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Polymers, Volume 10, Issue 4

2018 April - 121 articles

Cover Story: Chitin deacetylases (CDAs) catalyze the hydrolysis of acetamido groups in GlcNAc residues of chitin, chitosan, and chitooligosaccharides (COS). The deacetylation specificity exhibited by CDAs is diverse, some enzymes being specific for single positions, others showing multiple attacks, processivity or random actions. The “subsite capping model” proposes that specificity is partly governed by a series of dynamic loops that shape the substrate binding cleft, which differ among CDAs on a highly conserved protein core. The structures, specificities, and biotech applications of bacterial and fungal CDAs are reviewed here. View the paper here.
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Articles (121)

  • Review
  • Open Access
537 Citations
26,269 Views
17 Pages

Biomedical Applications of Chitosan and Its Derivative Nanoparticles

  • Dongying Zhao,
  • Shuang Yu,
  • Beini Sun,
  • Shuang Gao,
  • Sihan Guo and
  • Kai Zhao

23 April 2018

Chitosan is a biodegradable natural polymer with many advantages such as nontoxicity, biocompatibility, and biodegradability. It can be applied in many fields, especially in medicine. As a delivery carrier, it has great potential and cannot be compar...

  • Article
  • Open Access
19 Citations
6,588 Views
13 Pages

Multienzyme Immobilized Polymeric Membrane Reactor for the Transformation of a Lignin Model Compound

  • Rupam Sarma,
  • Md. Saiful Islam,
  • Mark P. Running and
  • Dibakar Bhattacharyya

23 April 2018

We have developed an integrated, multienzyme functionalized membrane reactor for bioconversion of a lignin model compound involving enzymatic catalysis. The membrane bioreactors were fabricated through the layer-by-layer assembly approach to immobili...

  • Article
  • Open Access
56 Citations
8,506 Views
13 Pages

22 April 2018

The surface treatment of fabrics in an atmospheric environment may pave the way for commercially viable plasma modifications of fibrous matters. In this paper, we demonstrate a durably superhydrophobic cotton cellulose fabric prepared in a single-ste...

  • Article
  • Open Access
40 Citations
10,165 Views
18 Pages

22 April 2018

A new and eco-friendly mussel-inspired surface modification pathway for bamboo fiber (BF) is presented in this study. The self-assembly polydopamine (PDA) coating can firmly adhere on BF surface, which also serves as a bridge to graft octadecylamine...

  • Article
  • Open Access
17 Citations
9,797 Views
9 Pages

21 April 2018

Shape is an essential property of polymeric particles. Herein, we propose a simple method to synthesize polymeric particles with a well-controlled concave shape. Our method takes advantage of the powerful seeded emulsion polymerization strategy with...

  • Feature Paper
  • Article
  • Open Access
10 Citations
7,106 Views
12 Pages

21 April 2018

Silk-based materials are water-sensitive and show different physical properties at different humidities and under wet/dry conditions. To overcome the water sensitivity of silk-based materials, we developed a silk composite material with a fluoropolym...

  • Article
  • Open Access
28 Citations
11,090 Views
11 Pages

20 April 2018

In this study, epoxy molding compounds (EMCs) with aluminosilicate (AlS) and aluminum oxide (AlO) were fabricated as fillers by a twin-screw-extruder (TSE) and shaped to plate samples using injection molding. AlS and AlO, electrical insulating minera...

  • Article
  • Open Access
11 Citations
5,191 Views
13 Pages

19 April 2018

The main purpose of this work is to show the thermal dependence of the refractive and extinction indices of conjugated polymer films used in optoelectronics devices. Herein, we present the results of optical investigations performed for the following...

  • Article
  • Open Access
23 Citations
5,913 Views
18 Pages

19 April 2018

Reactive electrospinning is capable of efficiently producing in situ crosslinked scaffolds resembling the natural extracellular matrix with tunable characteristics. In this study, we aimed to synthesize, characterize, and investigate the in vitro cyt...

  • Article
  • Open Access
39 Citations
10,101 Views
16 Pages

19 April 2018

The objective of this study was to develop three-dimensional collagen/gelatin/hydroxyethyl cellulose composites in combination with gelatin or collagen-gelatin loaded microspheres. Microspheres were prepared by an emulsification/crosslinking method....

  • Article
  • Open Access
75 Citations
11,585 Views
19 Pages

Biocompatible and Antibacterial Nitric Oxide-Releasing Pluronic F-127/Chitosan Hydrogel for Topical Applications

  • Milena T. Pelegrino,
  • Bruna De Araujo Lima,
  • Mônica H. M. Do Nascimento,
  • Christiane B. Lombello,
  • Marcelo Brocchi and
  • Amedea B. Seabra

18 April 2018

Nitric oxide (NO) is involved in physiological processes, including vasodilatation, wound healing and antibacterial activities. As NO is a free radical, designing drugs to generate therapeutic amounts of NO in controlled spatial and time manners is s...

