2.1. Sound-Absorbing Composites Based on Natural Materials
The increasing environmental concerns and stringent regulations on synthetic materials have spurred significant interest in developing sustainable alternatives for sound insulation and absorption. In this context, the use of natural materials and residues of natural materials is of significant interest both for environmental protection and for the creation of environmentally friendly new composite materials.
Wood composites incorporating sustainable and recycled components from agricultural and industrial waste streams offer a viable alternative to traditional soundproofing materials. Hybridized natural fibers, such as pineapple, areca, and ramie, reinforced with wood-based industrial tea waste and epoxy matrices, have demonstrated effective sound absorption [
31].
One study [
32] created panels from various wood waste species (pine, oak, mahogany, and olive tree pruning) using different assembly techniques and adhesives. These panels demonstrated thermal and acoustic performance comparable to commercial products, with oak panels exhibiting particularly good sound absorption (α peak of 0.9) and insulation properties (transmission loss up to 11 dB).
The incorporation of wood plastic composite (WPC) into structural wood walls has been shown to affect sound insulation performance [
33]. This study found that WPC can be a viable substitute for traditional wood studs and that the type of external panel material significantly influences the overall sound insulation of the wall. Further improvements were achieved by using sound-absorbing materials as elastic strips.
The utilization of stranded driftwood residues as a building material with thermo-acoustic properties is explored in another study [
34]. The researchers investigate the thermal and acoustic characteristics of both unbound and mineralized (cement-based additive) samples. The results demonstrate that stranded driftwood residues, especially in their mineralized form, possess competitive thermo-acoustic properties, showing promise as a sustainable building material.
Many recent studies explore the potential of natural fibers in acoustic applications. One study evaluated the acoustic and mechanical properties of coir (Cocos nucifera) and fique (Furcraea Agavaceae) fibers and panels, finding that fique generally exhibited superior performance in most tests, particularly in high-frequency sound absorption due to its fiber diameter [
35]. Another study utilized water hyacinth and pineapple leaf fibers, combined with polylactic acid (PLA), in 3D-printed acoustic panels [
36]. This research demonstrated high sound absorption coefficients (α-max > 0.5 at high frequencies) at low fiber loadings, showcasing the potential for waste mitigation and sustainable material usage. The successful 3D printing of these biopolymer composites highlights the potential of additive manufacturing in creating lightweight, customizable acoustic panels.
The study of [
37] explored the use of waste flax fibers as the core material in multilayered panels, sandwiched between perlite layers of varying grain sizes. This approach resulted in panels with varying mechanical, thermal, and acoustic properties. The study found that perforation of the panels’ surface further enhanced the sound absorption coefficients, achieving values up to 0.95 at specific frequencies. This highlights the potential for optimizing acoustic performance through material selection and panel design.
Three-dimensional materials are of particular interest for light and effective soundproofing. A study [
38] investigated the sound insulation performance of 3D woven hybrid fabric-reinforced composites incorporating jute, E-glass, and biomass fillers such as coffee husk and waste palm fiber. These composites showed significantly enhanced sound insulation, with jute-based composites achieving noise reduction levels as high as 44.9 dB at 10,000 Hz. The study concluded that both coffee husk and palm fiber are effective and eco-friendly fillers.
Another study [
39] investigated the acoustic absorption of date palm midribs-based fabric acoustic panels. This research found that the panel thickness and density significantly influenced absorption, with optimal performance observed in certain configurations. These panels offer a sustainable and aesthetically pleasing alternative for interior design applications. Similarly, the potential of sunflower straw as a bio-based sound absorber was explored [
40].
The study of [
41] investigated the acoustic, mechanical, and thermal properties of epoxy composites reinforced with cotton, coconut, and sugarcane fibers. The results indicated that increasing the fiber content enhanced sound absorption, with coconut fiber composites exhibiting the highest sound absorption coefficient. Another study utilized pineapple leaf fiber and silica aerogel in mortars, demonstrating that the addition of pineapple leaf fiber offset the compressive strength reduction caused by silica aerogel [
42].
