1. Introduction
Rhenium appears extremely rarely in nature, only in a dispersed state, mainly in molybdenite, columbite and copper-bearing shales [
1]. Manganese, on the other hand, is the twelfth-most abundant metal in the Earth’s crust, occurring mainly in the form of oxides, carbonates and silicates. It is the most common heavy metal after iron [
2,
3,
4].
The chemical properties of rhenium determine its applications, mainly in the production of superalloys but also in catalysis [
5,
6]. Rhenium is a heavy metal with a high melting point (>3180 °C), significant density (21.0 g/cm
3), high hardness (Mohs 7), high strength, thermal and chemical resistance and can also be easily shaped by plastic processing. It is characterized by the highest modulus of elasticity of all refractory metals, −420 GPa [
1,
3,
7].
Manganese, on the other hand, is a hard, silvery and brittle metal with a pink luster. It is widely used as an additive in steel, lowering its melting point and improving its mechanical properties. It is pyrophoric when crushed. Manganese is in huge demand around the world due to its numerous and diverse applications, mainly in the production of steel and high-capacity batteries [
2,
8,
9].
The world’s annual production of rhenium is up to 75 tons, the vast majority of which is recovered from so-called primary raw materials, and only ~8 tons are produced from recycling [
1,
10,
11]. The main manufacturers of rhenium from recycling are countries such as the USA, Canada, Germany, Czechia and Poland [
1,
12]. Rhenium recycling was much greater in 2014–2015, generating 13 tons/year. Rhenium is manufactured as a side product during the production of other elements both from primary or secondary resources, for example, during the recovery of Co and Ni from superalloys scraps. Consequently, the production of rhenium is influenced by the demand for other metals like cobalt and nickel. Currently, on the metals market, cobalt is considered a critical material in most of the world [
13,
14,
15]. In contrast, nickel is a strategic material and therefore sought after, mainly due to the development of the battery industry [
16,
17].
However, the world annual production of manganese is not comparable to rhenium, as it constitutes ~6.2 million tons. South Africa is the world’s largest manufacturer of manganese, accounting for 33.5% of its global production. It should also be noted that most of the mining of manganese is concentrated in the Kalahari Desert, which is believed to contain over 70% of the world’s resources of this metal. Manganese is recycled mainly from iron and steel scraps; a small amount of it is recycled from aluminum beverage cans. The recycling rate is 37%, and the efficiency is estimated at 53% [
18,
19,
20].
This publication concerns the preparation of manganese(II) perrhenate dihydrate. Manganese and rhenium share many of the chemical characteristics of transition metals, including multiple valency, the ability to form stable complex ions, paramagnetism and catalytic properties. However, in many aspects, rhenium is chemically more similar to technetium than to manganese [
21,
22]. For this reason, Mn(ReO
4)
2∙2H
2O has potential for use in the production of alloys, catalysts or in electrical components [
23].
There are not many reports in the literature about the combination of rhenium and manganese and, consequently, about Mn(ReO4)2∙2H2O. There are several reports on the preparation, properties and use of manganese(II) perrhenate and its hydrates.
In 1949, W. T. Smith and G. E. Maxwell described the synthesis of manganese(II) perrhenate dihydrate, which was obtained as a result of the reaction of manganese(II) carbonate or manganese(II) hydroxide with perrhenic acid. This publication also specified the physicochemical properties of the above-mentioned compound, such as solubility, density and freezing point [
24].
In 1969, H. G. Mayfield, Jr. and W. E. Bull described the process of forming the complexes of manganese(II) perrhenate with pyridine [
25].
However, the synthesis of manganese(II) perrhenate from manganese(IV) oxide, metallic manganese and rhenium(VI) oxide has been patented and described in patent no. US 4027004A. It also explains the properties of the obtained manganese(II) perrhenate, which allows it to be used in electrical components [
23].
In 1981, K.V. Ovchinnikov and his team investigated the thermal decomposition of manganese(II) perrhenate in vacuum [
26].
In 1997, Charles Torardi and his team presented the magnetic properties of anhydrous manganese(II) perrhenate in a publication. This compound was found to have antiferromagnetic properties. It was also determined that anhydrous manganese(II) perrhenate has trigonal symmetry [
27].
A. Butz, G. Miehle, H. Paulus, P. Strauss and H. Fuess, in 1998, researched the crystallographic structure of manganese(II) perrhenate in dihydrate and anhydrous forms and published the results of the dihydrate dehydration process. This compound was obtained as a result of the reaction of manganese(II) carbonate with perrhenic acid. The process was carried out in a temperature range of 50–60 °C in the presence of carbon dioxide [
28].
