Search Results (401)

We explore the spontaneous emission dynamics of a giant atom coupled to a photonic Creutz ladder, focusing on how flat-band frustration and synthetic gauge fields shape atom–photon interactions. The Creutz ladder exhibits perfectly flat bands, Aharonov–Bohm caging, and topological features arising from its nontrivial hopping structure. By embedding the giant atom at multiple spatially separated sites, we reveal interference-driven emission control and the formation of nonradiative bound states. Using both spectral and time-domain analyses, we uncover strong non-Markovian dynamics characterized by persistent oscillations, long-lived entanglement, and recoherence cycles. The emergence of bound-state poles in the spectral function is accompanied by spatially localized photonic profiles and directionally asymmetric emission, even in the absence of band dispersion. Calculations of von Neumann entropy and atomic purity confirm the formation of coherence-preserving dressed states in the flat-band regime. Furthermore, the spacetime structure of the emitted field displays robust zig-zag interference patterns and synthetic chirality, underscoring the role of geometry and topology in photon transport. Our results demonstrate how flat-band photonic lattices can be leveraged to engineer tunable atom–photon entanglement, suppress radiative losses, and create structured decoherence-free subspaces for quantum information applications. Full article

Optical cooling is a key technique for preparing ultracold atoms in quantum technologies and precision experiments. We employ shortcut-to-adiabaticity (STA) techniques to accelerate and stabilize laser-based atomic cooling protocols. This approach improves the performance of conventional adiabatic momentum transfer schemes by addressing key limitations such as Doppler shifts, laser intensity fluctuations, and spontaneous emission. We first examine two- and three-level atomic systems subjected to counter-propagating laser pulses that induce momentum reduction through photon recoil. STA methods are then employed to construct pulse sequences that are robust against detuning errors and amplitude noise, outperforming standard $\pi$-pulse schemes in resilience. Meanwhile, we analyze the dissipative dynamics during the momentum transfer and demonstrate the superiority of the STA protocol in enhancing momentum transfer efficiency via accelerated control. The results demonstrate that STA can significantly improve both the efficiency and robustness of cooling. These findings have implications for applications in atomic physics, quantum information processing, and precision metrology. Full article

The paradigm-shift idea of murburn concept is no hypothesis but developed directly from fundamental facts of cellular/ecological existence. Murburn involves spontaneous and stochastic interactions (mediated by murzymes) amongst the molecules and unbound ions of cells. It leads to effective charge separation (ECS) and formation/recruitment of diffusible reactive species (DRS, like radicals whose reactions enable ATP-synthesis and thermogenesis) and emission of radiations (UV/Vis to ELF). These processes also lead to a chemo-electromagnetic matrix (CEM), ascertaining that living cell/organism react/function as a coherent unit. Murburn concept propounds the true utility of oxygen: generating DRS (with catalytic and electrical properties) on the way to becoming water, the life solvent, and ultimately also leading to phase-based macroscopic homeostatic outcomes. Such a layout enables cells to become simple chemical engines (SCEs) with powering, coherence, homeostasis, electro-mechanical and sensing–response (PCHEMS; life’s short-term “intelligence”) abilities. In the current review, we discuss the coacervate nature of cells and dwell upon the ways and contexts in which various radiations (either incident or endogenously generated) could interact in the new scheme of cellular function. Presenting comparative evidence/arguments and listing of systems with murburn models, we argue that the new perceptions explain life processes better and urge the community to urgently adopt murburn bioenergetics and adapt to its views. Further, we touch upon some distinct scientific and sociological contexts with respect to the outreach of murburn concept. It is envisaged that greater awareness of murburn could enhance the longevity and quality of life and afford better approaches to therapies. Full article

Internal combustion engine vehicles damage the environment and public health by emitting toxic fumes, such as CO₂ or CO and other trace compounds. The use of electric cars helps to reduce the emission of pollutants into the environment due to the use of batteries with no direct and local emissions. However, accidents of battery electric vehicles pose new challenges, such as thermal runaway. Such accidents can be serious and, in some cases, may result in uncontrolled overheating that causes the battery pack to spontaneously ignite. In particular, the most dangerous vehicles are heavy goods vehicles (HGVs), as they release a large amount of energy that generate high temperatures, poor visibility, and respiratory damage. This study aims to determine the potential consequences of large BEV fires in road tunnels using computational fluid dynamics (CFD). Furthermore, a comparison between a BEV and an ICEV fire shows the differences related to the thermal and the toxic impact. Furthermore, the adoption of a longitudinal ventilation system in the tunnel helped to mitigate the BEV fire risk, keeping a safer environment for tunnel users and rescue services through adequate smoke control. Full article

