The Application of Polymer Inclusion Membranes Based on CTA with 1-alkylimidazole for the Separation of Zinc(II) and Manganese(II) Ions from Aqueous Solutions
Abstract
:1. Introduction
2. Experimental
2.1. Reagents and Apparatus
2.2. Polymer Inclusion Membrane Preparation
2.3. Characteristics of PIMs
2.4. Transport Studies
3. Results and Discussion
3.1. The Characteristics of Membranes
3.2. Transport of Zn(II) and Mn(II) ions across PIMs
3.3. Recovery of Metal
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Carrier in the CTA-o-NPPE Membrane | Effective Pore Size, µm | Tortuosity | Roughness (Rq), nm |
---|---|---|---|
1-hexyl-imidazole (1) | 0.050 ± 0.002 | 2.32 | 5.90 ± 0.05 |
1-heptyl-imidazole (2) | 0.053 ± 0.002 | 2.35 | 6.10 ± 0.05 |
1-octyl-imidazole (3) | 0.054 ± 0.002 | 2.38 | 6.50 ± 0.05 |
1-nonyl-imidazole (4) | 0.055 ± 0.002 | 2.64 | 6.70 ± 0.05 |
1-decyl-midazole (5) | 0.057 ± 0.002 | 2.81 | 7.20 ± 0.05 |
Carrier | Metal Ions | J, μmol/m2⋅s | SZn(II)/Mn(II) |
---|---|---|---|
1 | Zn(II) | 1.97 | Zn(II) > Mn(II) 19.7 |
Mn(II) | 0.10 | ||
2 | Zn(II) | 2.04 | Zn(II) > Mn(II) 15.7 |
Mn(II) | 0.13 | ||
3 | Zn(II) | 2.13 | Zn(II) > Mn(II) 14.2 |
Mn(II) | 0.15 | ||
4 | Zn(II) | 2.43 | Zn(II) > Mn(II) 12.8 |
Mn(II) | 0.19 | ||
5 | Zn(II) | 2.65 | Zn(II) > Mn(II) 11.0 |
Mn(II) | 0.24 |
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Radzyminska-Lenarcik, E.; Ulewicz, M. The Application of Polymer Inclusion Membranes Based on CTA with 1-alkylimidazole for the Separation of Zinc(II) and Manganese(II) Ions from Aqueous Solutions. Polymers 2019, 11, 242. https://doi.org/10.3390/polym11020242
Radzyminska-Lenarcik E, Ulewicz M. The Application of Polymer Inclusion Membranes Based on CTA with 1-alkylimidazole for the Separation of Zinc(II) and Manganese(II) Ions from Aqueous Solutions. Polymers. 2019; 11(2):242. https://doi.org/10.3390/polym11020242
Chicago/Turabian StyleRadzyminska-Lenarcik, Elzbieta, and Malgorzata Ulewicz. 2019. "The Application of Polymer Inclusion Membranes Based on CTA with 1-alkylimidazole for the Separation of Zinc(II) and Manganese(II) Ions from Aqueous Solutions" Polymers 11, no. 2: 242. https://doi.org/10.3390/polym11020242