In
Z. Für Krist. -New Cryst. Struct., in the same year, an article was published presenting the results of research on the crystallographic structure of Mn(ReO
4)
2(H
2O)
2. The compound was obtained as a result of the reaction of manganese(II) carbonate with perrhenic acid [
29].
A work about [Mn(H
2O)
2](ReO
4)
2 was also published by J. Hetmańczyk and Ł. Hetmańczyk These studies were conducted using spectroscopic methods. The authors presented the dynamics of H
2O ligands and a perrhenate anion in the [Mn(H
2O)
2](ReO
4)
2 molecule at the moment of phase transition, as well as the crystallographic structure and thermal properties of the above-mentioned compounds. These compounds were obtained as a result of the reaction of manganese(II) carbonate with perrhenic acid [
30].
In 2021, B.C. Gong, H.C. Yang, J.F. Zhang, K. Liu and Z.Y. Lu conducted research in which they found that manganese(II) perrhenate, which has a wavy layered structure, doped with electrons exhibits ferromagnetic properties. They also determined that this compound can be a so-called van der Walls magnetic material, which means that it can be used for research on magnetism and in spintronics [
31].
In 2020, in
OSTI.GOV, a detailed crystallographic analysis of manganese(II) perrhenate was described. It showed that Mn(ReO
4)
2 crystallizes in a trigonal space group and its structure is two-dimensional [
32].
The objective of this study was to produce manganese(II) perrhenate dihydrate exclusively from two waste streams that, to the knowledge of the authors, have not been previously reported in the literature. Furthermore, the innovative method involves handling all waste materials, solid and liquid, to eliminate any loss of components and the need for further processing. This waste-free technology enables the production of high-purity manganese(II) perrhenate dihydrate, a valuable material for future novel applications in alloys, catalysts and electrical components. It is also in agreement with the principles of sustainable development and green transformation, and importantly, it meets the 6R principles in all six areas (rethink, refuse, reduce, reuse, repair and recycle) [
33].
2. Results and Discussion
2.1. Recovery of Manganese from Post-Leaching Solutions of Li–ion Battery Scrap and Analysis of the Obtained MnO2
Manganese precipitation tests were carried out using the post-leaching solutions of Li–ion battery scrap. Before the main precipitation of manganese, the solution was purified from Cu and then from Al and Fe. Copper was precipitated using 1 mole of iron in the form of metallic Fe powder for each mole of copper in the solution, which takes around 45 min with filtration. After filtering the precipitate, 30% H
2O
2 solution and then aqueous 20%NaOH solution were added over 30 min until the pH 5.2 was obtained. Neutralization was carried out at a temperature not exceeding 50 °C, and after obtaining the desired pH, the reaction was conducted for 30 min in the obtained conditions. After that time, the precipitated aluminum–iron sludge was filtered to obtain a solution that was sent for the manganese recovery tests.
Table 1 lists the compositions of all the solutions, and
Figure 1 shows (a) losses of valuable metals in the purification processes (Li, Mn, Co and Ni) and (b) efficiency of the precipitation of pollutants (Cu, Fe and Al).
As can be seen in
Figure 1, the losses of valuable metals (Li, Mn, Co and Ni) did not exceed 2% for each component, while the precipitation efficiencies of impurities, such as Cu, Fe and Al, were 99.84%, 99.97% and 99.96%, respectively.
In the next stage, the purified solution was sent for the manganese precipitation tests. Precipitation was carried out using a stoichiometric amount of KMnO4, and the resulting mixture was intensively stirred for 60 min at room temperature. After this time, the precipitate was vacuum-filtered, washed (with solutions of sulfuric acid and water) and analyzed. The solution from the filtration was directed to the recovery of other metals (Ni, Co and Li).
In this way, manganese(II) oxides were obtained, with the compositions depending on the purification stage listed in
Table 2. No significant losses of Ni, Li and Co were observed during the process. Cobalt and nickel losses, associated with MnO
2 precipitation, were reduced by proposing a recycling of the solutions resulting from the purification. For the selected manganese(II) oxide, after all purification steps, XRD analysis was performed (
Figure 2). During the research, a waste management method was developed (
Figure 3). SEM analysis was performed for the purified with 20% H
2SO
4 manganese(II) oxide—
Figure 4.
