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Chemosensors, Volume 10, Issue 4

2022 April - 29 articles

Cover Story: The development of porphyrin-based multifunctional materials destined both to capture carbon dioxide and to monitor toxic metal ions from waters represents an actual task of sustainable research. A carboxyl-substituted A3B porphyrin was obtained and fully characterized, and a novel porphyrin-k-carrageenan composite material able to capture CO2 in ambient conditions was realized. A good performance of 6.97 mmol CO2/1 g adsorbent was confirmed. An extension of this porphyrin-k-carrageenan material’s functionality toward Mn2+ detection from polluted waters and medical samples, relying on its synergistic partnership with gold nanoparticles (AuNPs), was achieved. The plasmonic porphyrin-k-carrageenan-AuNPs material detected Mn2+ in the range of concentration from 4.56 × 10−5 M to 9.39 × 10−5 M (5–11 mg/L). View this paper
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Articles (29)

  • Article
  • Open Access
1 Citations
3,579 Views
11 Pages

Real-Time Fluorescence Imaging of His-Tag-Driven Conjugation of mCherry Proteins to Silver Nanowires

  • Martyna Jankowska,
  • Karolina Sulowska,
  • Kamil Wiwatowski,
  • Joanna Niedziółka-Jönsson and
  • Sebastian Mackowski

In this work, we aimed to apply fluorescence microscopy to image protein conjugation to Ni-NTA modified silver nanowires in real time via the His-tag attachment. First, a set of experiments was designed and performed for the mixtures of proteins and...

  • Article
  • Open Access
12 Citations
3,527 Views
15 Pages

Monitoring water quality has become a goal to prevent issues related to human health and environmental conditions. In this sense, the concentration of metal ions in water sources is screened, as these are considered persistent contaminants. In this w...

  • Article
  • Open Access
16 Citations
3,707 Views
22 Pages

UV-Activated NO2 Gas Sensing by Nanocrystalline ZnO: Mechanistic Insights from Mass Spectrometry Investigations

  • Artem Chizhov,
  • Pavel Kutukov,
  • Alexander Gulin,
  • Artyom Astafiev and
  • Marina Rumyantseva

In this work, the photostimulated processes of O2 and NO2 molecules with the surface of ZnO under UV radiation were studied by in situ mass spectrometry in the temperature range of 30–100 C. Nanocrystalline needle-like ZnO was synthesize...

  • Article
  • Open Access
10 Citations
3,214 Views
10 Pages

In recent years, the use of ion-selective membranes in the sensing and assessment of environmental contaminants has become a critical goal. Using sodium tetraphenylborate (TPB) and phosphotungstic acid (PTA) as ion-pairing agents, two sensitive and s...

  • Article
  • Open Access
2 Citations
5,284 Views
18 Pages

A novel concept was successfully evaluated for the electrochemical quantitative analysis of zinc oxide nanoparticles originally in aqueous suspension. An aliquot of the suspension was first placed on the working area of a graphite screen-printed elec...

  • Article
  • Open Access
5 Citations
2,955 Views
10 Pages

Estimation of Grain Size in Randomly Packed Granular Material Using Laser-Induced Breakdown Spectroscopy

  • Songting Li,
  • Yaju Li,
  • Xiaolong Li,
  • Liangwen Chen,
  • Dongbin Qian,
  • Shaofeng Zhang and
  • Xinwen Ma

Grain size is one of the most important physical parameters for randomly packed granular (RPG) materials. Its estimation, especially in situ, plays a key role in many natural and industrial processes. Here, the application of laser-induced breakdown...

  • Article
  • Open Access
7 Citations
4,083 Views
15 Pages

Plasmin protease plays an important role in many processes in living systems, including milk. Monitoring plasmin activity is important for control of the nutritional quality of milk and other dairy products. We designed a biosensor to detect the prot...

  • Article
  • Open Access
2 Citations
3,137 Views
13 Pages

The suspension array technology (SAT) is promising for high-sensitivity multiplexed analysis of tumor markers. Barcodes as the core elements of SAT, can generate encoding fluorescence signals (EFS) and detection fluorescence signals (DFS) in the corr...

  • Article
  • Open Access
2 Citations
3,342 Views
16 Pages

Microfluidic-Enabled Multi-Cell-Densities-Patterning and Culture Device for Characterization of Yeast Strains’ Growth Rates under Mating Pheromone

  • Jing Zhang,
  • Wenting Shen,
  • Zhiyuan Cai,
  • Kaiyue Chen,
  • Qi Ouyang,
  • Ping Wei,
  • Wei Yang and
  • Chunxiong Luo

Yeast studies usually focus on exploring diversity in terms of a specific trait (such as growth rate, antibiotic resistance, or fertility) among extensive strains. Microfluidic chips improve these biological studies in a manner of high throughput and...

  • Article
  • Open Access
15 Citations
4,485 Views
13 Pages

Mercury ion is one of the most widespread heavy metal contaminants which can accumulate in the body through multiple channels, posing a detrimental impact on human health. We demonstrate a simple and low-cost method for the detection of Hg2+ assisted...

