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23 pages, 16611 KiB  
Article
Study on the Occurrence States and Enrichment Mechanisms of the Dispersed Elements Ga, Ge, and In in the Chipu Pb-Zn Deposit, Sichuan Province, China
by Tian Tan, Huijuan Peng, En Qin, Ziyue Wang and Xingxing Mao
Minerals 2025, 15(4), 341; https://doi.org/10.3390/min15040341 - 26 Mar 2025
Viewed by 187
Abstract
The dispersed elements Ga, Ge, and In are crucial strategic mineral resources often enriched in Pb-Zn deposits. The Chipu Pb-Zn deposit, located on the western edge of the Yangtze Block, lies to the north of the Sichuan-Yunnan-Guizhou (SYG) Pb-Zn metallogenic province with large [...] Read more.
The dispersed elements Ga, Ge, and In are crucial strategic mineral resources often enriched in Pb-Zn deposits. The Chipu Pb-Zn deposit, located on the western edge of the Yangtze Block, lies to the north of the Sichuan-Yunnan-Guizhou (SYG) Pb-Zn metallogenic province with large amounts of Emeishan basalt. Based on trace element and in situ sulfur isotope analyses by (LA)-ICP-MS, sphalerite is the main carrier mineral for Ga (17~420 ppm), Ge (3.87~444 ppm), and In (31~720 ppm). Ga or Ge correlate significantly with Cu, while In substitutes for Zn in sphalerite alongside Fe. Key substitution reactions include Ga3+ + Cu+ ↔ 2Zn2+, Ge4+ + 2Cu+ ↔ 3Zn2+, and 2In3+ + Fe2+ ↔ 4Zn2+. Sphalerite crystallized at medium to low temperatures (114–195 °C). Sulfide δ34S values (+3.48 to +24.74‰) suggest sulfur mainly originated from Dengying Formation marine sulfates via thermochemical sulfate reduction (TSR). Metal-bearing fluid release at 30 Ma post-Emeishan mantle plume activity (261–257 Ma) coincides with the Chipu deposit’s mineralization period (230–200 Ma), suggesting the Chipu deposit is associated with Emeishan plume activity. The magmatic activity drove basinal brine circulation, extracting In from intermediate-felsic igneous rocks and metamorphic basement. Elevated temperatures promoted the coupling of Fe and In into sphalerite, causing anomalous In enrichment. Full article
(This article belongs to the Special Issue Critical Metal Minerals, 2nd Edition)
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13 pages, 5457 KiB  
Article
Study on the Disintegration Resistance of Different Types of Schist on the Eastern Slope of the Tongman Open-Pit Mine
by Yiming Wen, Xiangdong Niu, Yongfeng Lu, Yong Cheng, Ping Lu, Jianbo Xia, You Lin, Li Tang, Qi Nie and Kaishan Lin
Processes 2025, 13(3), 915; https://doi.org/10.3390/pr13030915 - 20 Mar 2025
Viewed by 181
Abstract
This study aimed to investigate the disintegration resistance of schist on the eastern slope of the Tongman open-pit mine. It examined the effects of cycle number and mineral composition on the disintegration resistance indexes of four types of schist through thin section identification [...] Read more.
This study aimed to investigate the disintegration resistance of schist on the eastern slope of the Tongman open-pit mine. It examined the effects of cycle number and mineral composition on the disintegration resistance indexes of four types of schist through thin section identification and laboratory disintegration resistance tests. Furthermore, we analyzed the morphological characteristics of the disintegration residues using laboratory tests. Based on pore micro-damage theory, the mechanisms responsible for the differences in disintegration resistance among the four types of schist were further explored. The results show a negative correlation between the disintegration resistance index and the number of cycles. For the same number of cycles, the disintegration resistance indices for the four schist types were ranked as follows: greenish-gray chlorite-bearing muscovite schist > gray weakly chloritized biotite–muscovite schist > greenish-gray muscovite schist > gray muscovite schist. The disintegration residues of schist samples were categorized into four morphological patterns: thin sheet-like, moderately thick sheet-like, blocky, and granular. These patterns were then thoroughly elucidated. The differences in the disintegration resistance characteristics of schist were closely related to their material composition. The microstructural pore damage within the rock is the essential factor causing schist disintegration. Variations in rock porosity led to differing damage factors, which explain the distinct disintegration resistance characteristics observed across the four types of schist. The proposed preventive measures, developed through a systematic analysis of schist disintegration mechanisms, provide an effective framework for slope stability management. This research offers valuable insights into the weathering characteristics of rock masses in slope engineering, which is significant for understanding the progressive failure modes of disintegrating metamorphic formations. Full article
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24 pages, 11232 KiB  
Article
Microstructural Investigation of Variscan Late-Collisional Granitoids (Asinara Island, NW Sardinia, Italy): New Insights on the Relationship Between Regional Deformation and Magma Emplacement
by Diego Pieruccioni, Matteo Simonetti, Salvatore Iaccarino, Chiara Montomoli and Rodolfo Carosi
Geosciences 2025, 15(3), 108; https://doi.org/10.3390/geosciences15030108 - 18 Mar 2025
Viewed by 438
Abstract
In the framework of the geological mapping of sheet “n. 425—Asinara Island” (NW Sardinia, Italy) of the Italian National Geological Mapping Project (CARG Project), three late- to post-collisional Variscan intrusive units are recognized: (i) Castellaccio Unit; (ii) Punta Sabina Unit; and (iii) sheeted [...] Read more.