The purification of MnO
2 with 20% H
2SO
4 solution allowed to reduce the level of impurities below 0.20 wt% of each metal. Thus, MnO
2 was obtained, in which the amount of individual impurities such as Co, Ni, and Fe was (wt%): 0.20, 0.16 and <0.01, respectively (
Table 2).
As can be seen in
Figure 2, XRD analysis confirmed the possibility of producing MnO
2 using the described conditions, as the obtained diffractogram shows only the crystalline form of MnO
2. The form of the diffractogram indicates a large amount of the amorphous phase.
The obtained MnO2 precipitate was contaminated with cobalt and nickel but did not contain iron. After purification with a 20% H2SO4 solution, a product free of the above-mentioned elements was obtained. It was the substrate for the production of manganese(II) perrhenate.
2.2. Precipitation and Characterization of the Obtained Manganese(II)Perrhenate Dihydrate
The production of manganese(II) perrhenate dihydrate was carried out according to the reaction (1)
Purified MnO
2 (weighing 10 g) was added alternately with a 30% H
2O
2 solution (50 cm
3 of hydrogen peroxide for each 10 g of manganese(II) oxide) to the aqueous solutions of perrhenic acid with the concentrations of 18.0 or 295.0 g/dm
3 of Re. The tests were carried out at room temperature. In this way, a solution with the pH ranging from 6 to 7 was obtained. After reaching the pH, the solution was stirred for 90 min and successively filtered from the unreacted residue. The resulting solutions were directed to the evaporation to dryness, which was carried out at a temperature < 50 °C with an addition of 30% H
2O
2 solution using 15 cm
3 of hydrogen peroxide for every 50 g of rhenium. Evaporation tests were also carried out to obtain the first crystals. The crude wet sludge precipitated in this way was combined and sent to the cyclic purification stage. A 30 g portion of crude manganese(II) perrhenate dihydrate was used in the tests. Purification was carried out using recrystallization from water with an addition of 15 cm
3 of 30% aqueous H
2O
2 solution for every 50 g of Re in the precipitate and successively evaporated to obtain the first crystals. Four purification cycles were carried out. The results of the obtained tests are presented in
Table 3 and
Table 4.
Figure 5 and
Figure 6 illustrate the influence of the used rhenium concentration on the precipitation efficiency of the obtained manganese(II) perrhenate dihydrate and the influence of purification cycles on the purification efficiency of the obtained compound.
With the use of perrhenic acid with the rhenium concentrations of 18 and 295 g/dm3 both, similar Mn(ReO4)2·2H2O precipitation efficiencies were obtained using both precipitation methods. The efficiencies were high, for example, over 92%, while using the evaporation to dryness method. Therefore, the choice of acid concentration for the technology in industry will result from the scale of the production, the amount of waste solutions and the price of energy and will be analyzed at each stage of the technology implementation.
The use of the second stage of purification allows to obtain Mn(ReO4)2·2H2O of satisfactory purity, i.e., 9.29% of Mn, 62.9% of Re, 0.10% of Co and Ni and <0.01% of Fe.
In this way, 15.20 g of wet manganese(II) perrhenate dihydrate was obtained, which was dried at 100–110 °C until a constant weight was reached. Thus, manganese(II) perrhenate dihydrate weighing 14.54 g with a purity > 99% was obtained. XRD analysis was performed for this compound—
Figure 7.
As can be seen in the diffractogram (
Figure 7), a crystalline form of Mn(ReO
4)
2·2H
2O was obtained using the described conditions. This diffraction pattern also does not show any amorphous phases and substances.
For this Mn(ReO
4)
2·2H
2O, its solubility was also determined. The test results are presented in
Table 5.
The determined solubilities of Mn(ReO
4)
2·2H
2O obtained at various temperature values are consistent with the literature data [
24,
34]. Each test using the gravimetric method was repeated three times, giving consistent results on the solubility of manganese(II) perrhenate dihydrate. Standard deviations were calculated and are included in
Table 5.
The analysis of the conducted research on the precipitation of Mn(ReO4)2·2H2O showed that this compound can be obtained using purified MnO2, adding it alternately with the 30% H2O2 solution (50 cm3 of hydrogen peroxide for each 10 g of manganese(II) oxide) to the aqueous solution of perrhenic acid. The reaction should be carried out at room temperature for 30 min until a pH 6–7 is obtained. Mn(ReO4)2·2H2O, precipitated by evaporating the solution to dryness, should be purified by recrystallization from water with the addition of H2O2 at least twice. The purified Mn(ReO4)2·2H2O should be dried at 100–110 °C.
