare elements, with (Dy/Yb)n from 0.35 to 1.23 and (Sm/Yb)n from 0.63 to 2.62. The spidergram normalized to the primitive mantle shows negative Ba, Sr, Nb, Ta, Ti, and Eu anomalies (Eu* = 0.48–0.60) and positive Rb, Th, and U anomalies. The δ18O values vary within 6.3 to 10.2‰, and εNd(t) from +4.1 to +5.0. We observe gradual transitions from syenites to foyaites. Assimilation by syenite magma of the host carbonate rocks was followed to transition from silica-saturated to silica-undersaturated conditions and removal of anorthite from the melt, which then led to nepheline. Granites of the main phase show depleted lithophile incompatible elements in comparison with syenites and foyaites. They originate via interaction of magmas at the marginal part (endocontact zone) of the intrusion, corresponding to north contact of the granites with the host felsic rocks. In comparison, the rock composition of granite dykes is enriched in lithophile incompatible elements, except for Zr, Hf, and Ti. These rocks are formed due to the differentiation of syenite magma without a significant effect of host rock assimilation. Mantle magmas must be used as parent magmas for syenites based on analysis of the formation model of other alkaline intrusions, which are similar in age to the Saibar intrusion. In the line of syenite intrusions of the Altai-Sayan province, the Saibar intrusion is no exception, and its origin is related to the evolution of mafic magmas that arose during the melting of the mantle under the influence of a mantle plume. Full article
(This article belongs to the Special Issue Petrology and Ores of Igneous Alkaline Rocks and Carbonatites)
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25 pages, 9996 KB  
Article
REE Characteristics of Lower Cretaceous Limestone Succession in Gümüşhane, NE Turkey: Implications for Ocean Paleoredox Conditions and Diagenetic Alteration
by Merve Özyurt, M. Ziya Kırmacı, Ihsan Al-Aasm, Cathy Hollis, Kemal Taslı and Raif Kandemir
Minerals 2020, 10(8), 683; https://doi.org/10.3390/min10080683 - 30 Jul 2020
Cited by 55 | Viewed by 7628
Abstract
Trace and rare earth elements (REEs) are considered to be reliable indicators of chemical processes for the evolution of carbonate systems. One of the best examples of ancient carbonate successions (Berdiga Formation) is widely exposed in NE Turkey. The Lower Cretaceous limestone succession [...] Read more.
Trace and rare earth elements (REEs) are considered to be reliable indicators of chemical processes for the evolution of carbonate systems. One of the best examples of ancient carbonate successions (Berdiga Formation) is widely exposed in NE Turkey. The Lower Cretaceous limestone succession of Berdiga Formation may provide a case study that reveals the effect of ocean paleoredox conditions on diagenetic alteration. Measurement of major, trace and REEs was carried out on the Lower Cretaceous limestones of the Berdiga Formation, to reveal proxies for paleoredox conditions and early diagenetic controls on their geochemistry. Studied micritic limestone microfacies (MF-1 to MF-3) indicate deposition in the inner platform to a deep shelf or continental slope paleoenvironment during the Hauterivian-Albian. The studied limestone samples mainly exhibit low Mg-calcite characteristics with the general chemical formula of Ca98.35–99.34Mg0.66–1.65(CO3). They are mostly represented by a diagnostic REE seawater signature including (1) slight LREE depletion relative to the HREEs (ave. 0.72 of Nd/YbN and ave. 0.73 of Pr/YbN), (2) negative Ce anomalies (Ce/Ce* = 0.38–0.81; ave. 0.57), (3) positive La anomaly (La/La* = 0.21–3.02; ave. 1.75) and (4) superchondritic Y/Ho (ave. 46.26). Studied micritic limestones have predominantly low Hf (bdl to 0.5 µg/g), Sc (bdl to 2 µg/g) Th (bdl to 0.9 µg/g) contents suggesting negligible to minor shale contamination. These findings imply that micritic limestones faithfully record chemical signals of their parental and diagenetic fluids. The succession also exhibits high ratios of Eu/Eu* (1.01–1.65; ave. 1.29 corresponding to the positive Eu anomalies), Sm/Yb (1.26–2.74; ave. 1.68) and La/Yb ratios (0.68–1.35; ave. 