CO
2 fracturing is known as the best solution to improve the efficiency of the CO
2 replacement of natural gas hydrates, but the effect of CO
2 thickeners on CH
4-CO
2 replacement are barely noticed. In this work, the effect
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CO
2 fracturing is known as the best solution to improve the efficiency of the CO
2 replacement of natural gas hydrates, but the effect of CO
2 thickeners on CH
4-CO
2 replacement are barely noticed. In this work, the effect of four kinds of CO
2 thickener—including DL-Lactic acid, polyvinyl acetate, ethyl trifluoroacetate and octamethyl trisiloxane—on the CH
4-CO
2 replacement in quartz sand was measured thermodynamically and kinetically. The results show that the majority of the CO
2 thickeners had no effect on the equilibria of the CH
4 and CO
2 hydrates, except for DL-Lactic acid, where the temperature depression caused by the addition of 5.5 wt% DL-Lactic acid was about 0.52 and 0.48 K for the CH
4 and CO
2 hydrates, respectively. In the kinetic measurements, the CH
4-CO
2 replacement was promoted via the addition of the CO
2 thickeners, except DL-Lactic acid. The CO
2 thickeners were suggested to strengthen the CH
4-CO
2 replacement by enhancing the gas exchange in the pore space. Octamethyl trisiloxane, which could promote CH
4 recovery and CO
2 capture at a low concentration, was suggested to be an ideal CO
2 thickener for CH
4-CO
2 replacement.
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