Formation of ZrC–SiC Composites from the Molecular Scale through the Synthesis of Multielement Polymers
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Characterisations
2.3. Synthesis
2.3.1. Polycycloaddition (CuAAC)
Linear polycarbosilane (l-cPCS, as linear-clicked PCS)
Hyperbranched polycarbosilane (hb-cPCS, as hyperbranched-clicked PCS)
Zr-modified hyperbranched polycarbosilane (hb-cPZCS, as hyperbranched-clicked Zr-containing PCS)
2.3.2. Hydrosilylation
Linear polycarbosilane obtained by hydrosilylation (l-hPCS, as linear-hydrosilylated PCS)
Polyzirconocarbosilane obtained by hydrosilylation (l-hPZCS, as linear-hydrosilylated Zr-containing PCS)
2.4. Pyrolysis
3. Results and Discussion
3.1. Characterisation of the Polymeric Precursors
3.1.1. Polycarbosilanes (l-cPCS, hb-cPCS, and l-hPCS)
3.1.2. Zr-Containing Polycarbosilanes (hb-cPZCS, l-hPZCS)
Polymer | Reaction | Aspect | Solubility in Toluene * | Polymer Yield (%) |
---|---|---|---|---|
l-cPCS | Click-chemistry (CuAAC) | Brown solid | - | 84 |
hb-cPCS | Click-chemistry (CuAAC) | Orange gel | - | 92 |
hb-cPZCS | Click-chemistry (CuAAC) | Black solid | - | 66 |
l-hPCS | Hydrosilylation | Orange solid | ++ | 93 |
l-hPZCS | Hydrosilylation & Hydrozirconation | Brown solid | -- | 87 |
3.2. Thermal Behaviour of the Preceramic Polymers
3.2.1. Polycarbosilanes
PCS Obtained through CuAAC: l-cPCS and hb-cPCS
Two Linear Preceramic Precursors: l-cPCS and l-hPCS
3.2.2. Zr-Containing Polycarbosilanes (PZCS)
PCS and PZCS Obtained through Click-Chemistry: hb-cPCS and hb-cPZCS
PCS and PZCS Obtained through Hydrosilylation: l-hPCS and l-hPZCS
Ceramisation Mechanisms
3.3. Ceramics Issued from l-hPCS and l-hPZCS
3.4. Overview of the Thermal Behaviour of the Different Preceramic Polymers
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Polymer | Synthetic Process | Ceramic Yield (wt.%) | Organic-to-Inorganic Transition Range of Temperature (°C) | Ceramic Composition |
---|---|---|---|---|
l-cPCS | Click-chemistry (CuAAC) | 36 | 511 | SiC + Cgraphite |
hb-cPCS | Click-chemistry (CuAAC) | 58 | 489 | SiC + Cgraphite |
hb-cPZCS | Click-chemistry (CuAAC) | 54 | 407 | SiC + ZrC |
l-hPCS | Hydrosilylation | 62 | 780 | SiC + Camorphous |
l-hPZCS | Hydrosilylation and Hydrozirconation | 62 | 770 | SiC + ZrC |
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Bouzat, F.; Lucas, R.; Leconte, Y.; Foucaud, S.; Champavier, Y.; Coelho Diogo, C.; Babonneau, F. Formation of ZrC–SiC Composites from the Molecular Scale through the Synthesis of Multielement Polymers. Materials 2021, 14, 3901. https://doi.org/10.3390/ma14143901
Bouzat F, Lucas R, Leconte Y, Foucaud S, Champavier Y, Coelho Diogo C, Babonneau F. Formation of ZrC–SiC Composites from the Molecular Scale through the Synthesis of Multielement Polymers. Materials. 2021; 14(14):3901. https://doi.org/10.3390/ma14143901
Chicago/Turabian StyleBouzat, Fabien, Romain Lucas, Yann Leconte, Sylvie Foucaud, Yves Champavier, Cristina Coelho Diogo, and Florence Babonneau. 2021. "Formation of ZrC–SiC Composites from the Molecular Scale through the Synthesis of Multielement Polymers" Materials 14, no. 14: 3901. https://doi.org/10.3390/ma14143901