Search Results (42)

The interlayer oxidation zone-type Mengqiguer uranium deposit in the southern Yili Basin is a typical sandstone-hosted uranium deposit in northwest China, and the lower member of the Jurassic Xishanyao Formation is its main ore-hosting stratum. However, mineralogical and geochemical responses to redox evolution in the deposit have not been systematically constrained. In this study, we carried out detailed petrographic observation, X-ray diffraction analysis, electron probe microanalysis, and whole-rock geochemical analyses on samples from the interlayer oxidation zone in the lower member of the Xishanyao Formation. Kaolinite and illite are the dominant clay minerals in the deposit, with higher contents in oxidation zones than in transition and unaltered zones, while the illite–smectite mixed-layer content shows the opposite trend. The main uranium minerals are uranium oxides and coffinite. U, S and organic carbon are enriched in the transition zone, while the Fe³⁺/Fe²⁺ ratio increases with the oxidation degree. Comprehensive analysis on clay minerals shows that the ore-forming fluids evolved from acidic oxidized meteoric fluids to weakly alkaline reduced fluids; the uranium was mainly derived from the leaching of uraniferous sandstone. The formation of the deposit is controlled by sedimentary facies, tectonic uplift, organic–inorganic fluid interaction and redox reaction. This study provides detailed mineralogical and geochemical evidence for the metallogenic mechanism of interlayer oxidation zone-type uranium deposits, and has important guiding significance for uranium prospecting in the Yili Basin. Full article

This paper presents a comparative determination of rare earth elements (REEs) in sandstone-type uranium ore samples from Kazakhstan using a proposed rapid ICP-MS method following microwave digestion in a MARS 6 system with a mixed acid solution of HNO₃, HCl, and HF. To validate the rapid REE determination method, comparative measurements were performed using a certified uranium ore reference material provided by Ore Research & Exploration, representing sandstone-hosted uranium mineralization from a Tanzanian deposit (OREAS 120). Fractionation patterns of chondrite-normalized REEs in uranium ores from Kazakhstan were evaluated. Comparative data on REE distribution in sandstone- and magmatic-type uranium deposits from Australia and Tanzania are presented. Uranium ores of magmatic- and sandstone-hosted types exhibit distinct REE distribution patterns, reflecting differences in the nature of ore-forming processes. This study provides chondrite-normalized REE distribution profiles for major uranium deposit types from three countries, which are subsequently used to assess uranium ore paragenesis through simple linear regression analysis. This study is intended as an applied comparative synthesis of REE fractionation patterns in genetically contrasting uranium deposits, with particular relevance to deposit classification. Full article

Tamusu, the only identified super-large sandstone-hosted uranium deposit in the Bayingobi Basin, provides an important natural laboratory for evaluating ore-controlling factors and genetic models of sandstone-type uranium mineralization. Based on core descriptions from more than 200 boreholes, log facies analysis and geochemical environmental proxies, this study constrains the sedimentary–mineralization architecture and key controlling factors of the deposit. Uranium orebodies are mainly hosted in the upper member of the Lower Cretaceous Bayingobi Formation (Sq2) within a gravity flow-dominated fan-delta–lacustrine system. Braided distributary channel sands on the fan-delta plain and subaqueous distributary channel sands on the delta front constitute the principal uranium reservoirs, controlling both the migration pathways and storage space for U-bearing fluids. Mineralization is jointly governed by fan-delta architecture, interlayer oxidation zonation and reducing agents. The interlayer oxidation zone displays a north-thick–south-thin geometry, and uranium orebodies are concentrated at redox transition positions, with grades of 0.01–0.33 wt%. The metallogenic evolution can be summarized in three stages: syndepositional uranium pre-enrichment, interlayer oxidation mineralization, and a late hydrothermal/diagenetic overprint that mainly modified reservoir properties, favored ore preservation, and did not contribute to the primary uranium budget. Accordingly, a genetic model of “fan-delta architecture + interlayer oxidation control + late overprint and preservation” is proposed to guide exploration in the Bayingobi Basin and analogous sandstone-type uranium systems. Full article