Table 1 summarizes the acoustic properties of certain mineral, bio-based, and fiber composites.
The reported sound absorption coefficients (α) of various natural fiber composites reveal significant variations in performance, influenced by the material composition, structural design, and tested frequency ranges (
Figure 1).
Sheep wool demonstrates exceptional acoustic efficiency, achieving a peak α of 0.903 at 524 Hz, likely due to its porous, fibrous structure that effectively dissipates sound energy. Similarly, epoxy-based composites hybridized with pineapple/areca/ramie fibers and tea waste exhibit strong broadband absorption (α = 0.63 across 600–6300 Hz), attributed to their multi-scale porosity and reinforced polymer matrix. Paper sludge–clay composites and larch bark panels also perform well (α = 0.55 and 0.5, respectively), with their moderate absorption linked to the particle density and air gap integration. In contrast, mycelium-based composites show limited low-frequency absorption (α = 0.2 at 125–1000 Hz), suggesting a need for structural modifications (e.g., increased pore size or layered designs) to enhance performance. Notably, sugarcane, coconut, and cotton fiber composites exhibit lower absorption (α < 0.2 at 1600 Hz), likely due to insufficient fiber density or untreated surface morphology, highlighting opportunities for chemical or mechanical fiber treatments to improve energy dissipation.
Mycelium-based composites, produced through bio-based manufacturing processes and combined with wood fibers, represent a novel approach to creating sound-absorbing structures from waste paper substrates [
45]. The acoustic performance of these composites is influenced by material properties, such as the particle size, orientation, and density, as demonstrated in studies on larch bark panels [
46]. The inclusion of air gaps in paper sludge and clay composites with wood fibers has been shown to significantly enhance sound absorption [
43]. Their applications span building insulation, automotive components, and noise barriers, highlighting their potential for widespread adoption [
47].
Sheep wool and orange tree pruning fibers have also been utilized in wood composite sandwich panel structures, showcasing the versatility of waste materials [
44,
48].
Table 2 outlines a SWOT analysis based on the reviewed information about natural fiber-reinforced composites for acoustic applications.
The study utilizing
Arundo donax L. [
49] demonstrates a viable pathway for converting agricultural waste into functional building materials. The significant finding regarding the impact of the particle size on both the sound absorption and mechanical properties emphasizes the need for precise control over the processing parameters to optimize the final product. Larger particle sizes (2–4 mm) yielded better sound absorption in the Class D range, while smaller particles (0.25–1 mm) resulted in superior sound transmission loss, indicating potential applications in different acoustic scenarios.
The research employing cork granulates and egg white proteins [
50] highlights the potential of bio-based composites. The use of microwave foaming provides an energy-efficient method for creating lightweight, open-cell structures, improving thermal and acoustic insulation. The investigation into varying compositions and additives (eggshells and intumescent fillers) shows a path toward optimizing both acoustic performance and fire resistance. Future work should explore the scalability and cost-effectiveness of this approach for broader application in the construction sector.
The study utilizing coffee waste [
51] showcases a compelling example of a circular economy strategy. By combining coffee waste with a resin binder, sound-absorbing panels were created and tested in a real-world café setting. The observed reduction in reverberation time (RT) and improvement in acoustic definition (D50), quantified through ODEON simulations, confirm the effectiveness of this material.
An interesting approach in the use of foxtail millet husk powder in polypropylene composites demonstrates the potential of agricultural waste [
52]. The study showed that varying the fiber mass content and density affected sound absorption, with optimal combinations achieving a noise reduction coefficient (NRC) of 0.7 and an average sound absorption coefficient (SAC) of 0.63, comparable to commercial panels. The incorporation of air gaps and rigid backing materials further improved low-frequency sound absorption.