In the framework of the geological mapping of sheet “n. 425—Asinara Island” (NW Sardinia, Italy) of the Italian National Geological Mapping Project (CARG Project), three late- to post-collisional Variscan intrusive units are recognized: (i) Castellaccio Unit; (ii) Punta Sabina Unit; and (iii) sheeted dyke complex. Granitoid rocks from these intrusive units intruded into the medium- to high-grade metamorphic micaschist and paragneiss and the migmatitic complex. A range of deformation microstructures from sub-magmatic to low-temperature subsolidus conditions are recognized. The main observed microstructures are represented by chessboard patterns in quartz and by feldspar sub-grain rotation dynamic recrystallization, indicative of deformation at high-temperature conditions (T > 650 °C). Solid-state high-temperature deformations (T > 450 °C) are provided by feldspar bulging, myrmekites, quartz grain boundary migration and sub-grain rotation dynamic recrystallization. Low-temperature sub-solidus microstructures (T < 450 °C) consist of quartz bulging, mica kinks, and feldspar twinning and bending. These features highlight that the three intrusive units recorded tectonic stresses, which affected the granitoids during cooling without developing a strong penetrative meso/microstructural fabric, as observed in other sectors of the Variscan orogen. The complete sequence of deformation microstructures, recorded in all intrusive units, suggests a weak but still ongoing deformation regime during granitoid emplacement in the Variscan orogen of northwestern Sardinia. These observations are similar to the features highlighted in other sectors of the southern Variscan belt and suggest a complex interplay between transpressional-induced exhumation of the middle/deep crust and magma intrusion. Full article
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16 pages, 12450 KiB  
Article
Investigation and Evaluation of Geothermal Resources in Northern Shanxi Province, China
by Zhongxu Lu, Yang Yang, Yajun Mo, Haizhi Liao and Youlian Cai
Energies 2025, 18(6), 1494; https://doi.org/10.3390/en18061494 - 18 Mar 2025
Viewed by 176
Abstract
In this study, survey methods including seismic techniques and controlled-source audio-frequency magnetotelluric, drilling, and pumping tests were employed to investigate the geothermal systems and their formation mechanisms in northern Shanxi Province, China. The following characteristics were observed: (1) Geothermal resources in northern Shanxi [...] Read more.
In this study, survey methods including seismic techniques and controlled-source audio-frequency magnetotelluric, drilling, and pumping tests were employed to investigate the geothermal systems and their formation mechanisms in northern Shanxi Province, China. The following characteristics were observed: (1) Geothermal resources in northern Shanxi Province are primarily located in Archean metamorphic rocks and fracture zone aquifer groups. The direct heat source is likely uncooled magma chambers in the middle-upper crust, whereas the overlying layers consist of Quaternary, Neogene, and Paleogene deposits. (2) The high-temperature geothermal system is of the convective-conductive type: atmospheric precipitation and surface water infiltrate pore spaces and fault fractures to reach thermal storage, where they are heated. Hot water then rises along the fracture channels and emerges as shallow hot springs, and ongoing extensional tectonic activity has caused asthenospheric upwelling. The partial melting of the upper mantle forms basic basaltic magma, which ascends to the middle-upper crust and forms multiple magma chambers. Their heat is transferred to the shallow subsurface, causing geothermal anomalies. (3) Borehole YG-1 findings revealed that these geothermal resources are primarily static reserves. Our findings provide a foundation for further geothermal development in the region, including the strategic deployment of wells to improve geothermal energy extraction. Full article
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21 pages, 29782 KiB  
Article
Metallogenic Process of Forming the Large Xiangcaowa Karstic Bauxite Deposit from the Southern Margin of the North China Craton
by Wenxia Wang, Xuefei Sun, Lei Liu, Lihua Zhao, Rongrong Liang, Tongyi Zhang and Xuefei Liu
Minerals 2025, 15(3), 310; https://doi.org/10.3390/min15030310 - 17 Mar 2025
Viewed by 245
Abstract
North China Craton (NCC) formed the world’s largest karstic bauxite belt in the Late Carboniferous, with significant variations in metallogenic sources and conditions, which affect the overall understanding of karstic bauxite genesis. The Xiangcaowa bauxite deposit in the southern NCC is a large [...] Read more.
