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Batteries, Volume 7, Issue 2

2021 June - 21 articles

Cover Story: This study presents a method for deriving the distribution of the relaxation times (DRT) of lithium-ion batteries by evaluating the relaxation voltage after a current pulse. The method was experimentally validated by using both electrochemical impedance spectroscopy (EIS) and the proposed pulse evaluation to determine the DRT of automotive pouch-cells. DRT by pulse evaluation provided improved resolution of processes with large time constants, allowing identification of low-frequency impedance changes and correlated degradation mechanisms. The novel approach to battery diagnosis requires only relaxation periods and no additional equipment for EIS and is therefore applicable in battery management systems. View this paper
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Articles (21)

  • Article
  • Open Access
10 Citations
7,085 Views
19 Pages

Absolute Local Quantification of Li as Function of State-of-Charge in All-Solid-State Li Batteries via 2D MeV Ion-Beam Analysis

  • Sören Möller,
  • Takahiro Satoh,
  • Yasuyuki Ishii,
  • Britta Teßmer,
  • Rayan Guerdelli,
  • Tomihiro Kamiya,
  • Kazuhisa Fujita,
  • Kota Suzuki,
  • Yoshiaki Kato and
  • Martin Finsterbusch
  • + 2 authors

Direct observation of the lithiation and de-lithiation in lithium batteries on the component and microstructural scale is still difficult. This work presents recent advances in MeV ion-beam analysis, enabling quantitative contact-free analysis of the...

  • Article
  • Open Access
19 Citations
6,233 Views
18 Pages

Comparison of Aqueous- and Non-Aqueous-Based Binder Polymers and the Mixing Ratios for Zn//MnO2 Batteries with Mildly Acidic Aqueous Electrolytes

  • Oliver Fitz,
  • Stefan Ingenhoven,
  • Christian Bischoff,
  • Harald Gentischer,
  • Kai Peter Birke,
  • Dragos Saracsan and
  • Daniel Biro

Considering the literature for aqueous rechargeable Zn//MnO2 batteries with acidic electrolytes using the doctor blade coating of the active material (AM), carbon black (CB), and binder polymer (BP) for the positive electrode fabrication, different b...

  • Article
  • Open Access
10 Citations
5,561 Views
17 Pages

The safety requirements in vehicles continuously increase due to more automated functions using electronic components. Besides the reliability of the components themselves, a reliable power supply is crucial for a safe overall system. Different archi...

  • Article
  • Open Access
39 Citations
14,032 Views
14 Pages

A Comparison of Lithium-Ion Cell Performance across Three Different Cell Formats

  • Grace Bridgewater,
  • Matthew J. Capener,
  • James Brandon,
  • Michael J. Lain,
  • Mark Copley and
  • Emma Kendrick

To investigate the influence of cell formats during a cell development programme, lithium-ion cells have been prepared in three different formats. Coin cells, single layer pouch cells, and stacked pouch cells gave a range of scales of almost three or...

  • Article
  • Open Access
13 Citations
8,301 Views
20 Pages

Methodology for the Optimisation of Battery Hybrid Energy Storage Systems for Mass and Volume Using a Power-To-Energy Ratio Analysis

  • Gregory Tzermias,
  • Sam Akehurst,
  • Richard Burke,
  • Chris Brace,
  • Sunoj George,
  • Johan Bernards and
  • Christopher Smith

Increasingly stringent emission regulations and environmental concerns have propelled the development of electrification technology in the transport industry. Yet, the greatest hurdle to developing fully electric vehicles is electrochemical energy st...

  • Article
  • Open Access
43 Citations
14,185 Views
20 Pages

The distribution of relaxation times (DRT) analysis of impedance spectra is a proven method to determine the number of occurring polarization processes in lithium-ion batteries (LIBs), their polarization contributions and characteristic time constant...

  • Article
  • Open Access
4 Citations
3,489 Views
27 Pages

A unified evaluation framework for stochastic tools is developed in this paper. Firstly, we provide a set of already existing quantitative and qualitative metrics that rate the relevant aspects of the performance of a stochastic prognosis algorithm....

  • Article
  • Open Access
13 Citations
6,475 Views
15 Pages

The Influence of Li4Ti5O12 Preparation Method on Lithium-Ion Capacitor Performance

  • Taofeek Akintola,
  • Annadanesh Shellikeri,
  • Tawakalt Akintola and
  • Jim P. Zheng

In this study, the importance of the preparation technique of Li4Ti5O12 (LTO) anode on its performance in a lithium-ion capacitor (LIC) application was investigated. These desired characteristics include energy density, rate capability, and cycle lif...