Icariin (ICA) is widely recognized for its health benefits. In this work, we examined the intermolecular interactions between ICA and proteinase K (PK) via multi-spectroscopic techniques and molecular simulations. The experimental findings revealed that ICA quenched the fluorescence emission of PK by forming a noncovalent complex. Both hydrogen bonding and van der Waals interactions are essential for the complex’s formation. Then Förster resonance energy transfer (FRET), competitive experiments, and synchronous fluorescence spectroscopy were adopted to verify the formation of the complex. Molecular docking studies demonstrated that ICA could spontaneously bind to PK by hydrogen bonding and hydrophobic interactions, which is consistent with the spectroscopic results. The PK-ICA complex’s dynamic stability was evaluated using a 50 ns molecular dynamics (MD) simulation. The simulation results revealed no significant structural deformation or positional changes throughout the entire simulation period. The complex appears to be rather stable, as seen by the average root-mean-square deviation (RMSD) fluctuations for the host protein in the PK-ICA complex of 1.08 Å and 3.09 Å. These outcomes of molecular simulations suggest that ICA interacts spontaneously and tightly with PK, consistent with the spectroscopic findings. The approach employed in this research presents a pragmatic and advantageous method for examining protein–ligand interactions, as evidenced by the concordance between empirical and theoretical findings. Full article

In this work, a comprehensive theoretical investigation is carried out to explore the electronic and spectroscopic properties of selected diatomic molecular ions MgRb⁺ and SrRb⁺. Using high-level ab initio calculations based on a pseudopotential approach, along with large Gaussian basis sets and full valence configuration interaction (FCI), we accurately determine adiabatic potential energy curves, spectroscopic constants, transition dipole moments (TDMs), and permanent electric dipole moments (PDMs). To deepen our understanding of these systems, we calculate radiative lifetimes for vibrational levels in both ground and low-lying excited electronic states. This includes evaluating spontaneous and stimulated emission rates, as well as the effects of blackbody radiation. We also compute Franck–Condon factors and analyze photoassociation processes for both ions. Furthermore, to explore low-energy collisional dynamics, we investigate elastic scattering in the first excited states (2¹Σ⁺) describing the collision between the Ra atom and Mg⁺ or Sr⁺ ions. Our findings provide detailed insights into the theoretical electronic structure of these molecular ions, paving the way for future experimental studies in the field of cold and ultracold molecular ion physics. Full article

Encryption and decryption are essential components in signal processing and optical communication systems, providing data confidentiality, integrity, and secure high-speed transmission. We present a novel design and simulation of an all-optical encryption and decryption system operating at 120 Gb/s using carrier reservoir semiconductor optical amplifiers (CR-SOAs) embedded in Mach–Zehnder interferometers (MZIs). The architecture relies on two consecutive exclusive-OR (XOR) logic gates, implemented through phase-sensitive interference in the CR-SOA-MZI structure. The first XOR gate performs encryption by combining the input data signal with a secure optical key, while the second gate decrypts the encoded signal using the same key. The fast gain recovery and efficient carrier dynamics of CR-SOAs enable a high-speed, low-latency operation suitable for modern photonic networks. The system is modeled and simulated using Mathematica Wolfram, and the output quality factors of the encrypted and decrypted signals are found to be 28.57 and 14.48, respectively, confirming excellent signal integrity and logic performance. The influence of key operating parameters, including the impact of amplified spontaneous emission noise, on system behavior is also examined. This work highlights the potential of CR-SOA-MZI-based designs for scalable, ultrafast, and energy-efficient all-optical security applications. Full article