North China Craton (NCC) formed the world’s largest karstic bauxite belt in the Late Carboniferous, with significant variations in metallogenic sources and conditions, which affect the overall understanding of karstic bauxite genesis. The Xiangcaowa bauxite deposit in the southern NCC is a large deposit of uncertain provenance and genesis. This study employed geological, mineralogical, and chronology analysis to investigate the sources and genesis of Xiangcaowa bauxite, further contributing to a full understanding of the origin of bauxite throughout the NCC. Xiangcaowa ore-bearing rock series is composed of bauxite and claystone layers. The composition of bauxite ore encompasses diaspore, kaolinite, anatase, pyrite, zircon, and rutile. Widely developed mineral assemblages, such as diaspore–anatase–pyrite, indicate that bauxite is mainly formed in reducing and alkaline karstic depressions. Detrital zircons, aged ~450, ~520, ~950, and ~1100 Ma, predominantly originate from igneous rocks in the North Qinling Orogenic Belt (NQOB), and the ~1650 and ~2400 Ma zircon age populations are primarily from the southern margin of the NCC. Detrital rutiles, which are concentrated in 800–510 Ma, are primarily from the metamorphic rocks of the South Qinling Orogenic Belt (SQOB); rutiles aged ~1500–910 Ma are primarily from metamorphic rocks in the NQOB. These results confirm that the principal sources of the bauxite are the igneous and metamorphic rocks within the NQOB, along with the metamorphic rocks of the SQOB, while the basement rocks of the NCC contribute only minorly to its formation. A large karstic bauxite deposit was formed by the transport of large amounts of weathered material into extensive karstic depressions where reducing and alkaline conditions favoured diaspore deposition. Full article
(This article belongs to the Section Mineral Deposits)
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31 pages, 40437 KiB  
Article
Structural Characterization of the Pan-African Banyo Area (Western Cameroon Domain): Constraints from Field Observations, Structures and AMS
by Alys Calore Mengou, Bertille Edith Bella Nke, Théophile Njanko, Pierre Rochette, Roland Kanse Onana, François Demory and Emmanuel Njonfang
Geosciences 2025, 15(3), 99; https://doi.org/10.3390/geosciences15030099 - 10 Mar 2025
Viewed by 339
Abstract
The Banyo area, located in the southern prolongation of the Mayo Nolti shear zone trend, belongs to the western Cameroon domain of the Neoproterozoic Central African Belt (NCAB). It is made of granitic rocks that intrude metamorphic banded rocks. Both are sometimes mylonitized. [...] Read more.
The Banyo area, located in the southern prolongation of the Mayo Nolti shear zone trend, belongs to the western Cameroon domain of the Neoproterozoic Central African Belt (NCAB). It is made of granitic rocks that intrude metamorphic banded rocks. Both are sometimes mylonitized. The pluton is dominantly of paramagnetic behavior, as shown by the hysteresis loops and the Fe-bearing silicates crystals are the susceptibility carriers. AMS ellipsoids are dominantly of oblate shape, pointing to the importance of flattening during pluton emplacement. The anisotropy degree of magnetic susceptibility values (≤1.20) characterize the magmatic fabric flow. The microstructural study of the granite reveals magmatic, sub-magmatic, solid-state and mylonitic deformations. Field and AMS fabrics show evidence of polyphase deformation (D1–D3). The D1 phase is of flattening mechanism (flat-laying foliation). The D2 phase points to sinistral ductile simple shear accommodating moderate to steep dipping and N-S- to NW-SE-oriented foliations in plutonic and country rocks and conjugated E-W mylonitic foliation in country rocks bearing sub-horizontal- to moderate-plunge mineral stretching lineation. The D3 phase is of dextral ductile simple shear. σ- and δ-type kinematic markers in the pluton indicate sinistral top-to-south sense of shear movement, indicating a non-coaxial component of the tectonics. The magnetic fabrics of the pluton are parallel to those of the D2 deformation phase of the study area. The transpressive D2 and D3 events correlate with the D2 and D3 phases of the Pan-African tectonic dated at 613–585 Ma and 585–540 Ma, respectively. The pluton, then, emplaced during regional sinistral D2 deformation under transpressive regime. The emplacement of the NE Banyo granite took place as rock strips sheared in sinistral sense of shear movement. Full article
(This article belongs to the Section Structural Geology and Tectonics)
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28 pages, 2517 KiB  
Article
Petrography and Geochemistry of Lower Jurassic Sandstones in the Eastern Junggar Basin: Implications for Provenance and Tectonic Setting
by Furong Li, Zhi Zhang, Can Zhao, Jinqi Han, Jiaye Liu, Yaoyun Guo, Xinyu Tang, Chang Su, Xu Chang and Tong Wu
Minerals 2025, 15(3), 279; https://doi.org/10.3390/min15030279 - 9 Mar 2025
Viewed by 647
Abstract
The Junggar Basin basement comprises microcontinental blocks amalgamated through successive paleo-oceanic accretion events. Stratigraphic and provenance studies within the basin are crucial for reconstructing its evolution and understanding the closure of paleo-oceanic systems. This study presents an integrated petrographic and geochemical analysis of [...] Read more.