  • Article
  • Open Access
5 Citations
3,148 Views
10 Pages

Simple and Fast Two-Step Fully Automated Methodology for the Online Speciation of Inorganic Antimony Coupled to ICP-MS

  • Lindomar A. Portugal,
  • Edwin Palacio,
  • Víctor Cerdà,
  • Joao H. Santos-Neto,
  • Laura Ferrer and
  • Sergio L. C. Ferreira

A very simple, fast and non-chromatographic methodology for inorganic antimony speciation based on Multisyringe Flow Injection Analysis (MSFIA) employing online hydride generation (HG) ICP-MS was developed. The fully automated analysis is performed i...

  • Article
  • Open Access
19 Citations
4,400 Views
9 Pages

Novel, sensitive, selective, efficient and portable electrochemical biosensors are needed to detect residual contaminants of the pesticide 1-naphthyl methylcarbamate (carbaryl) in the environment, food, and essential biological fluids. In this work,...

  • Article
  • Open Access
6 Citations
3,553 Views
16 Pages

Design, Elaboration, and Characterization of an Immunosensor for the Detection of a Fungal Toxin in Foodstuff Analyses

  • Zeineb Ben Abdallah,
  • Halim Sghaier,
  • Ibtissem Gammoudi,
  • Fabien Moroté,
  • Sébastien Cassagnère,
  • Lena Romo,
  • Laure Béven,
  • Christine Grauby-Heywang and
  • Touria Cohen-Bouhacina

This work describes the complete elaboration of an immunosensor for the detection of the fungal B1 aflatoxin (AFB1). In a first step, a system made of three screen-printed electrodes (SPEs) was manufactured using gold, silver/silver chloride, and car...

  • Review
  • Open Access
27 Citations
7,765 Views
56 Pages

Plasmonic Nanomaterials for Colorimetric Biosensing: A Review

  • Adriano Acunzo,
  • Emanuela Scardapane,
  • Maria De Luca,
  • Daniele Marra,
  • Raffaele Velotta and
  • Antonio Minopoli

In the last few decades, plasmonic colorimetric biosensors raised increasing interest in bioanalytics thanks to their cost-effectiveness, responsiveness, and simplicity as compared to conventional laboratory techniques. Potential high-throughput scre...

  • Article
  • Open Access
12 Citations
3,833 Views
17 Pages

In2O3 Based Hybrid Materials: Interplay between Microstructure, Photoelectrical and Light Activated NO2 Sensor Properties

  • Abulkosim Nasriddinov,
  • Sergey Tokarev,
  • Olga Fedorova,
  • Ivan Bozhev and
  • Marina Rumyantseva

In this work, organic–inorganic hybrids based on nanocrystalline indium oxide and ruthenium (II) heteroleptic complexes were used as sensitive materials for room temperature light-activated NO2 detection. In2O3 was obtained by chemical precipit...

  • Article
  • Open Access
9 Citations
3,951 Views
14 Pages

Excellent Cooperation between Carboxyl-Substituted Porphyrins, k-Carrageenan and AuNPs for Extended Application in CO2 Capture and Manganese Ion Detection

  • Camelia Epuran,
  • Ion Fratilescu,
  • Ana-Maria Macsim,
  • Anca Lascu,
  • Catalin Ianasi,
  • Mihaela Birdeanu and
  • Eugenia Fagadar-Cosma

Significant tasks of the presented research are the development of multifunctional materials capable both to detect/capture carbon dioxide and to monitor toxic metal ions from waters, thus contributing to maintaining a sustainable and clean environme...

  • Article
  • Open Access
6 Citations
4,488 Views
11 Pages

Microbiological Risk Assessment of Ready-to-Eat Leafy Green Salads via a Novel Electrochemical Sensor

  • Simone Grasso,
  • Maria Vittoria Di Loreto,
  • Alyexandra Arienzo,
  • Valentina Gallo,
  • Anna Sabatini,
  • Alessandro Zompanti,
  • Giorgio Pennazza,
  • Laura De Gara,
  • Giovanni Antonini and
  • Marco Santonico

Nowadays, the growing interest in a healthy lifestyle, to compensate for modern stressful habits, has led to an increased demand for wholesome products with quick preparation times. Fresh and ready-to-eat leafy green vegetables are generally perceive...

  • Article
  • Open Access
14 Citations
3,957 Views
15 Pages

We have designed a new ternary structure to enhance the sensing properties of WS2 nanosheet (NS)-based gas sensors at room temperature (RT) in self-heating mode. SnO2 nanowires (NWs, 10–30 wt%) were added to WS2 NSs and then Au nanoparticles (N...

  • Article
  • Open Access
3 Citations
4,682 Views
27 Pages

Development of a Portable and Modular Gas Generator: Application to Formaldehyde Analysis

  • Anaïs Becker,
  • Nathaly Lohmann,
  • Christophe A. Serra and
  • Stéphane Le Calvé

This work aims at developing and validating under laboratory-controlled conditions a gas mixture generation device designed for easy on-site or laboratory calibration of analytical instruments dedicated to air monitoring, such as analysers or sensors...

