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Batteries, Volume 9, Issue 5

May 2023 - 49 articles

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Cover Story: This work reviews the suitability of polymorphic Li-Nb-O-based compounds for LIB operation. Additional experimental results obtained from neutron scattering and electrochemical experiments on amorphous LiNbO3 films are the focus of the present work. Neutron reflectometry reveals a higher porosity in ion-beam sputtered amorphous LiNbO3 films (22% free volume) than in other metal oxide films such as amorphous LiAlO2 (8% free volume). The films allow long-term cycling even for fast cycling with rates of 240C possessing reversible capacities as high as 600 mAhg−1. Electrochemical impedance spectroscopy (EIS) shows that the film atomic network is stable during cycling. The results anticipate that amorphous LiNbO3 layers also contribute to the capacity of positive (LiNixMnyCozO2, NMC) and negative LIB electrode materials such as carbon and silicon. View this paper

Articles (49)

  • Article
  • Open Access
4 Citations
2,517 Views
12 Pages

Readily Accessible M-Ferrocenyl-Phenyl Sulfonate as Novel Cathodic Electrolyte for Aqueous Organic Redox Flow Batteries

  • Dawei Fang,
  • Junzhi Zheng,
  • Xi Li,
  • Diandian Wang,
  • Yuxuan Yang,
  • Zhuling Liu,
  • Zongren Song and
  • Minghua Jing

Ferrocene derivatives are amongst the most promising electroactive organic electrolytes. The bottleneck problems of their application in aqueous redox flow batteries are their poor solubility and lower potential as well as the complexity of the modif...

  • Review
  • Open Access
16 Citations
5,874 Views
16 Pages

Recent Progress in Electrolyte Additives for Highly Reversible Zinc Anodes in Aqueous Zinc Batteries

  • Qibin Shen,
  • Yuanduo Wang,
  • Guanjie Han,
  • Xin Li,
  • Tao Yuan,
  • Hao Sun,
  • Yinyan Gong and
  • Taiqiang Chen

Aqueous zinc batteries (AZBs) are one of the most promising large-scale energy storage devices by virtue of their high specific capacity, high degree of safety, non-toxicity, and significant economic benefits. However, Zn anodes in aqueous electrolyt...

  • Article
  • Open Access
8 Citations
3,342 Views
11 Pages

Prefabrication of a Lithium Fluoride Interfacial Layer to Enable Dendrite-Free Lithium Deposition

  • Jie Ni,
  • Yike Lei,
  • Yongkang Han,
  • Yingchuan Zhang,
  • Cunman Zhang,
  • Zhen Geng and
  • Qiangfeng Xiao

Lithium metal is one of the most attractive anode materials for rechargeable batteries. However, its high reactivity with electrolytes, huge volume change, and dendrite growth upon charge or discharge lead to a low CE and the cycle instability of bat...

  • Article
  • Open Access
2,719 Views
16 Pages

A Polyacrylonitrile Shutdown Film for Prevention of Thermal Runaway in Lithium-Ion Cells

  • Jonathan Peter Charles Allen,
  • Marcin Mierzwa,
  • Denis Kramer,
  • Nuria Garcia-Araez and
  • Andrew L. Hector

The electrodeposition of a polymer (polyacrylonitrile, PAN) is used to reduce the risk of thermal runaway in lithium-ion batteries, which is the most important cause of battery accidents and fires. PAN was electrodeposited on a graphite battery elect...

  • Review
  • Open Access
15 Citations
4,965 Views
19 Pages

Integration of Flexible Supercapacitors with Triboelectric Nanogenerators: A Review

  • Yin Lu,
  • Tong Wu,
  • Zimeng Ma,
  • Yajun Mi,
  • Zequan Zhao,
  • Fei Liu,
  • Xia Cao and
  • Ning Wang

The ever-growing interest in wearable electronic devices has unleashed a strong demand for sustainable and flexible power sources that are represented by the combination of flexible energy harvesting with storage devices/technologies. Triboelectric n...

  • Article
  • Open Access
15 Citations
3,754 Views
15 Pages

Lithium-ion (Li-ion) batteries are considered to be one of the ideal energy sources for automotive and electronic products due to their size, high levels of charge, higher energy density, and low maintenance. When Li-ion batteries are used in harsh e...

  • Article
  • Open Access
16 Citations
4,063 Views
12 Pages

Mediating Lithium Plating/Stripping by Constructing 3D Au@Cu Pentagonal Pyramid Array

  • Yaohua Liang,
  • Wei Ding,
  • Bin Yao,
  • Fan Zheng,
  • Alevtina Smirnova and
  • Zhengrong Gu

Lithium (Li) metal is perceived as the “holy grail” of anodes for secondary batteries due to its innate merits. Regrettably, the commercial application of Li metal anodes (LMAs) has been hampered by problems derived from the uncontrollabl...

  • Article
  • Open Access
2 Citations
3,000 Views
17 Pages

Model-Based Analysis and Optimization of Acidic Tin–Iron Flow Batteries

  • Fuyu Chen,
  • Ying Wang,
  • Ying Shi,
  • Hui Chen,
  • Xinzhi Ma and
  • Qinfang Zhang

Acidic tin–iron flow batteries (TIFBs) employing Sn/Sn2+ and Fe2+/Fe3+ as active materials are regarded as promising energy storage devices due to their superior low capital cost, long lifecycle, and high system reliability. In this paper, the...

  • Article
  • Open Access
2 Citations
3,091 Views
16 Pages

Silicon has gained considerable attention as an anode material in lithium-ion batteries due to its high theoretical capacity. However, the significant volume changes that occur during lithiation/delithiation processes often result in poor cycling sta...

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Batteries - ISSN 2313-0105Creative Common CC BY license