A research work [
53] investigated the use of almond skin residues, a readily available agricultural byproduct, to produce building panels with enhanced acoustic and thermal properties. By incorporating different binder solutions (polyvinyl acetate glue and gum Arabic), researchers explored the correlation between material composition and acoustic (air-flow resistivity and sound absorption coefficient), thermal (conductivity, diffusivity, and volumetric heat capacity), and hygrothermal (water vapor permeability) performance.
A study [
54] that analyzed a bamboo particleboard coated with polyurethane varnish revealed that the coating significantly impacts the surface characteristics and acoustic properties. While the coating improves low-frequency sound absorption, it reduces high-frequency performance. The study highlights the importance of optimizing the coating thickness to achieve the desired acoustic outcomes. The effect of the board density on the noise reduction coefficient is also investigated, demonstrating the significance of the material density in the overall acoustic performance.
Bio-based polyurethane foam (PUF) composites offer another avenue for sustainable acoustic panel development [
55]. This study integrates nanofillers like carboxy-methyl cellulose (CMC), magnesium oxide (MgO), and bamboo charcoal (BC) into PUF using a PVA and borax slime matrix. Response surface methodology (RSM) is used to optimize the nanofiller weight percentages to maximize the noise reduction coefficient (NRC). The results showcase the potential of bio-based PUF composites for effective sound absorption, offering a sustainable solution for building interiors.
The study of [
56] explored the use of biomass fiber-reinforced polyester resins combined with tailed cavity resonators to improve sound absorption. The researchers employed an impedance tube technique to test various configurations, including single and multiple tailed cavities with added fibrous layers. The results demonstrated that tailored cavity inclusions can enhance sound absorption performance across a range of frequencies, particularly with hemp and kenaf fibers. The findings suggest that this method can create effective sound absorbers for interior applications.
The study of [
57] explored the acoustic performance of rice husk–PU-reinforced composite sound barriers, utilizing finite element analysis (ANSYS) to determine the sound absorption coefficients and transmission loss across a 0–4000 Hz frequency range. The results showed superior sound absorption at lower frequencies compared to existing data, and higher transmission loss at higher frequencies.
2.2. Sound-Absorbing Composites Based on Synthetic and Secondary Raw Materials
In contrast to bio-based approaches, research also investigates the optimization of synthetic materials for acoustic performance. One study examined the soundproofing properties of poly (vinyl chloride) (PVC) multilayered composites with alternating foam and film layers [
58]. The findings emphasized the importance of acoustic impedance mismatch and layer number in achieving high sound transmission loss (STL), suggesting avenues for optimizing existing materials. Another study focusing on a modular sandwich panel system for non-load-bearing walls tested various face sheet materials (gypsum plasterboard, fire-resistant gypsum plasterboard, and magnesium oxide board) with an extruded polystyrene (XPS) core [
59]. This research demonstrates the potential for improving the acoustic performance of modular wall systems through material selection and design optimization.
The utilization of industrial waste offered environmental benefits by reducing waste volume and mitigating noise pollution. The paper of [
60] focused on incorporating waste materials into composite panels. The use of waste tire rubber (WTR) in plywood composites showed a significant improvement in sound insulation properties with increasing WTR and adhesive content. The study also demonstrated the influence of pressing methods and veneer arrangement on the acoustic performance. Similarly, a study employed fly ash (FA) and WTR granules with cement to create sound-absorbing panels [
61]. This research demonstrated significant improvements in the average sound absorption coefficient (ASAC) and noise reduction coefficient (NRC) with varying proportions of the waste materials.
Several studies focus on the use of agricultural and industrial waste streams for acoustic panel production. One paper investigates the creation of composite acoustic panels using waste tire textile fibers (WTTFs) and paper sludge (PS) bound with polyvinyl acetate (PVA) [
62]. The researchers found that varying the proportions of these waste materials significantly impacted the panels’ sound absorption and transmission loss. Optimal combinations yielded average sound absorption coefficients (αavg) as high as 0.50 and a sound transmission loss (TLeq) up to 28.3 dB, demonstrating the viability of these waste materials in acoustic applications.