  • Article
  • Open Access
8 Citations
12,875 Views
11 Pages

Factors Influencing the Formation of Sodium Hydroxide by an Ion Exchange Membrane Cell

  • Jimmy Aurelio Rosales-Huamani,
  • Juan Taumaturgo Medina-Collana,
  • Zoila Margarita Diaz-Cordova and
  • Jorge Alberto Montaño-Pisfil

The present study aimed to evaluate the factors that influence the formation of sodium hydroxide (NaOH) by means of an electrolytic cell with ion exchange membranes. To achieve this experiment, the NaOH production cell had to be designed and built in...

  • Article
  • Open Access
21 Citations
8,693 Views
15 Pages

Electrical Characterization of Li-Ion Battery Modules for Second-Life Applications

  • Daniel Kehl,
  • Torben Jennert,
  • Frank Lienesch and
  • Michael Kurrat

The reuse and repurposing of lithium-ion batteries for transportation in stationary energy systems improve the economic value of batteries. A precise suitability test at the beginning of the second life is therefore necessary. Common methods such as...

  • Article
  • Open Access
42 Citations
10,468 Views
20 Pages

Novel intelligent battery systems are gaining importance with functional hardware on the cell level. Cell-level hardware allows for advanced battery state monitoring and thermal management, but also leads to additional thermal interactions. In this w...

  • Article
  • Open Access
20 Citations
7,387 Views
22 Pages

A low-pressure drop stack design with minimal shunt losses was explored for vanadium redox flow batteries, which, due to their low energy density, are used invariably in stationary applications. Three kilowatt-scale stacks, having cell sizes in the r...

  • Article
  • Open Access
30 Citations
6,258 Views
13 Pages

Global Warming Potential of a New Waterjet-Based Recycling Process for Cathode Materials of Lithium-Ion Batteries

  • Leonard Kurz,
  • Mojtaba Faryadras,
  • Ines Klugius,
  • Frederik Reichert,
  • Andreas Scheibe,
  • Matthias Schmidt and
  • Ralf Wörner

Due to the increasing demand for battery electric vehicles (BEVs), the need for vehicle battery raw materials is increasing. The traction battery (TB) of an electric vehicle, usually a lithium-ion battery (LIB), represents the largest share of a BEV’...

  • Article
  • Open Access
49 Citations
26,527 Views
23 Pages

The lifetime of the battery significantly influences the acceptance of electric vehicles. Calendar aging contributes to the limited operating lifetime of lithium-ion batteries. Therefore, its consideration in addition to cyclical aging is essential t...

  • Article
  • Open Access
10 Citations
5,746 Views
27 Pages

The temperature and the temperature gradient within the battery pack of an electric vehicle have a strong effect on the life time of the battery cells. In the case of automotive applications, a battery thermal management (BTM) system is required to m...

  • Article
  • Open Access
23 Citations
8,051 Views
17 Pages

Although lithium-sulfur (Li-S) batteries are one of the promising candidates for next-generation energy storage, their practical implementation is limited by rapid capacity fading due to lithium polysulfide (LiPSs) formation and the low electronic co...

  • Article
  • Open Access
77 Citations
21,587 Views
26 Pages

Early Detection of Failing Automotive Batteries Using Gas Sensors

  • Christiane Essl,
  • Lauritz Seifert,
  • Michael Rabe and
  • Anton Fuchs

Safety for automotive lithium-ion battery (LIB) applications is of crucial importance, especially for electric vehicle applications using batteries with high capacity and high energy density. In case of a defect inside or outside the cell, serious sa...

  • Article
  • Open Access
3 Citations
4,839 Views
16 Pages

During the operation of the negative electrode, some critical processes take place, which are limiting factors for the operation of lead–acid batteries. To improve the efficiency of the negative active material and minimize these processes, external...

  • Article
  • Open Access
39 Citations
10,189 Views
19 Pages

Lithium-ion batteries (LIBs) are a dominant state-of-the-art energy storage system and have importance in the automotive sector. Still, LIBs suffer from aging effects and serious hazards from failing batteries are possible. These failures can lead to...

  • Article
  • Open Access
25 Citations
7,620 Views
18 Pages

Float currents are steady-state self-discharge currents after a transient phase—caused by anode overhang, polarization, etc.—is accomplished. The float current is measured in this study with a standard test bench for five 18650 cells (Samsung 25R) at...

  • Article
  • Open Access
16 Citations
7,180 Views
8 Pages

Determination of Diffusion Coefficients of Lithium in Solid Electrolyte LiPON

  • Alexander Rudy,
  • Alexander Mironenko,
  • Victor Naumov,
  • Alena Novozhilova,
  • Alexander Skundin and
  • Ivan Fedorov

A structural model of LiPON solid electrolyte, containing elements that simulate drift conductivity, diffusion conductivity, and leakage current was proposed. The dependence of the impedance of the structural model on frequency was calculated, and th...

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Batteries - ISSN 2313-0105