Based on the described research, this new, innovative, hydrometallurgical technology was developed for obtaining manganese(II) perrhenate dihydrate that was produced entirely from waste, i.e., superalloy scrap and Li–ion batteries. The next stage of the research will be to find a real application of manganese(II) perrhenate dihydrate in the catalytic, battery and defense industries. Research will be carried out on the possibility of obtaining manganese(II) perrhenate dihydrate with dedicated physicochemical properties, e.g., grain size below 100 nm.
3. Materials and Methods
3.1. Materials
Perrhenic acid, used in this research, was obtained by leaching the superalloy scrap (
Figure 8) with a mixture of acids with an addition of oxidants. The compositions of the materials are shown in
Table 6 [
35,
36]. In this way, a solution was obtained containing 1.1 g/dm
3 of Re and mainly nickel but also cobalt, chromium and aluminum. This solution was directed to the sorption of rhenium using a weakly basic ion exchange resin A170 (Purolite, King of Prussia, PA, USA, hydroxide form). The solution obtained after the sorption of rhenium was directed to the recovery of valuable metal components (Ni and Co), while rhenium absorbed in the ion exchange resin was eluted with an aqueous ammonia solution (25%, Chempur, Piekary Śląskie, Poland, p.a.). Ammonium perrhenate was crystallized from the obtained ammonia eluate, which was then dissolved in water and directed to the sorption of ammonium ions using a strongly acidic cation exchange resin C160 (Purolite, USA, hydrogen form) [
37,
38]. The post-sorption solution, containing perrhenic acid, was sent to the concentration stage, or manganese(II) perrhenate was obtained directly from it.
Figure 9 shows the laboratory equipment used in the preparation of perrhenic acid using the method described above. Perrhenic acid used in the conducted research differed in rhenium concentration. The first type came directly from the ion exchange process and was not concentrated. The second type of perrhenic acid was first concentrated and then used to obtain manganese(II) perrhenate dihydrate.
In this way, two types of perrhenic acid were obtained, containing (1) 18.0 g/dm
3 of Re and <0.0001% of Ca, K, Mg, Cu, Na, Mo, Ni, Pb, Fe, NH
4+, Bi, Zn, W, As and Al each and (2) 295.0 g/dm
3 of Re; <0.0005% of K; <0.0002% of NH
4+; and <0.0001% of Ca, Mg, Cu, Na, Mo, Ni, Pb, Fe, Bi, Zn, W, As and Al each [
38].
The solutions obtained after the leaching of the black mass from Li–ion batteries were used as the source of manganese—
Table 7. Battery masses for the leaching process were obtained as a result of using the technology developed and patented by Łukasiewicz-IMN [
39,
40].
After leaching, a solution with the composition of 2.50 g/dm3 of Al, 25.60 g/dm3 of Co, 2.56 g/dm3 of Li, 6.54 g/dm3 of Mn, 2.50 g/dm3 of Cu, 8.20 g/dm3 of Ni and 1.80 g/dm3 of Fe was obtained, which was directed to the MnO2 precipitation tests.
The following materials and reagents were used in this research: sulfuric acid (95%, Chempur, Piekary Śląskie, Poland, p.a.), aqueous solution of hydrogen peroxide (30%, P.P.H. Stanlab, Lublin, Poland, p.a.), demineralized water (<2 μS/cm, Łukasiewicz-IMN, Gliwice, Poland), sodium hydroxide (>98% Stanlab, Poland, p.a.), KMnO4 (99% P.P.H. Stanlab, Lublin, Poland, p.a.) and Fe dust (>98%, Chempur, Piekary Śląskie, Poland, p.a.).
3.2. Analyses
All analyses were performed at the Łukasiewicz Research Network—Institute of Non-Ferrous Metals, mainly at the Centre for Analytical Chemistry (Gliwice, Poland).
The rhenium content in manganese(II) perrhenate and perrhenic acid was determined by thin-layer X-ray fluorescence spectrometry using an X-ray fluorescence spectrometer (ZSX Primus, Rigaku, Tokyo, Japan).
Ammonium ions in the aqueous solutions of perrhenic acid were determined by a distillation method with titration after distillation—the Nessler method.
