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Polymers, Volume 9, Issue 5

2017 May - 32 articles

Cover Story: The copolymerization of 4-pentenoic acid and (-)-perillic acid-based pentafluorophenyl active esters with N-phenyl maleimide (PhMI) has been studied. Depending on the choice of monomer and solvent, penultimate effects were witnessed that resulted in the preferential formation of periodic ABA monomer sequences. Alternatively, copolymers could be obtained in which the active ester containing monomers are separated by an average number of PhMI units (≥ 1) that is controlled by the monomer feed ratio. Post-polymerization functionalization with amines can be used to prepare functional polymers with defined monomer sequences. By Niels ten Brummelhuis. View the paper
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Articles (32)

  • Article
  • Open Access
36 Citations
11,955 Views
19 Pages

21 May 2017

In this work, a number of chain extended moisture-curable urethane prepolymers were synthesized in order to develop isocyanate terminated urethane prepolymer formulations that would simultaneously display both high adhesive strength and low viscosity...

  • Article
  • Open Access
188 Citations
12,227 Views
24 Pages

21 May 2017

Today, none of the wound dressings available on the market is fully capable of reproducing all the features of native skin. Herein, an asymmetric electrospun membrane was produced to mimic both layers of skin. It comprises a top dense layer (manufact...

  • Article
  • Open Access
8 Citations
7,102 Views
15 Pages

Synthesis and Study of Shape-Memory Polymers Selectively Induced by Near-Infrared Lights via In Situ Copolymerization

  • Tianyu Fang,
  • Liang Fang,
  • Shunping Chen,
  • Lingyu Li,
  • Hengming Huang,
  • Chunhua Lu and
  • Zhongzi Xu

20 May 2017

Shape-memory polymers (SMPs) selectively induced by near-infrared lights of 980 or 808 nm were synthesized via free radical copolymerization. Methyl methacrylate (MMA) monomer, ethylene glycol dimethylacrylate (EGDMA) as a cross-linker, and organic c...

  • Article
  • Open Access
28 Citations
8,868 Views
18 Pages

20 May 2017

The aim of this study was to report the fabrication of porous scaffolds with pre-designed internal pores using a fused deposition modeling (FDM) method. Polycaprolactone (PCL) is a suitable material for the FDM method due to the fact it can be melted...

  • Article
  • Open Access
54 Citations
14,513 Views
23 Pages

Glass Fiber Reinforced Polymer (GFRP) Bars for Enhancing the Flexural Performance of RC Beams Using Side-NSM Technique

  • Md. Akter Hosen,
  • U. Johnson Alengaram,
  • Mohd Zamin Jumaat,
  • N. H. Ramli Sulong and
  • Kh. Mahfuz ud Darain

19 May 2017

Reinforced concrete (RC) structures require strengthening for numerous factors, such as increased load, modification of the structural systems, structural upgrade or errors in the design and construction stages. The side near-surface mounted (SNSM) s...

  • Article
  • Open Access
22 Citations
7,699 Views
13 Pages

19 May 2017

The goal of this study is to explore a new strategy to improve the mechanical and hydrophobic properties of bacterial cellulose (BC) mats. The present work is the first to report the preparation of in situ self-assembled BC nanocomposites using elect...

  • Article
  • Open Access
16 Citations
7,022 Views
23 Pages

Intensification of Electrochemical Performance of AA7075 Aluminum Alloys Using Rare Earth Functionalized Water-Based Polymer Coatings

  • Atzin C. Ferrel-Álvarez,
  • Miguel A. Domínguez-Crespo,
  • Aidé M. Torres-Huerta,
  • Hongbo Cong,
  • Silvia B. Brachetti-Sibaja and
  • Ana B. López-Oyama

18 May 2017

This work reports the effect of different amounts of ceria nanoparticles on UV resistance and barrier properties of water-based polyurethane (WPU) on glass and AA7075 aluminum alloy substrates. Hybrid coatings were synthesized from an aliphatic WPU–H...

  • Article
  • Open Access
6 Citations
6,487 Views
14 Pages

Evaluation of Amphiphilic Peptide Modified Antisense Morpholino Oligonucleotides In Vitro and in Dystrophic mdx Mice

  • Mingxing Wang,
  • Bo Wu,
  • Peijuan Lu,
  • Sapana N. Shah,
  • Jason D. Tucker,
  • Lauren E. Bollinger and
  • Qilong Lu

15 May 2017

A series of amphiphilic peptides modified PMO (Pt-PMO) were prepared, and their antisense effect and toxicity were evaluated both in vitro and in mdx mice. The results showed that the exon-skipping performance of Pt-PMO are relative to the structure...

