Influence of Phenethyl Acetate and Naphthalene Addition before and after Pyrolysis on the Quantitative Analysis of Bio-Oil
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Experimental and Analysis Methods
2.3. Data Evaluation
3. Results and Discussion
3.1. Thermal Stability Analysis of Internal Standards
3.2. Study of Potential Interactions between Typical Biomass Components and Internal Standards
3.3. Effects of Adding Standards before and after Pyrolysis on the Generation of Biowaste Pyrolytic Products
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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RT(min) | Formula | Compound | Relative Mass Content (%) | |||
---|---|---|---|---|---|---|
AP-phe | AP-nap | BP-phe | BP-nap | |||
5.45 | C5H4O2 | Furfural | 3.6 | 5.01 | 0.6 | 0.88 |
7.84 | C6H12O2 | 3-methylvaleric acid | 2.76 | 2.75 | 0.73 | 1.12 |
8.34 | C6H6O | phenol | 2.24 | 1.91 | 0.68 | 0.58 |
11.80 | C10H8 | Naphthalene * | - | 5.11 | - | 56.71 |
12.84 | C10H12O2 | Phenylethyl acetate * | 4.28 | - | 64.79 | - |
14.17 | C10H14N2 | Nicotine | 34.01 | 32.97 | 16.7 | 17.68 |
19.85 | C20H38 | Neophytadiene | 4.3 | 3.79 | 1.58 | 1.76 |
21.07 | C16H32O2 | Palmitic acid | 3.76 | 2.78 | 0.92 | 0.82 |
27.95 | C18H35NO | Oleamide | 7.23 | 12.18 | 7.78 | 5.81 |
31.19 | C8H5N3O4 | 4-Nitrophthalichydrazide | 2.84 | 1.96 | 0.56 | 2.57 |
Other compounds | 34.98 | 31.54 | 5.66 | 12.07 |
RT(min) | Formula | Compound | Relative Mass Content (%) | |||
---|---|---|---|---|---|---|
AP-phe | AP-nap | BP-phe | BP-nap | |||
5.43 | C5H4O2 | Furfural | 4.51 | 6.06 | 3.24 | 2.04 |
9.27 | C10H18O | Eucalyptol | 1.35 | 1.93 | 1.19 | 1.04 |
10.02 | C7H8O | P-cresol | 2.00 | 1.78 | 1.03 | 1.25 |
10.26 | C7H8O2 | Guaiacol | 7.6 | 7.35 | 5.47 | 5.09 |
11.80 | C10H8 | Naphthalene * | - | 3.59 | - | 43.55 |
11.90 | C8H10O2 | 2-Methoxy-4-methylphenol | 6.12 | 5.83 | 4.24 | 4.75 |
12.84 | C10H12O2 | Phenylethyl acetate * | 2.2 | - | 54.93 | - |
13.17 | C9H12O2 | 4-ethylguaiacol | 3.69 | 3.44 | 2.13 | 2.62 |
13.70 | C9H10O2 | 4-vinyl-2-methoxyphenol | 4.44 | 3.95 | 2.67 | 3.78 |
14.17 | C8H10O3 | 2,6-Dimethoxyphenol | 2.38 | 2.5 | 1.68 | 2.09 |
14.26 | C10H12O2 | 2-Methoxy-3-(2-propenyl)-phenol | 1.41 | 1.41 | 1.08 | 1.44 |
14.84 | C8H8O3 | Vanillin | 3.41 | 3.23 | 2.39 | 2.99 |
15.42 | C9H12O3 | 3,5-Dimethoxy-4-hydroxytoluene | 1.32 | 1.56 | 0.82 | 1.20 |
15.48 | C10H12O2 | (E)-2-Methoxy-4-(1-propenylphenol) | 4.11 | 4.86 | 2.88 | 4.00 |
15.96 | C9H10O3 | Vanilla ethyl ketone | 2.38 | 2.17 | 1.57 | 1.88 |
16.51 | C10H12O3 | 4-hydroxy-3-methoxypro-piophenone | 1.45 | 1.48 | 0.9 | 1.17 |
18.85 | C10H10O3 | 4-hydroxy-3-methoxycinnamaldehyde | 2.09 | 2.41 | 1.33 | 2.25 |
27.95 | C22H43NO | Erucamide | 2.89 | 3.51 | 3.6 | 6.7 |
Other compounds | 46.65 | 41.21 | 8.85 | 12.16 |
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Song, X.; Wei, M.; Gao, Q.; Pan, X.; Yang, J.; Wu, F.; Hu, H. Influence of Phenethyl Acetate and Naphthalene Addition before and after Pyrolysis on the Quantitative Analysis of Bio-Oil. Energies 2020, 13, 6202. https://doi.org/10.3390/en13236202
Song X, Wei M, Gao Q, Pan X, Yang J, Wu F, Hu H. Influence of Phenethyl Acetate and Naphthalene Addition before and after Pyrolysis on the Quantitative Analysis of Bio-Oil. Energies. 2020; 13(23):6202. https://doi.org/10.3390/en13236202
Chicago/Turabian StyleSong, Xuyan, Min Wei, Qiang Gao, Xi Pan, Junpeng Yang, Fan Wu, and Hongyun Hu. 2020. "Influence of Phenethyl Acetate and Naphthalene Addition before and after Pyrolysis on the Quantitative Analysis of Bio-Oil" Energies 13, no. 23: 6202. https://doi.org/10.3390/en13236202