The Junggar Basin basement comprises microcontinental blocks amalgamated through successive paleo-oceanic accretion events. Stratigraphic and provenance studies within the basin are crucial for reconstructing its evolution and understanding the closure of paleo-oceanic systems. This study presents an integrated petrographic and geochemical analysis of the Lower Jurassic Badaowan Formation sandstones in the Dongdaohaizi Depression, located in the eastern Junggar Basin. The results reveal a progressive decrease in lithic fragment content and an increase in quartz content from older to younger strata within the Badaowan Formation, indicating an increase in compositional maturity. Provenance analysis indicates that the sandstones are predominantly derived from tuffaceous rocks, granites, basalts, and minor metamorphic rocks. Heavy mineral assemblages, including zircon, chromian spinel, tourmaline, and garnet, suggest parent rocks consisting primarily of intermediate to acidic igneous rocks, mafic igneous rocks, and metamorphic rocks. Integrated petrographic and geochemical data from the surrounding areas of the Dongdaohaizi Depression confirm that the Badaowan Formation sandstones are primarily sourced from the eastern Kelameili Mountain. The continued uplift and migration of the Kelameili Mountain during the Early Jurassic played a dominant role in shaping the sedimentary provenance. LA-ICP-MS analyses reveal that the rare earth element (REE) concentrations in the Lower Jurassic sandstones are slightly lower than the average REE content of the upper continental crust. The sandstones exhibit weak differentiation between light and heavy REEs, reflecting a depositional environment characterized by anoxic reducing conditions. Geochemical results indicate a tectonic setting dominated by a passive continental margin and continental island arc in the source area. Synthesizing these findings with related studies, we propose that the Kelameili Ocean, as part of the Paleo-Asian Ocean, underwent a complex evolution involving multiple oceanic basins and microcontinental subduction–collision systems. From the Middle Ordovician to Late Silurian, the Kelameili region evolved as a passive continental margin. With the onset of subduction during the Middle Devonian to Early Carboniferous, the eastern Junggar Basin transitioned into a continental island arc system. This tectonic transition was likely driven by episodic or bidirectional subduction of the Kelameili Ocean. Full article
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22 pages, 8497 KiB  
Article
U-Pb and Lu-Hf Record of Two Metamorphic Events from the Peixe Alkaline Suite, Brasilia Belt: Textural and Isotopic Complexity in Zircon
by Marco Helenio Coelho, Luís Felipe Romero, Maria Virginia Alves Martins, Werlem Holanda, Marcelo Salomão, Guilherme Loriato Potratz, Armando Dias Tavares and Mauro Cesar Geraldes
Minerals 2025, 15(3), 274; https://doi.org/10.3390/min15030274 - 7 Mar 2025
Viewed by 361
Abstract
U-Pb and Lu-Hf isotopes, by inductively coupled plasma mass spectrometry and laser ablation (ICP-MS-LA), are reported in zircon grains from the Peixe Alkaline Suite. This unit comprises alkaline rocks such as syenites with nepheline, albite-oligoclase-biotite, and pegmatitic bodies. The zircon grain was imaged [...] Read more.
U-Pb and Lu-Hf isotopes, by inductively coupled plasma mass spectrometry and laser ablation (ICP-MS-LA), are reported in zircon grains from the Peixe Alkaline Suite. This unit comprises alkaline rocks such as syenites with nepheline, albite-oligoclase-biotite, and pegmatitic bodies. The zircon grain was imaged by cathodoluminescence (CL), which allowed the characterization of features within the crystal. These features comprise complex zone crosscuts, showing the existence of pulses that caused the intrusion of isotopically younger phases into the interior of the grain on a millimetric scale. The U-Pb results suggest a metamorphic event with Pb loss at 579 ± 3 Ma. They can be interpreted because of the collisional regional event of the Brasilia Orogen (Mara Rosa Orogeny). A second age grouping at 548 ± 2.5 Ma (MSWD = 8), obtained in areas with high luminescence fading laterally to oscillatory zoned domains with variations in the abundance of isotopes, is 33 Ma younger, demonstrating a rejuvenation of these areas through Pb loss. It is interpreted here as a second metamorphic event related to a collisional event (Santa Terezinha de Goiás arc). The Lu-Hf results for these areas indicate ƐHf values between −10 and −17, suggesting the existence of magmatic isotopic rework in a crustal environment. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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17 pages, 1978 KiB  
Review
Multiple Solutions of Ore-Forming Fluids of Carbonate Rock-Related Nephrite Deposits Constrained by Hydrogen and Oxygen Isotopes
by Ping Li, Zongting Liao, Qi Chen, Lijian Qi and Yungui Liu
Minerals 2025, 15(3), 272; https://doi.org/10.3390/min15030272 - 7 Mar 2025
Viewed by 211
Abstract
Hydrogen and oxygen isotopes of ore-forming fluid of nephrite deposits have always been changing due to mixings between different fluids and oxygen isotope exchanges between the ore-forming fluid and country rocks, resulting in that the tremolite (or actinolite) has to constantly re-establish new [...] Read more.