  • Article
  • Open Access
4 Citations
8,747 Views
12 Pages

15 May 2017

In the present work we introduce a novel method to create linear and rectangular micro-patterns of gold nanoparticles (Au NPs) on poly(ethylene glycol) (PEG) hydrogels. The strategy consists of removing Au NPs from defined regions of the silicon wafe...

  • Article
  • Open Access
44 Citations
6,488 Views
15 Pages

Calcium Silicate Improved Bioactivity and Mechanical Properties of Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) Scaffolds

  • Cijun Shuai,
  • Wang Guo,
  • Chengde Gao,
  • Youwen Yang,
  • Yong Xu,
  • Long Liu,
  • Tian Qin,
  • Hang Sun,
  • Sheng Yang and
  • Ping Wu
  • + 1 author

14 May 2017

The poor bioactivity and mechanical properties have restricted its biomedical application, although poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) had good biocompatibility and biodegradability. In this study, calcium silicate (CS) was incorpora...

  • Article
  • Open Access
6 Citations
5,617 Views
13 Pages

13 May 2017

We synthesized a series of copolybenzamides (PBA) through chain-growth condensation polymerization (CGCP) of 4-(octylamino)benzoate (M4OB) and methyl 3-(4-(octyloxy)benzylamino) benzoate (M3OOB) co-monomers. Well-defined copolybenzamides with close t...

  • Article
  • Open Access
21 Citations
7,780 Views
20 Pages

pH Dependence of Chitosan Enzymolysis

  • Bi Foua Claude Alain Gohi,
  • Hong-Yan Zeng,
  • A Dan Pan,
  • Jing Han and
  • Jian Yuan

13 May 2017

As a means of making chitosan more useful in biotechnological applications, it was hydrolyzed using pepsin, chitosanase and α-amylase. The enzymolysis behavior of these enzymes was further systematically studied for its effectiveness in the productio...

  • Article
  • Open Access
28 Citations
7,437 Views
19 Pages

13 May 2017

In this study, four novel donor–acceptor systems, 4-(2,3-dihydrothieno[3,4-b][1,4]dioxin -5-yl)-N-(4-(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)phenyl)-N-(4-nitrophenyl)aniline (NETPA), 4- (4-methoxythiophen-2-yl)-N-(4-(4-methoxythiophen-2-yl)phenyl)-...

  • Article
  • Open Access
3 Citations
8,528 Views
13 Pages

11 May 2017

A 1,1-diphenylethylene (DPE) derivative with an alkoxysilyl group (DPE-SiOEt) was synthesized. It was end-capped with poly(styryl)lithium (PSLi) and then copolymerized with styrene via living anionic polymerization (LAP) in a non-polar solvent at roo...

  • Article
  • Open Access
9 Citations
6,722 Views
19 Pages

10 May 2017

Three kinds of fiber reinforced plastic (FRP) composites, including modified polyurethane resin (LGD), epoxy resin (E44) and modified unsaturated polyester resin (D33) glass-fiber reinforced plastics, were subjected to a 5000 h multi-factor accelerat...

  • Article
  • Open Access
26 Citations
7,823 Views
9 Pages

Phosphine-sulfonate based palladium and nickel catalysts have been extensively studied in ethylene polymerization and copolymerization reactions. Previously, the majority of the research works focused on the modifications of the substituents on the p...

  • Article
  • Open Access
51 Citations
8,542 Views
9 Pages

Soy-Based Adhesive Cross-Linked by Phenol-Formaldehyde-Glutaraldehyde

  • Zhigang Wu,
  • Xuedong Xi,
  • Hong Lei and
  • Guanben Du

To prepare a low-formaldehyde soy-based adhesive with good water resistance, phenol-formaldehyde modified with glutaraldehyde (PFG) with lower free phenol and free formaldehyde contents was used to cross-link the soy-based adhesive. The results showe...