The Yaojia Formation in the northeastern Songliao Basin is a primary target horizon for sandstone-type uranium mineralization in the area. Understanding its provenance, composition, and depositional paleoclimate is of great significance for uranium exploration in the region. This study analyzed 58 sandstone and mudstone samples using petrographic thin-section observation, elemental geochemistry, and detrital zircon U-Pb geochronology. The results show that Yaojia Formation sandstones are feldspathic lithic quartzose sandstone (averaging 47% lithics, 32% quartz, and 21% feldspar, mainly K-feldspar), with moderate sorting and predominantly angular to subangular grains, indicating rapid denudation in the source area, medium- to short-distance transport, and rapid deposition. The chemical weathering index (CIA, 52–68) and the index of compositional variation (ICV, 0.83~1.26) are generally low, indicating moderate chemical weathering. Rb/Sr, Sr/Cu, Al₂O₃/MgO, CIA, MgO/CaO ratios indicate that the Yaojia Formation was deposited under predominantly arid–semiarid conditions, with later stages being wetter than earlier ones. Rare earth element (REE) characteristics indicate light REE enrichment, heavy REE depletion, and significant negative Eu anomalies. Combined with A-CN-K diagrams and discriminant plots such as La/Th-Hf and Co/Th-La/Sc, the provenance is primarily derived from felsic magmatic rocks in a post-orogenic extensional tectonic setting. Detrital zircon U-Pb ages are mainly concentrated at 119–153 Ma (64%), 160–183 Ma (14%), and 318.3–327.7 Ma (6%), showing the highest similarity to zircon age spectra from magmatic rocks in the Great Xing’an Range. The comprehensive results indicate that the clastic rocks of the Yaojia Formation in the study area were mainly sourced from Early Cretaceous felsic magmatic rocks in the Great Xing’an Range and have undergone short- to medium-distance transport and sedimentation under arid to semi-arid paleoclimatic conditions. Full article

The northern part of the Naomugeng Sag in the Erlian Basin shows favorable sandstone-type uranium mineralization in the lower member of the Saihan Formation. The sandstone thickness ranges from 39.67 to 140.36 m, with an average sand content ratio of 76.33%, indicating broad prospecting potential. This study focuses on samples from uranium ore holes and uranium-mineralized holes in the area, conducting grain-size analysis of uranium-bearing sandstones, heavy mineral assemblage analysis, and detrital zircon U-Pb dating to systematically investigate provenance characteristics. The results indicate that the uranium-bearing sandstones in the lower member of the Saihan Formation were primarily transported by rolling and suspension, characteristic of braided river channel deposits. The heavy mineral assemblage is dominated by zircon + limonite + garnet + ilmenite, suggesting that the sedimentary provenance is mainly composed of intermediate-acid magmatic rocks with minor metamorphic components. Detrital zircon U-Pb ages are mainly concentrated in the ranges of 294–217 Ma (Early Permian to Late Triassic), 146–112 Ma (Middle Jurassic to Early Cretaceous), 434–304 Ma (Late Carboniferous to Early Permian), and 495–445 Ma (Middle–Late Ordovician to Early Silurian). Combined with comparisons of the ages of surrounding rock masses, the provenance of the uranium-bearing sandstones is mainly derived from intermediate-acid granites of the Early Permian–Late Triassic and Middle Jurassic–Early Cretaceous periods in the southern part of the Sonid Uplift, with minor contributions from metamorphic and volcanic rock fragments. The average zircon uranium content is 520.53 ppm, with a Th/U ratio of 0.73, indicating that the provenance not only supplied detrital materials but also provided uranium-rich rock bodies that contributed essential metallogenic materials for uranium mineralization. This study offers critical insights for regional prospecting and exploration deployment. Full article

