Composites Based on Layered Silicate Minerals: Preparation, Characterization and Applications

A special issue of Minerals (ISSN 2075-163X). This special issue belongs to the section "Clays and Engineered Mineral Materials".

Deadline for manuscript submissions: closed (18 August 2023) | Viewed by 2705

Special Issue Editors


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Guest Editor
1. Process Engineering Department, Faculty of Science and Technology, University of Relizane, Relizane 48000, Algeria
2. Material Chemistry Laboratory (LCM), Université Oran1, BP.1524 Oran El Menaouer, Oran 31100, Algeria
Interests: layered silicates; nanocomposites; catalysis; adsorption

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Guest Editor
1. Material Chemistry Laboratory (LCM), Université Oran1, BP.1524 Oran El Menaouer, Oran 31100, Algeria
2. Department of Materials Engineering, Faculty of Chemistry, University of Sciences and Technology Mohamed Boudiaf, BP 1505, El-Mnaouer, Oran 31000, Algeria
Interests: porous materials; nanocomposites; catalysis; adsorption

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Guest Editor
Catalysis Research Group (CRG), Department of Chemistry, College of Science, King Khalid University, P.O. Box 9004, Abha 61413, Saudi Arabia
Interests: nanomaterials; mesoporous silica; nanocomposites; catalysis; water treatment

Special Issue Information

Dear Colleagues,

Layered silicates are natural materials that can be synthesized in a laboratory via hydrothermal synthesis. Compared to clay, these materials may have a higher ion exchange capacity and better chemical stability. The framework for these materials, predominantly comprising SiO4 tetrahedra, offer interesting properties through modifications of the SiOH/SiO interlayer groups.

The aim of this Special Issue is to bring together current articles concerning the extraction, characterization, identification of properties and the application of layered silicates as well as covering organic and inorganic modification; composite-layered silicate polymers; nanocomposite-layered silicate polymers; film and hydrogel composite-layered silicate polymers; their environmental applications for eliminating toxic substances (e.g., heavy metals, organic pollutants, and atmospheric and pathogenic bacteria); and their application in the pharmaceutical industry as active ingredients and/or to slow, extend or vectorize drug release.

Dr. Mokhtar Adel
Dr. Boukoussa Bouhadjar
Dr. Mohamed Abboud
Guest Editors

Manuscript Submission Information

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Keywords

  • layered silicate
  • metal-layered silicate nanocomposite
  • organic-layered silicate nanocomposite
  • polymer-layered silicate nanocomposite
  • layered silicate-based membrane
  • layered silicate-based hydrogel
  • sorbent-based layered silicate
  • atmospheric pollution
  • toxic substance removal
  • computer simulation
  • drug delivery

Published Papers (2 papers)

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Research

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20 pages, 4412 KiB  
Article
Gas Barrier Properties of Multilayer Polymer–Clay Nanocomposite Films: A Multiscale Simulation Approach
by Andrey Knizhnik, Pavel Komarov, Boris Potapkin, Denis Shirabaykin, Alexander Sinitsa and Sergey Trepalin
Minerals 2023, 13(9), 1151; https://doi.org/10.3390/min13091151 - 30 Aug 2023
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Abstract
The paper discusses the development of a multiscale computational model for predicting the permeability of multilayer protective films consisting of multiple polymeric and hybrid layers containing clay minerals as fillers. The presented approach combines three levels of computation: continuous, full atomic, and quantitative [...] Read more.
The paper discusses the development of a multiscale computational model for predicting the permeability of multilayer protective films consisting of multiple polymeric and hybrid layers containing clay minerals as fillers. The presented approach combines three levels of computation: continuous, full atomic, and quantitative structure–property correlations (QSPR). Oxygen and water are chosen as penetrant molecules. The main predictions are made using the continuum model, which takes into account the real scales of films and nanoparticles. It is shown that reliable predictions of the permeability coefficients can be obtained for oxygen molecules, which is not always possible for water. The latter requires the refinement of existing QSPR methods and interatomic interaction potentials for the atomistic level of calculations. Nevertheless, we show that the maximum effect on permeability reduction from the addition of clay fillers to the hybrid layer can be achieved by using nanoparticles with large aspect ratios and a high degree of orientational order. In addition, the use of the hybrid layer should be combined with the use of polymer layers with minimal oxygen and water permeability. The constructed model can be used to improve the properties of protective coatings for food and drug storage and to regulate the gas permeability of polymeric materials. Full article
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Review

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29 pages, 6049 KiB  
Review
Recent Advances in Antibacterial Metallic Species Supported on Montmorillonite Clay Mineral: A Review
by Adel Mokhtar, Abderrazzak Baba Ahmed, Boubekeur Asli, Bouhadjar Boukoussa, Mohammed Hachemaoui, Mohamed Sassi and Mohamed Abboud
Minerals 2023, 13(10), 1268; https://doi.org/10.3390/min13101268 - 28 Sep 2023
Cited by 3 | Viewed by 1322
Abstract
This review provides information on the latest advances in inorganic materials with antimicrobial properties based on a metallic species immobilized on the clay mineral montmorillonite realized between the years 2015 and 2023. This class has shown many promising results compared to certain organic [...] Read more.
This review provides information on the latest advances in inorganic materials with antimicrobial properties based on a metallic species immobilized on the clay mineral montmorillonite realized between the years 2015 and 2023. This class has shown many promising results compared to certain organic agents. Montmorillonite in natural and/or modified forms is a good platform for the storage and release of metallic species, and several researchers have worked on this mineral owing to its cation exchange capacity, low cost, biocompatibility, and local availability. The preparation methods and the properties such as the antibacterial, antifungal, and toxicological activities of this mineral are discussed. The main characteristics of this antibacterial class for the elimination of pathogenic bacteria were examined and the known weak points of its antimicrobial application are discussed, leading to suggestions for further research. Full article
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