Search Results (411)

Natural sand extraction for concrete manufacturing is a global issue for ecological balance and environmental concerns. This study introduced three mixes with three newly developed sand types to replace natural sand in concrete manufacturing. Additionally, three more mixes were made by incorporating optimized 10% silica fume. The durability of the prepared mixes was evaluated at high temperatures of (150–750 °C) at the interval of 150 °C and against immersion in a 5% sulfuric acid solution for 28, 56, 91, and 182 days, respectively. The study’s results reported the stability of the samples up to 300 °C, and then the fall of the samples started at 450 °C. Severe damage in the samples was formed at about 600 °C, and finally, a total collapse was seen at 750 °C. From (150 to 750 °C), the mix TYPE-3SSFC with a sustainable sand combination (50% recycled sand + 45% desert sand + 5% crumb rubber) and 10% silica fume showed better resistance than the other mixes. The compressive strength in the mix TYPE-3SSFC was 20.6%, 16.3%, 14.7%, 21.3%, 26.5%, and 43.2% higher than the mix TYPE-3SC with 10% silica fume. The mix TYPE-3SSFC with optimized 10% silica fume content showed better resistance against 5% sulfuric acid solution than those without silica fume. By morphological analysis, the mix TYPE-3SSFC showed that the interface improved due to the dense interconnectivity of the concrete mix between the crumb rubber paste and silica fume content. A dense calcite crystal was also seen in the mixture, which confirmed the study’s results. The mix with TYPE 2-Sand (100% recycled sand) revealed inferior results, low stability, and high damage. Thus, 100% recycled sand is not recommended for structural concrete. Full article

This study investigates the use of preliminary thermochemical activation in a NaHCO₃ solution under elevated pressure and temperature to modify the chemically stable and hard-to-process phase composition of various mineral raw materials and improve the recovery of valuable components. The method was tested on various types of mineral raw materials, including slag from the reductive smelting of red mud from alumina production prior to acid leaching, ash before chemical beneficiation, gibbsite–kaolinite bauxite prior to gravity separation, and nephelines, for which the sintering process was replaced with chemical beneficiation. The slag from the reductive smelting of red mud was also tested before acid leaching. The activation of slag enhanced tricalcium silicate formation lead to leaching recoveries of ~96% for rare earth elements, ~92% for TiO₂, ~98% for CaO and Al₂O₃, and 50% for Fe₂O₃, compared to much lower values without activation. With ash, activation eliminated the sillimanite and hedenbergite phases, increased mullite and free silica, and formed calcite, resulting in a 15–20% higher silica recovery. With gibbsite–kaolinite bauxite, activation altered kaolinite, siderite, quartz, and hematite contents; eliminated calcium silicate; and improved the silicon modulus of the sand fraction by 35.9% during gravity beneficiation. For nepheline ore, activation promoted the formation of albite and hydrosodalite, eliminated corundum and andradite, and increased silica recovery from 33.58% to 59.6%. These results demonstrate that thermochemical activation effectively transforms mineral structures and significantly improves the efficiency of subsequent beneficiation processes. Full article

High-performance geopolymer concrete (HPGC) is an eco-friendly type of concrete that is traditionally made of slag, silica fume (SF), and quartz sand. Recycling industrial waste in HPGC presents an eco-friendly approach for maximizing sustainability in the construction sector. This study evaluates the impact of incorporating recycled fine aggregates like crumb rubber (CR), glass waste (GW), and ceramic waste (CW) as partial replacements for quartz sand in HPGC at 10%, 20%, and 40% by volume. GW and CW were also used in binder size as full replacements for SF. The novelty of this research lies in its comprehensive evaluation of waste-integrated HPGC under diverse conditions, including mechanical performance, durability (water absorption, sulfate/chloride/acid resistance), thermal stability (up to 600 °C), and microstructure analysis, while addressing critical gaps in eco-friendly construction materials. The results indicate that CW significantly enhanced compressive strength, increasing by 24–29% at 10% and 40% replacement levels, whereas CR reduced strength by 69.2–83.5%. GW effectively decreases water absorption by 66–72% compared to CW and CR. Both CW and GW improved chemical resistance, reducing compressive strength loss by 15–33% under sulfate and acid attacks. CW exhibited superior residual strength at 600 °C, reaching 96.4 MPa, compared to 54.5 MPa for GW. However, fully replacing SF with GW or CW as a binder resulted in performance deterioration, making it unsuitable. This study demonstrates that incorporating recycled waste materials in HPGC enhances its mechanical and durability properties, making it a viable option for sustainable construction. The findings support the integration of CW and GW as eco-friendly alternatives in HPGC applications. Full article