Sandstone-hosted uranium deposits represent one of the most critical global uranium resources suitable for in situ recovery, with their formation closely associated with organic matter (OM). We conducted a systematic literature review to synthesize over 100 published studies sourced from authoritative databases (Elsevier, Google Scholar, Web of Science, Scopus, CNKI, etc.). This study systematically summarizes the types and geological characteristics of OM in sandstone reservoirs and thoroughly analyzes the geochemical mechanisms by which OM regulates the transport and precipitation of aqueous uranium. By integrating case studies of representative sandstone uranium deposits globally, three major OM-related metallogenic models are proposed with distinct core characteristics: the humic-dominated model is driven by the complexation and direct reduction of uranium by humic substances/coal-derived OM; the roll-front model relies on reactions between oxidized uranium-bearing fluids and scattered OM, as well as microbially generated sulfides at the migration front; and the seepage-related model is fueled by upward-migrating deep hydrocarbon fluids (petroleum, methane) that act as both uranium carriers and reductants. Furthermore, this review explores the spatial coupling relationships between OM distribution and uranium mineralization in typical geological settings, evaluates the guiding significance of OM for uranium exploration, and outlines key unresolved scientific issues. The findings refine the genetic theoretical framework of sandstone-hosted uranium deposits and provide important technical support and theoretical guidance for future uranium exploration deployment and resource potential evaluation. Full article

A large-scale sandstone-type uranium deposit, recently discovered within the petroleum field of the Jingchuan area on the southwestern margin of the Ordos Basin, exemplifies a classic case of uranium exploration success achieved through the analysis of petroleum geological data including borehole logs. By synthesizing borehole radioactive logs and seismic surveys, we delineated target sandstone geometry, connectivity, and ore-controlling structures (e.g., paleochannels, redox interfaces). This study establishes a novel methodology for sandstone-type uranium exploration in petroliferous basins, unifying geophysical and geochemical datasets to define drill-validated targets. We integrated detailed core logging, petrography, and assay data to delineate the deposit’s geology. This included the host strata composition, ore-body morphology, mineralogy, and alteration assemblages. Our analysis identified the critical controls on mineralization: sandbody architecture, structural framework, and redox zonation. Based on these constraints, we constructed a genetic metallogenic model. Furthermore, we elucidated the mechanistic role of hydrocarbons in uranium mineralization and demonstrated the strategic potential of repurposing legacy oilfield data for synergistic uranium targeting. The Jingchuan uranium deposit provides both an exploration blueprint and theoretical foundations for uranium targeting in analogous sedimentary basins. Full article

The Erlian Basin, an important research area for sandstone-type uranium deposit exploration in China, is affected by overburden layers, resulting in indistinct characteristics of uranium anomalies in airborne gamma-ray spectrometry (AGS). To harness the potential of AGS, it is imperative to develop effective verification methods that can identify the spatial relationship between weak uranium anomalies and deep uranium-rich geological bodies. This study presents a comprehensive investigation of geophysical and geochemical measurements conducted in four distinct areas. There is a significant positive correlation between the ground gamma spectrometry equivalent uranium (eU_GGS) content, soil radon concentration (C_Rn), geoelectrochemical uranium (U_GEC), and metal activity state uranium (U_MAS) content directly above and at the edges of uranium-rich geological bodies. When the buried depth of the uranium-rich geological body exceeds 100 m, the eU_GGS content above these deep uranium bodies increases by (0.4–1.2) × 10⁻⁶ g/g compared to background areas, while the C_Rn levels at the edges of these bodies increase by more than 5000 Bq/m³, which is 3–5 times higher than the regional average. Meanwhile, the U_GEC and U_MAS contents show sawtooth-like uranium peak anomalies on their profiles, and their peak-to-background ratio is greater than 5. The verification methods and corresponding interpretation indicators, namely GGS, C_Rn, GEC and MAS measurements, can quickly reveal the spatial relationship and provide a reliable basis for concealed uranium deposit exploration. Full article