The use of recycled plastics also shows promise. A study investigated the creation of acoustic panels from recycled plastic bottles and PET felt [
63]. Beyond demonstrating promising acoustic properties, this research prioritized biocompatibility, performing antifungal resistance tests, VOC emission assessments, and cell viability experiments to ensure the safety of the material for use in healthcare environments, where noise reduction is crucial.
The utilization of recycled materials is also a significant theme. A study explored the potential of fly ash, a waste product from thermal power plants, and recycled polyethylene terephthalate (PET) fibers in the creation of lightweight composite aerogels [
64]. These aerogels exhibited low density, high porosity, and good thermal and acoustic insulation properties, demonstrating a promising approach to waste reduction and resource recovery in the construction sector.
The potential of incorporating waste rubber particles into concrete has also been explored [
65]. This research analyzed the use of rubber buffing dust (RBD) and recovered crumb rubber (RCR) as partial replacements for natural fine aggregate. While the incorporation of RBD negatively impacted certain mechanical properties, RCR-modified concrete maintained sufficient compressive strength and exhibited improved sound absorption, particularly at thicknesses of 15 and 25 mm. This study demonstrates the possibility of diverting significant waste streams while potentially improving a material’s acoustic performance.
The sound insulation properties of wood waste tire rubber composite (WRCP) panels were assessed [
66]. This research highlighted the influence of the rubber content and adhesive type on the sound insulation performance, demonstrating that increased rubber and PMDI adhesive content led to improved soundproofing properties.
The paper of [
67] investigates the soundproofing performance of panels made from acrylonitrile butadiene styrene (ABS) chips, a waste product from the milling process. The research analyzes factors influencing sound insulation, including panel thickness, distance from the sound source, and receptor position. The results indicate that the ABS panels exhibit promising acoustic properties, offering a viable and eco-friendly alternative for sound barrier construction.
Another study [
68] focuses on repurposing plastic caps, another common waste product. The researchers create prototypes using various combinations of plastic caps and sustainable materials like jute, textile waste, hemp felt, and cork board. Their findings show that these panels can achieve sound reduction indices up to 30 dB at certain frequencies and near-unity sound absorption coefficients in tailored configurations, indicating their potential application as lightweight sound insulation elements or for room acoustic conditioning.
The study of [
69] compares the thermal and environmental performance of panels made from various industrial and agricultural waste materials, including cork scraps, rice husk, coffee chaff, and end-of-life granulated tires. The results based on LCA methodology indicate that combinations of cork, rice husk, and coffee chaff offer a good balance between thermal performance and minimal environmental impact.
The use of recycled materials is another significant area of research. A study examined the thermal and acoustic properties of panels made from cardboard packaging, egg boxes, polyester, and felt [
70]. These panels demonstrated acceptable thermal and acoustic performance (Rw = 19 dB, αw = 0.30, NRC = 0.64), showcasing the potential for reusing waste materials in construction. Another study focused on the reuse of waste textile face masks made of polyamide fabric [
71], evaluating their thermal, acoustic, and fire performance. The results indicated that the recycled polyamide fiber offers comparable thermal insulation to glass or mineral wool, and good sound absorption at medium and high frequencies. The research also investigated recycled bovine leather cutting waste for panel production [
72], evaluating the panels’ thermal, acoustic, and hygrothermal properties. The results indicated good sound absorption and transmission loss properties, demonstrating the feasibility of using leather waste in acoustic applications. Finally, the acoustic properties of virgin cork were investigated [
73], revealing its potential as a sustainable acoustic absorber, particularly with the outer bark facing upwards, exhibiting high sound absorption coefficients in the 1–5 kHz range.