Nano-silica (NS) is used to enhance the mechanical and durability properties of cementitious materials; however, its frequent tendency to agglomerate limits its effectiveness and uniform distribution within the cement matrix. The main goal of this study was to improve NS dispersion and therefore to improve the properties of the concrete by coating NS onto standard sand particles (sand@NS) using the Stöber method, creating a composite material that acts as a filler, nucleation site, and highly reactive pozzolanic agent. The resulting sand@NS was incorporated into cement mixtures, and its compressive strength was measured after 3, 7, and 28 days of curing. In addition, water absorption and microstructural density were also evaluated. Comparative results showed that sand@NS significantly enhanced early-age hydration and initial strength, with a 145% increase in compressive strength at 28 days compared to the reference, whereas free NS resulted in a 120% increase. The early-age strength improvement was mainly due to the increased number of nucleation centers, while later strength gains were attributed to pozzolanic activity of the immobilized NS. Additionally, sand@NS reduced water absorption and increased microstructural density, even with reduced cement content, supporting more sustainable and eco-efficient concrete production. This work shows a promising, scalable, and cost-effective strategy to maximize the performance of NS in cementitious systems and supports its broader adoption in advanced construction materials. Full article

To address the challenges of low permeability, high gas adsorption, and a fragile structure in coalbed methane reservoirs, this study developed a high-strength composite proppant with an activated carbon skeleton via nitric acid pretreatment, silica–alumina sol coating, and calcination. Orthogonal experiments optimized the preparation conditions: 30–40 mesh activated carbon, Si/Al molar ratio of 4:1, calcination at 650 °C for 2 h. The resulting proppant exhibited an excellent performance: a single-particle compressive strength of 55.5 N, porosity of 33.2%, crushing rate of only 2.3% under 50 MPa closure pressure, and permeability 48.5% higher than quartz sand. In simulated acidic coalbed environments (pH 3–5), its acid corrosion rate was <2.8%, and it enhanced methane desorption by 16.2% compared to pure coal. Additionally, the proppant showed a superior transport performance in fracturing fluids, with better distribution uniformity in fractures than ceramsite, and its hydrophobic surface (contact angle 115.32°) improved fracturing fluid flowback efficiency. This proppant integrates high strength, good conductivity, gas desorption promotion, and corrosion resistance, offering a novel material solution for efficient coalbed methane extraction. Full article

Soil–structure contacts often govern deformation and stability in foundations and buried infrastructure. Rubber waste is used in soil mixtures to enhance geotechnical performance and promote environmental sustainability. This study investigates the peak and residual shear strength of sand–steel interfaces, where the sand is mixed with recycled rubber. It also develops predictive machine learning (ML) models based on the experimental data. Two silica sands, medium and coarse, were mixed with two rubber gradations; however, Rubber B was included only in limited comparative tests at a fixed content. Ring-shear tests were performed against smooth and rough steel plates under normal stresses of 25 to 200 kPa to capture the full τ–δ response. Nine input variables were considered: median particle size (D₅₀), regularity index (RI), porosity (n), coefficients of uniformity (C_u) and curvature (C_c), rubber content (RC), applied normal stress (σ_n), normalised roughness (R_n), and surface hardness (HD). These variables were used to train multiple linear regression (MLR) and random forest regression (RFR) models. The models were trained and validated on 96 experimental data points derived from ring-shear tests across varied material and loading conditions. The machine learning models facilitated the exploration of complex, non-linear relationships between the input variables and both peak and residual interfacial shear strength. Experimental findings demonstrated that particle size compatibility, rubber content, and surface roughness significantly influence interface behaviour, with optimal conditions varying depending on the surface type. Moderate inclusion of rubber was found to enhance strength under certain conditions, while excessive content could lead to performance reduction. The MLR model demonstrated superior generalisation in predicting peak strength, whereas the RFR model yielded higher accuracy for residual strength. Feature importance analyses from both models identified the most influential parameters governing the shear response at the sand–steel interface. Full article