The characteristics of interlayer oxidation zones constrain sandstone-type uranium mineralization. This study conducted a quantitative characterization of the interlayer oxidation zones in the uranium-bearing reservoir of the Saihan Formation in the central Wulanchabu Subbasin of the Erlian Basin through sand dispersion system mapping, the analysis of sedimentary debris components, environmentally sensitive parameters, and elemental geochemical characteristics. The formation mechanisms and controlling factors of interlayer oxidation zones were investigated, along with uranium mineralization patterns. Research findings reveal that the sandbodies in the study area primarily consist of red sandstone, yellow sandstone, gray ore-bearing sandstone, and primary gray sandstone, representing strong oxidation zones, weak oxidation zones, transitional zones, and reduction zones, respectively. Although the mineral debris content shows minimal variation among different zones, feldspar dissolution is more prevalent in oxidized zones. During interlayer oxidation, environmentally sensitive parameters exhibit an ascending trend from strong oxidation zones through weak oxidation zones and reduction zones to mineralized transitional zones. Four transition metal elements (Co, Ni, Zn, and Mo) demonstrate enrichment in mineralized transitional zones. The development of interlayer oxidation zones is directly controlled by reservoir heterogeneity and sedimentary environments. Oxidation subzones primarily occur in sandbodies with moderate thickness (40–80 m), sand content ratios of 40%–80%, and 2–10 or 10–18 mudstone barriers (approximately 20 m thick), mainly in braided river channels and channel margin deposits. Reduction zones develop in thicker sandbodies (~100 m) with higher sand contents (~80%), fewer mudstone barriers (2–8 layers), greater thickness (40–80 m), and predominantly channel margin deposits. Transitional zones mainly occur in braided distributary channels and floodplain deposits. When oxygen-bearing uranium fluids infiltrate reservoirs, oxygen reacts with reductants like organic matter, whereFe²⁺ oxidizes to Fe³⁺, S²⁻ reacts with oxygen, and U⁴⁺ oxidizes to U⁶⁺, migrating as uranyl complexes. As oxygen depletes, Fe³⁺ reduces to Fe²⁺, combining with S²⁻ to form pyrite between mineral grains. Uranyl complexes reduce to precipitate as pitchblende, while some U⁴⁺ reacts with SiO₄⁴⁻, forming coffinite, occurring as colloids around quartz debris or pyrite. The concurrent enrichment of certain transition metal elements occurs during this process. Full article

The drilling core sampling and chemical analysis method for the quantitative determination of solid mineral deposits has several drawbacks, including a low core drilling efficiency, a high core sampling cost, and a long chemical analysis cycle. In current uranium quantification practices, advanced techniques have been developed to preliminarily determine the formation of uranium content based on the interpretation results of natural $\gamma$-ray total logging. However, such methods still require supplementary core chemical analysis to derive the uranium–radium–radon balance coefficient, which is then used for equilibrium correction to obtain the true uranium content within the uranium-bearing layer. Furthermore, conventional prompt neutron time spectrum logging is constrained by low count rates, resulting in slow logging speeds that fail to meet the demands of practical engineering applications. To address this, this study proposes a uranium quantification method that corrects the natural $\gamma$-ray total logging using prompt neutron time spectrum logging. Additionally, a calibration parameter determination method necessary for quantitative interpretation is constructed. Experimental results from standardized model wells indicate that, in sandstone-type uranium deposits, the absolute error of uranium content is within $\pm 0.002\%\mathrm{eU}$, and the relative error is within $\pm 2.5\%$. These findings validate the feasibility of deriving the uranium–radium–radon balance coefficient without relying on core chemical analysis. Compared with the prompt neutron time spectrum logging method, the proposed approach significantly improves the logging speed while producing results that are essentially consistent with those of natural $\gamma$-ray total logging. It provides an efficient and accurate solution for uranium quantitative interpretation. Full article

A combination of microstructural, fluid inclusion, and in situ sulfur isotopic analyses of pyrite, along with major and trace element studies of the mineralization-hosting sandstone, reveals the complexity of its genesis from the Jurassic Toutunhe Formation in the Liuhuanggou sandstone-hosted uranium deposit, Southern Junggar Basin. Based on field geological investigations and the geochemical characteristics, it is concluded that the source of the ore-bearing sandstones originates from felsic igneous rocks in the Northern Tianshan and Central Tianshan regions. Through optical microscopy and scanning electron microscopy (SEM), three generations of pyrite were identified: framboidal pyrite, concentric overgrown pyrite, and sub-idiomorphic to idiomorphic cement pyrite. The sulfur isotopes of the pyrite were analyzed using laser ablation multi-collector inductively coupled plasma mass spectrometry (LA-MC-ICP-MS). The results indicate that each type of pyrite has distinct sulfur isotope compositions (the framboidal pyrite: −16.85‰ to +2.16‰, the concentric overgrown pyrite: −7.86‰ to +10.32‰, the sub-idiomorphic to idiomorphic cement pyrite: +9.16‰ to +16.77‰). The framboidal pyrite and the sub-idiomorphic to idiomorphic cement pyrite were formed through bacterial sulfate reduction (BSR), while the concentric overgrown pyrite was formed through thermochemical sulfate reduction (TSR) triggered by the upward migration of hydrocarbons. The discovery of hydrocarbon inclusions provides evidence for the involvement of deep-seated reducing fluids in uranium mineralization. Uranium mineralization occurred in two distinct stages: (1) The early stage involved the interaction of uranium-bearing fluids with reductants in the mineralization-hosting strata under the influence of groundwater dynamics, leading to initial uranium enrichment. (2) The later stage involved the upward migration of deep-seated hydrocarbons along faults, which enhanced the reducing capacity of the sandstone and resulted in further uranium enrichment and mineralization. Full article