  • Feature Paper
  • Article
  • Open Access
4 Citations
6,534 Views
13 Pages

Synthesis and Functionalization of Periodic Copolymers

  • Falk Kubatzki,
  • Lucas Al-Shok and
  • Niels Ten Brummelhuis

For the copolymerization of non-conjugated olefins and maleimides, it is known that under certain conditions periodic ABA monomer sequences are formed. In this work, such a copolymerization is used to create polymers which have defined (periodic) mon...

  • Article
  • Open Access
52 Citations
8,623 Views
12 Pages

Soy protein isolate (SPI)-based materials are abundant, biocompatible, renewable, and biodegradable. In order to improve the tensile strength (TS) of SPI films, we prepared a novel composite film modified with microcrystalline cellulose (MCC) and met...

  • Article
  • Open Access
66 Citations
9,723 Views
16 Pages

Effect of Maleic Anhydride-Modified Poly(lactic acid) on the Properties of Its Hybrid Fiber Biocomposites

  • Abubakar Umar Birnin-Yauri,
  • Nor Azowa Ibrahim,
  • Norhazlin Zainuddin,
  • Khalina Abdan,
  • Yoon Yee Then and
  • Buong Woei Chieng

This work investigated the effect of maleic anhydride (MA)-modified poly(lactic acid) (PLA), which is melt-blended with different untreated and aqueous borax (BR)-treated hybrid oil palm empty fruit bunch fibers (EFBF)/Kenaf core fibers (KCF), and co...

  • Article
  • Open Access
29 Citations
14,775 Views
11 Pages

Syneresis in Gels of Highly Ferulated Arabinoxylans: Characterization of Covalent Cross-Linking, Rheology, and Microstructure

  • Ana M. Morales-Burgos,
  • Elizabeth Carvajal-Millan,
  • Yolanda L. López-Franco,
  • Agustín Rascón-Chu,
  • Jaime Lizardi-Mendoza,
  • Norberto Sotelo-Cruz,
  • Francisco Brown-Bojórquez,
  • Alexel Burgara-Estrella and
  • Martin Pedroza-Montero

Arabinoxylans (AXs) with high ferulic acid (FA) content (7.18 µg/mg AXs) were cross-linked using laccase. Storage (G’) modulus of AX solutions at 1% (AX-1) and 2% (AX-2) (w/v) registered maximum values of 409 Pa and 889 Pa at 180 min and 83 min, resp...

  • Article
  • Open Access
46 Citations
7,632 Views
11 Pages

The objective of this work is to characterize and investigate the blood compatibility of polyurethane (PU)/mustard oil composites fabricated using electrospinning technique. The fabricated scaffold was characterized using scanning electron microscopy...

  • Article
  • Open Access
23 Citations
8,889 Views
11 Pages

Highly Branched poly(5-amino-1-pentanol-co-1,4-butanediol diacrylate) for High Performance Gene Transfection

  • Ming Zeng,
  • Dezhong Zhou,
  • Singwei Ng,
  • Jonathan O′Keeffe Ahern,
  • Fatma Alshehri,
  • Yongsheng Gao,
  • Luca Pierucci,
  • Udo Greiser and
  • Wenxin Wang

The top-performing linear poly(β-amino ester) (LPAE), poly(5-amino-1-pentanol-co-1,4-butanediol diacrylate) (C32), has demonstrated gene transfection efficiency comparable to viral-mediated gene delivery. Herein, we report the synthesis of a series o...

  • Article
  • Open Access
28 Citations
8,776 Views
18 Pages

Synthesis, Characterization and the Solvent Effects on Interfacial Phenomena of Jatropha Curcas Oil Based Non-Isocyanate Polyurethane

  • Mhd. Abd. Cader M. Haniffa,
  • Yern Chee Ching,
  • Cheng Hock Chuah,
  • Yong Ching Kuan,
  • De-Shin Liu and
  • Nai-Shang Liou

Non-isocyanate polyurethane (NIPU) was prepared from Jatropha curcas oil (JCO) and its alkyd resin via curing with different diamines. The isocyanate-free approach is a green chemistry route, wherein carbon dioxide conversion plays a major role in NI...

  • Article
  • Open Access
82 Citations
17,122 Views
12 Pages

A Modified Ceramic-Coating Separator with High-Temperature Stability for Lithium-Ion Battery

  • Chuan Shi,
  • Jianhui Dai,
  • Chao Li,
  • Xiu Shen,
  • Longqing Peng,
  • Peng Zhang,
  • Dezhi Wu,
  • Daoheng Sun and
  • Jinbao Zhao

29 April 2017

In this work, the ceramic coating separator (CCS-CS) prepared with polyethylene (PE) separator, Al2O3 inorganic particles, carboxymethyl cellulose sodium (CMC) and styrene-butadiene rubber (SBR) mix binders is further modified by coating with a thin...