  • Article
  • Open Access
22 Citations
4,909 Views
10 Pages

Angular Photochromic LC Composite Film for an Anti-Counterfeiting Label

  • Yanzi Gao,
  • Wenhuan Yao,
  • Jian Sun,
  • Kexuan Li and
  • Lanying Zhang

18 April 2018

In the harsh application environment, improving the mechanical properties of liquid crystal materials is a fundamental and important problem in the design of anti-counterfeit materials. In this paper, by a stepwise polymerization of first, photo-poly...

  • Article
  • Open Access
19 Citations
6,272 Views
12 Pages

Antifungal Paper Based on a Polyborneolacrylate Coating

  • Jiangqi Xu,
  • Yujia Bai,
  • Meijiao Wan,
  • Yanhui Liu,
  • Lei Tao and
  • Xing Wang

17 April 2018

Paper documents and products are very susceptible to microbial contamination and damage. Fungi are mainly responsible for those biodeterioration processes. Traditional microbicidal strategies constitute a serious health risk even when microbes are de...

  • Article
  • Open Access
44 Citations
12,551 Views
12 Pages

17 April 2018

A high performance ladder-like structured methacrylate siloxane hybrid material (LMSH) was fabricated via simple hydrolytic sol–gel reaction, followed by free-radical polymerization. A structurally ordered siloxane backbone, the ladder-like str...

  • Article
  • Open Access
30 Citations
4,867 Views
19 Pages

17 April 2018

A series of π-conjugated polymers containing alternating benzoselenadiazole (BSe)-bi(thiophene derivative)-carbazole or benzoththiadiazole (BSe)-bi(thiophene derivative)-fluorene units were designed and synthesized. Thiophene derivatives, namely 3...

  • Article
  • Open Access
20 Citations
5,864 Views
23 Pages

17 April 2018

Thermoresponsive nanoparticles are promising smart materials for many applications. However, a rational design for applications requires a deeper understanding and experimental verification of the various parameters that influence the thermoresponsiv...

  • Article
  • Open Access
6 Citations
6,869 Views
12 Pages

Non-Leachable Hydrophilic Additives for Amphiphilic Coatings

  • Guillaume Gillet,
  • Fabrice Azemar,
  • Fabienne Faÿ,
  • Karine Réhel and
  • Isabelle Linossier

16 April 2018

Amphiphilic surfaces are particularly effective at inhibiting the adhesion of microorganisms (bacteria, cells, microalgae, etc.) in liquid media. The aim of this study is to determine the best hydrophilic linker to promote bonding between poly(ethyle...

  • Article
  • Open Access
28 Citations
10,496 Views
15 Pages

16 April 2018

The properties of rubber are strongly influenced by the distribution of filler within the polymer matrix. Here, we introduce a Monte Carlo-based morphology generator. The basic elements of our model are cubic cells, which, in the current version, can...

  • Article
  • Open Access
9 Citations
5,373 Views
14 Pages

16 April 2018

We present a numerical study in which large-scale bulk simulations of self-assembled DNA constructs have been carried out with a realistic coarse-grained model. The investigation aims at obtaining a precise, albeit numerically demanding, estimate of...

  • Review
  • Open Access
122 Citations
13,493 Views
51 Pages

15 April 2018

Non-viral gene delivery vectors have lagged far behind viral ones in the current pipeline of clinical trials of gene therapy nanomedicines. Even when non-viral nanovectors pose less safety risks than do viruses, their efficacy is much lower. Since th...

  • Article
  • Open Access
27 Citations
5,575 Views
14 Pages

14 April 2018

A new adsorbent was prepared via modified poly(glycidyl methacrylate) with 8-aminoquinoline (AQ-PGMA) for the recovery of Pd(II) from solution. The practical application values of AQ-PGMA, including efficiency, selectivity and reusability for the rec...

  • Article
  • Open Access
32 Citations
7,548 Views
10 Pages

14 April 2018

Can microbial cellulose (MC) be used as a bio-carrier for 1,3-dihydroxy-2-propanone (DHA)? The aim of this study was to examine the possibility of using MC as a biomaterial for DHA transferring into the stratum corneum and inducing changes in skin co...

  • Article
  • Open Access
33 Citations
11,660 Views
13 Pages

14 April 2018

The effect of the chemical structure and functionality of three structurally different thiols on the cross-linking of acrylated epoxidized soybean oil and on the properties of the resulting polymers was investigated in this study. 1,3-Benzenedithiol,...

