Search Results (25)

Silicone pressure-sensitive adhesives are a prominent group of adhesive materials used in many contemporary industrial sectors. This is due to their high resistance to difficult operating conditions, especially high temperatures. They are used, among other areas, in the automotive industry or in power engineering, as fastening or insulation systems operating at high temperatures. Previous studies have demonstrated the beneficial effect of mineral fillers on further increases in thermal resistance and dimensional stability of silicone pressure-sensitive adhesives. This paper presents the results of research on the effect of adding rose quartz as a filler to silicone pressure-sensitive adhesives based on polydimethylsiloxanes, on the adhesion parameters of the obtained adhesives and their thermal resistance and dimensional stability at elevated temperatures. The self-adhesive tapes obtained showed increased resistance and thermal stability while maintaining the required performance parameters. Among the tested compositions, optimal PSA parameters were achieved for Q2-7358 resin filled with 0.5 pph of rose quartz particles: adhesion exceeded industrial requirements by more than 15%, and tack met those requirements. Furthermore, low (and consistent) shrinkage (0.4% after one week) and cohesion—evaluated as hold time > 72 h—were recorded. As the most important parameter for studied compositions, thermal resistance (SAFT) substantially increased (>225 h) in comparison to neat resin (150 h). Full article

In this study, a high-performance MoS₂-based strain-gauge pressure was sensor fabricated entirely below 80 °C, enabling direct integration onto flexible polyethylene terephthalate (PET) substrates. The sensor comprised a three-layer MoS₂ channel (~2 nm) patterned via dry transfer and O₂/Ar plasma etching, interfaced with Cr/Au electrodes. This wafer-scale and cost-effective fabrication route preserves the crystallinity of the film and prevents substrate degradation. The sensor achieved a gauge factor of ~104 under compression, representing a fifty-fold improvement over conventional metal foil gauges (~2), with a linear response across both compressive and tensile regimes. Mechanical robustness was confirmed through repeated bending and tape adhesion tests, with no degradation in electrical performance. When configured as a Wheatstone bridge, this device exhibits normalized sensitivity suitable for real-time monitoring, with response and recovery times below 200 ms. These results establish O₂/Ar-plasma-patterned MoS₂ architectures as a scalable, cost-effective platform for next-generation flexible sensors, outperforming metal-foil technology in applications including seat-occupancy detection, wearable physiological monitoring, and tactile interfaces for soft robotics. Full article

In this work, new self-adhesive materials were obtained based on cross-linked silicone self-adhesives obtained by modifying the composition with the addition of a silicon filler, olivine. Silicone pressure-sensitive resin DOWSIL 7358 was used as a basis and modified with various amounts of olivine. New materials (self-adhesive tape samples) were characterized in terms of peel adhesion, tack, cohesion at room and elevated temperatures, SAFT test (shear adhesion failure temperature), pot life (storage stability), and shrinkage (dimensional stability). During the tests, an increase in thermal resistance (>225 °C) and a drastic reduction in shrinkage values (below 0.5%) were noted for all modified samples tested. All tests were performed in compliance with international standards, e.g., FINAT FTM 1, FINAT FTM 8, FINAT FTM 9, FINAT FTM 14, and GTF 6001. This allows us to conclude that the new material has significant application potential due to the good performance results. The results of adhesion and tack were in ranges accepted in the PSA industry, cohesion was kept at an unchanged level (above 72 h), and a great increase in the thermal resistance was observed (from 147 °C for pure resin to high above 225 °C for even the smallest additions of the olivine powder. Moreover, the shrinkage of prepared adhesive films was reduced significantly. In the available literature, there are no references to the modification of adhesives using powdered silicon minerals of natural origin, which is a novelty due to their higher bulk density compared to commercial powdered silicon fillers. Full article