Every year, a large amount of antibiotics enter aquatic environments globally through discharging of pharmaceutical wastewater and domestic sewage, emissions from agriculture, and livestock, posing a severe threat to ecosystems and human health. Therefore, it is essential to develop efficient adsorption materials for rapid removal of antibiotics in water. In this study, abundant and renewable wetland plants (lotus leaves, Arundo donax, and canna lilies) were utilized as raw materials to prepare biochar through slow pyrolysis combined with KOH chemical activation. The prepared biochar was employed to adsorb typical tetracycline (TC) antibiotics (TC-HCl, CTC-HCl, OTC-HCl) from water. The results showed that the optimum biochar (LBC-600 (1:3)) was prepared at a pyrolysis temperature of 600 °C with the mass ratio of KOH to lotus leaf of 1:3. The optimum pH for the adsorption of the three antibiotics were 5, 4, and 3, respectively. The highest adsorption rates reached 93.32%, 81.44%, and 83.76% for TC-HCl, CTC-HCl, and OTC-HCl with 0.6 g/L of biochar, respectively. At an initial antibiotic concentration of 80 mg·L⁻¹, the maximum adsorption capacities achieved 40.17, 27.76, and 24.6 mg·g⁻¹ for TC-HCl, CTC-HCl, and OTC-HCl, respectively. The adsorption process conformed to the pseudo-second-order kinetic and Langmuir isotherm models, indicating that it was a spontaneous endothermic process and primarily involved monolayer chemical adsorption. This study transformed wetland plant waste into adsorbent and applied it for antibiotic removal, providing a valuable resource utilization strategy and technical support for recycling wetland plant residues and antibiotic removal from water environments. Full article

Antioxidant gel foams are promising materials for coal mine fire prevention due to their unique physicochemical properties. To address the limitations of conventional suppression methods under high-temperature conditions, this study investigates a newly developed antioxidant gel foam and its mechanism in inhibiting coal spontaneous combustion. A novel antioxidant gel foam was formulated by incorporating TBHQ and modified montmorillonite into a sodium alginate-based gel system. This formulation enhances the thermal stability, water retention, and free radical scavenging capacity of the gel. This study uniquely combines multi-scale experimental methods to evaluate the performance of this material in coal fire suppression. Multi-scale experiments, including FTIR, leakage air testing, programmed temperature rise, and small-scale fire extinction, were conducted to evaluate its performance. Experimental results indicate that the antioxidant gel foam exhibits excellent thermal stability in the temperature range of 200–500 °C. Its relatively high decomposition temperature enables it to effectively resist structural damage in high-temperature environments. During thermal decomposition, the gel releases only a small amount of gas, while maintaining the integrity of its internal micro-porous structure. This characteristic significantly delays the kinetics of coal oxidation reactions. Further research revealed that the spontaneous combustion ignition temperature of coal samples treated with the gel was significantly higher, and the oxygen consumption rate during spontaneous combustion was significantly reduced, indicating that the gel not only effectively suppressed the acceleration of the combustion reaction but also significantly reduced the release of harmful gases such as HCl. Scanning electron microscope analysis confirmed that the gel maintained a good physical structure under high temperatures, forming an effective oxygen barrier, which further enhanced the suppression of coal spontaneous combustion. These findings provide important theoretical and practical guidance for the application of antioxidant gel foams in coal mine fire prevention and control, confirming that this material has great potential in coal mine fire safety, offering a new technological approach to improve coal mine safety. Full article