A different approach utilized post-industrial textile waste (cotton/polyester) and natural rubber to create sound insulation materials [
74]. The study optimized the molding parameters to achieve sound absorption and noise reduction coefficients comparable to commercially available panels. Increased panel thickness further enhanced the sound insulation properties. Finally, a study assessed the acoustic properties of sawdust and fine sharp sand for soundproof security doors [
75]. The results indicated that this locally sourced and readily available material provided comparable acoustic performance to imported products.
The study using wool waste [
76] showed high sound absorption coefficients, particularly above 500 Hz, with the thermal conductivity comparable to conventional materials. The use of chitosan and gum Arabic as binders adds another dimension to the sustainability of the approach. The study on recycled denim [
77] shows impressive results, achieving high sound absorption coefficients and demonstrating the potential for optimizing properties through a varying thickness, density, and resin content. The use of response surface methodology (RSM) is noteworthy, demonstrating a systematic approach to material optimization.
Waste cotton fabric (WCF), a significant textile waste stream, has shown promise as a reinforcing agent in polylactic acid (PLA) composites for construction applications [
78]. The researchers investigated the effects of the processing parameters on the composite’s mechanical and thermal properties and demonstrated that combining the WCF/PLA composite with porous sound-absorbing materials resulted in enhanced sound absorption capabilities. This approach offers a viable route for textile waste recycling while contributing to improved building acoustics.
2.3. Bio-Fiber and Wood Composites Based on Mineral Binder
The main aim of this chapter is to provide a systematic and thorough assessment of bio-fiber and wood-based composites that employ mineral binders. This research aims to clarify the fundamental mechanisms that dictate the physical and mechanical properties of these composites through the analysis of the current literature and experimental data. The primary objective is to find and assess effective solutions for boosting the performance attributes of wood–wool composites, concentrating on improving their structural integrity, durability, and functional efficiency.
The idea of combining vegetable fibrous filler and mineral binder has such positive properties as environmental friendliness, mechanical stability, fire resistance, and good acoustic characteristics. Based on modern requirements, the advantage of this composition is its low impact on the environment during production and operation, reducing energy consumption and carbon dioxide emissions throughout the entire life cycle of the material [
79,
80] (
Table 3).
Building materials derived from plant-based resources, including various bio-fiber components and wood particles, have been utilized by humans since ancient times. Among the earliest examples are wall materials created by combining natural clay with straw. Clay, representing the most basic form of mineral binder [
81], exhibits certain limitations, such as low water resistance and a tendency to soften under humid conditions. However, upon drying, clay forms a relatively strong monolith, wherein straw acts as both a filling and reinforcing agent. This combination also imparts favorable thermal and acoustic insulation properties to the material. A notable advantage of mineral–organic composites is their enhanced fire resistance compared to materials composed solely of organic raw materials, such as wood.
When examining wood–cement and analogous materials, it is essential to consider historical context, particularly the production and use of such materials in earlier periods. Historically, these materials were often employed due to the limited availability of alternative options and the absence of advanced technologies for producing polymers and composites. In contrast, contemporary interest in developing and utilizing materials with natural fillers is primarily motivated by the growing emphasis on environmental sustainability. Modern efforts are driven by the aspiration to reduce the ecological impact, promote a cleaner environment, and minimize the carbon footprint of construction materials. This shift reflects a broader commitment to sustainable practices and the development of eco-friendly solutions in material science.
The most recent publications cover a wide range of cement-bonded materials. The table below shows the trends in the materials under study and the main directions of research into their properties (
Table 4).
A summary of the properties of the submitted materials based on published data is shown in
Table 5.