This study aims to investigate the mechanical behavior of cement mortar and concrete through a hybrid approach that integrates artificial intelligence (AI) techniques with finite element modeling (FEM). Support Vector Machine (SVM) models with Radial Basis Function (RBF) and polynomial kernels, along with Multilayer Perceptron (MLP) neural networks, were employed to predict the compressive strength (Fc) and flexural strength (Fs) of cement mortar incorporating nano-silica (NS) and micro-silica (MS). The dataset comprises 89 samples characterized by six input parameters: water-to-cement ratio (W/C), sand-to-cement ratio (S/C), nano-silica-to-cement ratio (NS/C), micro-silica-to-cement ratio (MS/C), and curing age. Simultaneously, the axial compressive behavior of C20-grade concrete was numerically simulated using the Concrete Damage Plasticity (CDP) model in ABAQUS, with stress–strain responses benchmarked against the analytical models proposed by Mander, Hognestad, and Kent–Park. Due to the inherent limitations of the finite element software, it was not possible to define material models incorporating NS and MS; therefore, the simulations were conducted using the mechanical properties of conventional concrete. The SVM-RBF model demonstrated the highest predictive accuracy with RMSE values of 0.163 (R² = 0.993) for Fs and 0.422 (R² = 0.999) for Fc, while the Mander model showed the best agreement with experimental results among the FEM approaches. The study demonstrates that both the SVM-RBF and CDP-based modeling approaches serve as robust and complementary tools for accurately predicting the mechanical performance of cementitious composites. Furthermore, this research addresses the limitations of conventional FEM in capturing the effects of NS and MS, as well as the existing gap in integrated AI-FEM frameworks for blended cement mortars. Full article

This study investigates sustainable mortars using lightweight synthetic sand (LSS), made from dune sand and recycled PET bottles, to replace natural sand (0–100% by volume). This aligns with circular economy principles by valorizing plastic waste into a construction aggregate. LSS is produced via controlled thermal treatment (250 ± 5 °C, 50–60 rpm), crushing, and sieving (≤3.15 mm), leading to a significantly improved interfacial transition zone (ITZ) with the cement matrix. The evaluation included physico-mechanical tests (density, strength, UPV, dynamic modulus, ductility), thermal properties (conductivity, diffusivity, heat capacity), porosity, sorptivity, alkali–silica reaction (ASR), and SEM. The results show LSS incorporation reduces mortar density (4–23% for 25–100% LSS), lowering material and logistical costs. While compressive strength decreases (35–70%), these mortars remain suitable for low-stress applications. Specifically, at ≤25% LSS, composites retain 80% of their strength, making them ideal for structural uses. LSS also enhances ductility and reduces dynamic modulus (18–69%), providing beneficial flexibility. UPV decreases (8–39%), indicating improved acoustic insulation. Thermal performance improves (4–18% conductivity reduction), suggesting insulation applicability. A progressive decrease in sorptivity (up to 46%) enhances durability. Crucially, the lack of ASR susceptibility reinforces long-term durability. This research significantly contributes to the repurposing of plastic waste into sustainable cement-based materials, advancing sustainable material management in the construction sector. Full article

The present study deals with hydrate formation with binary gaseous mixtures consisting of carbon dioxide mixed with ethane at varying concentrations. Since the production of hydrates is recognised as a stochastic process and also due to the marked influence that experimental apparatuses often have on the results, the continuous updating of the literature with new experimental data is needed. Hydrates were produced and dissociated in excess water and in unstirred conditions. The dissociation values were collected and tabulated. Each test was plotted and compared with the phase boundary equilibrium conditions of pure ethane and pure carbon dioxide hydrates. The results confirmed the lowering of pressures required for hydrate formation with the increase in ethane concentration in the gas mixture. In detail, the dissociation condition for CO₂/C₂H₆ hydrates was tested within the following thermodynamic ranges: 0.1–13 °C and 11.26–36.75 bar for the 25/75 vol% mixture, 0.1–13 °C and 9.74–35.07 bar for the 50/50 vol% mixture and 7.0–12.9 °C and 17.36–30.05 bar for the 75/25 vol% mixture. When 75 vol% ethane was used, the dissociation of hydrates occurred at conditions corresponding to the phase equilibrium of pure ethane hydrates, denoting that the system reached the most favourable thermodynamic conditions possible despite the presence of 25 vol% CO₂. Full article