The following instrumental techniques were used to determine the concentrations of Mn, Li, Cu, Mo, Pb, Bi, Zn, W, As, Al, Mg, Ca, K, Mg, Na, Fe, Co and Ni: GFAAS (graphite furnace atomic absorption spectroscopy; Z-2000, HITACHI, Tokyo, Japan), ICP-OES (inductively coupled plasma-optical emission spectroscopy; ULTI-MA 2, HORIBA Jobin-Ivon, Kyoto, Japan), ICP-MS (inductively coupled plasma-mass spectroscopy; Nexion, PerkinElmer, Waltham, MA, USA), FAAS, (flame atomic absorption spectrometry; THERMO SOLAAR S4, Thermo Fisher Scientific, Waltham, MA, USA, equipped with a flame module—deuterium background and correction) and ICP-OES (Optima 5300V, Perkin Elmer, Waltham, MA, USA).
XRD analyses were also performed at the Łukasiewicz Research Network—Institute of Non-Ferrous Metals, Centre of Functional Materials (Gliwice, Poland). The diffraction patterns were prepared using a Rigaku MiniFlex 600 XRD diffractometer equipped with an X-ray tube with a wavelength of 1.5406 Å, a D/TeX silicon strip detector and a Soller slit with a high resolution of 2.5” on the primary and scattered beam, calibrated using NIST SRM (Standard Reference Material) 640d Si powder.
SEM analyses were also performed at the Łukasiewicz Research Network—Institute of Non-Ferrous Metals, Centre of Advanced Materials Technologies, using a high-resolution Zeiss Gemini 1525 scanning electron microscope, equipped with a Quantax xFlash®6 Bruker Nano X-ray spectrometer.
For the precipitated and purified manganese(II) perrhenate dihydrate, its solubility was measured using a gravimetric method.
Figure 10 shows the used laboratory equipment. The excess amount of salt was dissolved in water with a conductivity of 0.06 μS in a thermostated reactor with a heating jacket with a working capacity of 0.5 × 10
−3 m
3. The saturated solution was stirred for 4 h using a magnetic stirrer at a constant temperature. The temperature was controlled using a Huber Ministat CC-K6 thermostat (accuracy +/−0.02 °C). After stabilization, a sample of the saturated solution was taken using a syringe equipped with a filter with a pore diameter of 0.22 μm. In order to avoid crystallization during sample collection, the filter and syringe were heated to a temperature 5 °C higher than the solution temperature. The sample was dried in a laboratory dryer at 30 °C. The solubility of manganese(II) perrhenate was calculated based on the mass difference. The experiments were carried out for four temperature values, i.e., 0 °C, 10 °C, 20 °C and 30 °C. Each measurement was repeated three times.
4. Conclusions
This work showed that with the use of manganese(II) oxide, precipitated from the post-leaching solutions of the black mass from Li–ion batteries, after prior purification from Cu, Fe, and Al (pH = 5.2)—respectively, steps 1 and 2—Mn(ReO
4)
2·2H
2O can be obtained. MnO
2 precipitation should be carried out at a temperature not exceeding 50 °C for 30 min using a stoichiometric amount of KMnO
4—step 3. The precipitated MnO
2 should be washed using a 20% solution of sulfuric acid and then water—steps 4 and 5. Purified MnO
2 should be added alternately with a 30% H
2O
2 solution (50 cm
3 of hydrogen peroxide for each 10 g of manganese(II) oxide) to an aqueous solution of perrhenic acid. The reaction should be carried out at room temperature for 30 min to obtain a pH of 6–7—step 6. Mn(ReO
4)
2·2H
2O precipitated by evaporating the solution to dryness—step 7—should be purified by recrystallization from water with the addition of H
2O
2 a minimum of two times—step 8. The purified Mn described (ReO
4)
2·2H
2O should be dried at a temperature of 100–110 °C—step 9. Using the described procedure, Mn(ReO
4)
2·2H
2O with a purity > 99.0% and with a good precipitation efficiency can be obtained. A complete diagram of the entire developed technology is shown in
Figure 11.
Figure 11 shows the diagram of the developed method in its entirety, with all the recirculation possibilities and indication of the so-called auxiliary operations. The blue line shows the recycling of sludge formed after the neutralization of perrhenic acid to prevent the loss of manganese and rhenium. The purple line represents the recirculation of the solutions resulting from the purification of Mn(ReO
4)
2·2H
2O to minimize the losses of rhenium and manganese. The orange line shows the recycling of the solutions from MnO
2 purification to minimize the manganese loss.