The data indicate that compressive strengths for these materials typically range from 15 to 55 MPa, showcasing certain formulations’ potential to effectively support structural demands. For instance, the upper echelon of compressive strength seen in modified wood–cement composites, which can exceed 50 MPa, exemplifies how targeted treatments and formulations can optimize performance, ensuring they meet or exceed that of traditional concrete. Flexural strength, often a critical factor for load-bearing applications, generally demonstrates variability based on the wood content. With values ranging from 5 to 28 MPa, the trends reveal that while increased wood content can lead to reduced flexural strength, innovative mixture designs are mitigating this issue. The findings suggest that incorporating smaller wood particles or using advanced binding agents can improve the overall mechanical integrity, allowing for a balanced approach that prioritizes sustainability without significantly compromising strength. Thermal conductivity data present another compelling aspect of these composites. The lower thermal conductivity observed in wood–cement composites, particularly those containing lightweight aggregates, indicates an enhanced potential for energy efficiency in building applications. This property is increasingly significant as the construction industry shifts toward designing energy-efficient structures that comply with strict environmental standards. Water absorption rates vary across composite types, with some formulations reaching absorption levels as high as 25%. This variance often correlates with the presence of untreated wood fibers, which can compromise durability if not addressed. However, treatments and the proper formulation of mixtures can significantly improve moisture resistance, making wood–cement composites more viable for outdoor applications.
One of the most widely used wood–cement materials in the 20th century was sawdust concrete, a composite consisting of sawdust, sand, Portland cement as the binder, and lime as an additive. This material exhibited favorable mechanical properties, including a compressive strength ranging from 1 to 10 MPa, making it suitable for monolithic applications in low-rise construction. However, sawdust concrete also presented notable limitations, particularly its high density (700–1400 kg/m
3), which contributed to suboptimal thermal insulation properties, as evidenced by a thermal conductivity coefficient (λ) exceeding 0.2 W/(m·K). The incorporation of porous concrete also shows promise. A study investigating different mix designs of porous concrete, using various aggregates, demonstrated weighted absorption coefficients (αw) ranging from 0.30 to 0.75, depending on the thickness and mounting conditions [
100]. This highlights the potential for this material to be effective in indoor and outdoor acoustic applications.
One of the most widely used wood–cement composite materials at the end of the 20th century was arbolite. The name “arbolite” is derived from the Latin word arbor (meaning “wood”) and the Greek word λίθος (meaning “stone”). This material utilizes specially prepared wood chips with a specific granulometric composition and shape as the organic filler. The structural framework of arbolite is formed by wood fibrous particles bonded together by hardened cement paste (HCP), effectively combining the advantageous properties of both wood and concrete. Among its notable characteristics is its fire resistance; arbolite is difficult to ignite and, when exposed to high temperatures, it smolders rather than burning with an open flame. Additionally, arbolite contributes to a healthy indoor microclimate and serves as an excellent substrate for plastering and the application of other finishing materials. Selected physical and mechanical properties of arbolite blocks produced by the Multibau company (Riga, Latvia) are presented in (
Table 6).
2.4. The Use of Alternative Binder in Bio-Fiber and Wood Composites
Despite the widespread use and climatic resilience of wood–cement compositions, several challenges persist, particularly concerning the interfacial zone between wood particles and the cement matrix. This interface often represents a weak point, affecting the overall performance and durability of the material. Additionally, the reliance on Portland cement as a binder poses significant environmental concerns due to its substantial carbon dioxide emissions during production. Projections indicate that global cement production will continue to rise until at least 2050 [
101], exacerbating its environmental impact. In response, researchers and policymakers are actively exploring strategies to reduce cement consumption in materials and to replace Portland cement clinker with more sustainable alternative binders [
102].
To address environmental challenges and explore effective alternatives to Portland cement clinker, a study [
103] investigated the production of wood–cement composites using porous bottom ash as a partial replacement for cement. The findings revealed that while the incorporation of bottom ash led to a reduction in bulk density and compressive strength, it also resulted in an increased water demand during the mixing process. This trade-off highlights the need for further optimization to balance the ecological benefits of reduced cement usage with the mechanical and physical properties required for practical applications.