Hydrogen and oxygen isotopes of ore-forming fluid of nephrite deposits have always been changing due to mixings between different fluids and oxygen isotope exchanges between the ore-forming fluid and country rocks, resulting in that the tremolite (or actinolite) has to constantly re-establish new isotope fractionation equilibriums with the dynamic fluid, which is of great significance to understand the genesis of hydrogen and oxygen isotopes of nephrite. Based on this, Taylor’s closed model and fluid mixing model are used to unravel the control of multi-stage evolution of ore-forming fluid on the δD and δ18O of nephrite. Although Taylor’s closed model is conducive to interpreting the genesis of nephrite with light δD and δ18O, such as Vitim nephrite, Russia, and Chuncheon nephrite, South Korea, it is unable to be effectively used in other nephrite. The fluid mixing model can quantitatively constrain proportions of different fluids during different ore-forming stages. Multiple solutions of ore-forming fluids of carbonate rock-related nephrite result from the absence of external constraints, such as isotope compositions of intrusive rocks, carbonate rocks, and meteoric water. Due to the generally heavy δ18O of country rocks, a small amount of meteoric water that enters the hydrothermal system in the later ore-forming stage is insufficient to offset the δ18O increment of nephrite caused by the oxygen isotope exchange between country rocks and water, which should be responsible for the abnormal heavy δ18O of Luodian nephrite, Dahua nephrite, Sanchakou nephrite, Xiaomeiling nephrite, etc., and not metamorphic water dominating their formation. Full article
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21 pages, 3815 KiB  
Article
Paleoenvironmental Controls and Economic Potential of Li-REY Enrichment in the Upper Carboniferous Coal-Bearing “Si–Al–Fe” Strata, Northeastern Qinshui Basin
by Ning Wang, Jun Zhao, Yingxia Xu, Mangen Mu, Shangqing Zhang, Libo Jing, Guoshu Huang, Liang Liu and Pengfei Tian
Minerals 2025, 15(3), 269; https://doi.org/10.3390/min15030269 - 5 Mar 2025
Viewed by 428
Abstract
Critical metals in coal-bearing strata have recently emerged as a frontier hotspot in both coal geology and ore deposit research. In the Upper Carboniferous coal-bearing “Si–Al–Fe” strata (Benxi Formation) of the North China Craton (NCC), several critical metals, including Li, Ga, Sc, V, [...] Read more.
Critical metals in coal-bearing strata have recently emerged as a frontier hotspot in both coal geology and ore deposit research. In the Upper Carboniferous coal-bearing “Si–Al–Fe” strata (Benxi Formation) of the North China Craton (NCC), several critical metals, including Li, Ga, Sc, V, and rare earth elements and Y (REY or REE + Y), have been discovered, with notable mineralization anomalies observed across northern, central, and southern Shanxi Province. However, despite the widespread occurrence of outcrops of the “Si–Al–Fe” strata in the northeastern Qinshui Basin of eastern Shanxi, there has been no prior report on the critical metal content in this region. Traditionally, the “Si–Al–Fe” strata have been regarded as a primary source of clastic material for the surrounding coal seams of the Carboniferous–Permian Taiyuan and Shanxi Formations, which are known to display critical metal anomalies (e.g., Li and Ga). Given these observations, it is hypothesized that the “Si–Al–Fe” strata in the northeastern Qinshui Basin may also contain critical metal mineralization. To evaluate this hypothesis, new outcrop samples from the “Si–Al–Fe” strata of the Benxi Formation in the Yangquan area of the northeastern Qinshui Basin were collected. Detailed studies on critical metal enrichment were assessed using petrographic observations, mineralogy (XRD, X-ray diffractometer), and geochemistry (XRF, X-ray fluorescence spectrometer, and ICP-MS, inductively coupled plasma mass spectrometer). The results indicate that the siliceous, ferruginous, and aluminous rocks within the study strata exhibit varying degrees of critical metal mineralization, mainly consisting of Li and REY, with minor associated Nb, Zr, and Ga. The Al2O3/TiO2, Nb/Y vs. Zr/TiO2, and Nb/Yb vs. Al2O3/TiO2 diagrams suggest that these critical metal-enriched layers likely have a mixed origin, comprising both intermediate–felsic magmatic rocks and metamorphic rocks derived from the NCC, as well as alkaline volcaniclastics associated with the Tarim Large Igneous Province (TLIP). Furthermore, combined geochemical parameters, such as the CIA (chemical index of alteration), Sr/Cu vs. Ga/Rb, Th/U, and Ni/Co vs. V/(V + Ni), indicate that the “Si–Al–Fe” strata in the northeastern Qinshui Basin were deposited under warm-to-hot, humid climate conditions, likely in suboxic-to-anoxic environments. Additionally, an economic evaluation suggests that the “Si–Al–Fe” strata in the northeastern Qinshui Basin hold considerable potential as a resource for the industrial extraction of Li, REY, Nb, Zr, and Ga. Full article
