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Advanced Functional Polymer‐Derived Ceramic Fibers: Preparation, Properties and Applications

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Polymeric Materials".

Deadline for manuscript submissions: closed (31 July 2021) | Viewed by 6890

Special Issue Editors


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Guest Editor
Directeur de l'Institut Européen des Membranes (IEM-UMR5635 ENSCM, UM, CNRS), Universite de Montpellier, Place Eugene Bataillon, F-34095 Montpellier, France
Interests: boron nitride; fibers; nanotubes; nanostructured ceramics; porous ceramics; hierarchical materials; molecular an polymeric precursors of non-oxide ceramics; borazine; borazine-based preceramic polymers; boron-based materials for hydrogen storage
Special Issues, Collections and Topics in MDPI journals

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Guest Editor
Institut Européen des Membranes UMR5635, Montpellier, France
Interests: polymer-derived ceramics; ceramics; microfluidics; micro/nanofabrication; 3D printing; porous materials; biomaterials; fibers; nanostructures; membranes
Special Issues, Collections and Topics in MDPI journals

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Guest Editor
Institut Europeen des Membranes, National Graduate School of Chemistry of Montpellier (ENSCM), University of Montpellier, Montpellier, France
Interests: nanomaterials; micro/nanofibers; electrospinning; electrode materials; materials for biology applications

Special Issue Information

Dear Colleagues,

During the last few decades, high-performance non-oxide ceramics have become of great interest due to their unique and diverse features. They display excellent thermal stability and mechanical properties, which make them potential candidates for many applications in severe environments involving high temperatures and high stresses. Since the polymer-derived ceramics (PDCs) route was set up, new functional ceramics have been designed with a thourough control of the composition and the shape of the materials. In particular, fibers have aroused interest when it comes to technical and engineering applications.

This Special Issue will focus on the various non-oxide polymer-derived ceramic fibers, from elaboration to final use. Major sub-topics include synthesis of the preceramic polymers, and their spinning and thermal treatment behaviors.

With regard to high-temperature structural applications, several studies have reported that binary (SiC, Si3N4, BN), ternary (SiCN) and even quaternary (SiBCN) fibers, prepared by means of meltspinning or electrospinning, are very promizing candidates to be used as reinforcements for thermostructural composites.

Thus, this Special Issue will assess how designing the molecular architecture, tailoring the chemical composition, rheology, spinnability and pyrolysis performance can influence the functional properties of fibers, together with their potential applications. In this context, the research published in this issue will sustain the impact of the PDCs route as the most suitable tool for developing advanced fibers for energy, environment and high-technology applications. Thus, in addition to high-temperature structural applications, including composite materials and other areas such as filters, membranes, etc., will be of great value.

It is our pleasure to invite you to submit a manuscript to this Special Issue. Full papers, communications, and reviews are all welcome.

Prof. Dr. Philippe Miele
Dr. Chrystelle Salameh
Prof. Dr. David Cornu
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Materials is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • Polymer derived ceramics
  • preceramic polymers
  • non-oxide ceramics
  • fibers
  • electrospinning
  • meltspinning
  • boron nitride
  • silicon carbonitride
  • silicoboron carbonitride
  • silicon carbide

Published Papers (1 paper)

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Review

18 pages, 7499 KiB  
Review
High-Temperature Properties and Applications of Si-Based Polymer-Derived Ceramics: A Review
by Zhongkan Ren, Shakir Bin Mujib and Gurpreet Singh
Materials 2021, 14(3), 614; https://doi.org/10.3390/ma14030614 - 29 Jan 2021
Cited by 43 | Viewed by 6013
Abstract
Ceramics derived from organic polymer precursors, which have exceptional mechanical and chemical properties that are stable up to temperatures slightly below 2000 °C, are referred to as polymer-derived ceramics (PDCs). These molecularly designed amorphous ceramics have the same high mechanical and chemical properties [...] Read more.
Ceramics derived from organic polymer precursors, which have exceptional mechanical and chemical properties that are stable up to temperatures slightly below 2000 °C, are referred to as polymer-derived ceramics (PDCs). These molecularly designed amorphous ceramics have the same high mechanical and chemical properties as conventional powder-based ceramics, but they also demonstrate improved oxidation resistance and creep resistance and low pyrolysis temperature. Since the early 1970s, PDCs have attracted widespread attention due to their unique microstructures, and the benefits of polymeric precursors for advanced manufacturing techniques. Depending on various doping elements, molecular configurations, and microstructures, PDCs may also be beneficial for electrochemical applications at elevated temperatures that exceed the applicability of other materials. However, the microstructural evolution, or the conversion, segregation, and decomposition of amorphous nanodomain structures, decreases the reliability of PDC products at temperatures above 1400 °C. This review investigates structure-related properties of PDC products at elevated temperatures close to or higher than 1000 °C, including manufacturing production, and challenges of high-temperature PDCs. Analysis and future outlook of high-temperature structural and electrical applications, such as fibers, ceramic matrix composites (CMCs), microelectromechanical systems (MEMSs), and sensors, within high-temperature regimes are also discussed. Full article
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