  • Article
  • Open Access
21 Citations
6,218 Views
16 Pages

Towards More Sustainable Material Formulations: A Comparative Assessment of PA11-SGW Flexural Performance versus Oil-Based Composites

  • Helena Oliver-Ortega,
  • José Alberto Méndez,
  • Rafel Reixach,
  • Francesc Xavier Espinach,
  • Mònica Ardanuy and
  • Pere Mutjé

14 April 2018

The replacement of commodity polyolefin, reinforced with glass fiber (GF), by greener alternatives has been a topic of research in recent years. Cellulose fibers have shown, under certain conditions, enough tensile capacities to replace GF, achieving...

  • Article
  • Open Access
19 Citations
5,852 Views
14 Pages

Synthesis of an Efficient S/N-Based Flame Retardant and Its Application in Polycarbonate

  • Weiqiu Wen,
  • Jianwei Guo,
  • Xi Zhao,
  • Xiong Li,
  • Hongmei Yang and
  • Jem-Kun Chen

14 April 2018

Considering the poor compatibility and water-resistance of sulfonate flame retardants for polycarbonate (PC), an efficient S/N-based flame retardant named 1,3,5,7-tetrakis(phenyl-4-sulfonyl-melamine)adamantane (ASN) has been developed. Fire propertie...

  • Article
  • Open Access
45 Citations
7,490 Views
15 Pages

Comparative Study of Diethylaminoethyl-Chitosan and Methylglycol-Chitosan as Potential Non-Viral Vectors for Gene Therapy

  • Sergei V. Raik,
  • Stanislav Andranovitš,
  • Valentina A. Petrova,
  • Yingying Xu,
  • Jenny Ka-Wing Lam,
  • Gordon A. Morris,
  • Alexandra V. Brodskaia,
  • Luca Casettari,
  • Andreii S. Kritchenkov and
  • Yury A. Skorik

14 April 2018

In this paper, we compared the transfection efficiency and cytotoxicity of methylglycol-chitosan (MG-CS) and diethylaminoethyl-chitosan (DEAE-CSI and DEAE-CSII with degrees of substitution of 1.2 and 0.57, respectively) to that of Lipofectamine (used...

  • Article
  • Open Access
18 Citations
6,501 Views
15 Pages

14 April 2018

Enhancing drug loading efficacy and stability of polymeric micelles remains a grand challenge. Here we develop adamantane-based star copolymers adamantane-[poly(ε-caprolactone)-b-poly(2-(diethylamino)ethyl methacrylate)-b-poly(poly(ethylene glycol) m...

  • Article
  • Open Access
14 Citations
7,002 Views
15 Pages

13 April 2018

In the recent studies on chitosan hydrogels, it was found that understanding both rheological and structural properties plays an important role in their application. Therefore, a combination of two independent techniques was applied to investigate mi...

  • Article
  • Open Access
6 Citations
3,960 Views
10 Pages

13 April 2018

The equilibrium volume of a polyelectrolyte gel results from a balance between the tendency to swell caused by outbound polymer/counterion diffusion along with Coulomb interactions on the one hand; and, on the other, the elastic resilience of the cro...

  • Article
  • Open Access
28 Citations
5,657 Views
15 Pages

Structural Changes of Bagasse dusring the Homogeneous Esterification with Maleic Anhydride in Ionic Liquid 1-Allyl-3-methylimidazolium Chloride

  • Huihui Wang,
  • Wei Chen,
  • Xueqin Zhang,
  • Yi Wei,
  • Aiping Zhang,
  • Shijie Liu,
  • Xiaoying Wang and
  • Chuanfu Liu

13 April 2018

The maleation of bagasse could greatly increase the compatibility between bagasse and composite matrixes, and the percentage of substitution (PS) of bagasse maleates could be regulated in the homogeneous system. However, due to the complicated compon...

  • Article
  • Open Access
11 Citations
5,122 Views
17 Pages

13 April 2018

In order to prepare efficient luminescent organic–inorganic hybrid materials embedded with a lanthanide (Ln3+) complex with polycarboxylate ligands, Ln3+-doped di-ureasils with 4,4-oxybis(benzoic acid) and 1,10-phenanthroline ligands were synthesized...

  • Article
  • Open Access
6 Citations
5,445 Views
12 Pages

13 April 2018

Wooden magnetic activated carbon fibers (WMACFs) with hierarchical pore structures were obtained by adding magnetic iron oxide (Fe3O4) nanoparticles into the liquefied wood. The structures and properties of WMACFs were analyzed by scanning electronmi...