In this study, we analysed cocoa (a dried and fully fermented seed of Theobroma cacao L.) from two Amazonian cultivars and a commercial sample of the Amazonian variety EETP801, grown under sustainable organic conditions, in comparison to CCN51 cocoa grown on a neighbouring commercial farm using standard practises and a European commercial cacao powdered beverage. The overall metabolite profile of the 70% aq acetone sample cocoa extracts was analysed using high-performance TLC analyses (HPTLC), and the xanthine alkaloids were analysed using quantitative liquid chromatography–UV photodiode array (HPLC-DAD) analyses. The volatile fraction in the headspace of the freshly ground cocoa was subjected to solid phase micro-extraction and analysed by gas chromatography–mass spectrometry (HS-SPME/GC-MS). Total polyphenol content was determined by the Folin–Ciocalteu method. Despite the reduced production of cocoa by the EETP801 cultivar in comparison with the CCN51 cultivar, the obtained produce is significantly richer in theobromine (130 mg vs. 170 mg per g of cacao), with CCN51 having a double concentration of theophylline (12.6 vs. 6.5 mg per g of cacao). Qualitatively, the two Amazonian cocoa samples had a similar polyphenolic composition (per the HPTLC fingerprint). HS-SPME/GC-MS analyses revealed that all the samples show a spontaneous emission profile mainly rich in non-terpene derivatives, of which hydrocarbons and pyrazines are the most abundant groups. The most represented volatile organic compound is n-tridecane for both EETP801 and CCN51. The variability in the artisan fermentation and roasting processes influenced certain aspects of the volatile composition as reflected by the trimethyl pyrazine/tetramethyl pyrazine ratio, which was zero in EETP-801 and lower than 1 in CCN51. Acetic acid was absent in CCN51 but significant (c.a. 5.5.%) in EETP801 and the commercial samples. The cultivar EETP801 is a viable option for a more ecologically conscious sector of the cocoa beverages consumer group. Full article

To investigate the fire prevention and suppression characteristics of coal gangue slurry grouting in goafs and the enhanced regulatory mechanisms of additives, the slurry-forming performance of coal gangue slurry was tested. The effects of heating temperature, grouting thickness, and heating duration on the surface temperature distribution characteristics were analyzed. Temperature-programmed experiments were conducted to examine the influence of various additives on the spontaneous combustion propensity of coal gangue, with a comparative analysis of the inhibitory effects between ammonium polyphosphate (APP) and other additives. The results demonstrate that the prepared coal gangue slurry exhibited no segregation or sedimentation, with a plasticity index consistent with standard grouting material requirements, confirming its superior stability. The central, maximum, and minimum surface temperatures of the slurry showed polynomial functional relationships with heating temperature. Surface temperature initially increased and then decreased with grouting thickness, with 10 cm identified as the critical thickness for temperature transition. Overall, the central, maximum, and minimum surface temperatures increased progressively with rising heating temperatures. In addition, under all tested conditions, the average surface temperature remained below 80 °C for slurries with >5 cm grouting thickness, meeting fire prevention requirements. However, the CO and CO₂ concentrations increased significantly as heating temperatures rose from 100 °C to 300 °C. At grouting thicknesses of 9–12 cm, CO and CO₂ emissions occurred only at 300 °C and decreased with increasing thickness. The coal gangue slurry modified with ammonium polyphosphate (APP) additives exhibited optimal antioxidant performance, significantly suppressing CO and CO₂ emissions, which further diminished with higher additive dosages. The findings of this study provide critical insights into the fire prevention performance of coal gangue slurry grouting and the application of additives in this field. Full article

In this paper we investigate the non-Markovian dynamics of a giant atom coupled to a one-dimensional photonic lattice with synthetic gauge fields. By engineering a complex-valued hopping amplitude, we break reciprocity and explore how chiral propagation and phase-induced interference affect spontaneous emission, bound-state formation, and atom–field entanglement. The giant atom interacts with the lattice at multiple, spatially separated sites, leading to rich interference effects and decoherence-free subspaces. We derive an exact expression for the self-energy and perform real-time Schrödinger simulations in the single-excitation subspace, for the atomic population, von Neumann entropy, field localization, and asymmetry in emission. Our results show that the hopping phase $\varphi$ governs not only the directionality of emitted photons but also the degree of atom–bath entanglement and photon localization. Remarkably, we observe robust bound states inside the photonic band and directional asymmetry, due to interference from spatially separated coupling points. These findings provide a basis for engineering non-reciprocal, robust, and entangled light–matter interactions in structured photonic systems. Full article

