Clean Technol., Volume 3, Issue 4 (December 2021) – 12 articles

Hydrogen is recognized as a promising and attractive energy carrier to decarbonize the sectors responsible for global warming, such as electricity production, industry, and transportation. However, although hydrogen releases only water as a result of its reaction with oxygen through a fuel cell, the hydrogen production pathway is currently a challenging issue since hydrogen is produced mainly from thermochemical processes (natural gas reforming, coal gasification). On the other hand, hydrogen production through water electrolysis has attracted a lot of attention as a means to reduce greenhouse gas emissions by using low-carbon sources such as renewable energy (solar, wind, hydro) and nuclear energy. In this context, by providing an environmentally-friendly fuel instead of the currently-used fuels (unleaded petrol, gasoline, kerosene), hydrogen can be used in various applications such as transportation (aircraft, boat, vehicle, and train), energy storage, industry, medicine, and power-to-gas. This article aims to provide an overview of the main hydrogen applications (including present and future) while examining funding and barriers to building a prosperous future for the nation by addressing all the critical challenges met in all energy sectors. Full article

Analyzing the impact of climate variables into the operational planning processes is essential for the robust implementation of a sustainable power system. This paper deals with the modeling of the run-of-river hydropower production based on climate variables on the European scale. A better understanding of future run-of-river generation patterns has important implications for power systems with increasing shares of solar and wind power. Run-of-river plants are less intermittent than solar or wind but also less dispatchable than dams with storage capacity. However, translating time series of climate data (precipitation and air temperature) into time series of run-of-river-based hydropower generation is not an easy task as it is necessary to capture the complex relationship between the availability of water and the generation of electricity. This task is also more complex when performed for a large interconnected area. In this work, a model is built for several European countries by using machine learning techniques. In particular, we compare the accuracy of models based on the Random Forest algorithm and show that a more accurate model is obtained when a finer spatial resolution of climate data is introduced. We then discuss the practical applicability of a machine learning model for the medium term forecasts and show that some very context specific but influential events are hard to capture. Full article

A sustainable design of production systems is essential for the future viability of the economy. In this context, biointelligent production systems (BIS) are currently considered one of the most innovative paths for a comprehensive reorientation of existing industrial patterns. BIS are intended to enable a highly localized on-demand production of personalized goods via stand-alone non-expert systems. Recent studies in this field have primarily adopted a technical perspective; this paper addresses the larger picture by discussing the essential issues of integrated production system design. Following a normative logic, we introduce the basic principle of systemic life cycle thinking in cellular units as the foundation of a management framework for BIS. Thereupon, we develop a coherent theoretical model of a future decentralized production system and derive perspectives for future research and development in key areas of management. Full article

In this paper, a composite control strategy for improved off-grid configuration based on photovoltaic (PV array), a wind turbine (WT), and a diesel engine (DE) generator to achieve high performance while supplying nonlinear loads is investigated. To operate the WT efficiently under variable speed conditions and to obtain accurate and fast convergence to the maximum global operating point without a speed sensor, an iterative interpolation method is integrated with the perturbation and observation (P&O) technique. To ensure the balance of power in the system and to achieve the maximum power from the PV array without using any maximum power point tracking (MPPT) method, and ensuring stable operation during the disturbance, a double-loop control strategy for a two-switches buck-boost converter is developed. Furthermore, to protect the synchronous generator of the diesel generator (DG) from the 5th and 7th order-harmonics created by the connected nonlinear loads and to solve the issue of the filter resonance, the interfacing three-phase inverter is controlled using an improved synchronous-reference frame algorithm (SRF) with virtual impedance active damping. The presented work demonstrates effective and efficient control along with improved performance and cost-effective option as compared to the similar works reported in the literature. The performance of the presented off-grid configuration and its developed composite control strategy are tested using MATLAB/Simulink and validated through small-scale hardware prototyping. Full article