This study focuses on the Hailijing sandstone-hosted uranium deposit in the Songliao Basin. Through a combination of petrographic analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), and geochemical analysis, the epigenetic alteration of the deposit was systematically investigated, and the alteration zonation was delineated. On this basis, the metallogenic mechanisms were further explored. The results indicate that six major types of alteration can be identified in the ore-bearing strata of the Hailijing uranium deposit: hematitization, limonitization, carbonatization, pyritization, clay mineralization (including kaolinite, illite, and illite-smectite mixed-layer), and baritization. The mineral assemblages at different stages of alteration vary: during the sedimentary diagenetic stage, the assemblage consists of “hematite + clay minerals + II-type pyrite (framboidal pyrite) + III-type pyrite (euhedral granular pyrite)”; during the uranium mineralization stage, it transitions to “ankerite + barite + I-type pyrite (colloidal pyrite) + minor kaolinite”; and in the post-ore stage, alteration is characterized by calcite cementation in red sandstones. Based on petrological, mineralogical, and geochemical characteristics, as well as the spatial distribution of the host gray sandstones, it is inferred that during uranium mineralization stage, the ore-bearing strata underwent reduction by uranium-rich reducing fluids sourced from the Lower Cretaceous Jiufotang Formation. The primary red sandstones of the Lower Yaojia Formation, formed under arid to semi-arid conditions, experienced varying degrees of reduction, resulting in a color transition from light red, brownish red, and yellowish brown to grayish-yellow and gray. Accordingly, four alteration zones are distinguished in the Hailijing uranium deposit: the primary red zone, weakly reduced pink zone, moderately reduced grayish-yellow zone, and strongly reduced gray zone. Furthermore, as the uranium-rich reducing fluids migrated from a high-temperature, high-pressure deep system to the low-temperature, low-pressure ore-bearing sandstone strata near the surface, uranium was unloaded, precipitated, and enriched, ultimately forming multi-layered and tabular-shaped uranium orebodies within the gray sandstone. This study elucidates the epigenetic alteration processes and metallogenic mechanisms of the Hailijing uranium deposit, providing a critical theoretical basis for further uranium exploration in the southern Songliao Basin. Full article

The Luhai uranium deposit is a large-scale uranium deposit newly discovered in recent years through comprehensive prospecting methods. It is located in the Basaiqi Paleochannel Uranium metallogenic belt of the Erlian Basin and is characterized by its shallow burial and large scale. This paper provides new data on the genetic processes of sandstone-type uranium mineralization through sedimentological and geochemical environmental indicators (such as Fe³⁺/Fe²⁺, organic carbon, total sulfur, etc.), analysis of C-O isotopes of carbonate cements and H-O isotopes of groundwater, and geochemical and mineralogical studies of uranium minerals, iron–titanium oxides (involving backscatter analysis, micro-area chemical composition determination, and elemental surface scanning), and organic matter. Sedimentological analysis shows that the ore- bearing layer in the upper member of the Saihan Formation developed a braided channel within floodplain subfacies, which control the distribution of uranium ore bodies. Uranium mineralogical observations, geochemical environmental indicators, and organic geochemical data indicate that the main reducing agents related to mineralization are pyrite, terrestrial plants, and deep-sourced oil and gas. The δD values of groundwater in the ore-bearing layer range from −95.34‰ to −90.68‰, and the δ¹⁸O values range from −12.24‰ to −11.87‰. For calcite cements, the δ¹⁸O_V-PDB values range from −24‰ to −11.5‰, and the δ¹⁸_OV-SMOW values range from 6.2‰ to 19‰. It was determined that the ore-forming fluid is mainly surface fresh water that entered the strata during the tectonic uplift stage, with local mixing of deep-sourced brine. Based on these data, the main modes of uranium mineralization in the paleochannel were obtained as follows: (1) Redox mineralization occurs due to the reducing medium within the sand body itself and the reduction caused by deep- sourced oil and gas generated from the Tengge’er and Arshan Formations. (2) Mineralization is achieved through the mixing of fluids from different sources. Furthermore, a genetic model related to uranium mineralization in the paleochannels of the Luhai area has been established: favorable uranium reservoirs were formed during the sedimentary period, and during the post-sedimentary stage, reverse structures promoted redox reactions and fluid-mixing-induced mineralization. The research findings can provide guidance for the exploration of paleochannel sandstone-type uranium deposits in other areas of the Erlian Basin. Full article