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21 pages, 8306 KiB  
Article
Magmatic–Hydrothermal Processes of the Pulang Giant Porphyry Cu (–Mo–Au) Deposit, Western Yunnan: A Perspective from Different Generations of Titanite
by Mengmeng Li, Xue Gao, Guohui Gu and Sheng Guan
Minerals 2025, 15(3), 263; https://doi.org/10.3390/min15030263 - 3 Mar 2025
Viewed by 385
Abstract
The Yidun island arc was formed in response to the Late Triassic westward subduction of the Ganzi–Litang oceanic plate, a branch of the Paleo-Tethys Ocean. The Zhongdian arc, located in the south of the Yidun island arc, has relatively large number of porphyry [...] Read more.
The Yidun island arc was formed in response to the Late Triassic westward subduction of the Ganzi–Litang oceanic plate, a branch of the Paleo-Tethys Ocean. The Zhongdian arc, located in the south of the Yidun island arc, has relatively large number of porphyry (skarn) type Cu–Mo ± Au polymetallic deposits, the largest of which is the Pulang Cu (–Mo–Au) deposit with proven Cu reserves of 5.11 Mt, Au reserves of 113 t, and 0.17 Mt of molybdenum. However, the relationship between mineralization and the potassic alteration zone, phyllic zone, and propylitic zone of the Pulang porphyry deposit is still controversial and needs further study. Titanite (CaTiSiO5) is a common accessory mineral in acidic, intermediate, and alkaline igneous rocks. It is widely developed in various types of metamorphic rocks, hydrothermally altered rocks, and a few sedimentary rocks. It is a dominant Mo-bearing phase in igneous rocks and contains abundant rare earth elements and high-field-strength elements. As an effective geochronometer, thermobarometer, oxybarometer, and metallogenic potential indicator mineral, titanite is ideal to reveal the magmatic–hydrothermal evolution and the mechanism of metal enrichment and precipitation. In this paper, major and trace element contents of the titanite grains from different alteration zones were obtained using electron probe microanalysis (EPMA) and laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) to define the changes in physicochemical conditions and the behavior of these elements during the process of hydrothermal alteration at Pulang. Titanite in the potassic alteration zone is usually shaped like an envelope. It occurs discretely or is enclosed by feldspar, with lower contents of CaO, Al, Sr, Zr and Hf; a low Nb/Ta ratio; high ∑REE + Y, U, Th, Ta, Nb, and Ga content; and high FeO/Al2O3 and LREE/HREE ratios. This is consistent with the characteristics of magmatic titanite from fresh quartz monzonite porphyry in Pulang and other porphyry Cu deposits. Titanite in the potassium silicate alteration zone has more negative Eu anomaly and a higher U content and Th/U ratio, indicating that the oxygen fugacity decreased during the transformation to phyllic alteration and propylitic alteration in Pulang. High oxygen fugacity is favorable for the enrichment of copper, gold, and other metallogenic elements. Therefore, the enrichment of copper is more closely related to the potassium silicate alteration. The molybdenum content of titanite in the potassium silicate alteration zone is 102–104 times that of the phyllic alteration zone and propylitic alteration zone, while the copper content is indistinctive, indicating that molybdenum was dissolved into the fluid or deposited in the form of sulfide before the medium- to low-temperature hydrothermal alteration, which may lead to the further separation and deposition of copper and molybdenum. Full article
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23 pages, 8147 KiB  
Article
Thermochronology of the Kalba–Narym Batholith and the Irtysh Shear Zone (Altai Accretion–Collision System): Geodynamic Implications
by Alexey Travin, Mikhail Buslov, Nikolay Murzintsev, Valeriy Korobkin, Pavel Kotler, Sergey V. Khromykh and Viktor D. Zindobriy
Minerals 2025, 15(3), 243; https://doi.org/10.3390/min15030243 - 26 Feb 2025
Viewed by 313
Abstract
The granitoids of the Kalba–Narym batholith and the Irtysh shear zone (ISZ) are among the main geological features of the late Paleozoic Altai accretion–collision system (AACS) in Eastern Kazakhstan. Traditionally, it is believed that late Paleozoic strike-slip faults played a pivotal role at [...] Read more.