In remote areas, extending a power line to the primary electricity grid can be very expensive and power losses are high, making connections to the grid almost impossible. A well-designed microgrid that integrates renewable energy resources can help remote areas reduce investment costs and power losses while providing a reliable power source. Therefore, investigating the design of an independent and economically practical microgrid system for these areas is necessary and plays an important role. This paper introduces a design procedure to design an isolated microgrid using HOMER software (HOMERPro 3.14.5) for remote areas. In Vietnam, due to the obstruction of the mountainous terrain or the isolated island location, many remote areas or islands need electrification. A simple case study of a hybrid system with a 60 kW peak load demand on Con Dao island in Vietnam is used to illustrate the proposed design method. Specifically, a hybrid system that includes a PV system, batteries, and a diesel generator is designed. To provide the full information of the designed hybrid system designed, each solution is analyzed and evaluated in detail according to the sensitivity parameters. Full article

Carbon capture is the most critical stage for the implementation of a technically viable and economically feasible carbon capture and storage or utilization scheme. For that reason, carbon capture has been widely studied, with many published results on the technical performance, modelling and, on a smaller scale, the costing of carbon capture technologies. Our objective is to review a large set of published studies, which quantified and reported the CO₂ capture costs. The findings are grouped, homogenised and standardised, and statistical models are developed for each one of the categories. These models allow the estimation of the capture costs, based on the amount of CO₂ captured and the type of source/separation principle of the capture technology used. Full article

In this work, Rhodiasolv^® PolarClean was employed as a more sustainable solvent for the preparation of poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) flat sheet membranes via phase inversion technique by coupling vapour induced phase separation (VIPS) and non-solvent induced phase separation (NIPS) processes. Preliminary calculations based on Hansen solubility parameters well predicted the solubilization of the polymer in the selected solvent. The effect of exposure time on humidity and the influence of polyethylene glycol (PEG), polyvinyl pyrrolidone (PVP) and sulfonated polyether sulfone (S-PES) on membrane properties and performance, were evaluated. Three different coagulation bath compositions were also explored. The obtained membranes, prepared using a more sustainable approach, were compared with those produced with the traditional toxic solvent N-methyl-2-pyrrolidone (NMP) and characterised in terms of morphology, porosity, wettability, pore size, surface roughness and mechanical resistance. The potential influence of the new solvent on the crystallinity of PVDF-HFP-based membranes was also evaluated by infrared spectroscopy. The adjustment of the parameters investigated allowed tuning of the membrane pore size in the microfiltration (MF) and ultrafiltration (UF) range resulting in membranes with various morphologies. From the water permeability and rejection tests, performed with methylene blue dye, the prepared membranes showed their potentiality to be used in MF and UF applications. Full article

Nowadays, most indoor cooling control strategies are based solely on the dry-bulb temperature, which is not close to a guarantee of thermal comfort of occupants. Prior research has shown cooling energy savings from use of a thermal comfort control methodology ranging from 10 to 85%. The present research advances prior research to enable thermal comfort control in residential buildings using a smart Wi-Fi thermostat. “Fanger’s Predicted Mean Vote model” is used to define thermal comfort. A machine learning model leveraging historical smart Wi-Fi thermostat data and outdoor temperature is trained to predict indoor temperature. A Long Short-Term-Memory neural network algorithm is employed for this purpose. The model considers solar heat input estimations to a residence as input features. The results show that this approach yields a substantially improved ability to accurately model and predict indoor temperature. Secondly, it enables a more accurate estimation of potential savings from thermal comfort control. Cooling energy savings ranging from 33 to 47% are estimated based upon real data for variable energy effectiveness and solar exposed residences. Full article

A number of technological challenges need to be overcome if algae are to be utilized for commercial fuel production. Current economic assessment is largely based on laboratory scale up or commercial systems geared to the production of high value products, since no industrial scale plant exits that are dedicated to algal biofuel. For macroalgae (‘seaweeds’), the most promising processes are anaerobic digestion for biomethane production and fermentation for bioethanol, the latter with levels exceeding those from sugar cane. Currently, both processes could be enhanced by increasing the rate of degradation of the complex polysaccharide cell walls to generate fermentable sugars using specifically tailored hydrolytic enzymes. For microalgal biofuel production, open raceway ponds are more cost-effective than photobioreactors, with CO₂ and harvesting/dewatering costs estimated to be ~50% and up to 15% of total costs, respectively. These costs need to be reduced by an order of magnitude if algal biodiesel is to compete with petroleum. Improved economics could be achieved by using a low-cost water supply supplemented with high glucose and nutrients from food grade industrial wastewater and using more efficient flocculation methods and CO₂ from power plants. Solar radiation of not <3000 h·yr⁻¹ favours production sites 30° north or south of the equator and should use marginal land with flat topography near oceans. Possible geographical sites are discussed. In terms of biomass conversion, advances in wet technologies such as hydrothermal liquefaction, anaerobic digestion, and transesterification for algal biodiesel are presented and how these can be integrated into a biorefinery are discussed. Full article