Excessive Zn(II) ions in aquatic environments pose significant risks to both human health and ecological systems due to their toxic effects, bioaccumulation potential, and interference with essential biological processes. To address this issue, a novel analcime@calcium aluminate@polyethylene glycol 400 (ACP) nanocomposite was fabricated using the hydrothermal technique, alongside an analcime@calcium aluminate (AC) nanocomposite for the efficient elimination of Zn(II) ions from aqueous media. X-ray diffraction (XRD) analysis affirmed the successful formation of crystalline phases, revealing average crystallite sizes of 72.93 nm for AC and 63.60 nm for ACP. Energy-dispersive X-ray spectroscopy (EDX) confirmed the elemental composition of the nanocomposites, showing that AC primarily contained oxygen, sodium, aluminum, silicon, and calcium, whereas ACP incorporated 19.3% carbon due to the polyethylene glycol 400. Field emission scanning electron microscopy (FE-SEM) revealed that AC exhibited hexagonal and platelet-like structures, whereas ACP displayed more dispersed and layered morphologies. High-resolution transmission electron microscopy (HR-TEM) confirmed the presence of stacked platelet-like structures in AC and more defined, separated nanosheets in ACP. The maximum adsorption capacities of AC and ACP were 149.93 and 230.95 mg/g, respectively. The adsorption pathway of Zn(II) ions onto ACP nanocomposite involved three primary interactions: electrostatic attraction facilitated by calcium aluminate, ion exchange provided by analcime, and complexation promoted by polyethylene glycol 400. Thermodynamic analysis indicated that the adsorption process was exothermic, spontaneous, and primarily chemical in nature. Kinetic modeling confirmed that adsorption followed the pseudo-second-order model, while isotherm studies demonstrated adherence to the Langmuir model, indicating monolayer adsorption on homogeneous sites. Full article

The misuse of fentanyl poses significant social risks, and accurately and swiftly detecting fentanyl in field settings presents a considerable challenge. Herein, we have designed and synthesized a fluorescent probe TP-CF₃-COOH, which is composed of carboxyl- and trifluoromethyl-binding center tetraphenyl butadiene. The unique centrosymmetric configuration of the TP-CF₃-COOH probe allows for the construction of a fluorescence “on–off” mechanism recognition platform by spatially matching fentanyl and its metabolite norfentanyl. Importantly, this study reveals that the interaction of fentanyl or norfentanyl with TP-CF₃-COOH results in spontaneous self-assembly, generating a three-dimensional complex sphere that is smaller than the two-dimensional sheet fluorescence probe. This self-assembly process results in the quenching of fluorescence. Theoretical calculations demonstrate that this process is accompanied by intermolecular through-space charge transfer during self-assembly, leading to a blue shift in emission wavelength. As a result, the TP-CF₃-COOH fluorescent probe enables the quantitative detection of fentanyl/norfentanyl within a range of 1 × 10⁻²–1 × 10³ μg/L, with limits of detection of 2 × 10⁻⁴ μg/L and 3 × 10⁻⁴ μg/L, respectively. This cost-effective, rapid, and sensitive fluorescent probe holds great potential for the onsite screening and detection of fentanyl and its analogues. Full article

Traditional nanoparticle aerogels suffer from inherent brittleness and thermal instability at elevated temperatures. In recent years, ceramic nanofiber aerogels, utilizing flexible nanofibers as structural units, have emerged as mechanically resilient alternatives with ultrahigh porosity (>90%). However, their thermal insulation capabilities are compromised by micron-scale pores (10–100 μm) and overdependence on ultralow density, which exacerbates mechanical fragility. This study pioneers a gas-phase self-assembly strategy to fabricate Si₃N₄ nanoparticle reinforced Si₃N₄ nanofiber aerogels (SNP-R-SNFA) with gradient pore architectures. By leveraging methyltrimethoxysilane/vinyltriethoxysilane composite aerogel (MVa) as a reactive template, we achieved spontaneous growth of Si₃N₄ nanofiber films (SNP-R-SNF) featuring nanoparticle-fiber interpenetration and porosity gradients. The microstructure formation mechanism of SNP-R-SNF was analyzed using field-emission scanning electron microscopy. Layer assembly and hot-pressing composite technology were employed to prepare the SNP-R-SNFA, which showed low density (0.033 g/cm³), exceptional compression resilience, insensitive frequency dependence of dielectric properties (ε′ = 2.31–2.39, tan δ < 0.08 across 8–18 GHz). Infrared imaging displayed backside 893 °C cooler than front, demonstrating superior insulation performance. This study not only provides material solutions for integrated electromagnetic wave-transparent/thermal insulation applications but more importantly establishes an innovative paradigm for enhancing the mechanical robustness of nanofiber-based aerogels. Full article