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Fiber Spinning: Materials and Techniques (Second Volume)

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Polymeric Materials".

Deadline for manuscript submissions: closed (20 January 2024) | Viewed by 2569

Special Issue Editor


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Guest Editor
Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia
Interests: polymer physical chemistry; colloid chemistry; rheology; polymer processing; fiber spinning; additive technologies
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Fiber spinning is one of the most complicated processes in the field of polymer processing. It is connected with the preparation of very thin and weak filaments, their collection to threads (yarns), and the final processing to textile or technical fibers and fabrics. Fiber spinning from melts is easier than from polymer solutions because when planning the subsequent processes it is necessary to overcome numerous issues connected with the choice of solvent, solution properties, and the selection of spinning method (wet, dry–wet jet, and dry), including the spinneret geometry, nature of coagulant, washing, orientation, drying procedures, and so on. Using solution spinning liquids of different chemical compositions requires a detailed consideration of their regeneration and recuperation methods. The development of composite fibers is usually stipulated, with the combination of one fiber in two or more polymers, coating the main fiber using a protective jacket, and introducing reinforcing or functional additives such as disperse particles, fire retardants, biological additives, and others. Self-absorbable threads from polylactide, polyglycolide, and their copolymers for use as surgical materials are also treated with special coatings that reduce the “sawing” effect when the material passes through the tissues, and also reduces the capillarity and fibrillation. In some cases, the solution method seems more attractive for preparing composite fibers because of the possibility of mixing two or more polymers in one fiber, to distribute uniformly solid or liquid additives at ambient conditions, in order to prepare reasonable precursors for carbon fibers. The most popular materials for precursors are cellulose and polyacrylonitrile fibers spun via solutions, as well as dopes that almost always contain additives. For these reasons, the preparation of composite fibers requires knowledge of physical and colloid chemistry, thermodynamics, rheology, chemical technology, mechanics, and other branches of science.

All of these are the driving forces of this Special Issue of Materials.

Prof. Dr. Valery Kulichikhin
Guest Editor

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Keywords

  • fiber spinning
  • polymer processing
  • polymer physical chemistry
  • colloid chemistry
  • rheology
  • composite fibers
  • functional additives

Published Papers (2 papers)

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Research

16 pages, 6302 KiB  
Article
Transformation of Specific Dispersion Interactions between Cellulose and Polyacrylonitrile in Solutions into Covalent Interactions in Fibers
by Markel I. Vinogradov, Lyudmila K. Golova, Igor S. Makarov, Galina N. Bondarenko, Ivan S. Levin, Natalia A. Arkharova and Valery G. Kulichikhin
Materials 2023, 16(17), 5843; https://doi.org/10.3390/ma16175843 - 26 Aug 2023
Viewed by 724
Abstract
Morphological transformations in emulsions of cellulose and polyacrylonitrile (PAN) ternary copolymers containing acrylonitrile, methyl acrylate, and methylsulfonate comonomers in N-methylmorpholine-N-oxide were studied over the entire range of concentrations depending on temperature and intensity of the deformation action. Based on the [...] Read more.
Morphological transformations in emulsions of cellulose and polyacrylonitrile (PAN) ternary copolymers containing acrylonitrile, methyl acrylate, and methylsulfonate comonomers in N-methylmorpholine-N-oxide were studied over the entire range of concentrations depending on temperature and intensity of the deformation action. Based on the morphological and rheological features of the system, the temperature-concentration range of spinnability of mixed solutions was determined, and composite fibers were spun. The fibers are characterized by a heterogeneous fibrillar texture. Studies of the structure of the fibers, carried out using X-ray diffraction analysis, revealed a decrease in cellulose crystallinity with an increase in the content of PAN. The study of the thermal properties of the obtained fibers, carried out using DSC, and chemical transformations in them in a wide temperature range by high-temperature diffuse reflection IR spectroscopy made it possible to reveal a new intense exothermic peak on the thermograms at 360 °C, which according to the IR spectra corresponds to the transformation of intermacromolecular physical interactions of the PAN and cellulose into covalent bonds between polymers. In addition, the ester groups found during the thermal treatment of the PAN part of the composite fibers in the pyrolysis zone can have a key effect on the process of their further carbonization. Full article
(This article belongs to the Special Issue Fiber Spinning: Materials and Techniques (Second Volume))
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18 pages, 7142 KiB  
Article
Influence of Alkyl Acrylate Nature on Rheological Properties of Polyacrylonitrile Terpolymers Solutions, Spinnability and Mechanical Characteristics of Fibers
by Ivan Yu. Skvortsov, Nikita M. Maksimov, Mikhail S. Kuzin, Roman V. Toms, Lydia A. Varfolomeeva, Elena V. Chernikova and Valery G. Kulichikhin
Materials 2023, 16(1), 107; https://doi.org/10.3390/ma16010107 - 22 Dec 2022
Cited by 5 | Viewed by 1327
Abstract
The influence of alkyl acrylate comonomers in the rank of methyl- (MA), butyl- (BA), ethylhexyl- (EGA), and lauryl- (LA) in ternary copolymers based on acrylonitrile, alkyl acrylate and acrylamide (PAN-alkyl acrylate) on their solutions rheological behavior in dimethyl sulfoxide (DMSO), and mechanical properties [...] Read more.
The influence of alkyl acrylate comonomers in the rank of methyl- (MA), butyl- (BA), ethylhexyl- (EGA), and lauryl- (LA) in ternary copolymers based on acrylonitrile, alkyl acrylate and acrylamide (PAN-alkyl acrylate) on their solutions rheological behavior in dimethyl sulfoxide (DMSO), and mechanical properties of the spun fibers have been investigated. To reveal the role of molecular weight, two series of copolymers with molecular weights of ~50 and 150 kg/mol have been studied. It was shown that the nature of the alkyl acrylate does not significantly affect the rheological behavior of their solutions regardless of the length of the alkyl substituent and the content of the alkyl acrylate in copolymers. An exception is the high-molecular PAN-LA, which is characterized by a non-Newtonian behavior at lower concentrations. Two series of fibers were spun from the characterized ranks of low and high-molecular-weight copolymer solutions. For all copolymers, a 2.5–5-fold increase in the strength and elastic modulus of the fiber was found with an increase in Mw. It has been shown that PAN-MA and PAN-LA fibers have a tensile strength of 800 MPa that is 1.5–3 times higher than that of other copolymers spun in the same conditions. Full article
(This article belongs to the Special Issue Fiber Spinning: Materials and Techniques (Second Volume))
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