Tests during methane hydrate (MH) production in Japan have shown that excessive water production is a primary challenge in MH development. It can lead to sand production, inhibit effective reservoir depressurization, and hinder gas production. This study investigated the ability of a reactive grout, produced by the in situ reaction of CO₂ with sodium silicate (SS), to inhibit water generation from unconsolidated sand layers by forming a water-blocking gel barrier. The performance of this grout was evaluated through laboratory experiments using silica sand as a porous medium. Under controlled conditions, diluted SS and CO₂ were sequentially injected. The injection and gelation processes were monitored in real time using CT scanning, and SEM was employed to analyze the microstructure of the reaction products. The results indicated that SS exhibited piston-like flow, with elevated concentrations increasing viscosity and promoting more uniform injection. CO₂ injection resulted in successful in situ gel formation. A homogeneous gel distribution decreased permeability by ~98% when the SS concentration was 25 wt%. However, at 50 wt%, rapid localized gelation caused preferential flow paths and reduced sealing efficiency. These findings highlight the potential of CO₂ reactive grouting for water management in MH exploitation and the importance of optimizing injection parameters. Full article

Lost circulation, a prevalent challenge in drilling engineering, poses significant risks including drilling fluid loss, wellbore instability, and environmental contamination. Conventional plugging materials often exhibit an inadequate performance under high-temperature, high-pressure (HTHP), and complex formation conditions. To address that, this study developed a high-performance gel–resin composite plugging material resistant to HTHP environments. By optimizing the formulation of bisphenol-A epoxy resin (20%), hexamethylenetetramine (3%), and hydroxyethyl cellulose (1%), and incorporating fillers such as nano-silica and walnut shell particles, a controllable high-strength plugging system was constructed. Fourier-transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA) confirmed the structural stability of the resin, with an initial decomposition temperature of 220 °C and a compressive strength retention of 14.4 MPa after 45 days of aging at 140 °C. Rheological tests revealed shear-thinning behavior (initial viscosity: 300–350 mPa·s), with viscosity increasing marginally to 51 mPa·s after 10 h of stirring at ambient temperature, demonstrating superior pumpability. Experimental results indicated excellent adaptability of the system to drilling fluid contamination (compressive strength: 5.04 MPa at 20% dosage), high salinity (formation water salinity: 166.5 g/L), and elevated temperatures (140 °C). In pressure-bearing plugging tests, the resin achieved a breakthrough pressure of 15.19 MPa in wedge-shaped fractures (inlet: 7 mm/outlet: 5 mm) and a sand-packed tube sealing pressure of 11.25 MPa. Acid solubility tests further demonstrated outstanding degradability, with a 97.69% degradation rate after 24 h in 15% hydrochloric acid at 140 °C. This study provides an efficient, stable, and environmentally friendly solution for mitigating drilling fluid loss in complex formations, exhibiting significant potential for engineering applications. Full article

Legged rovers are gaining interest for planetary exploration due to their high mobility. However, loose regolith on celestial surfaces like the Moon and Mars often leads to slippage as legs disturb the soil. To address this, a walking technique has been proposed that enhances soil support by transmitting vibrations from the robot’s legs. This approach aims to improve mobility by increasing the ground’s bearing capacity. To evaluate its effectiveness in space-like environments, this study experimentally investigates the effect of vibration on bearing capacity under low atmospheric pressure, which can influence soil behavior due to reduced air resistance. Using Silica No. 5 and Toyoura sand as test materials, experiments were conducted to compare bearing capacities under standard and low pressure. The results demonstrate that applying vibration significantly improves bearing capacity and that the influence of atmospheric pressure is minimal. These findings support the viability of vibration-assisted locomotion for planetary rovers operating in low-pressure extraterrestrial environments. Full article