The present study aims at comparing the life cycle environmental impacts of polyunsaturated fatty acids production (PUFA) from microalgae and farmed fish. PUFA production from microalgae cultivated via heterotrophy and photoautotrophy was assessed and compared. The primary energy demand (PED) and environmental impacts (EI) of PUFA production from microalgae via heterotrophy were significantly lower compared to PUFA produced via photoautotrophy. Furthermore, PED and EI of PUFA production from fish farmed in marine net pens were assessed. The results indicated that the PED and EI of PUFA production from farmed fish are higher than that produced from microalgae cultivated via heterotrophy. Therefore, the results suggest that PUFA produced from microalgae via heterotrophy could substitute fish oil from an environmental perspective. Furthermore, life cycle analysis results indicate that PUFA derived from microalgae could potentially replace fish oil in the fish feed, thus reducing the pressure on oceans. Full article

Dimethyl carbonate (DMC) and glycidol are considered industrially important chemical entities and there is a great benefit if these moieties can be synthesized from biomass-derived feedstocks such as glycerol or its derivatives. In this report, both DMC and glycidol were synthesized in an integrated process from glycerol derived 1,3-dichloro-2-propanol and CO₂ through a metal-free reaction approach and at mild reaction conditions. Initially, the chlorinated cyclic carbonate, i.e., 3-chloro-1,2-propylenecarbonate was synthesized using the equivalent interaction of organic superbase 1,8-diazabicyclo [5.4.0] undec-7-ene (DBU) and 1,3-dichloro-2-propanol with CO₂ at room temperature. Further, DMC and glycidol were synthesized by the base-catalyzed transesterification of 3-chloro-1,2-propylenecarbonate using DBU in methanol. The synthesis of 3-chloro-1,2-propylenecarbonate was performed in different solvents such as dimethyl sulfoxide (DMSO) and 2-methyltetrahydrofuran (2-Me-THF). In this case, 2-Me-THF further facilitated an easy separation of the product where a 97% recovery of the 3-chloro-1,2-propylenecarbonate was obtained compared to 63% with DMSO. The use of DBU as the base in the transformation of 3-chloro-1,2-propylenecarbonate further facilitates the conversion of the 3-chloro-1,2 propandiol that forms in situ during the transesterification process. Hence, in this synthetic approach, DBU not only eased the CO₂ capture and served as a base catalyst in the transesterification process, but it also performed as a reservoir for chloride ions, which further facilitates the synthesis of 3-chloro-1,2-propylenecarbonate and glycidol in the overall process. The separation of the reaction components proceeded through the solvent extraction technique where a 93 and 89% recovery of the DMC and glycidol, respectively, were obtained. The DBU superbase was recovered from its chlorinated salt, [DBUH][Cl], via a neutralization technique. The progress of the reactions as well as the purity of the recovered chemical species was confirmed by means of the NMR analysis technique. Hence, a single base, as well as a renewable solvent comprising an integrated process approach was carried out under mild reaction conditions where CO₂ sequestration along with industrially important chemicals such as dimethyl carbonate and glycidol were synthesized. Full article

As renewable energy sources are spreading, the problems of energy usage, transport and storage arise more frequently. In order that the performance of energy producing units from renewable sources, which have a relatively low efficiency, should not be decreased further, and to promote sustainable energy consumption solutions, a living lab conception was elaborated in this project. At the pilot site, the produced energy (by PV panels, gas turbines/engines) is stored in numerous ways, including hydrogen production. The following uses of hydrogen are explored: (i) feeding it into the national natural gas network; (ii) selling it at a H-CNG (compressed natural gas) filling station; (iii) using it in fuel cells to produce electricity. This article introduces the overall implementation plan, which can serve as a model for the hybrid energy communities to be established in the future. Full article