  • Article
  • Open Access
4 Citations
6,264 Views
12 Pages

Reinforced PEI/PVdF Multicore-Shell Structure Composite Membranes by Phase Prediction on a Ternary Solution

  • Jihye Chae,
  • Sejoon Park,
  • Dong Young Kim,
  • Han-Ik Joh,
  • Jong Man Kim,
  • Sungho Lee and
  • Seong Mu Jo

13 April 2018

To construct a polyetherimide (PEI)-reinforced polyvinylidene fluoride (PVdF) composite membrane with multicore-shell structure, a ternary solution was prepared and electrospun by single-nozzle electrospinning. A theoretical prediction was made for t...

  • Article
  • Open Access
8 Citations
5,739 Views
12 Pages

Influence of Polycation Composition on Electrochemical Film Formation

  • Sabine Schneider,
  • Corinna Janssen,
  • Elisabeth Klindtworth,
  • Olga Mergel,
  • Martin Möller and
  • Felix Plamper

12 April 2018

The effect of polyelectrolyte composition on the electrodeposition onto platinum is investigated using a counterion switching approach. Film formation of preformed polyelectrolytes is triggered by oxidation of hexacyanoferrates(II) (ferrocyanide), le...

  • Article
  • Open Access
57 Citations
6,744 Views
12 Pages

12 April 2018

The effects of different extraction temperatures (4 and 80 °C) on the physicochemical properties and antitumor activity of water soluble polysaccharides (CMPs-4 and CMPs-80) from Cordyceps militaris (C. militaris) were evaluated in this study. The re...

  • Article
  • Open Access
43 Citations
7,700 Views
13 Pages

Novel Nano-Liposome Formulation for Dry Eyes with Components Similar to the Preocular Tear Film

  • Marta Vicario-de-la-Torre,
  • María Caballo-González,
  • Eva Vico,
  • Laura Morales-Fernández,
  • Pedro Arriola-Villalobos,
  • Beatriz De las Heras,
  • José Manuel Benítez-del-Castillo,
  • Manuel Guzmán,
  • Thomas Millar and
  • Irene T. Molina-Martínez
  • + 1 author

11 April 2018

Dry eye is commonly treated with artificial tears; however, developing artificial tears similar to natural tears is difficult due to the complex nature of tears. We characterized and evaluated a novel artificial tear formulation with components simil...

  • Article
  • Open Access
6 Citations
4,149 Views
18 Pages

11 April 2018

A novel model for a network of polymer chains is proposed considering the distribution of polymer chains inside the composite in this work. Some factors that influence the distribution of polymer chains are quantitatively investigated, such as extern...

  • Article
  • Open Access
15 Citations
5,017 Views
16 Pages

11 April 2018

Three solution-processable D-A-type conjugated polymers P1, P2 and P3 were successfully synthesized via the Pd-catalyzed Stille cross-coupling copolymerization approach, with 6,8-Dibromo-3,3-bis-decyl-3,4-dihydro-2H-thieno[3,4-b][1,4] dioxepine (M1)...

  • Review
  • Open Access
40 Citations
6,434 Views
26 Pages

Aliphatic Polyester Nanofibers Functionalized with Cyclodextrins and Cyclodextrin-Guest Inclusion Complexes

  • Ganesh Narayanan,
  • Jialong Shen,
  • Ramiz Boy,
  • Bhupender S. Gupta and
  • Alan E. Tonelli

11 April 2018

The fabrication of nanofibers by electrospinning has gained popularity in the past two decades; however, only in this decade, have polymeric nanofibers been functionalized using cyclodextrins (CDs) or their inclusion complexes (ICs). By combining ele...

  • Article
  • Open Access
65 Citations
9,224 Views
12 Pages

KnowVolution of the Polymer-Binding Peptide LCI for Improved Polypropylene Binding

  • Kristin Rübsam,
  • Mehdi D. Davari,
  • Felix Jakob and
  • Ulrich Schwaneberg

10 April 2018

The functionalization of polymer surfaces by polymer-binding peptides offers tremendous opportunities for directed immobilization of enzymes, bioactive peptides, and antigens. The application of polymer-binding peptides as adhesion promoters requires...

  • Article
  • Open Access
18 Citations
6,050 Views
22 Pages

Morphology, Nucleation, and Isothermal Crystallization Kinetics of Poly(Butylene Succinate) Mixed with a Polycarbonate/MWCNT Masterbatch

  • Thandi P. Gumede,
  • Adriaan S. Luyt,
  • Ricardo A. Pérez-Camargo,
  • Agnieszka Tercjak and
  • Alejandro J. Müller

10 April 2018

In this study, nanocomposites were prepared by melt blending poly(butylene succinate) (PBS) with a polycarbonate (PC)/multi-wall carbon nanotubes (MWCNTs) masterbatch, in a twin-screw extruder. The nanocomposites contained 0.5, 1.0, 2.0, and 4.0 wt%...

