Polymer-SiO2 Composites II

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Composites and Nanocomposites".

Deadline for manuscript submissions: 31 July 2024 | Viewed by 1240

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Guest Editor
University College, Yonsei University, Incheon 21983, Republic of Korea
Interests: silicon chemistry; semiconductor manufacturing material
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Special Issue Information

Dear Colleagues,

Silica is a common, particularly attractive material that is all around us. Silicon and oxygen are the two most abundant elements in the Earth’s crust, and their combination, silica, has been used in various fields. The bond enthalpy of Si–O is much larger than that of the C–O bond, rendering the thermal stability of silica, and its larger bond angle and longer bond length provide bond flexibility. In addition, uncondensed OH groups (silanol) on the silica surface make it easy for silica to connect with other materials, such as organic compounds, metal oxides, and metals. 

Through the hybridization of silica with suitable materials, polymer/SiO2 composites can be customized in many ways to meet the needs of new cutting-edge technologies. For example, investigations on their applications in sensors, photoactive materials, filters, anodes in lithium-ion batteries, drug delivery systems, catalysts, and biocompatible materials have been conducted.

This Special Issue will cover, but will not be limited to, the following aspects of polymer/SiO2 composite chemistry and technology: novel preparation methods for polymer/SiO2 composites; mechanism of formation of polymer/SiO2 composites; novel micro- and macrostructural analysis of polymer/SiO2 composites; novel chemical and physical properties of polymer/SiO2 composites; and applications of polymer/SiO2 composites.

Prof. Dr. Hyeon Mo Cho
Guest Editor

Manuscript Submission Information

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Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • silica-based polymer
  • SiO2-based polymer
  • polymer
  • composite
  • sol-gel
  • organic–inorganic composite

Published Papers (1 paper)

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Research

15 pages, 4899 KiB  
Article
Mitigation of Silicon Contamination in Fuel Cell Gasket Materials through Silica Surface Treatment
by Yoo Lim Sim, Jaewon Lee, Su Min Oh, Dong Beom Kim, Kijong Kim, Sung-Hyeon Baeck, Sang Eun Shim and Yingjie Qian
Polymers 2024, 16(7), 914; https://doi.org/10.3390/polym16070914 - 26 Mar 2024
Viewed by 473
Abstract
Gaskets and seals are essential components in the operation of proton exchange membrane (PEM) fuel cells and are required for keeping hydrogen and air/oxygen within their individual compartments. The durability of these gaskets and seals is necessary, as it influences not only the [...] Read more.
Gaskets and seals are essential components in the operation of proton exchange membrane (PEM) fuel cells and are required for keeping hydrogen and air/oxygen within their individual compartments. The durability of these gaskets and seals is necessary, as it influences not only the lifespan but also the electrochemical efficiency of the PEM fuel cell. In this study, the cause of silicon leaching from silicone gaskets under simulated fuel cell conditions was investigated. Additionally, to reduce silicon leaching, the silica surface was treated with methyltrimethoxysilane, vinyltriethoxysilane, and (3,3,3-trifluoropropyl)trimethoxysilane. Changes in the silica surface chemistry were investigated by scanning electron microscopy, energy dispersive X-ray spectroscopy, thermogravimetric analysis, elemental analysis, X-ray photoelectron spectroscopy, and Fourier transform infrared spectroscopy. Inductively coupled plasma-optical emission spectroscopy analysis revealed that surface-treated silica was highly effective in reducing silicon leaching. Full article
(This article belongs to the Special Issue Polymer-SiO2 Composites II)
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