  • Article
  • Open Access
2 Citations
2,753 Views
14 Pages

Photonics of Viburnum opulus L. Extracts in Microemulsions with Oxygen and Gold Nanoparticles

  • Anna Tcibulnikova,
  • Evgeniia Zemliakova,
  • Dmitry Artamonov,
  • Vasily Slezhkin,
  • Liubov Skrypnik,
  • Ilia Samusev,
  • Andrey Zyubin,
  • Artemy Khankaev,
  • Valery Bryukhanov and
  • Ivan Lyatun

In this paper, the optical properties of viburnum extract flavonoids in the visible region of the spectrum were investigated and their use as a potential photosensitizer of singlet oxygen for photodynamic therapy was evaluated. The presence of long-l...

  • Article
  • Open Access
21 Citations
3,814 Views
12 Pages

Spectroscopic Study of Phytosynthesized Ag Nanoparticles and Their Activity as SERS Substrate

  • Volodymyr Dzhagan,
  • Oleksandr Smirnov,
  • Mariia Kovalenko,
  • Nazar Mazur,
  • Oleksandr Hreshchuk,
  • Nataliya Taran,
  • Svitlana Plokhovska,
  • Yaroslav Pirko,
  • Alla Yemets and
  • Dietrich R. T. Zahn
  • + 1 author

The affordable and scalable synthesis of noble metal nanoparticles that are biocompatible without additional functionalization steps has been a growing field of research, stimulated by numerous prospective applications of these NPs. In the case of ph...

  • Review
  • Open Access
21 Citations
5,666 Views
19 Pages

The Role of Surface Enhanced Raman Scattering for Therapeutic Drug Monitoring of Antimicrobial Agents

  • Stefano Fornasaro,
  • Dana Cialla-May,
  • Valter Sergo and
  • Alois Bonifacio

The rapid quantification of antimicrobial agents is important for therapeutic drug monitoring (TDM), enabling personalized dosing schemes in critically ill patients. Highly sophisticated TDM technology is becoming available, but its implementation in...

  • Article
  • Open Access
13 Citations
3,812 Views
12 Pages

Design and Characterization of a Microwave Transducer for Gas Sensing Applications

  • Giovanni Gugliandolo,
  • Krishna Naishadham,
  • Giovanni Crupi and
  • Nicola Donato

Gas sensors have wide applications in several fields, spanning diverse areas such as environmental monitoring, healthcare, defense, and the evaluation of personal and occupational exposure to hazardous chemicals. Different typologies of gas sensors h...

  • Communication
  • Open Access
3 Citations
3,627 Views
15 Pages

Comparative Analysis of Derivative Parameters of Chemoresistive Sensor Signals for Gas Concentration Estimation

  • Nina K. Plugotarenko,
  • Tatiana N. Myasoedova,
  • Sergey P. Novikov and
  • Tatiana S. Mikhailova

Signals from resistive gas sensors based on zirconium dioxide and silicon–carbon films have been extensively investigated to estimate gas concentration. In this study, the change in the normalized resistance of the sensor’s response under...

  • Article
  • Open Access
31 Citations
4,299 Views
17 Pages

Grape Cultivar Identification and Classification by Machine Olfaction Analysis of Leaf Volatiles

  • Ali Khorramifar,
  • Hamed Karami,
  • Alphus Dan Wilson,
  • Amir Hosein Afkari Sayyah,
  • Anastasiia Shuba and
  • Jesús Lozano

Development of electronic technologies for precise identification of fruit crop cultivars in agricultural production provides an effective means for assuring product quality and authentication. The capabilities of discriminating between grape (Vitis ...

  • Article
  • Open Access
14 Citations
3,529 Views
31 Pages

This study aims to develop a spatial dual-sensor module for acquiring visible and near-infrared images in the same space without time shifting and to synthesize the captured images. The proposed method synthesizes visible and near-infrared images usi...

  • Review
  • Open Access
20 Citations
7,193 Views
17 Pages

Accurate and timely detection of infectious pathogens is urgently needed for disease treatment and control of possible outbreaks worldwide. Conventional methods for pathogen detection are usually time-consuming and labor-intensive. Novel strategies f...

  • Article
  • Open Access
6 Citations
3,799 Views
11 Pages

This study proposes a bidirectional chemical sensor platform using ambipolar double-gate ion-sensitive field-effect transistors (ISFET) with microwave-assisted Ni-silicide Schottky-barrier (SB) source and drain (S/D) on a fully depleted silicon-on-in...

  • Article
  • Open Access
11 Citations
3,996 Views
13 Pages

Perfluoroisobutyronitrile (C4F7N), an environment-friendly insulating gas, has excellent insulating properties and has the potential to be used in gas-insulated equipment when mixed with CO2. Selecting suitable adsorption materials to adsorb the deco...

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Chemosensors - ISSN 2227-9040