0.9) compared to modern seawater and wide range of Y/Ho ratios (29.33–70.00; ave. 46.26) which are between seawater and hydrogenetic Fe-Mn crusts. Several lines of geochemical evidence suggest water-rock interaction between parental seawater and basaltic rocks at elevated temperatures triggered by hydrothermal activity associated with Early Cretaceous basaltic magma generation. The range of Ce/Ce* values is suggestive of mostly oxic to dysoxic paleoceanographic conditions, with a sudden change to dysoxic conditions (Ce/Ce* = 0.71–0.81), in the uppermost part of the MF-1. This is followed by an abrupt deepening paleoenvironment with a relative increase in the oxic state of the seawater and deposition of deeper water sediments (MF-2 and MF-3) above a sharp transition. The differences in microfacies characteristics and foraminifera assemblage between MF-1 and overlying facies (MF-2 and MF-3) may also confirm the change in paleoceanographic conditions. Therefore, REEs data obtained from studied limestones have the potential to contribute important information as to regional paleoceanographic conditions of Tethys during an important period in Earth history. Full article
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83 pages, 38477 KB  
Review
Ruby Deposits: A Review and Geological Classification
by Gaston Giuliani, Lee A. Groat, Anthony E. Fallick, Isabella Pignatelli and Vincent Pardieu
Minerals 2020, 10(7), 597; https://doi.org/10.3390/min10070597 - 30 Jun 2020
Cited by 47 | Viewed by 65626
Abstract
Corundum is not uncommon on Earth but the gem varieties of ruby and sapphire are relatively rare. Gem corundum deposits are classified as primary and secondary deposits. Primary deposits contain corundum either in the rocks where it crystallized or as xenocrysts and xenoliths [...] Read more.
Corundum is not uncommon on Earth but the gem varieties of ruby and sapphire are relatively rare. Gem corundum deposits are classified as primary and secondary deposits. Primary deposits contain corundum either in the rocks where it crystallized or as xenocrysts and xenoliths carried by magmas to the Earth’s surface. Classification systems for corundum deposits are based on different mineralogical and geological features. An up-to-date classification scheme for ruby deposits is described in the present paper. Ruby forms in mafic or felsic geological environments, or in metamorphosed carbonate platforms but it is always associated with rocks depleted in silica and enriched in alumina. Two major geological environments are favorable for the presence of ruby: (1) amphibolite to medium pressure granulite facies metamorphic belts and (2) alkaline basaltic volcanism in continental rifting environments. Primary ruby deposits formed from the Archean (2.71 Ga) in Greenland to the Pliocene (5 Ma) in Nepal. Secondary ruby deposits have formed at various times from the erosion of metamorphic belts (since the Precambrian) and alkali basalts (from the Cenozoic to the Quaternary). Primary ruby deposits are subdivided into two types based on their geological environment of formation: (Type I) magmatic-related and (Type II) metamorphic-related. Type I is characterized by two sub-types, specifically Type IA where xenocrysts or xenoliths of gem ruby of metamorphic (sometimes magmatic) origin are hosted by alkali basalts (Madagascar and others), and Type IB corresponding to xenocrysts of ruby in kimberlite (Democratic Republic of Congo). Type II also has two sub-types; metamorphic deposits sensu stricto (Type IIA) that formed in amphibolite to granulite facies environments, and metamorphic-metasomatic deposits (Type IIB) formed via high fluid–rock interaction and metasomatism. Secondary ruby deposits, i.e., placers are termed sedimentary-related (Type III). These placers are hosted in sedimentary rocks (soil, rudite, arenite, and silt) that formed via erosion, gravity effect, mechanical transport, and sedimentation along slopes or basins related to neotectonic motions and deformation. Full article
(This article belongs to the Special Issue Mineralogy and Geochemistry of Ruby)
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