It is important to highlight that Portland cement and cement-based binders create a dense microstructure in the paste and ensure a high-quality interfacial zone with plant fibers. However, these binders do not facilitate moisture exchange within the material, which is a critical factor for envelope structures to maintain an optimal indoor microclimate and prevent the formation of dew points within the wall. In contrast, hemp–lime compositions address these requirements effectively [
104]. Traditional hemp concrete is composed of hemp shives and lime binder (hydrated lime, Ca(OH)
2), which hardens through carbonation, forming a monolithic structure. The density of hemp–lime materials typically does not exceed 750 kg/m
3, and their compressive strength is generally less than 1 MPa [
105,
106]. While these properties are sufficient to provide self-bearing capacity and adequate thermal insulation for buildings, the low final strength and slow hardening rate of lime–hemp composites remain significant drawbacks.
The energy efficiency and hygrothermal properties of hemp–lime insulation materials have been extensively investigated and validated under real-world conditions [
107]. Measurements were conducted using a specially designed data logger equipped with temperature and humidity sensors, allowing for precise monitoring of the material’s performance. A comparison between theoretical and experimental U-values revealed slight discrepancies, which can be attributed to the moisture buffering capacity of hemp–lime composites. This property enhances thermal comfort by regulating indoor humidity levels. The findings demonstrate that bio-based materials, such as hemp–lime, are highly effective as insulation in civil engineering applications, offering both energy efficiency and improved indoor environmental quality.
To enhance the mechanical properties of hemp–lime composites, hydraulic lime and mineral additives that promote pozzolanic reactions can be incorporated, thereby increasing the material’s final strength [
105]. Research has demonstrated that replacing lime with magnesium oxychloride cement (MOC) significantly improves the strength [
107] and accelerates the hardening process. Additionally, life cycle assessment studies have indicated that both magnesium-based and lime-based bio-composites exhibit similarly low environmental impacts, making them sustainable alternatives [
108].
Innovative advancements have also led to the development of hemp composite boards using a magnesium-based binder. These boards, measuring 500 by 1200 mm with thicknesses ranging from 25 to 50 mm, were designed primarily as shell elements for building frames. The interior spaces between the boards are filled with a lightweight lime–hemp mixture, creating a system that combines structural integrity with excellent thermal insulation and acoustic properties. This approach ensures that the fiber composite not only supports the building’s framework but also enhances the energy efficiency and comfort of the enclosed structure.
It is important to emphasize that the physical and mechanical properties of natural fiber composites are significantly influenced by the shape and size of the natural fiber material [
109]. These factors affect the composite’s structural integrity, density, and overall performance. To address the inherent hydrophilicity of natural fibers, such as hemp shives, and improve their water resistance, advanced modification techniques can be employed. One effective approach involves the application of water-repellent sol–gel coatings, which create a protective barrier on the fiber surface, enhancing its durability and resistance to moisture [
110]. Such modifications not only improve the material’s performance in humid conditions but also expand its potential applications in construction and other industries.
By adjusting the proportions between the binder and the filler, a wide range of densities can be achieved, typically ranging from 200 to 600 kg/m
3 or higher. Studies have shown that lightweight hemp composites exhibit a thermal conductivity coefficient of approximately 0.55 W/m·K in a dry state, while denser composites (600 kg/m
3) demonstrate a significantly lower thermal conductivity of 0.16 W/m·K [
111]. However, it has been observed that the thermal conductivity coefficient can increase substantially (by 50–70%) at relative humidity levels of 75% or higher. This phenomenon is attributed to the high hygroscopicity of the material, which can have both beneficial and detrimental effects depending on the application.
The aforementioned composites were formulated using a magnesium oxychloride cement (MOC) binder. The ratio of MgO to hemp shives varied from 0.5 (for a density of 200 kg/m3) to 3 (for a density of 600 kg/m3). The preparation of the hemp composite involved several steps: firstly, the hemp shives were pre-moistened, then mixed with dry MgO powder. Subsequently, a MgCl2·6H2O water solution (in a 1:1 ratio) was added at 63% by mass of MgO, and the mixture was thoroughly blended in a laboratory pan mixer. The resulting formulation was poured into oiled plywood formworks, subjected to a load of 2 kN/m2, and cured for 24 h.