The study of pore structure in low-permeability sandstone uranium deposits has become a key factor in the profitability of uranium mining. In this paper, pore and fracture distribution in the target sandstone were determined by using mercury injection parameters. Single and multi-fractal models are used to calculate the heterogeneity of pore and fracture volume distribution. Moreover, the correlation between compressibility and the heterogeneity of pore distribution has been studied. The results are as follows. (1) All the samples can be divided into three types by using maximum mercury injection volume and mercury withdrawal efficiency. Type A is represented by a lower maximum mercury injection volume (less than 0.5 cm³·g⁻¹) and a higher mercury withdrawal efficiency (larger than 25%). The volume percentage of pores whose diameter is less than 100 nm and 100~1000 nm in type A samples is larger than that of type B and C samples since in this type of sample, micropores are developed. (2) The fractal dimension value assessed using the Menger model has a good linear relationship with the thermodynamic model, which indicates that the abovementioned models have good consistency in characterizing the pore distribution of tight sandstone. Multi-fractal results show that the lower pore volume in the selected samples controls the heterogeneity of pore distribution in the overall sample. (3) As the effective stress increases, the permeability damage rate gradually increases in a power exponential equation. The correlation between porosity and compressibility is weaker, indicating that only a portion of the pore volume in the sample provides compression space. As the pore volume of 100~1000 nm increases, the compressibility decreases linearly, indicating that pore volumes larger than 1000 nm provide compression space for all the selected samples. Full article

Sandstone-type uranium deposits hold significant value and promise within China’s uranium resource portfolio, with the majority of these deposits found at the junctions of basins and mountains within Mesozoic and Cenozoic basins. The Kamust uranium mining area, located in the eastern part of the Junggar Basin, represents a significant recent discovery. Prior research on this deposit has been confined to two-dimensional analyses, which pose limitations for a comprehensive understanding of the deposit’s three-dimensional characteristics. To address the issue of uranium resource reserve expansion, this study employs 3D geological modeling and visualization techniques, guided by uranium deposit models and mineral prediction methods. First, a 3D model database of the Kamust uranium deposit was constructed, comprising drill holes, uranium ore bodies, ore-controlling structures, interlayer oxidation zones, and provenance areas. This model enables a transparent and visual representation of the spatial distribution of favorable mineralization horizons, structures, stratigraphy, and other predictive elements in the mining area. Second, based on the three-dimensional geological model, a mineral prediction model was established by summarizing the regional mineralization mechanisms, ore-controlling factors, and exploration indicators. Combined with big-data technology, this approach facilitated the quantitative analysis and extraction of ore-controlling factors, providing data support for the three-dimensional quantitative prediction of deep mineralization in the Kamust uranium deposit. Finally, using three-dimensional weights of evidence and three-dimensional information-quantity methods, comprehensive information analysis and quantitative prediction of deep mineralization were conducted. One prospective area was quantitatively delineated, located east of the Kalasay monocline, which has been well-validated in geological understanding. The research indicates that the area east of the Kalasay monocline in the Kamust mining district has significant exploration potential. Full article