The granitoids of the Kalba–Narym batholith and the Irtysh shear zone (ISZ) are among the main geological features of the late Paleozoic Altai accretion–collision system (AACS) in Eastern Kazakhstan. Traditionally, it is believed that late Paleozoic strike-slip faults played a pivotal role at all stages of the development of the AACS, they were supposed to control deformation, magmatism, and ore deposits. This work is devoted to solving the problem of the tectonic evolution of the AACS based on the reconstruction of the thermal history of granitoids of the Kalba–Narym batholith in connection with the Chechek metamorphic dome structure, which is one of the highly metamorphosed blocks mapped within the ISZ. The new geological and geochronological data presented in this work allowed us to establish the sequence of formation of the Kalba–Narym granitoid batholith and link it with the evolution of the Irtysh shear zone (ISZ). It was revealed that in the late Carboniferous–early Permian (312–289 Ma), during the NE–SW compression, the Irtysh shear zone formed as a gently dipping thrust system into which gabbro of the Surov massif intruded. The combined manifestation of magmatic and tectonic processes caused the formation of tectonic mélange with cataclastic gabbro and metamorphic rocks of the Chechek metamorphic dome structure (312–289 Ma). Compression caused the formation of a cover-thrust structure. The thickening of the crust under the probable thermal action of the Tarim plume led to the formation of the early Permian Kalba–Narym batholith (297–284 Ma) within the Kalba–Narym terrane. Denudation of the orogen occurred before the Early Triassic (280–229 Ma). In this way the sequence of formation of the Kalba–Narym batholith and the ISZ is consistent with the concepts of the stages of plume-lithosphere interaction within the AACS under the influence of the late Carboniferous–early Permian Tarim igneous province, but in the cover-thrust tectonic setting. Full article
(This article belongs to the Special Issue Developments in Geochronology and Dating of Shear Zone Deformation)
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29 pages, 15871 KiB  
Article
How Stiff Was Armorica During the Variscan Orogeny? A Reappraisal of the “Bretonian” Phase in Central Brittany
by Michel Faure, Eric Marcoux, Marc Poujol and Clément Masson
Geosciences 2025, 15(2), 60; https://doi.org/10.3390/geosciences15020060 - 10 Feb 2025
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Abstract
In collision belts, the upper plate is generally less deformed than the lower one that underwent syn-metamorphic ductile shearing, and frequently late-collisional crustal melting. Concerning the Variscan orogeny, it is widely accepted that the Armorica microcontinent represented the upper plate of the collision [...] Read more.
In collision belts, the upper plate is generally less deformed than the lower one that underwent syn-metamorphic ductile shearing, and frequently late-collisional crustal melting. Concerning the Variscan orogeny, it is widely accepted that the Armorica microcontinent represented the upper plate of the collision system. In France, the Central-North-Armorican Domain belonged to this upper plate whose southern margin in the Pontivy–Coray area exposes metamorphic rocks. There, structural and metamorphic studies indicate that an early tectono-metamorphic event (M0-M1) with biotite–garnet–staurolite–kyanite assemblage, crystallized at 0.9 GPa and 500 °C, is characterized by a top-to-the NW shearing. This event was followed by an HT event (M2) at ca 800–900 °C, coeval with a domal structure. In micaschists, monazite yields an LA-ICP-MS age at 351 Ma ascribed to M2. M0-M1-M2 events developed before the Late Carboniferous pluton emplacement at ca 315 Ma (M3 event). The tectono-metamorphic succession documents that Armorica was not a rigid block but underwent a synmetamortphic ductile deformation during the Famennian–Tournaisian (360–355 Ma) collision redefined here as the late episode of the “Bretonian orogenic phase”, whereas the pre-Famennian Bretonnian episode is ascribed to oceanic subduction. These new data allow us to reassess the geodynamic evolution of this part of the Variscan orogen. Full article
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20 pages, 7333 KiB  
Article
Experimental Simulation Investigation on Slab Buckling Rockburst in Deep Tunnel
by Chao Ren, Xiaoming Sun, Manchao He and Dongqiao Liu
Appl. Sci. 2025, 15(4), 1682; https://doi.org/10.3390/app15041682 - 7 Feb 2025
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Abstract
The relationship between slabbing failure and rockburst has become a hot issue in rockburst research. In this paper, the experimental system of impact rockburst is used to conduct a simulation experiment of rockburst induced by slab failure on metamorphic sandstone samples taken from [...] Read more.