  • Review
  • Open Access
126 Citations
12,537 Views
16 Pages

Biomedical and Microbiological Applications of Bio-Based Porous Materials: A Review

  • T. M. S. Udenni Gunathilake,
  • Yern Chee Ching,
  • Kuan Yong Ching,
  • Cheng Hock Chuah and
  • Luqman Chuah Abdullah

29 April 2017

Extensive employment of biomaterials in the areas of biomedical and microbiological applications is considered to be of prime importance. As expected, oil based polymer materials were gradually replaced by natural or synthetic biopolymers due to thei...

  • Article
  • Open Access
7 Citations
6,271 Views
19 Pages

Systematic Study of a Library of PDMAEMA-Based, Superparamagnetic Nano-Stars for the Transfection of CHO-K1 Cells

  • Ullrich Stahlschmidt,
  • Valérie Jérôme,
  • Alexander P. Majewski,
  • Axel H.E. Müller and
  • Ruth Freitag

28 April 2017

The introduction of the DNA into mammalian cells remains a challenge in gene delivery, particularly in vivo. Viral vectors are unmatched in their efficiency for gene delivery, but may trigger immune responses and cause severe side-reactions. Non-vira...

  • Article
  • Open Access
23 Citations
7,262 Views
19 Pages

CAGW Peptide Modified Biodegradable Cationic Copolymer for Effective Gene Delivery

  • Xinghong Duo,
  • Jun Wang,
  • Qian Li,
  • Agnaldo Luis Neve,
  • Mary Akpanyung,
  • Abdelilah Nejjari,
  • Zaidi Syed Saqib Ali,
  • Yakai Feng,
  • Wencheng Zhang and
  • Changcan Shi

28 April 2017

In recent years, gene therapy has become a promising technology to enhance endothelialization of artificial vascular grafts. The ideal gene therapy requires a gene carrier with low cytotoxicity and high transfection efficiency. In this paper, we prep...

  • Article
  • Open Access
69 Citations
8,983 Views
18 Pages

28 April 2017

In this article, three-dimensional (3D) microstuctured poly(3,4-ethylenedioxythiophene) (PEDOT)/reticulated vitreous carbon (RVC) composite electrodes with varying amount of PEDOT loadings were successfully prepared by electrochemical deposition meth...

  • Article
  • Open Access
19 Citations
9,092 Views
15 Pages

Surface Patterning of Gold Nanoparticles on PEG-Based Hydrogels to Control Cell Adhesion

  • Fang Ren,
  • Cigdem Yesildag,
  • Zhenfang Zhang and
  • Marga C. Lensen

26 April 2017

We report on a versatile and easy approach to micro-pattern gold nanoparticles (Au NPs) on 8-arm poly(ethylene glycol)-vinyl sulfone thiol (8PEG-VS-SH) hydrogels, and the application of these patterned Au NPs stripes in controlling cell adhesion. Fir...

  • Review
  • Open Access
173 Citations
12,963 Views
24 Pages

Chemo-Electrical Gas Sensors Based on Conducting Polymer Hybrids

  • Seon Joo Park,
  • Chul Soon Park and
  • Hyeonseok Yoon

26 April 2017

Conducting polymer (CP) hybrids, which combine CPs with heterogeneous species, have shown strong potential as electrical transducers in chemosensors. The charge transport properties of CPs are based on chemical redox reactions and provide various che...

  • Article
  • Open Access
39 Citations
7,763 Views
12 Pages

Development of Defatted Soy Flour-Based Adhesives by Acid Hydrolysis of Carbohydrates

  • Peitao Zheng,
  • Yuqi Li,
  • Feng Li,
  • Yangting Ou,
  • Qiaojia Lin and
  • Nairong Chen

25 April 2017

Soy-based adhesives are attracting increasing attention in recent years because they are a renewable and environmentally friendly raw material. Defatted soy flour (DSF), comprised of 50% protein and 40% carbohydrate, is the most widely used raw mater...

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Polymers - ISSN 2073-4360