Quality requirements for mineral aggregate for concrete used to construct pavement for busy highways are high because of the fatigue traffic loads and environmental exposure. The use of local aggregate for infrastructure projects could result in important sustainability improvements, provided that the concrete’s durability is assured. The objective of this study was to identify the potential alkaline reactivity of local greywacke aggregate and select appropriate mitigation measures against the alkali–silica reaction. Experimental tests on concrete specimens were performed using the miniature concrete prism test at 60 °C. Mixtures of coarse greywacke aggregate up to 12.5 mm with natural fine aggregate of different potential reactivity were evaluated in respect to the expansion, compressive strength, and elastic modulus of the concrete. Two preventive measures were studied—the use of metakaolin and slag-blended cement. A moderate reactivity potential of the greywacke aggregate was found, and the influence of reactive quartz sand on the expansion and instability of the mechanical properties of concrete was evaluated. Both crystalline and amorphous alkali–silica reaction products were detected in the cracks of the greywacke aggregate. Efficient expansion mitigation was obtained for the replacement of 15% of Portland cement by metakaolin or the use of CEM III/A cement with the slag content of 52%, even if greywacke aggregate was blended with moderately reactive quartz sand. It resulted in a relative reduction in expansion by 85–96%. The elastic modulus deterioration was less than 10%, confirming an increased stability of the elastic properties of concrete. Full article

Enhanced Geothermal Systems (EGS) require thermochemically stable proppant materials capable of sustaining fracture conductivity under harsh subsurface conditions. This study systematically investigates the response of commercial proppants to coupled thermo-hydro-chemical (THC) effects, focusing on chemical stability and microstructural evolution. Four proppant types were evaluated: an ultra-low-density ceramic (ULD), a resin-coated sand (RCS), and two quartz-based silica sands. Experiments were conducted under simulated EGS conditions at 130 °C with daily thermal cycling over a 25-day period, using diluted site-specific Utah FORGE geothermal fluids. Static batch reactions were followed by comprehensive multi-modal characterization, including scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS), X-ray diffraction (XRD), and micro-computed tomography (micro-CT). Proppants were tested in both granular and powdered forms to evaluate surface area effects and potential long-term reactivity. Results indicate that ULD proppants experienced notable resin degradation and secondary mineral precipitation within internal pore networks, evidenced by a 30.4% reduction in intragranular porosity (from CT analysis) and diminished amorphous peaks in the XRD spectra. RCS proppants exhibited a significant loss of surface carbon content from 72.98% to 53.05%, consistent with resin breakdown observed via SEM imaging. While the quartz-based sand proppants remained morphologically intact at the macro-scale, SEM-EDS revealed localized surface alteration and mineral precipitation. The brown sand proppant, in particular, showed the most extensive surface precipitation, with a 15.2% increase in newly detected mineral phases. These findings advance understanding of proppant–fluid interactions under low-temperature EGS conditions and underscore the importance of selecting proppants based on thermo-chemical compatibility. The results also highlight the need for continued development of chemically resilient proppant formulations tailored for long-term geothermal applications. Full article

Glass microspheres are essential components in horizontal road markings due to their retroreflective properties, enhancing visibility and safety under low-light conditions. Traditionally produced from soda-lime glass made with high-purity silica from sand, their manufacturing raises environmental concerns amid growing global sand scarcity. This study explores the viability of rice husk ash (RHA)—a high-silica byproduct of rice processing—as a sustainable raw material for microsphere fabrication. A glass composition containing 70 wt% SiO₂ was formulated using RHA and melted at 1500 °C. Microspheres were produced through flame spheroidization and characterized following the Brazilian standard NBR 16184:2021 for Type IB beads. The RHA-derived microspheres exhibited high sphericity, appropriate size distribution (63–300 μm), density of 2.42 g/cm³, and the required acid resistance. UV-Vis analysis confirmed their optical transparency, and the refractive index was measured as 1.55 ± 0.03. Retroreflectivity tests under standardized conditions revealed performance comparable to commercial counterparts. These results demonstrate the technical feasibility of replacing conventional silica with RHA in glass microsphere production, aligning with circular economy principles and promoting sustainable infrastructure. Given Brazil’s significant rice production and corresponding RHA availability, this approach offers both environmental and socio-economic benefits for road safety and material innovation. Full article