The relationship between slabbing failure and rockburst has become a hot issue in rockburst research. In this paper, the experimental system of impact rockburst is used to conduct a simulation experiment of rockburst induced by slab failure on metamorphic sandstone samples taken from the deep-buried horseshoe-shaped tunnel in Gaoloushan, with “pan-shaped” rockburst pits on site and laboratory simulation experiments, which prove the rationality of the experimental results of rockburst. The quantitative analysis of the displacement field in the process of the slab buckling rockburst is carried out, which shows that the slab structure will undergo a long period of gestation before its formation, and the formation of the slab structure will accelerate the occurrence of rockburst. This type of rockburst has attenuation characteristics in the process of rockburst; in addition, the phenomenon of “slab buckling circle” is found. The generation of the “slab buckling circle” and the formation of slab buckling cracks are inconsistent, which is a time-lagged fracture in engineering. The relationship between the rupture parameters of rockburst disaster rock mass and time shows a compound exponential growth relationship, revealing that the mechanism of the slab buckling rockburst can be regarded as the result of the combined action of shear crack and tension crack, which plays a leading role, reflecting the characteristic of progressive fracture development. It is a typical progressive fracture-induced instability rockburst model, which is a strain-lag rockburst. Full article
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40 pages, 14218 KiB  
Article
Geochemistry and Petrogenesis of Permo–Triassic Silicic Volcanic Rocks from the Circum-Rhodope Belt in the Vardar/Axios Zone, Northern Greece: An Example of a Post-Collision Extensional Tectonic Setting in the Tethyan Realm
by Argyro Asvesta
Geosciences 2025, 15(2), 48; https://doi.org/10.3390/geosciences15020048 - 2 Feb 2025
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Abstract
The western side of the Vertiskos Unit crystalline basement in northern Greece is fringed by a Permo–Triassic low-grade metamorphic volcano-sedimentary complex that belongs to the Circum-Rhodope Belt (CRB), which is an important part of the Vardar/ Axios oceanic suture zone. The silicic volcanic [...] Read more.
The western side of the Vertiskos Unit crystalline basement in northern Greece is fringed by a Permo–Triassic low-grade metamorphic volcano-sedimentary complex that belongs to the Circum-Rhodope Belt (CRB), which is an important part of the Vardar/ Axios oceanic suture zone. The silicic volcanic rocks from the CRB are mainly rhyolitic to rhyodacitic lavas with aphyric and porphyritic textures as well as pyroclastic deposits. In this study, geochemical data obtained with X-ray fluorescence (XRF) for the CRB silicic volcanic rocks are reported and discussed to constrain their petrogenesis and tectonic setting. The rocks are peraluminous and show enrichment in K, Rb, Th, Zr, Y, and Pb while being depleted in Ba, Sr, Nb, P, and Ti, and they have Zr + Nb + Y + Ce > 350 ppm, which are characteristic features of anorogenic A-type granites. They have a Y/Nb ratio > 1.2 and belong to A2-subtype granitoids, implying crust-derived magma in a post-collisional tectonic setting. The high Rb/Sr ratio (3.45–39.14), the low molar CaO/(MgO + FeOt) ratio, and the CaO/Na2O ratio (<0.5), which they display, indicate that metapelites are the magma sources. Their low Al2O3/TiO2 ratio (<100), consistent with their high zircon saturation temperatures (average TZr = 886 °C), and their low Pb/Ba ratio (average 0.06) reveal that they were generated by biotite dehydration melting. The increased Rb/Sr ratio relative to that of presumable parental metapelites of the Vertiskos Unit, coupled with their low Sr/Y ratio (0.12–1.08), reflects plagioclase and little or no garnet in the source residue, indicating magma derivation at low pressures of 0.4–0.8 GPa that correspond to a depth of ~15–30 km. The nearby tholeiitic basalts and dolerites, interstratified with the Triassic pelagic sediments, indicate bimodal volcanism in the region. They also support a model involving an upwelling asthenosphere that underplated the Vertiskos Unit basement, supplying the heat required for crustal melting at low pressures. The Permo–Triassic magmatism marks the transition from an orogenic to an anorogenic environment during the initial stage of continental breakup of the Variscan basement in a post-collision extensional tectonic framework, leading to the formation of the nascent Mesozoic Neo-Tethyan Maliac–Vardar Ocean. This apparently reveals that the Variscan continental collision between the Gondwana-derived Vertiskos and Pelagonian terranes must have been completed by at least the earliest Late Permian. Full article
(This article belongs to the Section Geochemistry)
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