Supramolecular Coordination Complexes: Synthesis and Applications

A special issue of Inorganics (ISSN 2304-6740). This special issue belongs to the section "Coordination Chemistry".

Deadline for manuscript submissions: closed (31 March 2024) | Viewed by 1474

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Departament de Química Inorgànica i Orgànica, Secció de Química Inorgànica, Universitat de Barcelona, c/Martí i Franquès 1-11, 08028 Barcelona, Spain
Interests: synthesis; NMR spectroscopy; coordination chemistry; nuclear magnetic resonance
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Dear Colleagues,

Coordination supramolecular chemistry has evolved to a stage whereby a large number of well-defined structures have been prepared through the establishment of metal–ligand interactions between small buildings blocks. In recent decades, an increasing number of combinations between acceptor metal compounds and organic or metallo-organic donor fragments have been used as building blocks, thus allowing the obtention of a huge variety of supramolecular architectures and assemblies. One of the most attractive features of this kind of compounds is the suitability for a great variety of applications. On one hand, the use of building blocks with specific functionalities can produce species with the desired properties. On the other hand, the formation of supramolecular entities can give rise to compounds with new properties that can be used in a wide range of potential applications, such as catalysis, sensoring, or switching devices, among others.

In this Special Issue, we wish to cover the most recent advances in the synthesis and applications of supramolecular coordination compounds (SCCs). This will also contribute to the discovery of new strategies and collaborations among researchers in the field.

Dr. Montserrat Ferrer
Guest Editor

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Keywords

  • ligand design and synthesis
  • supramolecular chemistry
  • organometallic chemistry
  • self-assembly
  • noncovalent interactions
  • coordination compound/complex

Published Papers (1 paper)

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Research

9 pages, 2631 KiB  
Article
Luminescent Cadmium(II)-Based 12-MC-4 Metallacrown Complex with 2-Methylmercaptobenzohydroxamic Acid Ligand
by Sriram Sundaresan, Christoph Gamer, Mortiz J. Förster, Luca M. Carrella and Eva Rentschler
Inorganics 2023, 11(9), 362; https://doi.org/10.3390/inorganics11090362 - 5 Sep 2023
Viewed by 1034
Abstract
We reported herein the synthesis, structure determination and emission properties of a cubic molecular Cd(II) coordination cluster whose faces are composed of 12-MC-4 metallacrown units built up from Cd2+ and 2-methylmercaptobenzohydroxamic acid (LmmbHA), resulting in [CdII14( [...] Read more.
We reported herein the synthesis, structure determination and emission properties of a cubic molecular Cd(II) coordination cluster whose faces are composed of 12-MC-4 metallacrown units built up from Cd2+ and 2-methylmercaptobenzohydroxamic acid (LmmbHA), resulting in [CdII14(LmmbHA)126−O)(DMF)10](ClO4)2·3H2O. The polynuclear complex obtained was characterised by single crystal X-ray diffraction at 193 K. The bulk sample was also analysed by elemental analysis. UV-Vis and emission spectra of the complex were measured in chloroform, as well as the emission spectra of the ligand for comparison. The results of the emission studies revealed that both the ligand and the complex are weakly emissive. Full article
(This article belongs to the Special Issue Supramolecular Coordination Complexes: Synthesis and Applications)
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