For polyacrylate latex pressure-sensitive adhesives (PSAs), high peel strength is of crucial significance. It is not only a key factor for ensuring the long-lasting and effective adhesive force of polyacrylate latex PSAs but also can significantly expand their application scope in many vital fields, such as packaging, electronics, and medical high-performance composite materials. High peel strength can guarantee that the products maintain stable and reliable adhesive performance under complex and variable environmental conditions. However, at present, the peel strength capacity of polyacrylate latex PSAs is conspicuously insufficient, making it difficult to fully meet the urgent market demand for high peel strength, and severely restricting their application in many cutting-edge fields. Therefore, based on previous experimental studies, and deeply inspired by the adhesion mechanism of natural marine mussels, in this study, a traditional polyacrylate latex PSA was ingeniously graft-modified with 3,4-dihydroxybenzaldehyde (DHBA) through the method of monomer-starved seeded semi-continuous emulsion polymerization, successfully synthesizing novel high-peel-strength polyacrylate latex pressure-sensitive adhesives (HPSAs) with outstanding strong adhesion properties, and the influence of DHBA content on the properties of the HPSAs was comprehensively studied. The research results indicated that the properties of the modified HPSAs were comprehensively enhanced. Regarding the water resistance of the adhesive film, the minimum water absorption rate was 4.33%. In terms of the heat resistance of the adhesive tape, it could withstand heat at 90 °C for 1 h without leaving residue upon tape peeling. Notably, the adhesive properties were significantly improved, and when the DHBA content reached 4.0%, the loop tack and 180° peel strength of HPSA₄ significantly increased to 5.75 N and 825.4 gf/25 mm, respectively, which were 2.5 times and 2 times those of the unmodified PSA, respectively. Such superior adhesive performance of HPSAs, on the one hand, should be attributed to the introduction of the bonding functional monomer DHBA with a rich polyphenol structure; on the other hand, the acetal structure formed by the grafting reaction of DHBA with the PSA effectively enhanced the spatial network and crosslink density of the HPSAs. In summary, in this study, the natural biological adhesion phenomenon was ingeniously utilized to increase the peel strength of pressure-sensitive adhesives, providing a highly forward-looking and feasible direct strategy for the development of environmentally friendly polyacrylate latex pressure-sensitive adhesives. Full article

The article describes new silicone self-adhesive adhesives modified with the addition of talc. The obtained self-adhesive materials were characterized to determine their adhesive properties (adhesion, cohesion, and adhesion) and functional properties (pot life of the composition, shrinkage, and thermal properties of adhesives). Novel materials exhibited high thermal resistance above 225 °C while maintaining or slightly reducing other values (adhesion, cohesion, shrinkage, and tack). Selected composition: T 0.1 was used to prepare self-adhesives in industrial-scale production. Moreover, conducted test results revealed that the addition of talc delayed the thermal decomposition of the adhesive and provided reduced intensity of smoke emissions during combustion as well as the flammability of the adhesive layer. Full article

This publication describes the influence of residue monomers in synthesized pressure-sensitive adhesives based on acrylics on their main properties—tack, peel adhesion, shear strength and shrinkage—in the form of transfer tapes used for joining wooden elements in the furniture industry. The discussed carrier-free adhesive tapes are synthesized via photo-crosslinking and photopolymerization with UV radiation of the photoreactive prepolymers sandwiched between two adhesive siliconized polyester films. The simultaneous crosslinking and polymerization processes carried out under UV lamps placed simultaneously above and below the crosslinked photoreactive polymer layer lead to the production of a carrier-free adhesive film. The preliminary target of these studies was to investigate how the intensity of UV radiation and the time of its exposure affect the viscosity of the photoreactive compositions and the content of unreacted monomers in them. Next, the influence of the crosslinking agent concentration and UV irradiation time on the content of unreacted monomers after the crosslinking process was tested. The last step of the studies was the investigation of the influence of the residue monomer concentration on the application properties of the obtained pressure-sensitive adhesive layers. The typical PSA application properties were tested on the wood samples: tack, peel adhesion, shear strength (cohesion) and shrinkage. Full article

The incorporation of a naphthyl curing agent (NCA) can enhance the thermal stability of pressure-sensitive adhesives (PSAs). In this study, a PSA matrix was synthesized using a solution polymerization process and consisted of butyl acrylate, acrylic acid, and an ethyl acrylate within an acrylic copolymer. Benzoyl peroxide was used as an initiator during the synthesis. To facilitate the UV curing of the solvent-borne PSAs, glycidyl methacrylate was added to introduce unsaturated carbon double bonds. The resulting UV-curable acrylic PSA tapes exhibited longer holding times at high temperatures (150 °C) compared to uncross-linked PSA tapes, without leaving any residues on the substrate surface. The thermal stability of the PSA was further enhanced by adding more NCA and increasing the UV dosage. This may be attributed to the formation of cross-linking networks within the polymer matrix at higher doses. The researchers successfully balanced the adhesion performance and thermal stability by modifying the amount of NCA and UV radiation, despite the peel strength declining and the holding duration shortening. This research also investigated the effects of cross-linking density on gel content, molecular weight, glass transition temperature, and other properties of the PSAs. Full article