  • Article
  • Open Access
24 Citations
5,202 Views
14 Pages

9 April 2018

The detection technique of component defects is currently only realized to detect offline defects and online surface defects during automated fiber placement (AFP). The characteristics of stress waves can be effectively applied to identify and detect...

  • Communication
  • Open Access
4,076 Views
10 Pages

Huge Enhancement of Luminescence from a Coaxial-Like Heterostructure of Poly(3-methylthiophene) and Au

  • Bo-Hyun Kim,
  • Hojin Lee,
  • Do Hyoung Kim,
  • Seokho Kim,
  • Jinho Choi,
  • Gil Sun Lee,
  • Dong Hyuk Park and
  • Sunjong Lee

9 April 2018

Recently, the light-matter interaction at nanoscale has attracted great interest from physicists, chemists and material scientists, as it gives peculiar optical properties that couldn’t be observed at the bulk scale. The synthesis and characterizatio...

  • Article
  • Open Access
25 Citations
7,921 Views
13 Pages

9 April 2018

Skin autografts are in great demand due to injuries and disease, but there are challenges using live tissue sources, and synthetic tissue is still in its infancy. In this study, an electrocompaction method was applied to fabricate the densely packed...

  • Communication
  • Open Access
12 Citations
5,292 Views
13 Pages

In Situ Raman Spectroscopy as a Tool for Structural Insight into Cation Non-Ionomeric Polymer Interactions during Ion Transport

  • Krzysztof Artur Bogdanowicz,
  • Domenico Pirone,
  • Judit Prats-Reig,
  • Veronica Ambrogi,
  • José Antonio Reina and
  • Marta Giamberini

9 April 2018

Low-modified liquid-crystalline polyether (CP36), as a model compound, was synthesised with the purpose of preparing a membrane with columnar ionic channels. A free-standing cation permselective biomimetic membrane was successfully prepared and found...

  • Article
  • Open Access
26 Citations
6,703 Views
11 Pages

Selenide-Containing Polyimides with an Ultrahigh Intrinsic Refractive Index

  • Qilong Li,
  • Jiandong Zhang,
  • Xiangqiang Pan,
  • Zhengbiao Zhang,
  • Jian Zhu and
  • Xiulin Zhu

9 April 2018

This work developed novel selenium-containing polyimides with a high intrinsic refractive index. Four polyimides with different selenium contents and repeat unit structures were designed and synthesized via amine-dianhydride polycondensation of one o...

  • Review
  • Open Access
91 Citations
14,931 Views
26 Pages

9 April 2018

In this paper, recent developments in the chemical design of functional microgels are summarized. A wide range of available synthetic methods allows the incorporation of various reactive groups, charges, or biological markers inside the microgel netw...

  • Article
  • Open Access
27 Citations
7,716 Views
15 Pages

9 April 2018

In this study, the polysaccharides (PPs) from pomelo peels were investigated for their structural characteristics and antitumor mechanism on sarcoma S180-bearing mice. Components, FT-IR, and GC analysis showed that PPs, mainly composed of glucose, we...

  • Article
  • Open Access
30 Citations
5,065 Views
20 Pages

Effect of Polysiloxanes on Roughness and Durability of Basalt Fibres–Reinforced Cement Mortar

  • Danuta Barnat-Hunek,
  • Grzegorz Łagód,
  • Stanisław Fic and
  • Monika Jarosz-Hadam

9 April 2018

The influence of roughness and the way it affects the adhesion properties and surface free energy (SFE) of polysiloxanes hydrophobised basalt fibres–reinforced cement mortars were determined in this article. The physical properties of mortars were in...

  • Article
  • Open Access
8 Citations
5,241 Views
16 Pages

The Influence of Accelerated UV-A and Q-SUN Irradiation on the Antibacterial Properties of Hydrophobic Coatings Containing Eucomis comosa Extract

  • Małgorzata Mizielińska,
  • Urszula Kowalska,
  • Piotr Salachna,
  • Łukasz Łopusiewicz and
  • Michał Jarosz

9 April 2018

The purpose of this research was to examine the antimicrobial properties against Gram-positive bacteria, as well as the water vapour characteristic of polylactic acid (PLA) films covered with a methyl–hydroxypropyl–cellulose (MHPC)/cocoa butter carri...

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Polymers - ISSN 2073-4360