This study investigates electrodialysis (ED) performance for desalination and concentration of monovalent salts (NaCl, NH
4Cl, KCl, and NaNO
3) at varying mass concentrations. Systematic comparisons of current efficiency (
η), energy consumption, water loss, desalination rate
ηsalt,
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This study investigates electrodialysis (ED) performance for desalination and concentration of monovalent salts (NaCl, NH
4Cl, KCl, and NaNO
3) at varying mass concentrations. Systematic comparisons of current efficiency (
η), energy consumption, water loss, desalination rate
ηsalt, and other key parameters reveal salt-specific behaviors and process determinants. Experimental results show distinct performance hierarchies across operational phases. In the 1% desalination phase, KCl achieved optimal performance with 95.3% salt removal, a dilute
η of 99.96%, a production capacity (
Q) of 54.95 L/(h·m
2), and a unit energy consumption (
Eu) of 3.24 kWh/t. This performance outshone that of NaCl (
ηsalt = 95.2%) and NaNO
3 (
ηsalt = 89.5%), with NH
4Cl showing the lowest value (80.6%) in this phase. This trend inversely correlated with cation hydration energies. On the other hand, in the 3% concentration phase, NH
4Cl demonstrated superior performance with a concentrate
η of 83.49%, a flux of 35.71 L/(h·m
2), and the lowest
Eu (5.30 kWh/t), despite a lower concentration factor (5.33) than NaNO
3 (6.48). These findings highlight that KCl is ideal for energy-efficient brine treatment (<3% salinity), while NH
4Cl is better suited to high-purity recovery. Although NaNO
3 has a high
Eu during concentration, it is favorable for applications where minimizing energy usage is critical.
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