Removable pressure-sensitive adhesives (PSAs) are used in the production of self-adhesive materials such as protective films, masking tapes or biomedical electrodes. This work presents a new and environmentally friendly method of obtaining this type of adhesive materials, i.e., photochemically induced free radical telomerization. Adhesive binders to removable PSAs, i.e., the photoreactive acrylic telomer syrups (ATS) were prepared from n-butyl acrylate, acrylic acid, and 4-acrylooxybenzophenone. Tetrabromomethane (CBr₄) or bromotrichloromethane (CBrCl₃) were used as the telogens. ATS was modified with unsaturated polybutadiene resin and a radical photoinitiator. Adhesive compositions were coated onto a carrier and UV cross-linked. The effects of the chemical nature of telomers (i.e., terminal Br or Cl atoms) and their molecular weight (K-value), as well as the cross-linking degree on adhesive properties of PSAs, were studied. It was found that with the increase in telogen content in the system, the dynamic viscosity of ATS and K-value of acrylic telomers decrease, and the conversion of monomers increases. CBr₄ turned out to be a more effective chain transfer agent than CBrCl₃. Moreover, telomers with terminal Br-atoms (7.5 mmol of CBr₄), due to slightly lower molecular weights and viscosity, showed a higher photocrosslinking ability (which was confirmed by high cohesion results at 20 and 70 °C, i.e., >72 h). Generally, higher values of the temperature at which adhesive failure occurred were noted for PSAs based on ATS with lower telogen content (7.5 mmol), both CBr₄ and CBrCl₃. The excellent result for removable PSA was obtained in the case of telomer syrup Br-7.5 crosslinked with a 5 J/cm² dose of UV-radiation (adhesion ca.1.3 N/25 mm, and cohesion > 72 h). Full article

Silicones are commonly used as adhesives when high-quality materials are required due to harsh environmental conditions such as high temperature, humidity, etc. To ensure high resistance to environmental conditions, including high temperatures, modifications of silicone adhesives are made using fillers. The characteristics of a modified silicone-based pressure-sensitive adhesive with filler are the focus of this work. Functionalized palygorskite was prepared in this investigation by grafting 3-mercaptopropyltrimethoxysilane (MPTMS) onto palygorskite (palygorskite-MPTMS). The palygorskite was functionalized using MPTMS under dried conditions. FTIR/ATR spectroscopy, thermogravimetric analysis, and elemental analysis were all used to characterize the obtained palygorskite-MPTMS. MPTMS loading onto palygorskite was also proposed. The results demonstrated that palygorskite’s initial calcination favors the grafting of functional groups on its surface. New self-adhesive tapes based on palygorskite-modified silicone resins have been obtained. This functionalized filler allows for the improvement of the compatibility of palygorskite with specific resins for application in heat-resistant silicone pressure-sensitive adhesives. The new self-adhesive materials showed increased thermal resistance while maintaining good self-adhesive properties. Full article

The preparation of a new “eternally alive adhesive” based on silicone pressure-sensitive adhesives with clinoptilolite is presented. Neat and acid-modified (i.e., treated with sulfuric acid (VI)) clinoptilolite was used. The effect of clinoptilolite acid treatment on the adhesive properties of pressure-sensitive adhesive tapes was tested. The obtained tapes exhibited increased thermal resistance when compared to the reference tapes. Despite introducing the filler, the pressure-sensitive adhesive tapes maintained good functional properties. The new self-adhesive materials show promising implementation potential where increased thermal resistance is required. Full article

In the presented work, organophilized montmorillonites (OMMT) with selected quaternary ammonium compounds (QAC) with different chemical structure ((trioctylmethylammonium chloride—A336, dimethyloctadecyl[3-trimethoxysilyl)propyl]ammonium chloride—D, cetyltrimethylammonium bromide—CTAB, 2-methacryloxyethyltrimethylammonium chloride—MOA) were obtained and used as fillers for physically modified silicone pressure-sensitive adhesives (Si-PSA). Before OMMT addition into Si-PSA matrix, they were analyzed via TGA and XRD techniques. Type of chemical structure of QAC affected d-spacing of OMMT. New self-adhesive materials were obtained based on prepared Si-PSA compositions by adding the obtained fillers to the polymer matrix. New tapes exhibit a good level of useful properties as adhesion, cohesion, and tack—the values did not change or slightly decreased; in addition, the tapes with addition of OMMT showed high thermal resistance reaching the measuring limit of the test equipment—to 225 °C. Full article