It is important to note that magnesium oxychloride cement (MOC) exhibits excellent adhesion to organic fillers, making it a suitable binder for bio-based composites. However, MOC has lower water resistance compared to Portland cement, and its high hygroscopicity poses a significant limitation, particularly for applications in external structures exposed to high relative humidity. Research has demonstrated that the incorporation of certain mineral additives and salts can substantially enhance the water resistance of MOC-based composites. For instance, the properties of MOC cement modified with rice husk silica have been explored in [
112], while the influence of fly ash and silica fume on improving the water-resistant properties of MOC has been investigated in [
113]. Additionally, studies have shown that replacing the activating magnesium chloride solution with a magnesium sulfate solution can significantly reduce the material’s hygroscopicity, thereby improving its performance in humid conditions [
114].
Other researchers have demonstrated that gypsum can also serve as an effective binder in bio-fiber composites [
115]. In such studies, hemp fibers were utilized to produce reinforced gypsum composites, which exhibited significant improvements in mechanical properties compared to unreinforced gypsum. Specifically, the inclusion of hemp reinforcement increased the flexural strength by up to 320% and enhanced the energy absorption capacity, indicating a strong interfacial bond between the gypsum matrix and the plant fibers. Another promising alternative binder is magnesium phosphate cement (MPC), which has been explored for its potential in bio-composite applications [
116]. MPC offers advantages such as rapid hardening, high early strength, and good durability, making it a viable option for specialized construction needs.
An innovative approach involves the use of rice husks in cement-based composites designed for acoustic barriers and thermal insulating layers [
117]. In this study, the authors incorporated rice husks, treated wood, and recycled rubber granules as fillers, resulting in a material with a density of approximately 1000 kg/m
3, a thermal conductivity coefficient of 0.20 W/m·K, and a bending strength of up to 3 MPa.
In another study [
118], researchers developed a cement-bonded wood–wool composite using eucalyptus (Eucalyptus camaldulensis) and poplar (Populus deltoides) fibers, with calcium chloride (CaCl
2) added as a modifying agent to enhance the material’s properties.
Further research [
119] focused on the development of low-density wood–cement particleboards for interior wall finishes. The resulting material achieved a flexural strength of up to 8 MPa and a density of 0.7 kg/m
3, making it suitable for lightweight construction applications.
A novel prefabricated wall system utilizing wood–wool cement composite panels was also developed [
120]. These panels, measuring 600 × 2400 mm with thicknesses ranging from 25 to 100 mm, were shown to significantly improve construction efficiency and performance.
The study “Modelling and optimization of the sound absorption of wood-wool cement boards” [
121] aimed to enhance the acoustic properties of wood–wool cement boards (WWCBs). WWCBs, which have been in use for nearly a century, are valued for their excellent acoustic, thermal insulation, and aesthetic properties, making them an attractive and eco-friendly option for interior decoration. The material typically has a density range of 300 to 550 kg/m
3, achieved by maintaining a wood–wool-to-binder ratio of 0.43 to 0.57 in the mix composition.
In the paper “The recycling potential of wood waste into wood-wool/cement composite” [
122], the authors explored the effective utilization of wood waste in composite materials. They concluded that wood waste could successfully replace up to 50% of the conventional materials without compromising performance.
It is also worth noting that the production of wood–cement composites generates significant amounts of fine waste containing hydrated cement paste and wood particles. Researchers P. Argalis et al. developed novel bio-based materials by repurposing waste from cement–wool board manufacturing [
123,
124]. These materials were rigorously tested for properties such as density, thermal conductivity, and compressive strength, demonstrating the potential for sustainable waste utilization in construction materials.
A summary of the advantages and disadvantages of bio-fiber and wood composites using mineral binders is presented in
Table 7.