This research was carried on newly obtained innovative materials—self-adhesive one-sided tapes based on silicone pressure-sensitive adhesives. In order to obtain tapes, the stable adhesive composition was subjected to physical modification by incorporating into it various amounts of selected silicon fillers. The produced pressure-sensitive adhesives were tested for viscosity and thermogravimetric analysis, as well as the manufactured tapes; i.e., peel adhesion, tack, cohesion at room and elevated temperature, SAFT test (shear adhesive failure temperature), and shrinkage. The prepared self-adhesive tapes retained their self-adhesive properties at a level close to the initial level while increasing the thermal resistance by 70–75 °C, reaching the level of 220–225 °C. The new self-adhesive materials have application potential and can be used as a material for special applications in the field of electrical engineering and heavy industry. Full article

Research was carried out on the influence of various silicone compounds on the properties of pressure-sensitive adhesives. Silicone-based pressure-sensitive adhesives have good self-adhesive properties and are used in many different industries. However, their thermal resistance is relatively low. In order to improve this property, modifications were made to these adhesives. Compositions were tested, such as viscosity or thermogravimetric analysis, as well as tests of finished products in the form of self-adhesive tapes, i.e., peel adhesion, tack, cohesion at room and elevated temperature, SAFT test (Shear Adhesive Failure Temperature), pot-live (viscosity) and shrinkage. During the tests, an increase in thermal resistance (225 °C), lower shrinkage (0.08%), and lower viscosity was achieved (16.5 Pas), which is a positive phenomenon in the technology of pressure-sensitive adhesives. Thanks to this research, the properties of silicone self-adhesive adhesives have been significantly improved. Full article

Medical adhesives are used to secure wound care dressings and other critical devices to the skin. Without means of safe removal, these stronger adhesives are difficult to painlessly remove from the skin and may cause medical-adhesive-related skin injuries (MARSI), including skin tears and an increased risk of infection. Lower-adhesion medical tapes may be applied to avoid MARSI, leading to device dislodgement and further medical complications. This paper outlines the development of a high-adhesion medical tape designed for low skin trauma upon release. By warming the skin-attached tape for 10–30 s, a significant loss in adhesion was achieved. A C14/C18 copolymer was developed and combined with a selected pressure-sensitive adhesive (PSA) material. The addition of 1% C14/C18 copolymer yielded the largest temperature-responsive drop in surface adhesion. The adhesive film was characterized using AFM, and distinct nanodomains were identified on the exterior surface of the PSA. Our optimized formulation yielded 67% drop in adhesion when warmed to 45 °C, perhaps due to melting nanodomains weakening the adhesive–substrate boundary layer. Pilot clinical testing resulted in a significant decrease in pain when a heat pack was used for removal, giving an average pain reduction of 66%. Full article

In this article, a novel form of thermal interface material (TIM), represented by three industrially manufactured pressure-sensitive adhesive (PSA) tapes with electrical insulating properties, is characterized regarding its applicability in an electric motor with air-gap winding. Firstly, the adhesion performances, in terms of the winding process, were investigated experimentally. Here, every TIM shows sufficient shear strength for the wire–TIM joints, as well as peel adhesion to the laminated iron core. Secondly, the thermal–physical properties of the TIMs are inspected experimentally via laser flash analysis (LFA) and differential scanning calorimetry (DSC). For every TIM, the value of the thermal resistance can double if the relatively smooth surface (R_a = 0.2 μm) of the adjacent layers is interchanged with a rougher one (R_a = 2.0–3.7 μm). Additionally, the TIM’s performance at the system level is examined. Therefore, a flat test section, according to the specifications of the original motor, is studied experimentally and numerically utilizing infrared (IR) thermography and the finite element method (FEM). The focus is set on the heat flow and temperature distribution in the test section under varying thermal loads, mass flow, and variety of TIMs. Full article